SU434637A3 - INSECTOACAREMATOCID - Google Patents
INSECTOACAREMATOCIDInfo
- Publication number
- SU434637A3 SU434637A3 SU1467354A SU1467354A SU434637A3 SU 434637 A3 SU434637 A3 SU 434637A3 SU 1467354 A SU1467354 A SU 1467354A SU 1467354 A SU1467354 A SU 1467354A SU 434637 A3 SU434637 A3 SU 434637A3
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- insectoacarematocid
- thiophosphoric acid
- insecticide
- warm
- alkyl
- Prior art date
Links
- 150000001875 compounds Chemical class 0.000 description 4
- 241001143309 Acanthoscelides obtectus Species 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- 230000000895 acaricidal effect Effects 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 230000000749 insecticidal effect Effects 0.000 description 2
- 239000002917 insecticide Substances 0.000 description 2
- 230000001069 nematicidal effect Effects 0.000 description 2
- 150000003579 thiophosphoric acid derivatives Chemical class 0.000 description 2
- 229910001369 Brass Inorganic materials 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical group [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- RYYWUUFWQRZTIU-UHFFFAOYSA-N Thiophosphoric acid Chemical compound OP(O)(S)=O RYYWUUFWQRZTIU-UHFFFAOYSA-N 0.000 description 1
- 239000000642 acaricide Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000003282 alkyl amino group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Chemical group 0.000 description 1
- 239000000460 chlorine Chemical group 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 231100000225 lethality Toxicity 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 239000005645 nematicide Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- -1 thiophosphoric acid ester amide ester Chemical class 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000925 very toxic Toxicity 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
- C07F9/165—Esters of thiophosphoric acids
- C07F9/20—Esters of thiophosphoric acids containing P-halide groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/22—Amides of acids of phosphorus
- C07F9/24—Esteramides
- C07F9/2404—Esteramides the ester moiety containing a substituent or a structure which is considered as characteristic
- C07F9/2412—Esteramides the ester moiety containing a substituent or a structure which is considered as characteristic of unsaturated acyclic alcohols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/22—Amides of acids of phosphorus
- C07F9/26—Amides of acids of phosphorus containing P-halide groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
1one
Изобретение относитс к применению производных тиофосфорной кислоты в качестве инсектицида, акарицида и нематоцида.This invention relates to the use of thiophosphoric acid derivatives as an insecticide, acaricide, and nematocide.
Известно использование в качестве инсектицида производного тиофосфорной кислоты тионофосдринаIt is known to use thionophosphorin thiophosphoric acid derivative as an insecticide.
(СНзО).,Р-0-С СН-СООСНз(CH3)., P-0-C CH-SOOCH3
сн,sn,
Однако это соединение очень токсично дл теплокровных. Замена метоксигруппы на алкиламиногруппу снижает его токсичность дл теплокровных животных.However, this compound is very toxic to warm-blooded animals. Replacing the methoxy group with an alkylamino group reduces its toxicity to warm-blooded animals.
Предлагаемое изобретение предусматривает использование в качестве инсектоакаронематоцида эфироамида тиофосфорной кислоты общей формулыThe present invention provides for the use of thiophosphoric acid ester amide ester as an insecticoacarone matic acid
Е.ОхИ/XE.OhI / X
Р-0-С С R NH-i COOB,,Р-0-С С R NH-i COOB ,,
Нт,Nt,
где Ri и R2 - одинаковые или алкилы Ci-€4; Rs - алкил Ci-GS; X - водород, хлор или бром.where Ri and R2 are identical or alkyl Ci € 4; Rs is alkyl Ci-GS; X is hydrogen, chlorine or bromine.
Данное соединение может быть получено, например, взаимодействием эфиродихлорангидрида тиофосфорной кислотыThis compound can be obtained, for example, by reacting thiophosphoric acid ether dichloride.
5five
СК il/XSC il / X
Р-0-С -С С1I СООКт.Р-0-С -С С1I СООКт.
СИ-.Si-
со спиртом R, ОН, с последующей обработкой реакционной смеси амином R2NH2, где Ri, R2, Ra и X имеют выщеуказанные значени . Формы применени соединений обычные.with alcohol R, OH, followed by treatment of the reaction mixture with an amine R2NH2, where Ri, R2, Ra and X are as defined above. Forms of the use of compounds are common.
Ниже приведены примеры, иллюстрирующие инсектицидную, акарицидную и нематоцидную активность соединений согласно предлагаемому изобретению.Below are examples illustrating the insecticidal, acaricidal and nematocidal activity of the compounds according to the invention.
Инсектицидное действие против Bruchidius obtectus (зерновка фасолева ), контактное действие. Чашки Петри диаметром в 7 см опрыскивают от 0,1 до 0,2 мл эмульсии, содержащей 0,0125% действующего начала общей формулы. После сущки в течение 4 час помещают в каждую чащку 10 Bruchidius-Imagines и покрывают ее крышкой в виде решетки из латунной проволоки с мелкими отверсти ми . Насекомых оставл ют там при комнатной температуре и не дают им корма. 48 час спуст определ ют степень летальиости . Результаты приведены в табл. 1.Insecticidal action against Bruchidius obtectus (bean weevil), contact action. Petri dishes 7 cm in diameter are sprayed with 0.1 to 0.2 ml of an emulsion containing 0.0125% of the active principle of the general formula. After this, the Bruchidius-Imagines 10 are placed in each thicket for 4 hours and covered with a lid in the form of a lattice of brass wire with small holes. The insects are left there at room temperature and do not give them food. 48 hours later, the degree of lethality is determined. The results are shown in Table. one.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH1102869A CH526585A (en) | 1969-07-18 | 1969-07-18 | Anti parasitic thio phosphoric acid imide esters |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU434637A3 true SU434637A3 (en) | 1974-06-30 |
Family
ID=4369307
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU1703109A SU497779A3 (en) | 1969-07-18 | 1970-07-16 | Method for preparing thiophosphoric ester amides |
| SU1467354A SU434637A3 (en) | 1969-07-18 | 1970-07-16 | INSECTOACAREMATOCID |
| SU1703106A SU539531A3 (en) | 1969-07-18 | 1971-10-04 | Method for preparing thiophosphoric ester amides |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU1703109A SU497779A3 (en) | 1969-07-18 | 1970-07-16 | Method for preparing thiophosphoric ester amides |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU1703106A SU539531A3 (en) | 1969-07-18 | 1971-10-04 | Method for preparing thiophosphoric ester amides |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS57131707A (en) |
| AT (1) | AT315199B (en) |
| CH (3) | CH526585A (en) |
| CS (1) | CS199225B2 (en) |
| PL (1) | PL81290B1 (en) |
| SU (3) | SU497779A3 (en) |
| TR (1) | TR17496A (en) |
| ZA (1) | ZA704936B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8514853D0 (en) * | 1985-06-12 | 1985-07-17 | Sandoz Ltd | Controlling termites |
| JPH073627U (en) * | 1992-07-07 | 1995-01-20 | 幸雄 中濱 | Electric lift for medical beds |
-
1969
- 1969-07-18 CH CH1102869A patent/CH526585A/en not_active IP Right Cessation
- 1969-07-18 CH CH1564371A patent/CH526587A/en not_active IP Right Cessation
- 1969-07-18 CH CH1564271A patent/CH526586A/en not_active IP Right Cessation
-
1970
- 1970-07-16 SU SU1703109A patent/SU497779A3/en active
- 1970-07-16 CS CS705023A patent/CS199225B2/en unknown
- 1970-07-16 PL PL1970142106A patent/PL81290B1/pl unknown
- 1970-07-16 SU SU1467354A patent/SU434637A3/en active
- 1970-07-16 TR TR17496A patent/TR17496A/en unknown
- 1970-07-17 ZA ZA704936A patent/ZA704936B/en unknown
- 1970-07-17 AT AT654170A patent/AT315199B/en not_active IP Right Cessation
-
1971
- 1971-10-04 SU SU1703106A patent/SU539531A3/en active
-
1979
- 1979-09-17 JP JP54119986A patent/JPS57131707A/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| CH526585A (en) | 1972-08-15 |
| SU497779A3 (en) | 1975-12-30 |
| PL81290B1 (en) | 1975-08-30 |
| TR17496A (en) | 1975-07-23 |
| CH526586A (en) | 1972-08-15 |
| CH526587A (en) | 1972-08-15 |
| CS199225B2 (en) | 1980-07-31 |
| AT315199B (en) | 1974-05-10 |
| ZA704936B (en) | 1972-02-23 |
| SU539531A3 (en) | 1976-12-15 |
| JPS57131707A (en) | 1982-08-14 |
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