SE504803C2 - Treatment of pulp with complexing agents in at least two mixing steps without intermediate washing - Google Patents
Treatment of pulp with complexing agents in at least two mixing steps without intermediate washingInfo
- Publication number
- SE504803C2 SE504803C2 SE9502962A SE9502962A SE504803C2 SE 504803 C2 SE504803 C2 SE 504803C2 SE 9502962 A SE9502962 A SE 9502962A SE 9502962 A SE9502962 A SE 9502962A SE 504803 C2 SE504803 C2 SE 504803C2
- Authority
- SE
- Sweden
- Prior art keywords
- pulp
- mixing
- mixing steps
- complexing agent
- complexing agents
- Prior art date
Links
- 238000005406 washing Methods 0.000 title claims abstract description 6
- 239000008139 complexing agent Substances 0.000 title claims description 18
- 238000004061 bleaching Methods 0.000 claims abstract description 7
- 239000002184 metal Substances 0.000 claims abstract description 5
- 229910052751 metal Inorganic materials 0.000 claims abstract description 5
- 150000002739 metals Chemical class 0.000 claims abstract description 5
- 238000000034 method Methods 0.000 claims abstract 9
- 239000000835 fiber Substances 0.000 claims description 4
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 3
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 claims description 3
- DUYCTCQXNHFCSJ-UHFFFAOYSA-N dtpmp Chemical compound OP(=O)(O)CN(CP(O)(O)=O)CCN(CP(O)(=O)O)CCN(CP(O)(O)=O)CP(O)(O)=O DUYCTCQXNHFCSJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000002738 chelating agent Substances 0.000 abstract 2
- 238000009792 diffusion process Methods 0.000 description 5
- 230000014759 maintenance of location Effects 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 229940090960 diethylenetriamine pentamethylene phosphonic acid Drugs 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 229960003330 pentetic acid Drugs 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000001960 triggered effect Effects 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/1026—Other features in bleaching processes
- D21C9/1042—Use of chelating agents
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Paper (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Abstract
Description
504 803 tvättsteg där de frilagda och komplexbunda metalljonerna tvättas ut. Den frilagda vätskan som är anrikad på metalljoner går oftast till avlopp. 504 803 washing steps where the exposed and complexed metal ions are washed out. The exposed liquid that is enriched in metal ions usually goes to the drain.
De betingelser som normalt används i ett Q-steg är en temperatur på 70-90°C, en uppehållstid på 1-2 timmar, massa- koncentration 10-14%, pH 5-7 och komplexbildarsatsning 1-3 kg per ton massa. Från en strikt blekningssynpunkt är Q-steget egentligen ett onödigt behandlingssteg eftersom ingen ljushetshöjning sker där. Q-behandlingen är dock nödvändig för en framgångsrik klorfri blekning som framgått ovan. Om Q-steget kunde förenklas utan att effektiviteten i elimineringen av metaller minskade skulle stora besparingar kunna uppnås eftersom ett fullständigt bleksteg med blekningstorn är dyrbart.The conditions normally used in a Q-step are a temperature of 70-90 ° C, a residence time of 1-2 hours, pulp concentration 10-14%, pH 5-7 and complexing agent charge 1-3 kg per tonne of pulp. From a strictly bleaching point of view, the Q-step is actually an unnecessary treatment step because no increase in brightness takes place there. However, the Q-treatment is necessary for a successful chlorine-free bleaching as stated above. If the Q-step could be simplified without reducing the efficiency in the elimination of metals, large savings could be achieved because a complete bleaching step with bleaching tower is expensive.
Föreliggande uppfinning är inriktad på en lösning av ovanstående problem. Uppfinningen medför således en effektivi- sering av Q-steget genom att metallerna elimineras effektivt samtidigt som Q-steget förenklas med minskad investeringskostnad som följd i förhållande till ett konventionellt Q-steg.The present invention is directed to a solution to the above problems. The invention thus entails a streamlining of the Q-step by efficiently eliminating the metals at the same time as the Q-step is simplified with reduced investment cost as a result in relation to a conventional Q-step.
Uppfinningen är baserad på att det överraskande visat sig att Q-stegets effektivitet är avsevärt mindre påverkad av ökad reaktionstemperatur än av ökad retentionstid. Detta antyder enligt klassisk kemisk kinetik att Q-steget är diffusionsstyrt och inte reaktionstyrt. Detta medför att Q-steget bör utföras så att diffusionen underlättas och om detta görs effektivt kan därmed den totala retentionstiden ansevärt minskas.The invention is based on the fact that it has surprisingly been found that the efficiency of the Q-step is considerably less affected by increased reaction temperature than by increased retention time. According to classical chemical kinetics, this indicates that the Q-step is diffusion-controlled and not reaction-controlled. This means that the Q-step should be performed so that the diffusion is facilitated and if this is done efficiently, the total retention time can thus be considerably reduced.
Uppfinningens kännetecken framgår av patentkraven.The features of the invention appear from the claims.
Det bästa sättet att minska diffusionsmotståndet är att minska diffusionsavståndet för aktiva reaktanter och utlösta reaktionsprodukter och detta görs i teknisk skala genom effektiv omblandning, lämpligen i en mixer. Genom upprepad effektiv omblandning kan således retentionstiden i Q-steget minskas.The best way to reduce the diffusion resistance is to reduce the diffusion distance of active reactants and triggered reaction products and this is done on a technical scale by efficient mixing, preferably in a mixer. Thus, by repeated efficient mixing, the retention time in the Q-step can be reduced.
Antalet blandningssteg bör vara minst två, företrädesvis minst tre. Av ekonomiska skäl måste dock antalet blandningssteg och därmed antalet mixrar hållas på en rimlig nivå. Ett lämpligt antal kan vara 2-4 steg. En viss retentionstid mellan blandningsstegen är av godo, men denna tid behöver inte vara lång, eftersom diffusionshastigheten utan omblandning ändå är avsevärt so4 so3 långsammare än vad som kan uppnås genom omblandning, exempelvis i en mixer. Uppehållstiden mellan blandningsstegen skall således vara kort, mindre än 15 minuter, lämpligen mindre än 10 minuter och företrädesvis mindre än 5 minuter. Vidare skall blandnings- stegen utföras efter varandra utan mellanliggande tvätt. Den tvätt som erfordras för att avlägsna metallerna från massasuspensionen skall utföras efter det sista blandningssteget.The number of mixing steps should be at least two, preferably at least three. For economic reasons, however, the number of mixing steps and thus the number of mixers must be kept at a reasonable level. A suitable number can be 2-4 steps. A certain retention time between the mixing steps is good, but this time does not have to be long, since the diffusion rate without mixing is still considerably so4 so3 slower than what can be achieved by mixing, for example in a mixer. The residence time between the mixing steps should thus be short, less than 15 minutes, suitably less than 10 minutes and preferably less than 5 minutes. Furthermore, the mixing steps must be performed one after the other without intermediate washing. The washing required to remove the metals from the pulp suspension must be carried out after the last mixing step.
Komplexbildaren är lämpligen av typ EDTA (ethylenediamine- tetraacetic acid) eller DTPA (diethylenetriaminepentaacetic acid), men även andra typer av komplexbildare kan användas, exempelvis NTA (nitrilotriacetic acid) eller DTPMP (diethylenetriaminepenta- methylenephosphonic acid). Den totala mängden tillsatt komplex- bildare bör vara 0,5 - 5 kg per ton massa (räknat som ren komplexbildare), företrädesvis l - 3 kg per ton massa.The complexing agent is suitably of the type EDTA (ethylenediaminetetraacetic acid) or DTPA (diethylenetriaminepentaacetic acid), but other types of complexing agents can also be used, for example NTA (nitrilotriacetic acid) or DTPMP (diethylenetriaminepentamethylenephosphonic acid). The total amount of complexing agent added should be 0.5 - 5 kg per tonne of pulp (calculated as pure complexing agent), preferably 1 - 3 kg per tonne of pulp.
Hela tillsatsen av komplexbildare kan göras i det första blandningssteget varvid efterföljande blandningssteg enbart åstad- kommer en förnyad omblandning. Alternativt kan komplexbildaren tillsättas i flera av blandningsstegen. Tillsatsen bör då huvudsakligen göras i första steget och tillsatsmängden i efterföljande steg bör understiga 2 kg per ton massa per steg.The entire addition of complexing agents can be done in the first mixing step, whereby subsequent mixing steps only provide a renewed mixing. Alternatively, the complexing agent may be added in several of the mixing steps. The addition should then mainly be made in the first step and the amount of additive in the subsequent steps should be less than 2 kg per tonne of pulp per step.
Temperaturen i blandningsstegen bör vara över 70°C och lämpligen över 80°C. Ett föredraget temperaturintervall är 80 - 120 °C.The temperature in the mixing steps should be above 70 ° C and preferably above 80 ° C. A preferred temperature range is 80 - 120 ° C.
Trycket i hela Q-steget bör lämpligen vara 1 - 10 bar.The pressure in the entire Q-stage should suitably be 1 - 10 bar.
Särskilt effektiv inblandning kan åstadkommas genom användning av högintensiva mixrar som bryter upp fibernätverket i massan och åstadkommer en nära kontakt mellan fibrer och komplexbildare.Particularly effective mixing can be achieved by using high-intensity mixers which break up the fiber network in the pulp and provide a close contact between fibers and complexing agents.
Uppfinningen är givetvis inte begränsad till ovan angivna utföranden utan kan varieras inom ramen för uppfinningstanken.The invention is of course not limited to the above-mentioned embodiments but can be varied within the scope of the inventive idea.
Claims (9)
Priority Applications (11)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE9502962A SE504803C2 (en) | 1995-08-24 | 1995-08-24 | Treatment of pulp with complexing agents in at least two mixing steps without intermediate washing |
| DE69611680T DE69611680T2 (en) | 1995-08-24 | 1996-08-09 | Cellulose treatment with a complexing agent in at least two mixing stages without intermediate washing |
| PCT/SE1996/000996 WO1997008380A1 (en) | 1995-08-24 | 1996-08-09 | Treatment of pulp with chelating agent in at least two mixing steps without intermediate washing |
| AU68399/96A AU6839996A (en) | 1995-08-24 | 1996-08-09 | Treatment of pulp with chelating agent in at least two mixing steps without intermediate washing |
| PT96928765T PT846199E (en) | 1995-08-24 | 1996-08-09 | TREATMENT OF PASTE WITH CHELATING AGENT AT LEAST TWO STEPS OF MIXTURE WITHOUT INTERMEDIATE WASHING |
| CA002229212A CA2229212A1 (en) | 1995-08-24 | 1996-08-09 | Treatment of pulp with chelating agent in at least two mixing steps without intermediate washing |
| AT96928765T ATE198916T1 (en) | 1995-08-24 | 1996-08-09 | PULP TREATMENT WITH A COMPLEX FORMING AGENT IN AT LEAST TWO MIXING STAGES WITHOUT INTERMEDIATE WASHING |
| BR9610199A BR9610199A (en) | 1995-08-24 | 1996-08-09 | Chlorine-free pulp bleaching process |
| ES96928765T ES2153593T3 (en) | 1995-08-24 | 1996-08-09 | TREATMENT OF A PAPER PASTE WITH A CHELATING AGENT IN AT LEAST TWO STAGES OF MIXING WITHOUT INTERMEDIATE WASHING. |
| EP96928765A EP0846199B1 (en) | 1995-08-24 | 1996-08-09 | Treatment of pulp with chelating agent in at least two mixing steps without intermediate washing |
| NO980753A NO980753L (en) | 1995-08-24 | 1998-02-23 | Treatment of pulp with chelating agent in at least two steps without intermediate washing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE9502962A SE504803C2 (en) | 1995-08-24 | 1995-08-24 | Treatment of pulp with complexing agents in at least two mixing steps without intermediate washing |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| SE9502962D0 SE9502962D0 (en) | 1995-08-24 |
| SE9502962L SE9502962L (en) | 1997-02-25 |
| SE504803C2 true SE504803C2 (en) | 1997-04-28 |
Family
ID=20399294
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SE9502962A SE504803C2 (en) | 1995-08-24 | 1995-08-24 | Treatment of pulp with complexing agents in at least two mixing steps without intermediate washing |
Country Status (11)
| Country | Link |
|---|---|
| EP (1) | EP0846199B1 (en) |
| AT (1) | ATE198916T1 (en) |
| AU (1) | AU6839996A (en) |
| BR (1) | BR9610199A (en) |
| CA (1) | CA2229212A1 (en) |
| DE (1) | DE69611680T2 (en) |
| ES (1) | ES2153593T3 (en) |
| NO (1) | NO980753L (en) |
| PT (1) | PT846199E (en) |
| SE (1) | SE504803C2 (en) |
| WO (1) | WO1997008380A1 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE508239C2 (en) * | 1997-01-03 | 1998-09-21 | Sunds Defibrator Ind Ab | Treatment of pulp with complexing agents in at least one mixing step, without the use of the bleaching tower |
| EP2787120B1 (en) | 2008-06-20 | 2024-10-16 | Global Holdings II, Inc. | Recording sheet with improved optical properties |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE402335T1 (en) * | 1989-06-06 | 1992-04-09 | Eka Nobel Ab, Surte | METHOD FOR BLEACHING LIGNOCELLULOSE-CONTAINING CELLS. |
| SE469387B (en) * | 1992-05-11 | 1993-06-28 | Kamyr Ab | SEATING WHITE PILLOW WITHOUT USING CHLORIC CHEMICALS |
| SE502665C2 (en) * | 1993-06-11 | 1995-12-04 | Kvaerner Pulping Tech | Methods and reactor for ozone bleaching |
| SE501836C2 (en) * | 1993-09-21 | 1995-05-22 | Sunds Defibrator Ind Ab | Bleaching of chemical pulp whereby the pulp is treated with complexing agents before and after an ozone step |
-
1995
- 1995-08-24 SE SE9502962A patent/SE504803C2/en not_active IP Right Cessation
-
1996
- 1996-08-09 AU AU68399/96A patent/AU6839996A/en not_active Abandoned
- 1996-08-09 AT AT96928765T patent/ATE198916T1/en not_active IP Right Cessation
- 1996-08-09 ES ES96928765T patent/ES2153593T3/en not_active Expired - Lifetime
- 1996-08-09 PT PT96928765T patent/PT846199E/en unknown
- 1996-08-09 BR BR9610199A patent/BR9610199A/en not_active Application Discontinuation
- 1996-08-09 CA CA002229212A patent/CA2229212A1/en not_active Abandoned
- 1996-08-09 WO PCT/SE1996/000996 patent/WO1997008380A1/en not_active Ceased
- 1996-08-09 EP EP96928765A patent/EP0846199B1/en not_active Expired - Lifetime
- 1996-08-09 DE DE69611680T patent/DE69611680T2/en not_active Expired - Fee Related
-
1998
- 1998-02-23 NO NO980753A patent/NO980753L/en not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| ATE198916T1 (en) | 2001-02-15 |
| PT846199E (en) | 2001-06-29 |
| SE9502962D0 (en) | 1995-08-24 |
| DE69611680T2 (en) | 2001-05-10 |
| DE69611680D1 (en) | 2001-03-01 |
| NO980753L (en) | 1998-02-24 |
| EP0846199A1 (en) | 1998-06-10 |
| ES2153593T3 (en) | 2001-03-01 |
| BR9610199A (en) | 1998-08-04 |
| WO1997008380A1 (en) | 1997-03-06 |
| EP0846199B1 (en) | 2001-01-24 |
| NO980753D0 (en) | 1998-02-23 |
| AU6839996A (en) | 1997-03-19 |
| CA2229212A1 (en) | 1997-03-06 |
| SE9502962L (en) | 1997-02-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| NUG | Patent has lapsed |