SK42493A3 - Fungicidal agents - Google Patents
Fungicidal agents Download PDFInfo
- Publication number
- SK42493A3 SK42493A3 SK424-93A SK42493A SK42493A3 SK 42493 A3 SK42493 A3 SK 42493A3 SK 42493 A SK42493 A SK 42493A SK 42493 A3 SK42493 A3 SK 42493A3
- Authority
- SK
- Slovakia
- Prior art keywords
- composition
- weight
- less
- moisture content
- microns
- Prior art date
Links
- 239000000417 fungicide Substances 0.000 title description 2
- 239000000203 mixture Substances 0.000 claims abstract description 81
- 239000012990 dithiocarbamate Substances 0.000 claims abstract description 20
- PDQAZBWRQCGBEV-UHFFFAOYSA-N Ethylenethiourea Chemical compound S=C1NCCN1 PDQAZBWRQCGBEV-UHFFFAOYSA-N 0.000 claims abstract description 14
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 claims abstract description 13
- 238000000034 method Methods 0.000 claims abstract description 10
- 150000004659 dithiocarbamates Chemical class 0.000 claims abstract description 6
- 238000001694 spray drying Methods 0.000 claims abstract description 6
- 239000002245 particle Substances 0.000 claims description 37
- 239000000725 suspension Substances 0.000 claims description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 21
- 238000002360 preparation method Methods 0.000 claims description 14
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 4
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 claims description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 4
- 229910021529 ammonia Inorganic materials 0.000 claims description 2
- 230000036571 hydration Effects 0.000 claims description 2
- 238000006703 hydration reaction Methods 0.000 claims description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 2
- 239000000470 constituent Substances 0.000 claims 1
- 150000002019 disulfides Chemical class 0.000 abstract description 6
- 239000002002 slurry Substances 0.000 abstract description 6
- 230000000855 fungicidal effect Effects 0.000 abstract description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 229910052751 metal Inorganic materials 0.000 description 10
- 239000002184 metal Substances 0.000 description 10
- 150000003839 salts Chemical class 0.000 description 10
- 239000002270 dispersing agent Substances 0.000 description 6
- 238000009472 formulation Methods 0.000 description 6
- 238000009826 distribution Methods 0.000 description 5
- 239000011572 manganese Substances 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- QRNATDQRFAUDKF-UHFFFAOYSA-N 2-carbamothioylsulfanylethyl carbamodithioate Chemical compound NC(=S)SCCSC(N)=S QRNATDQRFAUDKF-UHFFFAOYSA-N 0.000 description 3
- 239000005802 Mancozeb Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- MZGNSEAPZQGJRB-UHFFFAOYSA-N dimethyldithiocarbamic acid Chemical compound CN(C)C(S)=S MZGNSEAPZQGJRB-UHFFFAOYSA-N 0.000 description 3
- YKSNLCVSTHTHJA-UHFFFAOYSA-L maneb Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S YKSNLCVSTHTHJA-UHFFFAOYSA-L 0.000 description 3
- 229920000940 maneb Polymers 0.000 description 3
- 229910052748 manganese Inorganic materials 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical group CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 3
- -1 1-methyl-1,2-ethanediyl Chemical group 0.000 description 2
- JMZRZEXRYJUHEB-UHFFFAOYSA-N 2-carbamothioylsulfanylethyl carbamodithioate;zinc Chemical compound [Zn].NC(=S)SCCSC(N)=S JMZRZEXRYJUHEB-UHFFFAOYSA-N 0.000 description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
- 239000005809 Metiram Substances 0.000 description 2
- 239000005843 Thiram Substances 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229920000257 metiram Polymers 0.000 description 2
- 238000003921 particle size analysis Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 229960002447 thiram Drugs 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- YFVKHKCZBSGZPE-UHFFFAOYSA-N 1-(1,3-benzodioxol-5-yl)-2-(propylamino)propan-1-one Chemical compound CCCNC(C)C(=O)C1=CC=C2OCOC2=C1 YFVKHKCZBSGZPE-UHFFFAOYSA-N 0.000 description 1
- YAUCKEPYKXHCFF-UHFFFAOYSA-N 2-carbamothioylsulfanylethyl carbamodithioate;manganese Chemical compound [Mn].NC(=S)SCCSC(N)=S YAUCKEPYKXHCFF-UHFFFAOYSA-N 0.000 description 1
- QSZOMCLHJKGKED-UHFFFAOYSA-N 2-carbamothioylsulfanylpropyl carbamodithioate Chemical compound NC(=S)SC(C)CSC(N)=S QSZOMCLHJKGKED-UHFFFAOYSA-N 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- 239000005823 Propineb Substances 0.000 description 1
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000011717 all-trans-retinol Substances 0.000 description 1
- 235000019169 all-trans-retinol Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- TYUWIWBZXGOFHY-UHFFFAOYSA-N carbamodithioic acid;prop-1-ene Chemical compound CC=C.NC(S)=S TYUWIWBZXGOFHY-UHFFFAOYSA-N 0.000 description 1
- QGJOPFRUJISHPQ-NJFSPNSNSA-N carbon disulfide-14c Chemical compound S=[14C]=S QGJOPFRUJISHPQ-NJFSPNSNSA-N 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- ZUTJDJAXWKOOOI-UHFFFAOYSA-N ethylene diurea Chemical group NC(=O)NCCNC(N)=O ZUTJDJAXWKOOOI-UHFFFAOYSA-N 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- AWTNYZMRDAMOGW-UHFFFAOYSA-L manganese(2+);dicarbamodithioate Chemical class [Mn+2].NC([S-])=S.NC([S-])=S AWTNYZMRDAMOGW-UHFFFAOYSA-L 0.000 description 1
- 238000010297 mechanical methods and process Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- KKMLIVYBGSAJPM-UHFFFAOYSA-L propineb Chemical group [Zn+2].[S-]C(=S)NC(C)CNC([S-])=S KKMLIVYBGSAJPM-UHFFFAOYSA-L 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 1
- 229960000281 trometamol Drugs 0.000 description 1
- 238000001238 wet grinding Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 235000009529 zinc sulphate Nutrition 0.000 description 1
- 239000011686 zinc sulphate Substances 0.000 description 1
- DUBNHZYBDBBJHD-UHFFFAOYSA-L ziram Chemical group [Zn+2].CN(C)C([S-])=S.CN(C)C([S-])=S DUBNHZYBDBBJHD-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
- A01N47/14—Di-thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/26—Oxidation products of dithiocarbamic acid derivatives, e.g. thiuram sulfides
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US87701092A | 1992-05-01 | 1992-05-01 | |
| US3400893A | 1993-03-19 | 1993-03-19 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SK42493A3 true SK42493A3 (en) | 1993-12-08 |
Family
ID=26710437
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SK424-93A SK42493A3 (en) | 1992-05-01 | 1993-04-30 | Fungicidal agents |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP0568378B1 (pt) |
| CN (1) | CN1043834C (pt) |
| AU (1) | AU658500B2 (pt) |
| BR (1) | BR9301705A (pt) |
| CZ (1) | CZ79493A3 (pt) |
| HU (1) | HUT63936A (pt) |
| IL (1) | IL105488A0 (pt) |
| LV (1) | LV10363B (pt) |
| SK (1) | SK42493A3 (pt) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2704387B1 (fr) | 1993-04-28 | 1995-06-09 | Rhone Poulenc Agrochimie | Compositions concentrees de matieres actives en agriculture. |
| CA2374249C (en) | 1999-05-31 | 2008-08-12 | Basf Aktiengesellschaft | Dithiocarbamate liquid formulations |
| JP2007517914A (ja) * | 2004-01-14 | 2007-07-05 | ダウ アグロサイエンシィズ エルエルシー | アルキレンビスジチオカルバメートを安定化する方法 |
| MX2009003657A (es) * | 2006-10-04 | 2009-04-22 | Dow Agrosciences Llc | Estabilizacion de fungicida de bisditiocarbamato. |
| EP2079312A1 (en) * | 2006-10-04 | 2009-07-22 | Dow AgroSciences LLC | Bisdithiocarbamate fungicide stabilization |
| CN102308821B (zh) * | 2007-10-15 | 2013-11-27 | 张少武 | 一种含有代森联的有效成分的杀菌剂组合物 |
| WO2014105855A2 (en) | 2012-12-31 | 2014-07-03 | Dow Agrosciences Llc | Compositions and methods to modulate the rate of ebis production from dithiocarbamate fungicides |
| EP2873322A1 (en) * | 2013-11-19 | 2015-05-20 | Taminco | Improved fumigant |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2848297A (en) * | 1953-10-12 | 1958-08-19 | Du Pont | Manganese ethylenebisdithiocarbamate stabilized by desiccant; method and package |
| DE1082764B (de) * | 1957-08-23 | 1960-06-02 | Borchers Ag Gebr | Schaedlingsbekaempfungsmittel |
| DE1202266B (de) * | 1961-10-06 | 1965-10-07 | Basf Ag | Verfahren zur Herstellung von Ammoniak enthaltenden Komplex-Verbindungen des Mangansalzes der AEthylen-bis-dithio-carbamidsaeure |
| FR1482885A (fr) * | 1966-03-01 | 1967-06-02 | Rhone Poulenc Sa | Stabilisation des éthylènebisdithiocarbamates métalliques |
| US3497598A (en) * | 1968-01-31 | 1970-02-24 | Du Pont | Process for producing spray dried manganese ethylene bisdithiocarbamate compositions |
| US3737551A (en) * | 1969-08-20 | 1973-06-05 | Vanderbilt Co R T | Wettable and dispersible powders |
| US5001150A (en) * | 1988-03-22 | 1991-03-19 | E. I. Du Pont De Nemours And Company | Nondusty spray dried mancozeb water-dispersible granules and the process for their production |
| US4898881A (en) * | 1988-04-14 | 1990-02-06 | Alco Chemical Corporation | Dry microbiocidal composition containing an ethylene bis-dithiocarbamate salt |
-
1993
- 1993-04-21 AU AU37048/93A patent/AU658500B2/en not_active Ceased
- 1993-04-22 IL IL105488A patent/IL105488A0/xx unknown
- 1993-04-29 EP EP93303381A patent/EP0568378B1/en not_active Expired - Lifetime
- 1993-04-30 LV LVP-93-270A patent/LV10363B/en unknown
- 1993-04-30 BR BR9301705A patent/BR9301705A/pt not_active IP Right Cessation
- 1993-04-30 CZ CZ93794A patent/CZ79493A3/cs unknown
- 1993-04-30 HU HU9301274A patent/HUT63936A/hu unknown
- 1993-04-30 SK SK424-93A patent/SK42493A3/sk unknown
- 1993-05-01 CN CN93106353A patent/CN1043834C/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| HU9301274D0 (en) | 1993-08-30 |
| EP0568378A1 (en) | 1993-11-03 |
| CN1043834C (zh) | 1999-06-30 |
| LV10363A (lv) | 1995-02-20 |
| CN1078853A (zh) | 1993-12-01 |
| EP0568378B1 (en) | 1999-06-23 |
| CZ79493A3 (en) | 1994-01-19 |
| IL105488A0 (en) | 1993-08-18 |
| BR9301705A (pt) | 1993-11-03 |
| AU658500B2 (en) | 1995-04-13 |
| LV10363B (en) | 1996-04-20 |
| HUT63936A (en) | 1993-11-29 |
| AU3704893A (en) | 1993-11-04 |
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