SU30151A1 - The method of obtaining oxidized organic compounds of metals - Google Patents
The method of obtaining oxidized organic compounds of metalsInfo
- Publication number
- SU30151A1 SU30151A1 SU57195A SU57195A SU30151A1 SU 30151 A1 SU30151 A1 SU 30151A1 SU 57195 A SU57195 A SU 57195A SU 57195 A SU57195 A SU 57195A SU 30151 A1 SU30151 A1 SU 30151A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- metals
- organic compounds
- oxidized organic
- obtaining oxidized
- water
- Prior art date
Links
- 229910052751 metal Inorganic materials 0.000 title description 6
- 239000002184 metal Substances 0.000 title description 6
- 150000002739 metals Chemical class 0.000 title description 5
- 238000000034 method Methods 0.000 title description 5
- 150000002894 organic compounds Chemical class 0.000 title description 4
- 150000003839 salts Chemical class 0.000 description 9
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 229910052787 antimony Inorganic materials 0.000 description 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 150000002736 metal compounds Chemical class 0.000 description 2
- 229910052752 metalloid Inorganic materials 0.000 description 2
- 150000002738 metalloids Chemical class 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- FAWGZAFXDJGWBB-UHFFFAOYSA-N antimony(3+) Chemical compound [Sb+3] FAWGZAFXDJGWBB-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000002895 emetic Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 150000004680 hydrogen peroxides Chemical class 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 150000001261 hydroxy acids Chemical class 0.000 description 1
- 150000004972 metal peroxides Chemical class 0.000 description 1
- 210000003097 mucus Anatomy 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000000176 sodium gluconate Substances 0.000 description 1
- 229940005574 sodium gluconate Drugs 0.000 description 1
- 235000012207 sodium gluconate Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- YPMOSINXXHVZIL-UHFFFAOYSA-N sulfanylideneantimony Chemical compound [Sb]=S YPMOSINXXHVZIL-UHFFFAOYSA-N 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 239000004552 water soluble powder Substances 0.000 description 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
Изобретение касаетс способа получени окисленных органических соединений металлов.The invention relates to a process for the preparation of oxidized organic metal compounds.
В советских патентах №№ 15609 и 15611 описаны способы получени растворимых соединений металлов и металлоидов с органическими соединени ми .Soviet patents Nos. 15609 and 15611 describe methods for the preparation of soluble metal compounds and metalloids with organic compounds.
Предлагаемый способ состоит в том, что дл получени окисленных органических соединений металлов обрабатывают комплексные соли металлов оксикарбоновых кислот алифатического р да перекис ми водорода или металлов, или кисл$)родом.The proposed method consists in processing complex metal salts of hydroxy carboxylic acids of aliphatic row with hydrogen peroxides or metals, or acid, to obtain oxidized organic compounds of metals.
Пример 1. 20 Z рвотного камн раствор ют при нагревании в 50 куб. см воды и к ним прибавл ют избыточное количество раствора перекиси водорода. После некоторого сто ни нейтрализуют разбавленным раствором едкого кали, фильтруют и осаждают фильтрат вливанием в метиловый спирт. Получают образовавшуюс комплексную соль в виде белого, легко растворимого в водеExample 1. 20 Z emetic stones are dissolved by heating in 50 cubic meters. cm of water and an excess amount of hydrogen peroxide solution is added to them. After some standing, it is neutralized with a dilute solution of potassium hydroxide, filtered, and the filtrate is precipitated by pouring into methyl alcohol. The resulting complex salt is obtained as a white, easily soluble in water.
(295)(295)
порошка. Из подкисленного раствора сероводородом осаждаетс серниста сурьма.powder. Antimony sulfide is precipitated from the acidified solution by hydrogen sulfide.
Пример 2. 20 t олов нно-виннокислого камн раствор ют в воде и приливают избыток перекиси водорода. Нейтрализуют разбавленным едким кали и выпаривают лучше всего под вакуумом досуха. Получают комплексную соль четырехвалентного олова в виде бесцветного порошка, раствор ющегос в воде при нагревании.Example 2. 20 t of a tin-tartaric stone is dissolved in water and excess hydrogen peroxide is added. Neutralized with dilute caustic potassium and evaporated best under vacuum to dryness. The tetravalent tin complex salt is obtained as a colorless powder that dissolves in water when heated.
Аналогичным способом могут быть подвергнуты окислению комплексные соли других металлов и металлоидов с винной кислотой или другими оксикислотами алифатического р да, как молочна , лимонна , слизева кислоты, при чем дл образовани солей могут быть применены и другие основани , как напр,, азотсодержащие .In a similar way, complex salts of other metals and metalloids with tartaric acid or other hydroxy acids of the aliphatic series, such as lactic, citric, mucus acid, can be subjected to oxidation, and other bases can be used to form salts, such as nitrogen containing.
П р и к е р 3. ЗЬ г глюконовокислой соли натри и трехатомной сурьмы раствор ют в 50 куб. см воды и добавл ют избыток 30%-го раствора перекиси водорода , одновременно предотвраща охлаждением сильное саморазогревание. После окончани реакции нейтрализуют разбавленным раствором едкого натра и перемешиванием с метиловым спиртом осаждают образовавшуюс комплексную соль. После сушки в эксикаторе получают бесцветный, легко растворимый в воде порошок.PRI KER 3. The sb of sodium gluconate and triatomic antimony is dissolved in 50 cu. cm of water and add an excess of 30% hydrogen peroxide solution, while simultaneously preventing cooling by strong self-heating. After completion of the reaction, it is neutralized with a dilute sodium hydroxide solution and the resulting complex salt is precipitated by stirring with methyl alcohol. After drying in a desiccator, a colorless, water-soluble powder is obtained.
Пример 4. 30 Z слизевокислой соли диэтиламина и трехвалентной сурьмы раствор ют в 50 куб. см воды и при охлаждении окисл ют избыток 30%-ой перекиси водорода. По окончании реакцииExample 4. 30 Z of the mucous salt of diethylamine and trivalent antimony are dissolved in a 50 cc. cm of water and when cooled, an excess of 30% hydrogen peroxide is oxidized. At the end of the reaction
нейтрализуют разбавленным раствором диэтиламина. Выпариванием раствора и сушкой в эксикаторе получают комплексную соль в виде бесцветного легко растворимого в виде порошка.neutralized with a dilute solution of diethylamine. By evaporation of the solution and drying in a desiccator, the complex salt is obtained as a colorless, easily soluble powder.
Предмет патента.The subject of the patent.
Способ получени окисленных органических соединений металлов, отличающийс тем, что, комплексные соли олова или сурьмы оксикарбоновых кислот алифатического р да обрабатывают или перекис ми водорода или металлов, или кислородом.A method of producing oxidized organic compounds of metals, characterized in that the complex salts of tin or antimony of the hydroxycarboxylic acids of the aliphatic series are treated with either hydrogen or metal peroxides or oxygen.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU57195A SU30151A1 (en) | 1929-10-29 | 1929-10-29 | The method of obtaining oxidized organic compounds of metals |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU57195A SU30151A1 (en) | 1929-10-29 | 1929-10-29 | The method of obtaining oxidized organic compounds of metals |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU30151A1 true SU30151A1 (en) | 1933-04-30 |
Family
ID=48347759
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU57195A SU30151A1 (en) | 1929-10-29 | 1929-10-29 | The method of obtaining oxidized organic compounds of metals |
Country Status (1)
| Country | Link |
|---|---|
| SU (1) | SU30151A1 (en) |
-
1929
- 1929-10-29 SU SU57195A patent/SU30151A1/en active
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