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SG11202000684XA - A method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst - Google Patents

A method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst

Info

Publication number
SG11202000684XA
SG11202000684XA SG11202000684XA SG11202000684XA SG11202000684XA SG 11202000684X A SG11202000684X A SG 11202000684XA SG 11202000684X A SG11202000684X A SG 11202000684XA SG 11202000684X A SG11202000684X A SG 11202000684XA SG 11202000684X A SG11202000684X A SG 11202000684XA
Authority
SG
Singapore
Prior art keywords
production
methyl methacrylate
heterogeneous catalyst
oxidative esterification
esterification
Prior art date
Application number
SG11202000684XA
Other languages
English (en)
Inventor
Dmitri A Kraptchetov
Kirk W Limbach
Daniel A Hickman
Andrew Heitsch
Victor J Sussman
Wen-Sheng Lee
Ramzy Shayib
Original Assignee
Rohm & Haas
Dow Global Technologies Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rohm & Haas, Dow Global Technologies Llc filed Critical Rohm & Haas
Publication of SG11202000684XA publication Critical patent/SG11202000684XA/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/39Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04Alumina
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44Palladium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48Silver or gold
    • B01J23/52Gold
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391Physical properties of the active metal ingredient
    • B01J35/394Metal dispersion value, e.g. percentage or fraction
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396Distribution of the active metal ingredient
    • B01J35/397Egg shell like
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396Distribution of the active metal ingredient
    • B01J35/399Distribution of the active metal ingredient homogeneously throughout the support particle
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/40Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • B01J8/067Heating or cooling the reactor
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/39Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester
    • C07C67/40Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester by oxidation of primary alcohols
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • C07C69/54Acrylic acid esters; Methacrylic acid esters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Dispersion Chemistry (AREA)
SG11202000684XA 2017-07-28 2018-06-25 A method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst SG11202000684XA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201762538261P 2017-07-28 2017-07-28
PCT/US2018/039228 WO2019022883A1 (fr) 2017-07-28 2018-06-25 Procédé de production de méthacrylate de méthyle par estérification oxydative à l'aide d'un catalyseur hétérogène

Publications (1)

Publication Number Publication Date
SG11202000684XA true SG11202000684XA (en) 2020-02-27

Family

ID=63047424

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11202000684XA SG11202000684XA (en) 2017-07-28 2018-06-25 A method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst

Country Status (9)

Country Link
US (1) US10829434B2 (fr)
EP (1) EP3658535B1 (fr)
JP (1) JP7189929B2 (fr)
KR (1) KR102639243B1 (fr)
CN (1) CN110997617A (fr)
CA (1) CA3071183A1 (fr)
SA (1) SA520411160B1 (fr)
SG (1) SG11202000684XA (fr)
WO (1) WO2019022883A1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MX2022016238A (es) * 2020-07-14 2023-02-02 Dow Global Technologies Llc Proceso y catalizador para esterificacion oxidante con catalizador mecanicamente fuerte y quimicamente resistente.

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2025992B2 (de) * 1969-06-20 1973-03-01 Verfahren zur herstellung von estern alpha,beta-olefinisch ungesaettigter aliphatischer carbonsaeuren
GB2008430B (en) 1977-11-17 1982-04-28 Asahi Chemical Ind Process for producing carboxylic esters
DE3018071C2 (de) 1979-05-17 1985-06-05 Asahi Kasei Kogyo K.K., Osaka Verfahren zur Herstellung von Carbonsäureestern
DE3306907A1 (de) 1983-02-26 1984-08-30 Basf Ag, 6700 Ludwigshafen Katalysator und seine verwendung zur herstellung von methylmethacrylat
DE69632788T2 (de) 1995-07-18 2005-07-14 Asahi Kasei Chemicals Corp. Katalysator zur herstellung von carbonsäureestern
TW377306B (en) 1996-12-16 1999-12-21 Asahi Chemical Ind Noble metal support
SG71815A1 (en) 1997-07-08 2000-04-18 Asahi Chemical Ind Method of producing methyl methacrylate
US7326806B2 (en) 2001-06-04 2008-02-05 Nippon Shokubai Co., Ltd. Catalyst for the preparation of carboxylic esters and method for producing carboxylic esters
MY139387A (en) 2004-11-17 2009-09-30 Asahi Kasei Chemicals Corp Oxidation catalyst and oxidation method
CN1931824A (zh) 2006-09-18 2007-03-21 鲁东大学 一种由不饱和醛连续制备不饱和羧酸酯的方法及催化剂
WO2009022544A1 (fr) 2007-08-13 2009-02-19 Asahi Kasei Chemicals Corporation Catalyseur pour la production d'ester d'acide carboxylique, son procédé de fabrication et procédé de fabrication d'ester d'acide carboxylique
MY151251A (en) * 2007-10-26 2014-04-30 Asahi Kasei Chemicals Corp Supported composite particle material, production process of same and process for producing compounds using supported composite particle material as catalyst for chemical synthesis
GB201102502D0 (en) 2011-02-14 2011-03-30 Johnson Matthey Plc Catalysts for use in reforming processes
GB201111819D0 (en) * 2011-07-11 2011-08-24 Johnson Matthey Plc Catalyst and method for its preparation
US9890105B2 (en) * 2013-04-19 2018-02-13 Evonik Roehm Gmbh Method for producing methylmethacrylate
TW201509900A (zh) * 2013-07-29 2015-03-16 Rohm & Haas 氧化酯化方法
EP2886528A1 (fr) 2013-12-20 2015-06-24 Evonik Industries AG Procédé de fabrication d'esters non saturés à partir d'aldéhydes par estérisation oxydative directe
EP2886529A1 (fr) 2013-12-20 2015-06-24 Evonik Industries AG Procédé de production de méthacrylate de méthyle
EP3170558A1 (fr) 2015-11-19 2017-05-24 Evonik Röhm GmbH Catalyseur pour l'esterification oxydative d'aldehydes en esters d'acide carbonique

Also Published As

Publication number Publication date
WO2019022883A1 (fr) 2019-01-31
CN110997617A (zh) 2020-04-10
JP7189929B2 (ja) 2022-12-14
BR112020001620A2 (pt) 2020-07-21
KR20200032129A (ko) 2020-03-25
KR102639243B1 (ko) 2024-02-21
EP3658535A1 (fr) 2020-06-03
JP2020528425A (ja) 2020-09-24
SA520411160B1 (ar) 2024-04-01
US10829434B2 (en) 2020-11-10
EP3658535B1 (fr) 2024-03-20
US20200165185A1 (en) 2020-05-28
CA3071183A1 (fr) 2019-01-31

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