SI9200184A - Composite fibre material based on natural fibre webs and process for its production and further processing into extruded mouldings - Google Patents
Composite fibre material based on natural fibre webs and process for its production and further processing into extruded mouldings Download PDFInfo
- Publication number
- SI9200184A SI9200184A SI929200184A SI9200184A SI9200184A SI 9200184 A SI9200184 A SI 9200184A SI 929200184 A SI929200184 A SI 929200184A SI 9200184 A SI9200184 A SI 9200184A SI 9200184 A SI9200184 A SI 9200184A
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- composite material
- fibers
- fiber
- binder
- fiber composite
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Classifications
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4266—Natural fibres not provided for in group D04H1/425
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4382—Stretched reticular film fibres; Composite fibres; Mixed fibres; Ultrafine fibres; Fibres for artificial leather
- D04H1/43835—Mixed fibres, e.g. at least two chemically different fibres or fibre blends
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4209—Inorganic fibres
- D04H1/4218—Glass fibres
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4274—Rags; Fabric scraps
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4374—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece using different kinds of webs, e.g. by layering webs
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4382—Stretched reticular film fibres; Composite fibres; Mixed fibres; Ultrafine fibres; Fibres for artificial leather
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/44—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
- D04H1/587—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives characterised by the bonding agents used
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Nonwoven Fabrics (AREA)
- Reinforced Plastic Materials (AREA)
Abstract
Description
EMPE-WERKE Ernst Pelz GmbH & Co. KGEMPE-WERKE Ernst Pelz GmbH & Co. KG KG
Vlakneni kompozitni material na osnovi run iz naravnih vlaken kot tudi postopek za njegovo kontinuimo pripravo in nadaljnjo predelavo v stiskanceNatural fiber-based fiber composite material as well as a process for its continuous preparation and further processing into presses
Izum se nanaša na vlakneni kompozitni material na osnovi run iz naravnih vlaken kot tudi na postopek za njegovo kontinuirno pripravo in nadaljnjo predelavo v večslojne stiskance.The invention relates to a fiber composite material based on a run of natural fibers, as well as a process for its continuous preparation and further processing into multilayer presses.
Področja uporabe za vlaknene kompozitne materiale kot tudi za iz njih pripravljene stiskance so izredno raznovrstna. Take materiale uporabljamo npr. v avtomobilski industriji kot elemente za notranje obloge vsakršne vrste, kot npr. surove nosilce za obloge vrat, odlagališča klobukov, obloge stebrov, obloge prtljažnika itd., ali v industriji embalaže ali gradbeni industriji. V območje surovin za take materiale štejemo elastomere, surovine lesna vlakna, tekstilna vlakna, nosilce steklenih vlaken in ojačene termoplastične umetne snovi, pri čemer so npr. za omenjeno področje uporabe v avtomobilski industriji odločilne naslednje lastnosti surovin: dušenje hrupa in komfort, izpolnjevanje varnostnih predpisov, trdnost proti obrabi, neobčutljivost proti vlagi, racionalna izdelavnost, majhna teža, sposobnost za demontiranje (servisiranje) in prenesljivost za okolje, če navedemo le nekaj primerov.The range of applications for fibrous composite materials as well as for compression molding is extremely diverse. Such materials are used e.g. in the automotive industry as elements for interior finishes of any kind, such as crude door lining brackets, hat dumps, pillar lining, trunk lining, etc., or in the packaging or construction industries. The range of raw materials for such materials includes elastomers, raw materials wood fibers, textile fibers, fiberglass supports and reinforced thermoplastic plastics, such as e.g. For the aforementioned field of application in the automotive industry, the following raw material characteristics are decisive: noise and comfort attenuation, compliance with safety regulations, wear resistance, moisture insensitivity, rational workmanship, light weight, ability to dismantle (service) and environmental portability, to name a few of cases.
Iz DE 32 39 732 je znan postopek, pri katerem pripravijo vmesni produkt iz v bistvu dveh različnih tipov vlaken, namreč iz celuloznega osnovnega vlakna in termoplastičnega nosilnega vlakna. Nosilna vlakna in osnovna vlakna so mehansko predhodno utrjena in jih že vnaprej skupaj pomešajo s sestavino, ki se utrjuje v toploti, v suhem stanju v mešalni napravi, primerni za ta namen. V gotovem vmesnem produktu se nahaja od začetka primešana sestavina, ki se utrjuje v toploti, v svojem prvotnem, neutijenem stanju. Odločilne hibe pri tem postopku so po eni strani visoka potreba po energiji pri predsušenju vlaken, ki v glavnem obstoje iz lesnih vlaken, in visoke temperature za predhodno utrjevanje mate s termoplastičnimi vlakni. Nadalje lahko visoka zračna vlažnost, ki nekontrolirano vdira, znatno moti izgotovitveni proces.DE 32 39 732 discloses a process for preparing an intermediate of essentially two different types of fibers, namely cellulose base fiber and thermoplastic carrier fiber. The carrier fibers and the base fibers are mechanically pre-cured and mixed together in advance with the heat-cured constituent in a dry state in a mixing device suitable for this purpose. The finished intermediate is from the beginning a mixed, heat-cured ingredient in its original, unmolded state. The decisive disadvantages of this process, on the one hand, are the high energy requirement for drying the fibers, which are mainly made of wood fibers, and the high temperature for pre-curing the thermoplastic fiber mat. Furthermore, high air humidity, which intrudes uncontrollably, can significantly interfere with the manufacturing process.
Pri drugem znanem postopku, ki je opisan v DE 28 30 320, omočijo kokosne mate s površinskimi masami okoli 1000 g/m2 z umetnimi smolami, pretežno utrljivimi poliestrskimi smolami. Tudi pri drugih znanih postopkih, kot je npr. opisano v DE 31 50 906, DE 28 43 139 ali DE 28 17 271, uporabijo umetne smole kot sredstva za vezanje vlaken. Neugodna pri teh postopkih je predvsem lahka hlapnost nekaterih sestavin uporabljenih kopolimerov, kot monostirena pri nenasičenih poliestrskih smolah in formaldehida pri fenolformaldehidnih formulacijah. Tukaj so zlasti potrebni delovno fiziološki ukrepi in ukrepi za zmanjšanje emulzije. Poleg tega sta za omočenje in prepojitev vlaknenih mat (pri debelinah mat okoli 10 mm) potrebna prebitna omakalna smola in uvaljanje smolne zmesi v klimatizirani atmosferi. Pri vmesnem skladiščenju z navijanjem omočenih mat nastanejo zaradi sedimentacije vodno tekoče smole v spodnje sloje in neenakomernega izhlapenja lahko hlapnih sestavin kopolimerov na površini znatne razlike gostot v matah. To vodi do napak materiala pri stiskanju v oblikovance kot tudi do znatnih obremenitev okolja.In another known process described in DE 28 30 320, coconut mats of a surface mass of about 1000 g / m 2 are wetted with artificial resins, predominantly curable polyester resins. Other known methods, such as e.g. described in DE 31 50 906, DE 28 43 139, or DE 28 17 271, use artificial resins as fiber bonding agents. The disadvantage of these processes is the low volatility of some of the constituents of the copolymers used, such as monostyrene for unsaturated polyester resins and formaldehyde in phenolformaldehyde formulations. In particular, work-related physiological and emulsion reduction measures are needed here. In addition, wetting and impregnation of fibrous mats (at mat thicknesses of about 10 mm) requires excess wetting resin and wetting of the resin mixture in an air-conditioned atmosphere. Intermediate storage by winding wetted mats results in a significant difference in the density of the mats due to the sedimentation of the aqueous liquid resin into the lower layers and the uneven evaporation of the volatile components of the copolymers on the surface. This leads to material defects in molding as well as significant environmental stresses.
Osnova izuma je naloga, da bi zagotovili tovrsten vlakneni kompozitni material kot tudi postopek za njegovo kontinuirno pripravo in nadaljnjo predelavo, ki bi omogočil, da bi se izognili zgoraj navedenim hibam.It is an object of the invention to provide such a fibrous composite material as well as a process for its continuous preparation and further processing, which would avoid the above defects.
V smislu izuma rešimo to nalogo z vlaknenim kompozitnim materialom na osnovi run iz naravnih vlaken, pri katerem imajo runa iz naravnih vlaken površinsko maso največ 200 g/m2. Ta novovrsten vlakneni kompozitni material se da, kot je v nadaljevanju še podrobneje opisano, pripraviti stroškovno ugodno in se ga da nadalje predelati v kontinuirnem postopku v nosilne oblikovance za npr. dele notranjih oblog v avtomobilski industriji ali nosilne dele za industrijo embalaže in gradbeno industrijo. V primerjavi z drugimi znanimi produkti se je s pridom izkazala izredno nizka površinska masa run iz naravnih vlaken in s tem bistveno poenostavljeno rokovanje npr. pri skladiščenju in transportu. Poleg tega se je na osnovi tega novega izhodnega materiala posrečilo razviti optimirane izdelovalne postopke za vlaknene kompozitne materiale in nadaljnje predelovalne postopke v stiskance in doseči izboljšane lastnosti glede dušenja zvoka, trdnosti, porušne trdnosti pri temperaturah -20 °C, dimenzijske stabilnosti, variabilne zunanje ploskovne izvedbe, manjših debelin sten pri višji trdnosti, ugodnejših reciklirnih kvot in višjih hidrotermičnih obstojnosti kot pri primerljivo pripravljenih kompozitnih materialih iz naravnih vlaken, predvsem na osnovi lesnih vlaken. Zaradi majhnih površinskih mas je dodatno potrebno manj energije za izhlapevanje za izgon vlage.According to the invention, this problem is solved with a fiber composite material based on a run of natural fibers, in which the runes of natural fibers have a surface mass of no more than 200 g / m 2 . This new fiber composite material can be prepared as cost-effective as described below, and further processed in a continuous process into supporting molds, e.g. parts of interior linings in the automotive industry or load-bearing parts for the packaging and construction industries. Compared to other known products, the extremely low surface mass of the run of natural fibers proved to be advantageous, and thus significantly simplified handling of e.g. in storage and transport. In addition, based on this new starting material, it has been possible to develop optimized fabrication processes for fibrous composite materials and further compression molding processes and to achieve improved sound attenuation properties, strength, fracture toughness at -20 ° C, dimensional stability, variable surface planar designs, smaller wall thicknesses at higher strength, more favorable recycling quotas and higher hydrothermal stability than for comparatively prepared natural fiber composite materials, mainly based on wood fibers. Due to the low surface mass, less energy is required for evaporation to expel moisture.
Prednostno imajo runa iz naravnih vlaken maksimalno debelino okoli 5 mm.Preferably, the natural fiber fleece has a maximum thickness of about 5 mm.
Za pripravo run iz naravnih vlaken predemo prednostno vlakna s premerom vlaken pod 10 μιη in celotno dolžino vlaken nad 100 mm ter utrdimo izključno mehansko.In order to prepare the run of natural fibers, preferably fibers with a diameter of less than 10 μιη and a total fiber length of more than 100 mm are passed over and solely mechanical.
Prednostno uporabimo za pripravo run iz naravnih vlaken pretežno lanena vlakna. Posebno upoštevanja vredna je pri tem nova surovinska baza, ki ne vsebuje le z ekološkega in ekonomskega stališča daljnosežne bodočnostne vidike. Poleg tega obstoji velik politični interes, da se pospešujejo in forsirajo projekti s produkti iz naravnih vlaken, ki podpirajo nacionalno kmetijstvo. Samoumevno lahko za runa iz naravnih vlaken v smislu izuma uporabimo tudi druga rastlinska vlakna, kot juto, kokos, slamo, trstiko, sisal, lesna vlakna ipd.Preferably, mainly flax fibers are used to prepare the run of natural fibers. Particularly noteworthy is the new raw material base, which not only has a far-reaching prospect in terms of ecology and economics. In addition, there is a strong political interest in promoting and promoting projects with natural fiber products that support national agriculture. It is self-evident that other vegetable fibers, such as jute, coconut, straw, reed, sisal, wood fibers, etc., can also be used for the fleece of natural fibers of the invention.
Alternativno naravnim vlaknom na rastlinski osnovi oz. v kombinaciji s temi lahko v smislu izuma uporabimo tudi vlakna na živalski osnovi, kot npr. ovčjo volno, rastlinske dlake iz odpadnih produktov itd.Alternatively to plant-based or natural fibers. in combination with these, animal-based fibers such as e.g. sheep wool, vegetable hair from waste products, etc.
Pri prednostni izvedbeni obliki izuma je predvideno, da na runa iz naravnih vlaken nanesemo vezivo, da dosežemo sposobnost stiskanja v oblikovance. V tej zvezi je možno vezivo reaktivna umetna smola, kot npr. dvokomponentna poliuretanska smola, prednostno v mešalnem razmerju poliol/izocianat med 100 : 160 in 100 : 200, ali penljiva epoksidna smola, pri čemer pri uporabah tovrstnih veziv prednostno dodamo dodatek, ki povzroči učinkovito odzračevanje vlaknenega kompozitnega materiala pred stiskanjem, kot še podrobneje opisujemo nadalje spodaj.In a preferred embodiment of the invention, it is provided that a binder is applied to the fleece of natural fibers to achieve the ability to press into the molds. In this connection, a possible binder is a reactive artificial resin such as e.g. a two-component polyurethane resin, preferably in a polyol / isocyanate mixing ratio of 100: 160 to 100: 200, or a foamy epoxy resin, with the use of such binders, preferably, an additive which causes effective venting of the fibrous composite material before compression, as further described below below.
Za omakanje run iz naravnih vlaken uporabljene reakcijske smole in dodatki so pri tem naravnani specialno na posebne lastnosti run iz naravnih vlaken, kot vključena celična vlaga in razmerje debeline vlaken proti dolžini vlaken. Nadalje je reakcijsko obnašanje umetnih smol optimirano zlasti na vlaknene površine in vlakneno gostoto naravnih vlaken. Ta natančna naravnava veziva na runa iz naravnih vlaken in nadalje spodaj še podrobneje opisan postopek nanašanja pogojujeta poleg tega za okolje prizanesljivo in higiensko neoporečno delo.The reaction resins used for wetting the run of natural fibers and the additives are specifically geared to the specific properties of the run of natural fibers, such as the cellular moisture involved and the ratio of fiber thickness to fiber length. Furthermore, the reaction behavior of artificial resins is optimized in particular to the fiber surfaces and fiber density of natural fibers. This precise alignment of the natural fiber fleece binder and the application process described in more detail below make it environmentally sound and hygienic work.
Druga alternativa za vezivo, ki se zahteva za dosego sposobnosti stiskanja run iz naravnih vlaken v oblikovance, je termoplastična umetna snov. Ta se tali pri ustreznem zvišanju temperature in tvori na ta način ustrezno omočenje površin runa, pri čemer sta tališče in točka utrditve termoplastičnega veziva ustrezno naravnana na zahteve predvidenega produkta in postopka. Kot termoplastične umetne snovi pridejo v poštev poleg polipropilena, polietilena ali zmesne formulacije teh spojin tudi spojine na osnovi rastlinskega olja, pri čemer lahko osnovno rastlinsko olje pridobimo iz Euphorbia lathyris, repice, High Olec-Sunflower ali drugih surovin z visokim deležem Clg-maščobnih kislin na znan način.Another alternative to the binder required to achieve the ability to compress run from natural fibers into molds is a thermoplastic plastic. This melts at a suitable temperature rise, thus forming a suitable wetting of the runes surfaces, with the melting point and the point of hardening of the thermoplastic binder being properly adjusted to the requirements of the intended product and process. As thermoplastic material, they come into consideration in addition to polypropylene, polyethylene or the blend formulation of these compounds as a compound based on vegetable oil, whereby the basic vegetable oil obtained from Euphorbia lathyris, rape, High Olec-Sunflower or other materials with a high proportion of C lg -fatty acids in a known manner.
Nadaljnja alternativa za v smislu izuma uporabno vezivo, ki je zlasti interesantno z vidika zagotovitve nove surovinske baze tudi za to komponento produkta, je dvokomponentni sistem na rastlinski osnovi, ki kot glavni komponenti zajema lignin (odpadni produkt pri pripravi papirja iz lesa) in glivico bele plesni, ki je sposobna reakcijske tvorbe z ligninom, pri čemer ta novovrstni vezivni sistem prednostno dodatno vsebuje iz krompirjevih lupin dobljeno pulpo, ki jo primešamo, posušeno v fin prašek, ligninski smoli.A further alternative to the useful binder of the invention, which is particularly interesting in terms of providing a new raw material base for this component of the product, is a two-component plant-based system comprising lignin (a waste product in the preparation of wood paper) and a white fungus as its main component. mold capable of reacting with lignin, wherein this new-type binder system preferably further comprises a pulp which is mixed from the potato peel, which is mixed, dried to a fine powder, lignin resin.
Prednostna izvedbena oblika izuma se odlikuje z dodatkom anorganskih ali organskih ojačevalnih materialov na osnovi steklenih vlaken, sinteznih vlaken in/ali naravnih vlaken na rastlinski in/ali živalski osnovi, kot je npr. juta, kokos, slama, trstika, sisal, lesna vlakna, ovčja volna, dlaka itd.. Da bi v izdelovalni postopek v smislu izuma, ki ga še podrobneje pojasnjujemo nadalje spodaj, integrirali efektivno recikliranje materiala, je prednosten ojačevalni material za vlakneni kompozitni material v smislu izuma reciklat iz samega vlaknenega kompozitnega materiala.A preferred embodiment of the invention is characterized by the addition of inorganic or organic reinforcing materials based on glass fibers, synthetic fibers and / or natural fibers on a plant and / or animal basis, such as e.g. jute, coconut, straw, reed, sisal, wood fiber, sheep wool, hair, etc .. In order to integrate effective material recycling into the manufacturing process of the invention, which is explained further below, reinforcing material for fibrous composite material is preferred according to the invention recyclates from the fibrous composite material itself.
Prednostno se nahaja ojačevalni material v predhodno vezani obliki kot vlakneni nosilec, npr. v obliki prej, sukancev, filamentnih prej, predilnih vlaken itd. ali kot tekstilna tkanina ali vlaknena mata.Preferably, the reinforcing material is pre-bonded as a fiber support, e.g. in the form of yarns, threads, filament yarns, spinning fibers, etc. or as a textile fabric or fiber mat.
Pri izumu nadalje predlagamo, da predhodno vezani ojačevalni material predhodno utrdimo z vezivom.The invention further proposes that the pre-bonded reinforcing material is pre-cured with a binder.
Izum se nadalje nanaša na postopek za kontinuimo pripravo vlaknenega kompozitnega materiala na osnovi run iz naravnih vlaken, pri katerem pripravimo runa iz naravnih vlaken s površinsko maso največ 200 g/m2.The invention further relates to a process for the continuous preparation of a fiber composite material based on a run of natural fibers, in which a fleece of natural fibers with a surface mass of not more than 200 g / m 2 is prepared.
Pri tem imajo runa iz naravnih vlaken prednostno največjo debelino okoli 5 mm ter jih prednostno spredemo iz vlaken s premerom vlaken pod 10 μια in celotno dolžino vlaken nad 100 mm ter utrdimo izključno mehansko.In this case, the fibers of the natural fibers preferably have a maximum thickness of about 5 mm and are preferably spun from fibers with a fiber diameter of less than 10 μια and a total fiber length of more than 100 mm and solidified exclusively mechanically.
Prednostno za pripravo run iz naravnih vlaken (iz zgoraj navedenih razlogov) pretežno uporabimo lanena vlakna.Preferably, linen fibers are used to prepare the run of natural fibers (for the reasons stated above).
Pri izumu nadalje predlagamo, da za pripravo run iz naravnih vlaken uporabimo pretežno vlakna na živalski osnovi.It is further proposed in the invention that mainly animal-based fibers are used for the preparation of natural fiber runes.
Prednostno uporabimo kot vlakna na živalski osnovi ovčjo volno, živalsko dlako iz odpadnih produktov ipd.Preferably, sheep wool, animal hair from waste products and the like are used as animal-based fibers.
Pri prednostni izvedbeni obliki postopka v smislu izuma runa iz naravnih vlaken pred nadaljnjo predelavo predhodno sušimo do vsebnosti preostale vlage največ 8 %.In a preferred embodiment of the process according to the invention, the natural fiber fleece is pre-dried to a residual moisture content of not more than 8% before further processing.
Za nadalje spodaj opisano nadaljnjo predelavo v stiskance je v smislu izuma predvideno, da na runa iz naravnih vlaken nanesemo vezivo, da dosežemo sposobnost stiskanja.For the further processing described below, compression molding according to the invention provides for the application of a binder to the fleece of natural fibers in order to achieve the compression capability.
Kot že zgoraj omenjeno lahko kot možno vezivo uporabimo reaktivno umetno smolo, pri čemer pridejo za to v poštev zlasti dvokomponentne poliuretanske smole ali penljive epoksidne smole. Zlasti prednostna je dvokomponentna poliuretanska smola z mešalnim razmerjem poliol/izocianat med 100 : 160 do 100 : 200. Tovrstne termične umetne smole nimajo nobenih lahko hlapnih sestavin, ki bi izhajale med izdelovalnim postopkom in postopkom nadaljnje predelave. S takojšno homogeno vezavo veziva v vlakneno matrico se lahko izognemo pojavom sedimentacije, ki vodijo do zgoraj omenjenih razlik v gostoti.As mentioned above, reactive synthetic resin can be used as a possible binder, especially two-component polyurethane resins or foamy epoxy resins. Particularly preferred is a two-component polyurethane resin with a mixing ratio of polyol / isocyanate between 100: 160 and 100: 200. Such thermal synthetic resins do not have any easily volatile constituents resulting from the manufacturing process and the further processing process. Immediate homogeneous bonding of the binder into the fiber matrix avoids the occurrence of sedimentation leading to the density differences mentioned above.
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Pri uporabi tovrstnih reaktivnih umetnih smol je posebno ugodno, če istočasno z ali po nanosu reaktivne umetne smole dodamo dodatek, ki povzroči učinkovito odzračevanje vlaknenega kompozitnega materiala pred stiskanjem, kot npr. kroglice iz pihanega stekla s premerom 2 do 4 mm. Ob uporabi takih dodatkov in anorganskih ali organskih ojačevalnih materialov pripravljene vlaknene kompozitne materiale lahko ob učinkovanju temperature okoli 90 do 110 °C in tlaku trajno oblikujemo in utrdimo v tridimenzionalne oblikovance. Pri tem so tovrstni stiskanci, kot je nadalje spodaj še podrobneje pojasnjeno, prednostno večslojni, pri čemer za to uporabljena runa v impregnirni stopnji oz. pri sobni temperaturi omočimo z reaktivno umetno smolo in v nadaljnji predelovalni stopnji obložimo z dodatki. Že zgoraj podrobneje opisana naravnava veziva in dodatka na runo iz naravnih vlaken in postopek nanašanja pogojujeta okolju prizanesljivo in higiensko neoporečno delo.The use of such reactive artificial resins is particularly advantageous if, at the same time as or with the application of the reactive artificial resin, an additive is added which causes an effective venting of the fibrous composite material prior to compression, such as e.g. 2 to 4 mm diameter blown glass beads. With the use of such additives and inorganic or organic reinforcing materials, the prepared fibrous composite materials can be permanently molded and solidified into three-dimensional molds, having a temperature effect of about 90 to 110 ° C and pressure. In this case, such presses, as explained below in more detail, are preferably multilayered, whereby the fleece used in the impregnation step or in the impregnation stage is used. at room temperature, it is wetted with reactive artificial resin and coated with additives in a further processing step. The adjustment of the binder and the additive to the fleece made from natural fibers described above and the process of application condition the environmentally sound and hygienic work.
Alternativno vezivo reaktivni umetni smoli je termoplastična umetna snov, ki jo pri postopku vtaljevanja vnesemo v runo iz naravnih vlaken. Kot termoplastične umetne snovi pridejo poleg polipropilena, polietilena ali zmesne formulacije teh spojin v poštev tudi spojine na osnovi rastlinskega olja, npr. spojine, pri katerih osnovni material rastlinsko olje dobimo iz Euphorbia lathyris, repice, High Olec-sunflower ali druge surovine z visokim deležem C18-maščobnih kislin.An alternative binder for reactive synthetic resin is a thermoplastic plastic that is introduced into the fleece of natural fibers during the process of melting. Thermoplastic plastics include, in addition to polypropylene, polyethylene or a mixed formulation of these compounds, vegetable oil based compounds, e.g. compounds in which the base material is a vegetable oil obtained from the Euphorbia lathyris, rape, High-Olec sunflower or other material with a high proportion of C 18 -fatty acids.
Glede predelave termoplastične umetne snovi obstoji razlika za predelavo preje opisanih reaktivnih umetnih smol v tem, da runo iz naravnih vlaken običajno predhodno segrejemo na tališče termoplastične umetne snovi, s čimer poteče stalitev v runo iz naravnih vlaken. Fakultativne dodatke za ojačenje nato prednostno nanesemo v naslednjih stopnjah postopka. Glede na nadaljnjo predelavo v večslojne stiskance se vsekakor nič ne spremeni v primerjavi z uporabo reaktivne umetne smole kot veziva.With regard to the processing of thermoplastic plastics, there is a difference for the processing of the reactive synthetic resins described above in that the fleece of natural fibers is usually pre-heated to the melting point of thermoplastic plastic, thereby expelling the placement into the fleece of natural fibers. Optional reinforcement additives are then preferably applied in the next steps of the process. Considering further processing into multilayer presses, there is definitely nothing to change compared to using reactive artificial resin as a binder.
Nadaljnje možno vezivo je, kot je že nadalje zgoraj opisano, dvokomponentni sistem na rastlinski osnovi, ki kot glavni komponenti zajema lignin in glivico bele plesni, ki je sposobna reakcijske tvorbe z ligninom, pri čemer temu novovrstnemu vezivnemu sistemu prednostno pred nanosom na runo iz naravnih vlaken dodatno dodamo iz krompirjevih olupkov dobljeno pulpo.Another possible binder is, as described above, a two-component plant-based system comprising as its main component lignin and a white mold fungus capable of reacting with lignin, with this new-type binder system being preferred over natural fleece application the pulp obtained from the potato peel is added to the fibers.
Prednostno lahko pri tem porabo energije za izvedbo postopka s takojšnjo termično izrabo preostalih snovi in integrirano energijsko rekuperacijo držimo na nizkem nivoju.Preferably, the energy consumption for carrying out the process with immediate thermal recovery of the remaining substances and integrated energy recovery can be kept low.
Pri tem lahko runa iz naravnih vlaken ojačimo z dodatkom anorganskih ali organskih ojačevalnih materialov na osnovi steklenih vlaken, sinteznih vlaken in/ali naravnih vlaken na rastlinski in/ali živalski osnovi. Prednostno lahko kot ojačevalni material uporabimo reciklat iz samega vlaknenega kompozitnega materiala. Ojačevalni material lahko uporabimo v predhodno vezani obliki kot vlakneni nosilec, npr. v obliki prej, sukancev, filamentnih prej, predilnih vlaken itd. ali kot tekstilno tkanino ali vlakneno mato, in predhodno vezani ojačevalni material v danem primeru predhodno utrdimo z vezivom. Končno se izum nanaša še na postopek za kontinuimo pripravo večslojnih stiskancev na osnovi vlaknenih kompozitnih materialov, na katerih je naneseno vezivo, kot so opisani nadalje zgoraj, ki se odlikuje s tem, da proge runa iz naravnih vlaken, na katere so nanesena veziva in so v danem primeru opremljene z dodatki za ojačenje in/ali odzračevanje in so v danem primeru predhodno zgoščene, predkonfekcioniramo, pri čemer se prirez ravna po dimenzijah stiskanca, ki ga je treba pripraviti.Natural fiber runes can be reinforced by the addition of inorganic or organic reinforcing materials based on glass fibers, synthesis fibers and / or natural fibers on a plant and / or animal basis. Preferably, recycled material from the fiber composite material itself can be used as a reinforcing material. The reinforcing material can be used in a pre-bound form as a fiber carrier, e.g. in the form of yarns, threads, filament yarns, spinning fibers, etc. or as a textile cloth or fiber mat, and the pre-bonded reinforcing material, if desired, is pre-cured with a binder. Finally, the invention relates to a process for the continuous preparation of multilayer presses based on fibrous composite materials on which a binder is applied, as described above, characterized in that the runes are made of natural fibers, on which binders are applied and are optionally provided with reinforcing and / or venting additives and, if appropriate, pre-concentrated, pre-confined, with the cut being made according to the dimensions of the press to be prepared.
Pri tem položimo prireže proge runa iz naravnih vlaken v 3 do 6 slojih tako drugega na drugega, da površini, na katero je naneseno vezivo, sledi nenasena površina.In this case, lay the strips of strips of natural fiber runes in 3 to 6 layers so that each other so that the surface to which the binder is applied is followed by an unpaved surface.
Prednostno večslojne mate iz naravnih vlaken predhodno zgostimo po celi površini preko valjčne proge ah ploščnega zgoščevanja na okoli 50 % končne debeline materiala in nato s stiskalnim orodjem ob uporabi na vsakokratno vezivo naravnane zvišane temperature in tlaka trajno oblikujemo v stiskance.Preferably, the multi-layer natural fiber mats are pre-compacted over the entire surface via a roller line or plate compacting to about 50% of the final thickness of the material, and then with a pressing tool, the temperature and pressure-oriented binder are permanently molded into presses.
Nadaljnje značilnosti in prednosti izuma so razvidne iz naslednjega opisa prednostnih izvedbenih oblik izuma, ki jih podrobneje pojasnjujemo s priloženo shematsko risbo. Pri tem kaže:Further features and advantages of the invention are apparent from the following description of preferred embodiments of the invention, which are explained in more detail in the accompanying schematic drawing. It shows:
sl. 1 shematsko predstavitev pozicioniranja vlaknenega substrata in valjčno vlečno napravo kot tudi kontinuirno predsušenje vlaknenega substrata s pretočno napravo in transportno smeijo;FIG. 1 is a schematic representation of the positioning of the fiber substrate and the roller traction device, as well as the continuous drying of the fiber substrate by a flow device and a transport laugh;
sl. 2 shematsko predstavitev mešalne glave za reakcijsko smolo z navedbo spremembe smeri in transportne naprave za vlakneni substrat kot tudi alternativno črtkano poleg tega razporeditev za nanašanje termoplastičnih umetnih snovi v tej stopnji;FIG. 2 is a schematic representation of the reaction resin mixer, indicating the change of direction and transport device for the fibrous substrate, as well as an alternative dashed layout for the application of thermoplastic plastics in this step;
sl. 3 shematsko predstavitev rezalne naprave za dodatna ojačevalna vlakna in nanašalne naprave za nanašanje pomožnih snovi kot tudi transportne naprave za vlakneni substrat ter shematsko predstavitev predhodne zgostitve materiala;FIG. 3 is a schematic representation of a cutting device for additional reinforcing fibers and deposition devices for the application of auxiliary substances, as well as a conveyor device for a fibrous substrate, and a schematic representation of the pre-thickening of the material;
sl. 4 shematsko predstavitev ločilne naprave z navedbo stopenj prostosti rezalne glave in naprave za odvajanje ločilnega medija kot tudi transportne naprave za vlaknene prireže, in shematsko predstavitev za namestitev slojev posameznih ploskih vlaknenih prirezov kot tudi pozicioniranje posameznih slojev;FIG. 4 is a schematic representation of the separation device, indicating the degrees of freedom of the cutting head and the device for separating the separation medium as well as the conveyor device for the fiber cuts, and a schematic representation for the placement of layers of individual flat fiber cuts as well as the positioning of the individual layers;
sl. 5 shematsko predstavitev naknadne zagostitvene naprave z navedbo dajalne smeri; in sl. 6 shematsko predstavitev naprave za avtomatsko vlaganje prirezov ploščnih polizdelkov v priključen stiskalni model z navedbo smeri gibanja in shematsko predstavitev samega stiskalnega modela.FIG. 5 is a schematic representation of a subsequent thickening device indicating the direction of delivery; and FIG. 6 is a schematic representation of a device for automatic insertion of cut-outs of plate semi-finished products into a connected compression model with indication of the direction of movement and a schematic representation of the compression model itself.
Posamezne slike - upoštevane v zaporedju njihovega zaporednega numeriranja predstavljajo potek v smislu izuma za kontinuimo pripravo večslojnih vlaknenih mat kot polizdelkov kot tudi njihovo nadaljnjo predelavo v stiskance.Individual images - Considered in the sequence of their sequential numbering, represent the course of the invention for the continuous preparation of multilayer fiber mats as semi-finished products as well as their further processing into presses.
Ta potek postopka se začne, kot je predstavljeno na sl. 1, s pozicioniranjem run 1 iz naravnih vlaken (npr. iz lanu) s površinsko maso okoli 150 g/m2, ki so utrjena izključno mehansko brez dodatnega veziva in imajo debelino okoli 4 mm. Z ugodnim razmerjem premera vlaken (manj kot 10 gm) proti celotni dolžini vlaken (več kot 100 mm) dosežemo pri predenju množico točk spojitve in točk zavozlanja, s čimer lahko dobimo zelo dobro mehansko trdnost. Ker je natezna trdnost zadostna, niso potrebna nikakršna dodatna sintetska ali druga ojačevalna vlakna oz. siceršnja pomožna sredstva za transport runa v transportni napravi 3.This process begins as shown in FIG. 1, by positioning run 1 of natural fibers (eg flax) with a surface mass of about 150 g / m 2 , which are exclusively mechanically cured without additional binder and have a thickness of about 4 mm. With a favorable fiber diameter ratio (less than 10 gm) to the total fiber length (more than 100 mm), a plurality of joining points and anchorage points are obtained in the spinning process, which gives very good mechanical strength. Since the tensile strength is sufficient, no additional synthetic or other reinforcing fibers or fibers are required. other auxiliaries for the transport of runes in a conveyor unit 3.
V desni polovici sl. 1 je shematsko prikazana priprava z oskrbovalnega valja odvijanega runa 1 iz naravnih vlaken. Naravna vlakna, kot lan, juta ipd., navzamejo zaradi svoje celularne strukture na naraven način, t.j. s sesalnimi in kapilarnimi učinki, po celotni ploskvi na široki fronti in v smeri debeline vlaknene slojitve vlago iz okolišnega zraka. Red velikosti navzema vlage niha glede na vrsto vlaken in sestavo vlaknenega runa med 10 in 20 vol.%. Bistvena prednost izuma je v tem, da vlakneno runo 1 z majhno površinsko maso, torej tudi majhno debelino slojenja in fino vlakneno porazdelitvijo, tvori večjo površino kot pri bolj grobih, gosteje naslojenih vlaknenih runih. Vlakneno runo lahko torej preko mrežnega transportnega traku dovajamo kontinuirno in z visoko transportno hitrostjo na predsušilno progo 2.In the right half of FIG. 1 is a schematic representation of the preparation of a natural fiber filament unwound runner 1 from a supply roll. Natural fibers, such as flax, jute, etc., are taken up naturally because of their cellular structure, i.e. with suction and capillary effects, moisture throughout the entire surface on the broad front and in the direction of the thickness of the fiber laminate from ambient air. The order of magnitude of the moisture uptake varies depending on the type of fiber and the composition of the fiber fleece between 10 and 20% by volume. An essential advantage of the invention is that the fiber web 1 with a small surface mass, ie also a small thickness of layering and a fine fiber distribution, forms a larger surface area than in the case of coarser, more densely layered fiber webs. The fiber fleece can therefore be fed continuously and at high speed to the pre-drying line 2 via a conveyor belt.
Predsušenje poteče s turbulentno proizvedenim in predsušenim vročim zrakom (temperatura okoli 80 do 100 °C), pri čemer je smer strujanja tako izbrana, da je tok vročega zraka usmerjen navpično glede na površino vlaknenega runa in križa transportno smer vlaknenega runa 1, s čimer izsilimo, da struja skozi vlakneno runo od zgoraj navzdol. Z vlažnostjo obložen zrak pod vlaknenim runom 1 kontinuirno odvajamo in ga nadalje vodimo za pripravo predreakcije (naželiranja) z reakcijsko smolo. Od zunaj stalno dovajamo sveže predsušeni zrak v predsušilno progo 2. Dovajanje zraka in potek predsušenja zagotavljata natančno določeno krmiljenje preostale vsebnosti vlage v vlaknenem runu 1, ki v smislu izuma ne znaša več kot 8 %.Drying expires with turbulently produced and dried hot air (temperature of about 80 to 100 ° C), the flow direction being chosen so that the flow of hot air is directed vertically relative to the surface of the fibrous fleece and crosses the transport direction of the fibrous fleece 1, thereby forcing to flow through the fiber fleece from the top down. The humidity-coated air under the fibrous fleece 1 is continuously drained and further guided to prepare the prereaction (reaction) with the reaction resin. Fresh air from the outside is continuously fed into the drying line 2. The air supply and the drying process provide a precise control of the residual moisture content of fiber fleece 1, which is not more than 8% according to the invention.
Na sl. 2 so alternativno predstavljene druga poleg druge predelovalne stopnje pri uporabi reaktivne umetne smole oz. termoplastične umetne snovi, pri čemer so bistveni elementi za predelavo termoplastične umetne snovi prikazani črtkano desno poleg dejanske risbe.In FIG. 2 are alternatively presented side by side with the second processing step in the use of reactive artificial resin or. thermoplastic plastics, the essential elements for thermoplastic plastics processing being shown dashed to the right next to the actual drawing.
V tej izgotovitveni fazi napršimo predsušeno vlakneno runo la z dvokomponentno reakcijsko smolo oz. staljeno termoplastično umetno smolo vnesemo v vlakneno runo la. Na sl. 3 je shematsko prikazana brizgalna glava 5 z dovodnima priključkoma A in B za dvokomponentno reakcijsko smolo, ki je prednostno poliuretanska smola z mešalnim razmerjem poliol/izocianat 100 : 160 do 100 : 200. Brizgalno glavo 5 vodimo s traverzirnimi gibi v prečni smeri na transportno napravo 3 za vlakneno runo.In this production phase, spray the pre-dried fiber fleece 1a with a two-component reaction resin. The molten thermoplastic artificial resin is introduced into the fiber fleece 1a. In FIG. 3 is a schematic representation of an injection head 5 with feed ports A and B for a two-component reaction resin, which is preferably a polyurethane resin with a mixing ratio of polyol / isocyanate 100: 160 to 100: 200. The injection head 5 is guided by traverse motions in the transverse direction to the transport device. 3 for fiber fleece.
Zgoraj opisano vezivo iz poliuretanske smole z na novo razvito poliester-poliolno zmesjo ima zaradi polarnosti svojih estrskih skupin visoko specifično adhezijo na površini vlaknenega runa in fakultativno vnesljivih ojačevalnih vlaknih 9a (glej sl. 3) kot tudi na nadaljnjih pomožnih snoveh. Usmeritvena receptura v smislu izuma za srednje hiter reakcijski sistem je taka, da pride do naželiranja površine veziva po izstopu reakcijske zmesi iz mešalne komore 5 v okoli 1,5 minutah. Trenutek naželiranja in s tem povečanje viskoznosti veziva je naravnano na izgotovitveni potek, ker je homogena vdelava veziva v vlakneno runo 1 in ovitje ojačevalnih vlaken in/ali pomožnih snovi predpostavka za homogen slojni kompozit. Variiranje izstopne hitrosti (s tlakom v mešalni komori 4) vpliva na intezivnost omočenja posameznih vlaken.The polyurethane resin binder described above with the newly developed polyester-polyol mixture has, due to the polarity of its ester groups, a high specific adhesion on the surface of the fibrous fleece and optional fiber reinforcing fibers 9a (see Fig. 3) as well as on further excipients. The directional formulation of the invention for a medium-speed reaction system is such that the binder surface is desired after leaving the reaction mixture from the mixing chamber 5 in about 1.5 minutes. The moment of glowing, and thus the increase in viscosity of the binder, is directed to the manufacturing process because homogeneous incorporation of the binder into the fiber web 1 and wrapping of reinforcing fibers and / or auxiliaries is a prerequisite for a homogeneous layer composite. Variation of the exit velocity (with pressure in the mixing chamber 4) influences the wetting intensity of the individual fibers.
Zgoraj omenjena preostala vsebnost vlage vlaknenega runa 1 ima v tej fazi postopka odločilen pomen, ker terminalne izocianatne skupine takoj predreagirajo z vlago in spravijo vezivo do penjenja. Med potekom penjenja naraste viskoznost veziva z ireverzibilnim zamreženjem tako, da pri prekoračenju trenutka sposobnosti tečenja ne moremo več doseči vezave vlaken in oprijema pokrivnega sloja. Potek penjenja je važna sestavina poteka omočenja, s tem se pospeši vdor veziva v vlaknene sloje. Vsekakor lahko zaradi previsokih temperatur okolja in vlažnosti vlaken pride predreakcija izven kontrole, kar bi imelo za posledico prezgodnjo vezavo in ne bi bila omogočena homogena povezava vlaknenih slojev.The residual moisture content of Fiber Fleece 1 mentioned above is crucial at this stage of the process, because terminal isocyanate groups immediately react with moisture and bring the binder to foaming. During the foaming process, the viscosity of the binder increases with irreversible crosslinking such that the bonding of the fibers and the adhesion of the coating layer can no longer be achieved when the flowability is exceeded. The foaming process is an important component of the wetting process, thus accelerating the intrusion of the binder into the fiber layers. In any case, due to the high ambient temperatures and the humidity of the fibers, the pre-reaction can be out of control, which would result in premature bonding and would not allow homogeneous bonding of the fiber layers.
Za mešanje in nanašanje v smislu izuma ekzaktno in hitro reagirajoče dvokomponentne vezivne zmesi pridejo za dosego zadostne dozirne točnosti v poštev predvsem visokotlačni strojni sistemi z batnimi črpalkami (dozirno območje okoli 6 g/s do 12 g/s). Traverzirno gibanje brizgalne glave 5 prečno na smer vlaknenega runa je prilagojeno taktnemu času poteka stiskanja. Enake izgotovitvene parametre uporabimo tudi pri ekspandirajočih sistemih epoksidnih smol, ki jih lahko prav tako uporabimo v smislu izuma.For mixing and application according to the invention, the exact and fast-reacting two-component binder mixtures are particularly suitable for achieving high dosing accuracy with high-pressure piston pump machine systems (dosing range of about 6 g / s to 12 g / s). The traverse movement of the injection head 5 transversely to the direction of the fibrous fleece is adjusted to the stroke time of the compression process. The same manufacturing parameters are also used for expanding epoxy resin systems which can also be used in the invention.
Pri uporabi termoplastičnih umetnih snovi kot veziv je treba le-ta uvaljati pri modifikaciji pravkar opisanih stopenj postopka preko (v danem primeru segrevanja sposobnih) valjev 6, 7 in 8. Dodatno pri tem spravimo vlakneno runo 1 kar najbolj ekzaktno na tališče umetne snovi, da dosežemo homogeno omočenje v trenutku nanosa veziva.When using thermoplastic plastics as a binder, the thermoplastic plastics must be rolled up when modifying the process steps just described via rollers 6, 7 and 8, as appropriate (in this case, heating). homogeneous wetting is achieved at the moment of application of the binder.
Postopek v smislu izuma omogoča v tej stopnji kontinuimo pripravo homogenega kompozitnega materiala iz naravnih vlaken. Spenjenje in naželiranje reaktivne umetne smole ali ohlajenje taline umetne snovi povzročijo, da se sprostijo sile krčenja, ki posamezne vlaknene pramene povežejo v profil s homogeno porazdelitvijo vlaken, vendar z različnimi materiali matrice.The process of the invention allows for the continuous preparation of a homogeneous natural fiber composite material at this stage. The clamping and glowing of the reactive resin or the cooling of the melt of the plastic cause the contraction forces to be released, which bind the individual fiber strands to a profile with a homogeneous distribution of fibers, but with different matrix materials.
Nastale sile skrčenja raztegnejo ali orientirajo predhodno organska vlakna in ustvarijo s tem delen prebitek veziva na površini vlaken. Ta prebitek je pri kasnejšem združevanju posameznih vlaknenih slojev potreben za popolno impregniranje. Poleg tega lahko s pomočjo postopka nanašanja veziva, količine in geometričnega orientiranja vlaken optimiramo nadaljnje impregniranje dodatnih vlaken, kot npr. steklenih vlaken 9a. Stopnjo prepojitve oz. globino prepojitve se prav tako da naravnati.The resulting shrinkage forces stretch or orient the previously organic fibers, thereby creating a partial excess of the binder on the fiber surface. This excess is necessary for complete impregnation in the subsequent aggregation of the individual fiber layers. In addition, further impregnation of additional fibers can be optimized by means of the binder deposition process, the amount and the geometric orientation of the fibers. fiberglass 9a. The degree of soaking or The penetration depth can also be adjusted.
Sl. 3 kaže na svoji desni polovici shematsko nanašanje ojačevalnega materiala, v konkretnem primeru v rezalnem orodju (cutter) 9 zdrobljene pramene steklenega rovinga (steklena vlakna) z dolžino vlaken npr. 50 do 70 mm. Vlakna padajo v prostem padu na površino runa iz naravnih vlaken, omočeno z vezivom, v trdnostno optimiranih slojih. Namesto s steklenim rovingom 9a lahko tvorimo ojačitvene sloje tudi z drugimi organskimi in anorganskimi vlakni. Alternativno so uporabna ojačitvena vlakna v predhodno vezani obliki kot vlakneni nosilci, kot npr. v obliki prej, sukancev, filamentnih prej, predilnih niti itd., kot tudi tekstilne tkanine in vlaknene mate.FIG. 3 shows, in its right half, a schematic representation of a reinforcing material, in the specific case in the cutter 9 of a broken strand of glass roving (fiberglass) with a fiber length of e.g. 50 to 70 mm. The fibers fall in free fall to the surface of the binder-coated natural fiber fleece surface in strength-optimized layers. Instead of glass roving 9a, other organic and inorganic fibers can also be reinforced. Alternatively, reinforcing fibers in pre-bonded form are useful as fiber supports, such as e.g. in the form of yarns, threads, filament yarns, spinning threads, etc., as well as textile fabrics and fibrous fabrics.
Pri uporabi cutteija 9 je potrebna natančna prilagoditev rotacijske hitrosti njegovih rezalnih valjev transportni hitrosti nosilnega vlaknenega runa la. Optimalno porazdelitev in število prekrižajočih se ojačevalnih vlaken 9a določimo z relativnim gibanjem padajočih vlaken v prostem padu glede na dolžinsko orientiranje hitrosti vlaknenega runa. V trenutku nalaganja ojačevalnih vlaken 9a na površino la vlaknenega runa prebitek veziva homogeno obda ojačevalna vlakna in morebitne nadaljnje dodatke Bg. Pri predelavi ojačevalnih mat oz. tkanin povežemo z dodatnim uvaljanjem preko valjačnika 11 ojačevalno matrico v ploskovnem kontaktu s površino vlaknenega runa, omočeno z vezivom.The use of cuttei 9 requires precise adjustment of the rotational speed of its cutting rollers to the transport speed of the carrier fiber web la. The optimal distribution and the number of intersecting reinforcing fibers 9a are determined by the relative motion of the falling fibers in free fall relative to the longitudinal orientation of the fiber fleece velocity. At the time of loading of the reinforcing fibers 9a on the surface 1a of the fiber fleece, the excess binder homogeneously surrounds the reinforcing fibers and any further additions of Bg. When processing reinforcement mats or. The fabrics are connected by an additional roll through the roller 11 of the reinforcing matrix in a flat contact with the surface of the fiber fleece moistened with a binder.
Približno istočasno z ojačevalnimi vlakni 9a naneseni dodatki Bg so lahko npr. kroglice iz pihanega stekla, ki jih doziramo preko lija 10. Te kroglice iz pihanega stekla uporabimo zlasti pri poliuretanskih reakcijskih smolah za odzračevanje in preprečevanje zračnih vključkov, ki v laminatu, ki ga je treba končno pripraviti (glej sl. 5), vodijo do pojavov delaminiranja v sistemu ojačevalna matrica/matrica veziva do popolne razpustitve posameznih vlaknenih slojev. Nadalje lahko vključena vlaga pri kasnejšem vplivu tlaka in zvišani temperaturi povzroči visoke parne tlake, ki kasneje pri stiskanju modelov v trenutku odprtja orodja povzročijo, da se posamezni vlakneni sloji razpočijo.At about the same time as the reinforcing fibers 9a, the Bg additives applied may be e.g. Blown glass beads dispensed via funnel 10. These blown glass beads are used in particular for polyurethane reaction resins to vent and prevent the air inclusions that eventually lead to the laminate (see Fig. 5). delamination in the system reinforcement matrix / binder matrix until complete dissolution of the individual fiber layers. Furthermore, the moisture involved in the later impact of pressure and elevated temperature can cause high vapor pressures, which later, when molding, at the moment of tool opening, cause the individual fiber layers to burst.
V smislu izuma predvideno namensko nanašanje dodatkov Bg in natančno pozicioniranje na površini lb vlaknenega runa je odločilnega pomena. To rešimo tako, da preko celotne površine la vlaknenega runa s pomočjo zbiralnega žleba 10 in oscilirajoče luknjane pločevine lOa (velikost in število lukenj sta naravnana na dodatek Bg) te dodatke enakomerno vdelamo v matrico veziva in matrico ojačevalnih vlaken.According to the invention, the intended application of Bg additives and the precise positioning on the surface of lb of fibrous fleece is crucial. This is solved by extending these additives evenly into the binder matrix and the reinforcing fiber matrix over the entire surface of the fiber fleece 1 through the collecting groove 10 and the oscillating hole plate lOa (the size and number of holes are adjusted to Bg).
Nato izvedemo predzgoščevanje preko valjčnika 11, da dosežemo zadostno homogenost. V tej stopnji postopka proizvedemo pri uporabi ekspandirajočih reaktivnih umetnih smol, kot opisane dvokomponentne poliuretanske smole ali ekspandirajoče epoksidne smole, definiran protitlak, tako da orientiramo ekspanzijsko smer veziva glede na strukturo vlaknenega runa in ojačevalno matrico. S tem je trenutek dovoda vlaknenega runa lb k valjčnemu paru 11 odločilen, ker pri nezadostno visoki viskoznosti veziva (čas v lončku, trenutek naželiranja) lahko pride do povezave ojačevalnega materiala 9a in dodatkov Bg z valjčno površino 11. Tudi dodatna preslojitev valjčnih površin 11 ne bi pomagala, ker so adhezijske sile veziva do kovin in umetnih snovi zelo visoke. Previsoka viskoznost, t.j. morebitno izsušenje površine lb veziva, prav tako ni zaželena, ker potem ni več zlepljenja posameznih slojev (glej sl. 4). Podajalna hitrost transportnega traku 3 je zato naravnana na rotacijsko hitrost valjčnega para 11, pri čemer spodnji valj lla ni gnan ločeno, ampak je togo postavljen.Then, pre-thickening is carried out via the roller 11 to achieve sufficient homogeneity. At this stage of the process, a defined backpressure is produced by using expanding reactive artificial resins, such as two-component polyurethane resins or expanding epoxy resins, to orient the expansion direction of the binder with respect to the fiber fleece structure and the reinforcing matrix. In this way, the moment of delivery of fiber fleece lb to the roller pair 11 is crucial, since insufficient viscosity of the binder (time in the crucible, the moment of gluttony) can lead to the connection of the reinforcing material 9a and the accessories Bg with the roller surface 11. Also, additional coating of the roller surfaces 11 does not would help because the adhesive forces of the binder to the metals and plastics are very high. Too high a viscosity, i.e. any drying of the surface of the lb binder is also not desirable, since then there is no longer any bonding of the individual layers (see Fig. 4). The feed speed of conveyor belt 3 is therefore adjusted to the rotational speed of the roller pair 11, with the lower roller lla not driven separately but rigidly positioned.
Na sl. 4 je shematsko predstavljena priprava prirezov iz vlaknenega kompozitnega materiala v smislu izuma in njegova nadaljnja predelava. V tej fazi ločimo kontinuirno preslojeno vlakneno runo lb’ v prireza x, y, podano z vsakokratno obliko surovega nosilnega dela. V transportni smeri zato dosežemo ekzaktno širino odrezka njenega runa. Kot praktična ločilna naprava se je izkazal rezalni sistem 12 z vodnim curkom. Ugodno je, da se pri reaktivnih poliuretanskih sistemih robovi rezov z zreagiranjem veziva z vlago takoj zadelajo, nadalje se s tem pogojeno tudi ne razpustijo prosta ojačevalna in runska vlakna 9a oz. 1 na robovih runa in s tem vodijo do napak materiala.In FIG. 4 is a schematic representation of the preparation of clippings of fibrous composite material according to the invention and its further processing. At this stage, we separate the continuous coated fiber web lb 'into the sections x, y, given by the respective shape of the crude carrier. Therefore, in the transport direction, the exact width of the cut of its fleece is reached. A water-jet cutting system 12 has proven to be a practical separation device. It is advantageous that in the case of reactive polyurethane systems, the edges of the cuts are immediately affected by the reaction of the binder with moisture, and further, the free reinforcing and runic fibers 9a and / or respectively are not conditionally dissolved. 1 at the edges of the runes and thus lead to material defects.
Narez surovega materiala lahko pri tem ločilnem postopku naravnamo na najmanjšo mero. Robovi rezov so neoporečno gladki in čisti brez ostankov prahu. Pri poteku rezanja dobljeno vodo zbiramo preko lovilnega žleba 13, čistimo oz. filtriramo in spet vodimo v krogotok. Potek rezanja je povezan z napredujočim gibanjem in hitrostjo transportnega traku 3, t.j. vodenje glave 12 z rezalnim curkom ima štiri stopnje prostosti.The cutting of the raw material can be minimized in this separation process. The edges of the cuts are immaculately smooth and clean with no residue of dust. In the course of cutting, the obtained water is collected through the catch groove 13, purified or. filtered and again run into a circuit. The cutting course is related to the progressive movement and speed of conveyor belt 3, i.e. running a head 12 with a cutting jet has four degrees of freedom.
V sledeči fazi postopka predkonfekcioniranja izdelamo preslojene in narezane sloje x, y iz vlaknenega runa v večslojne, npr. 3- do 5-slojne, vlaknene kompozitne mate. Na sl. 4 je pri tem shematsko prikazana naprava 14 za skladanje, ki kontinuirno dobavljane odseke x, y vlaknenih run ekzaktno sklada v več slojev. To izgotovitveno stopnjo izvedemo tako, da na mizo s škarjami, ki se da variirati v višino, položimo odrezke x, y vlaknenega runa drugega na drugega in pri dosegu želenega števila slojev s popolnoma zgoraj stisnjenim stiskalnim pehalom 15 kratkotrajno stisnemo drugega na drugega. Valjčni transportni trak 3 transportira mate kot polizdelke v sledečo stopnjo postopka. Tlak stiskanja in zadrževalni čas sta odvisna od želene končne debeline materiala dokončno stisnjenega surovega nosilnega dela (primer: končna debelina surovega nosilca okoli 2 mm zahteva predtlak stiskanja okoli 50 barov in zadrževalni čas 2 s). Tudi tukaj je treba takt prilagoditi celotnemu izgotovitvenemu ritmu.In the next stage of the pre-fabrication process, we fabricate coated and sliced layers x, y from fiber fleece into multilayers, e.g. 3- to 5-layer, fibrous composite mats. In FIG. 4 is a schematic representation of a stacking device 14 that continuously supplies sections x, y of fibrous run exactly in multiple layers. This manufacturing step is carried out by placing pieces of x, y of fibrous fleece on top of each other with height-adjustable scissors and, when reaching the desired number of layers, with a fully pressed compression pedal 15, press each other briefly. Roller conveyor belt 3 transports mats as semi-finished products to the next stage of the process. The compression pressure and holding time depend on the desired final material thickness of the crude support material finally compressed (example: a final crude carrier thickness of about 2 mm requires a compression preload of about 50 bar and a holding time of 2 s). Here, too, the tact must be adjusted to the overall rhythm of the work.
Tlak stiskanja in zadrževalni čas sta važna faktorja za homogeno povezavo posameznih slojev x, y med seboj, ker - prepostavljamo točno pozicioniranje slojev - so lastnosti materiala v znatni meri odvisne od neoporečne prepojitve in povezave vsakokratnih materialnih komponent med seboj. Nepravilnosti lahko vodijo do težkih napak v materialu oz. defektnih mest v gotovem surovem nosilnem delu.Compression pressure and retention time are important factors for the homogeneous bonding of individual layers x, y with each other, because - assuming accurate positioning of the layers - the material properties depend to a large extent on the impregnable penetration and the connection of the respective material components with each other. Inaccuracies can lead to serious material or material defects. defective sites in the finished raw load-bearing part.
Sl. 5 kaže shematsko naknadno zgostitev naslojenih odrezkov x, y vlaknenih run v mato 17 kot polizdelek. Že kot je zgoraj opisano, predstiskane, drug nad drugim zložene runske odseke x, y zgostimo v tej predelovalni stopnji na končno dimenzijo polizdelka. Ta naknadna zgostitev poteče preko valjčnega para 16, ki je izveden ustrezno predzagostitvenemu valjčnemu paru 11 po sl. 3. Poudariti je treba, da si sedaj prizadevamo, da bi dosegli 50 % končne debeline materiala pri gotovem delu, ker sicer ne dosežemo optimalno homogenega zalepljenja vsakokratnih posameznih vlaknenih slojev. S kontinuimim načinom izdelave dobimo tekoč, gospodaren in za okolje prizanesljiv produkcijski proces, ki ga lahko brez problemov integriramo v različne že obstoječe predelovalne postopke za stiskane mase. S tem novim postopkom za pripravo vlaknenih kompozitnih materialov na osnovi run iz naravnih vlaken lahko koncipiramo kar največje avtomatiziranje za produkcijo nosilcev oblog in dušilnih snovi.FIG. 5 shows a schematic post-condensation of layered sections of x, y fibrous run into mat 17 as a semi-finished product. As described above, the pre-pressed, stacked run sections x, y are compacted in this processing stage to the final dimension of the semi-finished product. This subsequent thickening expires via the roller pair 16, which is made according to the pre-thickening roller pair 11 of FIG. 3. It should be emphasized that we are now striving to achieve 50% of the final thickness of the material in the finished work, because otherwise the optimum homogeneous bonding of the respective individual fiber layers is not achieved. Continuous production means a smooth, economical and environmentally friendly production process that can be seamlessly integrated into various pre-existing compression processing processes. With this new process for the preparation of fiber composite materials based on the run of natural fibers, the greatest possible automation can be conceptualized for the production of lining carriers and damping materials.
Sl. 6 kaže končno še odvzem in vložitev kot tudi stiskanje mat 17 kot polizdelkov, pri čemer je shematsko predstavljeno avtomatsko dovajanje mate 17 kot polizdelka preko nasesalnih sistemov 18 ali mehanika prijemal za stiskalni model 19. Alternativno k temu je mogoče, da vmesno priključimo nadaljnje logistično optimirane predporazdelitvene sisteme, da bi lahko v danem primeru istočasno šaržirali več stiskalnic.FIG. 6 shows the final withdrawal and filing as well as the compression of the mat 17 as semi-finished products, with a schematic representation of the automatic feeding of the mat 17 as semi-finished via suction systems 18 or the gripper mechanics for the compression model 19. Alternatively, further logistically optimized interfaces can be provided. pre-distribution systems in order to be able to batch multiple presses in one case at a time.
V predhodnem opisu kot tudi v zahtevkih in priloženi risbi opisane značilnosti izuma so lahko bistvene tako posamič kot tudi v poljubni kombinaciji za uresničitev izuma v njegovih različnih izvedbenih oblikah.In the foregoing description, as well as in the claims and the accompanying drawing, the characteristics of the invention described may be essential both individually and in any combination for the realization of the invention in its various embodiments.
ZaFor
EMPE-WERKE Ernst Pelz GmbH & Co.KG:EMPE-WERKE Ernst Pelz GmbH & Co.KG:
Claims (51)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4127905 | 1991-08-22 | ||
| DE4139226A DE4139226A1 (en) | 1991-08-22 | 1991-11-23 | FIBER COMPOSITE MATERIAL ON THE BASIS OF NATURAL FIBER PLANTS AND A METHOD FOR THE CONTINUOUS PRODUCTION AND FURTHER PROCESSING OF COMPRESSED PARTS |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SI9200184A true SI9200184A (en) | 1993-03-31 |
Family
ID=25906630
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SI929200184A SI9200184A (en) | 1991-08-22 | 1992-08-21 | Composite fibre material based on natural fibre webs and process for its production and further processing into extruded mouldings |
Country Status (3)
| Country | Link |
|---|---|
| DE (1) | DE4139226A1 (en) |
| SI (1) | SI9200184A (en) |
| WO (1) | WO1993004226A1 (en) |
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| DE4308959C2 (en) * | 1992-07-09 | 1996-05-02 | Dierig Holding Ag | Use of a nonwoven made from natural materials |
| DE4321225A1 (en) * | 1993-06-25 | 1995-01-05 | Pelz Ernst Empe Werke | Panelling part for motor vehicles and process for its production |
| DE19500090A1 (en) * | 1994-01-29 | 1995-08-03 | Christiane Karawidas | Decorating material for room covering or furniture |
| DE4411010A1 (en) * | 1994-03-30 | 1994-08-18 | Thueringisches Inst Textil | Needle web for use as reinforcing material in natural fibre composites |
| DE4424328A1 (en) * | 1994-07-11 | 1996-01-18 | Burlefinger Roland | Building insulation material |
| AU675143B2 (en) * | 1994-08-08 | 1997-01-23 | Empe-Werke Ernst Pelz Gmbh & Co. Kg | A lining part for motor vehicles and a method for its production |
| DE4436981A1 (en) * | 1994-10-06 | 1996-04-11 | Hartmut Faerber | Lightweight moulded thermal insulation made from renewable resources |
| TR28260A (en) * | 1994-11-25 | 1996-04-24 | Pelz Ernst Empe Werke | The internal coating element for motor vehicles and the method for its production. |
| WO1996037355A1 (en) * | 1995-05-21 | 1996-11-28 | Möller Plast GmbH | Composite component, especially a composite cladding component, and process for its production |
| DE19712463A1 (en) * | 1997-03-25 | 1998-10-01 | Empe Findlay Ind Gmbh | Process for impregnating flat fiber structures with reactive multi-component systems |
| DE19859924C2 (en) * | 1998-12-23 | 2003-02-13 | Brocke Kg I B S | Process for producing a molded part |
| DE19939227B4 (en) * | 1999-08-18 | 2004-07-29 | Möller Plast GmbH | Composite material |
| DE10151357B4 (en) * | 2001-10-22 | 2006-12-28 | Deutsches Zentrum für Luft- und Raumfahrt e.V. | Fiber composite molding, intermediate and method for producing a fiber composite molding |
| DE10350943B4 (en) | 2002-11-02 | 2019-06-06 | Toyota Boshoku Kabushiki Kaisha | Composite with natural fibers and process for its preparation |
| FR2861081B1 (en) * | 2003-10-17 | 2007-01-05 | Arkema | COMPOSITION FORMED FROM MATERIALS OF VEGETABLE ORIGIN AND POLYMERS |
| DE102004024249B4 (en) * | 2004-05-11 | 2006-12-07 | Igv Institut Für Getreideverarbeitung Gmbh | Shaped soundproofing material and method for its production |
| DE102009024786A1 (en) | 2009-06-10 | 2010-12-16 | Daimler Ag | Producing fiber-reinforced plastic component, comprises heating, pressing and hardening layer of fiber foil in deforming press, where fiber foil is produced by mixing and dispersing hardenable reaction resin as plastic matrix in water |
| DE102009059975A1 (en) * | 2009-12-22 | 2011-06-30 | Sitech Sitztechnik GmbH, 38442 | Seat structure, particularly seat part or seat back of individual single or rear seat system for vehicle, has carrier part that is made of light-weight material and is formed as base body |
| DE202016002946U1 (en) * | 2016-05-03 | 2017-08-04 | Spengler Technology GmbH | Composite material |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2544019A (en) * | 1944-11-13 | 1951-03-06 | Wood Conversion Co | Manufacture of plastic-fiber composition |
| DE1504302A1 (en) * | 1963-12-06 | 1969-04-03 | Gluck Martin James | Mat-like material for the production of molded parts |
| US3335827A (en) * | 1964-11-17 | 1967-08-15 | Pellon Corp | Shaped articles and method of producing same |
| SE7707806L (en) * | 1976-07-06 | 1978-01-07 | Rochette Cenpa | SHEET FIBER MATERIAL AND USE THEREOF |
| DE2830320C3 (en) * | 1978-07-10 | 1981-07-02 | Ernst 8192 Geretsried Pelz | Process for the production of molded parts from nonwovens |
| DE2845112C3 (en) * | 1978-10-17 | 1981-11-05 | Casimir Kast Gmbh & Co Kg, 7562 Gernsbach | Process and plant for the production of mats from cellulosic fibers and process for the production of molded parts from these |
| GB2102037B (en) * | 1981-04-28 | 1984-11-28 | Tay Textiles Ltd | Jute reinforcement of plastics materials |
| EP0089975A1 (en) * | 1981-10-05 | 1983-10-05 | Tay Textiles Limited | Jute reinforcement of plastics materials |
| DE3150906C2 (en) * | 1981-12-22 | 1984-03-08 | Ernst 8192 Geretsried Pelz | Process for the production of molded parts from coconut, cotton or jute fiber fleece mats containing polyester resin |
| IT1157112B (en) * | 1982-12-03 | 1987-02-11 | Firab Spa Fabbrica Italiana Ri | MONOSTRATIFIED FIBROUS MATERIAL PARTICULARLY FOR PANELS FOR AUTOMOTIVE USE AND ITS MANUFACTURING PROCEDURE |
| US4580960A (en) * | 1983-10-04 | 1986-04-08 | Feber Search Partnership | Apparatus for making laminated lignocellulose fiber mats |
| FR2561577B1 (en) * | 1984-03-20 | 1986-09-12 | Isoroy Sa | MOLDABLE FIBROUS MATTRESS AND MANUFACTURING METHOD THEREOF |
| AT387798B (en) * | 1987-12-11 | 1989-03-10 | Kuehnsdorfer Gmbh | METHOD FOR PRODUCING A STORAGEABLE, HANDLABLE FIBER MAT, AND FIBER MAT MADE BY THE PROCESS |
| DE3820511A1 (en) * | 1988-06-16 | 1990-02-08 | Koelzer Klaus Kurt | REINFORCEMENT MATERIAL FOR DUROPLASTE |
| US5074959A (en) * | 1989-02-10 | 1991-12-24 | Ajinomoto Company, Inc. | Complex of fibers and fungi and a process for preparation thereof |
| GR1000831B (en) * | 1989-07-21 | 1993-01-25 | Demetrio Leone | Absorbing fibrous bezoar |
| DE3936011A1 (en) * | 1989-10-28 | 1991-05-02 | B & J Vliesstoff Gmbh | Packaging material - made of natural (waste9 fibre mats with corrugations |
| FR2657364B1 (en) * | 1990-01-23 | 1994-05-27 | Isoroy Sa | BIODEGRADABLE FIBROUS MATTRESS FOR AGRICULTURAL AND HORTICULTURAL USE. |
-
1991
- 1991-11-23 DE DE4139226A patent/DE4139226A1/en active Pending
-
1992
- 1992-08-21 SI SI929200184A patent/SI9200184A/en unknown
- 1992-08-21 WO PCT/DE1992/000709 patent/WO1993004226A1/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| DE4139226A1 (en) | 1993-03-11 |
| WO1993004226A1 (en) | 1993-03-04 |
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