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RU2220957C1 - N-[alkylphenoxypoly(ethyleneoxy)carbonylmethyl]heterilonium chlorides eliciting property of corrosion inhibitors and also bactericidal, virucidal and fungicide activity and method for their preparing - Google Patents

N-[alkylphenoxypoly(ethyleneoxy)carbonylmethyl]heterilonium chlorides eliciting property of corrosion inhibitors and also bactericidal, virucidal and fungicide activity and method for their preparing Download PDF

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RU2220957C1
RU2220957C1 RU2002133263/04A RU2002133263A RU2220957C1 RU 2220957 C1 RU2220957 C1 RU 2220957C1 RU 2002133263/04 A RU2002133263/04 A RU 2002133263/04A RU 2002133263 A RU2002133263 A RU 2002133263A RU 2220957 C1 RU2220957 C1 RU 2220957C1
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average degree
equal
hydroxyethylation equal
hydroxyethylation
preparing
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RU2002133263/04A
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RU2002133263A (en
Inventor
О.В. Угрюмов
О.А. Варнавска
О.А. Варнавская
В.Н. Хлебников
Н.А. Лебедев
Г.В. Романов
В.С. Угрюмова
П.С. Фахретдинов
А.З. Равилов
Ю.Н. Камзина
Г.Р. Юсупова
А.А. Шишко
И.Г. Гатиатуллин
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Открытое акционерное общество "Научно-исследовательский институт по нефтепромысловой химии"
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Abstract

FIELD: organic chemistry, chemical technology. SUBSTANCE: invention describes N- [alkylphenoxypoly(ethyleneoxy)- carbonylmethyl] heterilonium chlorides of the general formula:
Figure 00000007
wherein R is C8-C10-alkyl; n is average oxyethylation degree = 6-12;
Figure 00000008
represents
Figure 00000009
or
Figure 00000010
, or
Figure 00000011
, or
Figure 00000012
. Invention describes method for preparing indicated compounds that involves interaction of monochloroacetic acid with alkylphenoxypolyethylene glycols in the presence of cation-exchange resin KU-2 in H+-form as an acid catalyst in medium of boiling aromatic solvent with nitrogen-containing heterocyclic compounds among row of pyridine or quinoline. Invention provides preparing compounds eliciting properties of corrosion inhibitors, bactericidal, virucidal and fungicide activity. EFFECT: improved preparing method, valuable technical and medicinal properties of compounds. 3 cl, 6 tbl, 16 ex

Description

Текст описания в факсимильном виде (см. графическую часть)а Description text in facsimile form (see graphic part) a

Claims (3)

1. [N-Алкилфеноксиполи(этиленокси)карбонилметил]гетерилоний хлориды, общей формулы1. [N-Alkylphenoxypoly (ethyleneoxy) carbonylmethyl] heterilonium chloride, of the general formula
Figure 00000043
Figure 00000043
 где при R=алкил C8-C10;where at R = alkyl C 8 -C 10 ; n - средняя степень оксиэтилирования, равная 6;n is the average degree of hydroxyethylation equal to 6;
Figure 00000044
Figure 00000044
 при R=C8-C10;at R = C 8 -C 10 ; n - средняя степень оксиэтилирования, равная 10;n is the average degree of hydroxyethylation equal to 10;
Figure 00000045
Figure 00000045
 при R=C8-C10;at R = C 8 -C 10 ; n - средняя степень оксиэтилирования, равная 12;n is the average degree of hydroxyethylation equal to 12;
Figure 00000046
Figure 00000046
 при R=C8-C10;at R = C 8 -C 10 ; n - средняя степень оксиэтилирования, равная 6;n is the average degree of hydroxyethylation equal to 6;
Figure 00000047
Figure 00000047
 при R=C8-C10;at R = C 8 -C 10 ; n - средняя степень оксиэтилирования, равная 10;n is the average degree of hydroxyethylation equal to 10;
Figure 00000048
Figure 00000048
 при R=C8-C10;at R = C 8 -C 10 ; n - средняя степень оксиэтилирования, равная 12;n is the average degree of hydroxyethylation equal to 12;
Figure 00000049
Figure 00000049
 при R=C8-C10;at R = C 8 -C 10 ; n - средняя степень оксиэтилирования, равная 6;n is the average degree of hydroxyethylation equal to 6;
Figure 00000050
Figure 00000050
 при R=C8-C10;at R = C 8 -C 10 ; n - средняя степень оксиэтилирования, равная 10;n is the average degree of hydroxyethylation equal to 10;
Figure 00000051
Figure 00000051
 при R=C8-C10;at R = C 8 -C 10 ; n - средняя степень оксиэтилирования, равная 12;n is the average degree of hydroxyethylation equal to 12;
Figure 00000052
Figure 00000052
 при R=C8-C10;at R = C 8 -C 10 ; n - средняя степень оксиэтилирования, равная 6;n is the average degree of hydroxyethylation equal to 6;
Figure 00000053
Figure 00000053
 при R=C8-C10;at R = C 8 -C 10 ; n - средняя степень оксиэтилирования, равная 10;n is the average degree of hydroxyethylation equal to 10;
Figure 00000054
Figure 00000054
 при R=C8-C10;at R = C 8 -C 10 ; n - средняя степень оксиэтилирования, равная 12;n is the average degree of hydroxyethylation equal to 12;
Figure 00000055
Figure 00000055
 при R=C8-C10;at R = C 8 -C 10 ; n - средняя степень оксиэтилирования, равная 6;n is the average degree of hydroxyethylation equal to 6;
Figure 00000056
Figure 00000056
 при R=C8-C10;at R = C 8 -C 10 ; n - средняя степень оксиэтилирования, равная 10;n is the average degree of hydroxyethylation equal to 10;
Figure 00000057
Figure 00000057
 при R=C8-С10;at R = C 8 -C 10 ; n - средняя степень оксиэтилирования, равная 12;n is the average degree of hydroxyethylation equal to 12;
Figure 00000058
Figure 00000058
 2. Соединения по п.1, обладающие свойствами ингибиторов коррозии металлов, а также фунгицидной, бактерицидной и вирусоцидной активностью.2. The compounds according to claim 1, having the properties of metal corrosion inhibitors, as well as fungicidal, bactericidal and virucidal activity. 3. Способ получения соединений по п.1 взаимодействием монохлоруксусной кислоты с алкилфеноксиполиэтиленгликолями в присутствии кислотных катализаторов в среде кипящего ароматического растворителя с азеотропным удалением образовавшейся воды и последующей обработкой полученного продукта аминами при нагревании, отличающийся тем, что в качестве кислотного катализатора используют Н+ форму катионобменной смолы КУ-2, в качестве алкилфеноксиполиэтиленгликолей используют алкилфеноксиполиэтиленгликоли с R=алкил C8-С10, и n, равной 6, или 10, или 12, а в качестве аминов - азотсодержащие гетероциклические соединения ряда пиридина общей формулы3. The method of producing compounds according to claim 1 by the interaction of monochloracetic acid with alkylphenoxypolyethylene glycols in the presence of acid catalysts in a boiling aromatic solvent with azeotropic removal of the resulting water and subsequent processing of the resulting product with amines when heated, characterized in that H + is used as an acid catalyst in the form of cation exchange KU-2 resins, alkyl phenoxy polyethylene glycols with R = alkyl C 8 -C 10 , and n equal to 6, or 10, silt are used as alkyl phenoxy polyethylene glycols and 12, and as amines, nitrogen-containing heterocyclic compounds of the pyridine series of the general formula
Figure 00000059
Figure 00000059
 где R1=H, R2=Н, СН3; R3=H;where R 1 = H, R 2 = H, CH 3 ; R 3 = H; или ряда хинолина общей формулыor a series of quinoline of the general formula
Figure 00000060
Figure 00000060
 где R4=Н, СН3,where R 4 = N, CH 3 , или ряда изохинолина, формулыor a series of isoquinoline of the formula
Figure 00000061
Figure 00000061
RU2002133263/04A 2002-12-09 2002-12-09 N-[alkylphenoxypoly(ethyleneoxy)carbonylmethyl]heterilonium chlorides eliciting property of corrosion inhibitors and also bactericidal, virucidal and fungicide activity and method for their preparing RU2220957C1 (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2288920C1 (en) * 2005-07-06 2006-12-10 Всероссийский научный исследовательский ветеринарный институт (ВНИВИ) {[1-(ammonio)-3,5,7-triazaadamantyl]-methylcarbonyloxypoly-(alkyleneoxy)}propane chloride possessing bactericidal and fungicide activity and method for their preparing
WO2008157234A3 (en) * 2007-06-14 2009-05-28 Nalco Co Mono and bis-ester derivatives of pyridinium and quinolinium compounds as environmentally friendly corrosion inhibitors
RU2454488C1 (en) * 2011-03-30 2012-06-27 Ильдус Нуруллович Аликин Corrosion inhibitor in mineralised hydrogen sulphide-containing oilfield media

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2158140C2 (en) * 1998-12-01 2000-10-27 Всероссийский научно-исследовательский ветеринарный институт Disinfecting agent and method of its producing

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2158140C2 (en) * 1998-12-01 2000-10-27 Всероссийский научно-исследовательский ветеринарный институт Disinfecting agent and method of its producing

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2288920C1 (en) * 2005-07-06 2006-12-10 Всероссийский научный исследовательский ветеринарный институт (ВНИВИ) {[1-(ammonio)-3,5,7-triazaadamantyl]-methylcarbonyloxypoly-(alkyleneoxy)}propane chloride possessing bactericidal and fungicide activity and method for their preparing
WO2008157234A3 (en) * 2007-06-14 2009-05-28 Nalco Co Mono and bis-ester derivatives of pyridinium and quinolinium compounds as environmentally friendly corrosion inhibitors
US8585930B2 (en) 2007-06-14 2013-11-19 Nalco Company Mono and bis-ester derivatives of pyridinium and quinolinium compounds as environmentally friendly corrosion inhibitors
RU2454488C1 (en) * 2011-03-30 2012-06-27 Ильдус Нуруллович Аликин Corrosion inhibitor in mineralised hydrogen sulphide-containing oilfield media

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