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SE9704086L - UV absorbers of benzotriazoles with improved stability - Google Patents

UV absorbers of benzotriazoles with improved stability

Info

Publication number
SE9704086L
SE9704086L SE9704086A SE9704086A SE9704086L SE 9704086 L SE9704086 L SE 9704086L SE 9704086 A SE9704086 A SE 9704086A SE 9704086 A SE9704086 A SE 9704086A SE 9704086 L SE9704086 L SE 9704086L
Authority
SE
Sweden
Prior art keywords
resins
acrylic
melamine
benzotriazoles
absorbers
Prior art date
Application number
SE9704086A
Other languages
Swedish (sv)
Other versions
SE522379C2 (en
SE9704086D0 (en
Inventor
Ramanathan Ravichandran
Anthony David Debellis
Revathi Iyengar
Joseph Suhadolnik
Jean-Pierre Wolf
Robert Edward Detlefsen
Mervin Gale Wood
Original Assignee
Ciba Geigy Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Geigy Ag filed Critical Ciba Geigy Ag
Publication of SE9704086D0 publication Critical patent/SE9704086D0/en
Publication of SE9704086L publication Critical patent/SE9704086L/en
Publication of SE522379C2 publication Critical patent/SE522379C2/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3472—Five-membered rings
    • C08K5/3475—Five-membered rings condensed with carbocyclic rings
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/32—Radiation-absorbing paints
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
    • C07D249/16—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms condensed with carbocyclic rings or ring systems
    • C07D249/18—Benzotriazoles
    • C07D249/20—Benzotriazoles with aryl radicals directly attached in position 2
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6515—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having three nitrogen atoms as the only ring hetero atoms
    • C07F9/6518—Five-membered rings
    • C07F9/65188—Five-membered rings condensed with carbocyclic rings or carbocyclic ring systems
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3472—Five-membered rings
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
    • C09D161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C09D161/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
    • C09D161/28—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with melamine
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/48—Stabilisers against degradation by oxygen, light or heat

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Molecular Biology (AREA)
  • General Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)
  • Hydrogenated Pyridines (AREA)
  • Laminated Bodies (AREA)

Abstract

Benzotriazole UV absorbers which are substituted at the 5-position of the benzo ring by an electron withdrawing group exhibit enhanced durability and very low loss rates when incorporated into automotive coatings. Some of the benzotriazoles are new and may be incorporated into any organic material, as stabilizers. The coating compositions are based on thermoset acrylic melamine resins, acrylic urethane resins, epoxy carboxy resins, silane modified acrylic melamine resins, acrylic resins with carbamate pendant groups crosslinked with melamine or acrylic polyol resins crosslinked with melamine containing carbamate groups.
SE9704086A 1996-11-07 1997-11-07 UV absorbers of benzotriazoles with improved stability SE522379C2 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US74514696A 1996-11-07 1996-11-07

Publications (3)

Publication Number Publication Date
SE9704086D0 SE9704086D0 (en) 1997-11-07
SE9704086L true SE9704086L (en) 1998-05-08
SE522379C2 SE522379C2 (en) 2004-02-03

Family

ID=24995448

Family Applications (1)

Application Number Title Priority Date Filing Date
SE9704086A SE522379C2 (en) 1996-11-07 1997-11-07 UV absorbers of benzotriazoles with improved stability

Country Status (20)

Country Link
JP (1) JP4126364B2 (en)
KR (1) KR100488744B1 (en)
CN (1) CN1091127C (en)
AT (1) AT407642B (en)
AU (1) AU727301B2 (en)
BE (1) BE1011537A3 (en)
BR (1) BR9705437A (en)
CA (1) CA2220269A1 (en)
CH (1) CH693032A5 (en)
DE (1) DE19748658B4 (en)
DK (1) DK126697A (en)
ES (1) ES2134158B1 (en)
FR (1) FR2755444B1 (en)
GB (1) GB2319035B (en)
IT (1) IT1298471B1 (en)
NL (1) NL1007470C2 (en)
NO (1) NO975104L (en)
SE (1) SE522379C2 (en)
SG (1) SG71056A1 (en)
TW (1) TW467932B (en)

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EP1232148B1 (en) * 1999-11-16 2005-05-04 Ciba SC Holding AG Use of benzotriazole uv absorbers
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US6489486B2 (en) * 2000-02-21 2002-12-03 Roche Vitamins Inc. 2-hydroxyphenyl benzotriazoles as UV-A/B filters
US6566507B2 (en) 2000-08-03 2003-05-20 Ciba Specialty Chemicals Corporation Processes for the preparation of benzotriazole UV absorbers
US6353113B1 (en) 2000-08-03 2002-03-05 Ciba Specialty Chemicals Corporation Process for the preparation of 5-perfluoroalkyl substituted benzotriazole UV absorbers
MXPA03004655A (en) * 2000-11-27 2003-09-04 Ciba Sc Holding Ag Substituted 5-aryl and 5-heteroaryl-2-(2-hydroxyphenyl)-2h-benzotriazole derivatives as uv absorbers.
US6649770B1 (en) * 2000-11-27 2003-11-18 Ciba Specialty Chemicals Corporation Substituted 5-aryl-2-(2-hydroxyphenyl)-2H-benzotriazole UV absorbers, compositions stabilized therewith and process for preparation thereof
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JP5244437B2 (en) 2008-03-31 2013-07-24 富士フイルム株式会社 UV absorber composition
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CN102050823A (en) * 2010-10-27 2011-05-11 华东理工大学 Synthesis and representation of guanine analogue as novel light stabilizer
US9808675B2 (en) 2012-09-13 2017-11-07 Acushnet Company Golf ball compositions
US9227109B2 (en) * 2012-09-13 2016-01-05 Acushnet Company Golf ball compositions
JP6430964B2 (en) 2013-12-09 2018-11-28 株式会社Adeka Substrate with improved paintability
TWI483987B (en) * 2014-03-10 2015-05-11 Sino Japan Chemical Co Ltd Liquid reaction type ultraviolet absorber and manufacturing method and application thereof
CN111808320B (en) * 2014-08-05 2023-02-28 三吉油脂株式会社 Additive for imparting ultraviolet absorbing ability and/or high refractive index to substrate, and resin member using same
CN104327002A (en) * 2014-09-16 2015-02-04 德州宏坤医药中间体有限公司 Producing technology of benzotriazole-typed ultraviolet absorber
WO2016174788A1 (en) * 2015-04-30 2016-11-03 東海光学株式会社 Plastic lens
CN106316970A (en) * 2016-08-11 2017-01-11 重庆大学 Bis-benzotriazole containing organic dyestuff with super thermal stability
US10035043B2 (en) 2016-12-15 2018-07-31 Acushnet Company Golf ball incorporating highly crosslinked thermoset fluorescent microspheres and methods of making same
US10252112B2 (en) 2017-03-20 2019-04-09 Acushnet Company Golf ball composition
US10752720B2 (en) * 2017-06-26 2020-08-25 Johnson & Johnson Vision Care, Inc. Polymerizable blockers of high energy light
US10526296B2 (en) 2017-06-30 2020-01-07 Johnson & Johnson Vision Care, Inc. Hydroxyphenyl naphthotriazoles as polymerizable blockers of high energy light
US10723732B2 (en) 2017-06-30 2020-07-28 Johnson & Johnson Vision Care, Inc. Hydroxyphenyl phenanthrolines as polymerizable blockers of high energy light
US11993037B1 (en) 2018-03-02 2024-05-28 Johnson & Johnson Vision Care, Inc. Contact lens displaying improved vision attributes
US11543683B2 (en) 2019-08-30 2023-01-03 Johnson & Johnson Vision Care, Inc. Multifocal contact lens displaying improved vision attributes
US12486348B2 (en) 2019-08-30 2025-12-02 Johnson & Johnson Vision Care, Inc. Contact lens displaying improved vision attributes
US10935695B2 (en) 2018-03-02 2021-03-02 Johnson & Johnson Vision Care, Inc. Polymerizable absorbers of UV and high energy visible light
US12486403B2 (en) 2018-03-02 2025-12-02 Johnson & Johnson Vision Care, Inc. Polymerizable absorbers of UV and high energy visible light
US12534623B2 (en) 2018-03-02 2026-01-27 Johnson & Johnson Vision Care, Inc. Contact lens with improved tear film optical quality
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US11958824B2 (en) 2019-06-28 2024-04-16 Johnson & Johnson Vision Care, Inc. Photostable mimics of macular pigment
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Also Published As

Publication number Publication date
KR100488744B1 (en) 2005-11-29
NO975104L (en) 1998-05-08
GB9723303D0 (en) 1998-01-07
DE19748658A1 (en) 1998-05-14
BR9705437A (en) 1999-05-18
NL1007470A1 (en) 1998-05-11
CN1183442A (en) 1998-06-03
ES2134158B1 (en) 2000-05-01
FR2755444B1 (en) 2004-10-08
SE522379C2 (en) 2004-02-03
GB2319035A (en) 1998-05-13
AT407642B (en) 2001-05-25
KR19980042141A (en) 1998-08-17
ITMI972482A1 (en) 1998-05-07
CH693032A5 (en) 2003-01-31
ATA187497A (en) 2000-09-15
CN1091127C (en) 2002-09-18
JP4126364B2 (en) 2008-07-30
DE19748658B4 (en) 2015-08-20
GB2319035B (en) 2001-01-10
AU727301B2 (en) 2000-12-07
DK126697A (en) 1998-05-08
IT1298471B1 (en) 2000-01-10
ES2134158A1 (en) 1999-09-16
FR2755444A1 (en) 1998-05-07
SE9704086D0 (en) 1997-11-07
MX9708572A (en) 1998-09-30
NL1007470C2 (en) 1998-10-07
BE1011537A3 (en) 1999-10-05
SG71056A1 (en) 2000-03-21
JPH10140089A (en) 1998-05-26
AU4436097A (en) 1998-05-14
TW467932B (en) 2001-12-11
NO975104D0 (en) 1997-11-05
CA2220269A1 (en) 1998-05-07

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