SG96561A1 - Low-sulfur reforming processes - Google Patents
Low-sulfur reforming processesInfo
- Publication number
- SG96561A1 SG96561A1 SG200004098A SG4098A SG96561A1 SG 96561 A1 SG96561 A1 SG 96561A1 SG 200004098 A SG200004098 A SG 200004098A SG 4098 A SG4098 A SG 4098A SG 96561 A1 SG96561 A1 SG 96561A1
- Authority
- SG
- Singapore
- Prior art keywords
- hydrocarbons
- reactor system
- reforming
- sulfur
- reactors
- Prior art date
Links
- 238000002407 reforming Methods 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 4
- 229910052717 sulfur Inorganic materials 0.000 title abstract 4
- 239000011593 sulfur Substances 0.000 title abstract 4
- 229930195733 hydrocarbon Natural products 0.000 abstract 5
- 150000002430 hydrocarbons Chemical class 0.000 abstract 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 3
- 229910021536 Zeolite Inorganic materials 0.000 abstract 1
- 238000001833 catalytic reforming Methods 0.000 abstract 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 1
- 238000010410 dusting Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 239000010457 zeolite Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G35/00—Reforming naphtha
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G35/00—Reforming naphtha
- C10G35/04—Catalytic reforming
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G35/00—Reforming naphtha
- C10G35/04—Catalytic reforming
- C10G35/06—Catalytic reforming characterised by the catalyst used
- C10G35/095—Catalytic reforming characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Paints Or Removers (AREA)
- Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Abstract
There is disclosed a catalytic reforming method in which hydrocarbons are treated in a reactor system to produce an aromatics enriched product, said reactor system comprising: (a) a series of reactors (10,20,30), containing a catalyst bed comprising a sulfur sensitive zeolite reforming catalyst, and each being associated with (b) a respective furnace (11,21,31) each comprising a plurality of furnace tubes for heating hydrocarbons to an elevated temperature in the range of from 850 to 1025 F suitable for reforming, (c) a heat exchanger (12); and (d) a separator (13) for separating an aromatics enriched product from effluent gas; said method comprising passing hydrocarbons through said reactor system to contact the hydrocarbons with the reforming catalyst in said reactors and separating said aromatics enriched product from said effluent gas; wherein: (i) hydrocarbons are reformed in each of said reactors under low sulfur reforming conditions of less than 50ppb sulfur; and (ii) at least the furnace tubes of the reactor system are protected from carburization and metal dusting. Apparatus for carrying out the process is also described. <IMAGE>
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US66669691A | 1991-03-08 | 1991-03-08 | |
| US80282191A | 1991-12-06 | 1991-12-06 | |
| US80306391A | 1991-12-06 | 1991-12-06 | |
| US80321591A | 1991-12-06 | 1991-12-06 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SG96561A1 true SG96561A1 (en) | 2003-06-16 |
Family
ID=27505330
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SG200004098A SG96561A1 (en) | 1991-03-08 | 1992-03-06 | Low-sulfur reforming processes |
| SG1996009668A SG72690A1 (en) | 1991-03-08 | 1992-03-06 | Low-sulfur reforming process |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SG1996009668A SG72690A1 (en) | 1991-03-08 | 1992-03-06 | Low-sulfur reforming process |
Country Status (16)
| Country | Link |
|---|---|
| EP (3) | EP0798363B1 (en) |
| JP (1) | JP3836499B2 (en) |
| KR (1) | KR100230727B1 (en) |
| CN (1) | CN1039720C (en) |
| AT (1) | ATE159040T1 (en) |
| AU (1) | AU665534B2 (en) |
| BR (1) | BR9205738A (en) |
| DE (3) | DE69233084T2 (en) |
| ES (3) | ES2190551T3 (en) |
| HU (1) | HUT75107A (en) |
| MY (1) | MY109992A (en) |
| NO (1) | NO933165D0 (en) |
| OA (1) | OA09910A (en) |
| SA (1) | SA92130085B1 (en) |
| SG (2) | SG96561A1 (en) |
| WO (1) | WO1992015653A1 (en) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5405525A (en) * | 1993-01-04 | 1995-04-11 | Chevron Research And Technology Company | Treating and desulfiding sulfided steels in low-sulfur reforming processes |
| AU6161094A (en) * | 1993-01-04 | 1994-08-15 | Chevron Chemical Company | Hydrodealkylation processes |
| US5413700A (en) * | 1993-01-04 | 1995-05-09 | Chevron Research And Technology Company | Treating oxidized steels in low-sulfur reforming processes |
| US5575902A (en) * | 1994-01-04 | 1996-11-19 | Chevron Chemical Company | Cracking processes |
| US5658452A (en) * | 1994-01-04 | 1997-08-19 | Chevron Chemical Company | Increasing production in hydrocarbon conversion processes |
| US5516421A (en) * | 1994-08-17 | 1996-05-14 | Brown; Warren E. | Sulfur removal |
| US5565087A (en) * | 1995-03-23 | 1996-10-15 | Phillips Petroleum Company | Method for providing a tube having coke formation and carbon monoxide inhibiting properties when used for the thermal cracking of hydrocarbons |
| MX9700849A (en) * | 1995-06-07 | 1997-08-30 | Chevron Chem Co | Using hydrocarbon streams to prepare a metallic protective layer . |
| AU6846096A (en) * | 1995-08-18 | 1997-03-12 | Chevron Chemical Company Llc | Diffusion barriers for preventing high temperature hydrogen attack |
| US6497809B1 (en) * | 1995-10-25 | 2002-12-24 | Phillips Petroleum Company | Method for prolonging the effectiveness of a pyrolytic cracking tube treated for the inhibition of coke formation during cracking |
| WO1997028235A1 (en) * | 1996-02-02 | 1997-08-07 | Chevron Chemical Company Llc | Hydrocarbon processing in equipment having increased halide stress-corrosion cracking resistance |
| CN1043782C (en) * | 1996-03-21 | 1999-06-23 | 中国石油化工总公司 | Gasoline octane number-raising catalytic conversion method |
| US5914028A (en) * | 1997-01-10 | 1999-06-22 | Chevron Chemical Company | Reforming process with catalyst pretreatment |
| US5879538A (en) * | 1997-12-22 | 1999-03-09 | Chevron Chemical Company | Zeolite L catalyst in conventional furnace |
| US6120926A (en) * | 1998-11-10 | 2000-09-19 | International Fuel Cells, Llc | Inhibition of carbon deposition on fuel gas steam reformer walls |
| US6258330B1 (en) * | 1998-11-10 | 2001-07-10 | International Fuel Cells, Llc | Inhibition of carbon deposition on fuel gas steam reformer walls |
| WO2002000546A1 (en) * | 2000-06-28 | 2002-01-03 | Sanyo Electric Co., Ltd. | Fuel reforming reactor and method for manufacture thereof |
| CN1394981A (en) * | 2001-07-09 | 2003-02-05 | 李兰根 | Atmosphere heat treatment adjuvant and its application method |
| RU2292403C2 (en) * | 2002-07-09 | 2007-01-27 | Ланген ЛИ | Cocatalyst for heat treatment of atmosphere and method of its application, method of heat treatment and atmosphere for heat treatment with such cocatalyst |
| EP2910624B1 (en) * | 2007-10-31 | 2016-11-23 | China Petroleum & Chemical Corporation | Passivation process for a continuous reforming apparatus during the initial reaction |
| DE202009005950U1 (en) | 2009-04-27 | 2009-08-20 | Holland-Letz, Peter | Tissue for body cover for the application of medicines |
| US20120277500A1 (en) * | 2011-04-29 | 2012-11-01 | Uop Llc | High Temperature Platforming Process |
| US20120277511A1 (en) * | 2011-04-29 | 2012-11-01 | Uop Llc | High Temperature Platformer |
| CN102898265B (en) * | 2011-07-29 | 2014-08-06 | 中国石油化工股份有限公司 | Method for producing olefin |
| ES2549704B1 (en) * | 2014-04-30 | 2016-09-08 | Abengoa Hidrógeno, S.A. | Water vapor reforming reactor tube |
| EP3336055B1 (en) | 2016-12-19 | 2019-05-22 | L'air Liquide, Société Anonyme Pour L'Étude Et L'exploitation Des Procédés Georges Claude | Corrosion protected reformer tube with internal heat exchanger |
| CN115463662B (en) * | 2022-10-08 | 2023-06-02 | 中国矿业大学 | Preparation of supported intermetallic compound catalyst and application of supported intermetallic compound catalyst in hydrodeoxygenation of lignin-derived phenolic compounds |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4447316A (en) * | 1982-02-01 | 1984-05-08 | Chevron Research Company | Composition and a method for its use in dehydrocyclization of alkanes |
| US4634515A (en) * | 1985-10-25 | 1987-01-06 | Exxon Research And Engineering Company | Nickel adsorbent for sulfur removal from hydrocarbon feeds |
| US4692234A (en) * | 1986-04-09 | 1987-09-08 | Phillips Petroleum Company | Antifoulants for thermal cracking processes |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1149163A (en) * | 1966-03-22 | 1969-04-16 | Ici Ltd | Protection against carburisation |
| GB1362374A (en) * | 1970-06-17 | 1974-08-07 | Wisniewski L | Method of and composition for anti-corrosive protection by reduc tion of ionised metals on metal substrate |
| CH556396A (en) * | 1971-11-03 | 1974-11-29 | Buechler Josef Heinrich | Forming corrosion-preventing coatings on metals - by thermally decomposing paint contg. metal pigment and binder |
| US4348271A (en) * | 1981-07-14 | 1982-09-07 | Exxon Research & Engineering Co. | Catalytic reforming process |
| US4456527A (en) * | 1982-10-20 | 1984-06-26 | Chevron Research Company | Hydrocarbon conversion process |
| JPS62256946A (en) * | 1986-04-30 | 1987-11-09 | Nippon Kokan Kk <Nkk> | Cr-Mo steel with excellent creep embrittlement resistance and cold cracking resistance |
| FR2600668B1 (en) * | 1986-06-25 | 1989-05-19 | Inst Francais Du Petrole | CATALYTIC REFORMING PROCESS THROUGH AT LEAST TWO CATALYST BEDS |
-
1992
- 1992-03-06 EP EP97110024A patent/EP0798363B1/en not_active Expired - Lifetime
- 1992-03-06 DE DE69233084T patent/DE69233084T2/en not_active Expired - Lifetime
- 1992-03-06 AU AU15801/92A patent/AU665534B2/en not_active Ceased
- 1992-03-06 ES ES98100396T patent/ES2190551T3/en not_active Expired - Lifetime
- 1992-03-06 SG SG200004098A patent/SG96561A1/en unknown
- 1992-03-06 DE DE69232891T patent/DE69232891T2/en not_active Expired - Lifetime
- 1992-03-06 JP JP50830092A patent/JP3836499B2/en not_active Expired - Fee Related
- 1992-03-06 AT AT92908806T patent/ATE159040T1/en not_active IP Right Cessation
- 1992-03-06 ES ES97110024T patent/ES2201223T3/en not_active Expired - Lifetime
- 1992-03-06 BR BR9205738A patent/BR9205738A/en not_active IP Right Cessation
- 1992-03-06 EP EP98100396A patent/EP0845521B1/en not_active Expired - Lifetime
- 1992-03-06 WO PCT/US1992/001856 patent/WO1992015653A1/en not_active Ceased
- 1992-03-06 SG SG1996009668A patent/SG72690A1/en unknown
- 1992-03-06 HU HU9302543A patent/HUT75107A/en unknown
- 1992-03-06 ES ES92908806T patent/ES2108112T3/en not_active Expired - Lifetime
- 1992-03-06 KR KR1019930702697A patent/KR100230727B1/en not_active Expired - Fee Related
- 1992-03-06 EP EP92908806A patent/EP0576571B1/en not_active Expired - Lifetime
- 1992-03-06 DE DE69222633T patent/DE69222633T2/en not_active Expired - Lifetime
- 1992-03-07 MY MYPI92000372A patent/MY109992A/en unknown
- 1992-03-07 CN CN92102539A patent/CN1039720C/en not_active Expired - Fee Related
- 1992-09-05 SA SA92130085A patent/SA92130085B1/en unknown
-
1993
- 1993-09-06 OA OA60409A patent/OA09910A/en unknown
- 1993-09-06 NO NO933165A patent/NO933165D0/en unknown
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4447316A (en) * | 1982-02-01 | 1984-05-08 | Chevron Research Company | Composition and a method for its use in dehydrocyclization of alkanes |
| US4634515A (en) * | 1985-10-25 | 1987-01-06 | Exxon Research And Engineering Company | Nickel adsorbent for sulfur removal from hydrocarbon feeds |
| US4692234A (en) * | 1986-04-09 | 1987-09-08 | Phillips Petroleum Company | Antifoulants for thermal cracking processes |
Also Published As
| Publication number | Publication date |
|---|---|
| DE69232891D1 (en) | 2003-02-13 |
| SA92130085B1 (en) | 2006-04-22 |
| HUT75107A (en) | 1997-04-28 |
| EP0576571B1 (en) | 1997-10-08 |
| DE69232891T2 (en) | 2003-11-06 |
| OA09910A (en) | 1994-09-15 |
| AU1580192A (en) | 1992-10-06 |
| HU9302543D0 (en) | 1993-12-28 |
| ATE159040T1 (en) | 1997-10-15 |
| JP3836499B2 (en) | 2006-10-25 |
| DE69233084D1 (en) | 2003-07-03 |
| EP0576571A1 (en) | 1994-01-05 |
| WO1992015653A1 (en) | 1992-09-17 |
| CN1067258A (en) | 1992-12-23 |
| ES2201223T3 (en) | 2004-03-16 |
| ES2190551T3 (en) | 2003-08-01 |
| NO933165D0 (en) | 1993-09-06 |
| DE69222633D1 (en) | 1997-11-13 |
| DE69222633T2 (en) | 1998-04-23 |
| SG72690A1 (en) | 2000-05-23 |
| EP0798363A2 (en) | 1997-10-01 |
| JPH06507191A (en) | 1994-08-11 |
| EP0798363A3 (en) | 1998-03-11 |
| DE69233084T2 (en) | 2004-01-29 |
| KR100230727B1 (en) | 1999-11-15 |
| EP0576571A4 (en) | 1994-03-23 |
| EP0845521B1 (en) | 2003-01-08 |
| ES2108112T3 (en) | 1997-12-16 |
| EP0798363B1 (en) | 2003-05-28 |
| BR9205738A (en) | 1994-08-23 |
| EP0845521A1 (en) | 1998-06-03 |
| CN1039720C (en) | 1998-09-09 |
| AU665534B2 (en) | 1996-01-11 |
| MY109992A (en) | 1997-10-31 |
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