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RU2208628C2 - Multiphase detergent tablet and a method of washing in washing machine - Google Patents

Multiphase detergent tablet and a method of washing in washing machine Download PDF

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Publication number
RU2208628C2
RU2208628C2 RU2001104452/04A RU2001104452A RU2208628C2 RU 2208628 C2 RU2208628 C2 RU 2208628C2 RU 2001104452/04 A RU2001104452/04 A RU 2001104452/04A RU 2001104452 A RU2001104452 A RU 2001104452A RU 2208628 C2 RU2208628 C2 RU 2208628C2
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RU
Russia
Prior art keywords
phase
multiphase detergent
multiphase
detergent tablet
tablet
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Application number
RU2001104452/04A
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Russian (ru)
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RU2001104452A (en
Inventor
Патрицио РИЧЧИ (BE)
Патрицио РИЧЧИ
Бренда Франсез БЕННИ (GB)
Бренда Франсез БЕННИ
Кристофер Джеймс БАЙНДЕР (GB)
Кристофер Джеймс БАЙНДЕР
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Дзе Проктер Энд Гэмбл Компани
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Priority claimed from GBGB9815525.2A external-priority patent/GB9815525D0/en
Application filed by Дзе Проктер Энд Гэмбл Компани filed Critical Дзе Проктер Энд Гэмбл Компани
Publication of RU2001104452A publication Critical patent/RU2001104452A/en
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C11D17/0065—Solid detergents containing builders
    • C11D17/0073—Tablets
    • C11D17/0078—Multilayered tablets
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C11D17/0065—Solid detergents containing builders
    • C11D17/0073—Tablets
    • C11D17/0086—Laundry tablets
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C11D17/0065—Solid detergents containing builders
    • C11D17/0073—Tablets
    • C11D17/0091—Dishwashing tablets
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
    • C11D3/126—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in solid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
    • C11D3/1273—Crystalline layered silicates of type NaMeSixO2x+1YH2O
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3707—Polyethers, e.g. polyalkyleneoxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C11D3/3776—Heterocyclic compounds, e.g. lactam
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3792—Amine oxide containing polymers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38609—Protease or amylase in solid compositions only
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38645—Preparations containing enzymes, e.g. protease or amylase containing cellulase
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40—Dyes ; Pigments
    • C11D3/42—Brightening agents ; Blueing agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Molecular Biology (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)
  • Sealing With Elastic Sealing Lips (AREA)

Abstract

FIELD: household chemical goods. SUBSTANCE: tablet contains first phase in the form of formed body consisting of at least one form and second phase in the form of compressed body retained inside above form by adhesive force, tablet composition including one or more detergent active substances mainly concentrated in the second phase, which is supplemented by destruction agent. Formed body of the first phase is obtained under compaction pressure at least about 350 kg/sq.cm and the second phase is compressed to pressure less than about 350 kg/sq.cm. EFFECT: achieved excellent dissolution and cleaning characteristics in addition to good integrity and strength of tablets. 12 cl, 6 ex

Description

Текст описания в факсимильном виде (см. графическую часть). Description text in facsimile form (see graphic part).

Claims (12)

1. Многофазная детергентная таблетка для использования в моечной машине, где композиция таблетки содержит одно или более детергентных активных веществ и разрушающий агент, отличающаяся тем, что таблетка содержит а) первую фазу в виде сформированного тела, содержащего, по крайней мере, одну форму, и б) вторую фазу в виде спрессованного тела, содержащегося внутри указанной формы за счет адгезии, причем одно или более детергентных активных веществ преимущественно сконцентрированы во второй фазе и где вторая фаза дополнительно содержит разрушающий агент, при этом сформированное тело первой фазы получают при давлении прессования по крайней мере около 350 кг/см2, а вторую фазу прессуют при давлении менее чем около 350 кг/см2.1. A multiphase detergent tablet for use in a washing machine, where the tablet composition contains one or more detergent active substances and a destructive agent, characterized in that the tablet contains a) a first phase in the form of a shaped body containing at least one form, and b) the second phase in the form of a compressed body contained inside the specified form due to adhesion, moreover, one or more detergent active substances are mainly concentrated in the second phase and where the second phase additionally contains a reducing agent, wherein the formed body of the first phase is obtained at a compression pressure of at least about 350 kg / cm 2 , and the second phase is pressed at a pressure of less than about 350 kg / cm 2 . 2. Многофазная детергентная таблетка по п. 1, отличающаяся тем, что вторая фаза растворяется быстрее, чем первая фаза. 2. A multiphase detergent tablet according to claim 1, characterized in that the second phase dissolves faster than the first phase. 3. Многофазная детергентная таблетка по любому из пп.1 и 2, отличающаяся тем, что вторая фаза растворяется в посудомоечной машине в течение 5 мин. 3. A multiphase detergent tablet according to any one of claims 1 and 2, characterized in that the second phase dissolves in the dishwasher within 5 minutes. 4. Многофазная детергентная таблетка для использования в моечной машине по п.1, отличающаяся тем, что указанная таблетка сформирована таким образом, что по крайней мере 50%, предпочтительно по крайней мере 60%, более предпочтительно по крайней мере 80% по весу одного или более детергентных активных веществ поступает в моющий раствор в течение первых 10 мин, предпочтительно в течение первых 5 мин и более предпочтительно в течение первых 3 мин моечного процесса. 4. Multiphase detergent tablet for use in a washing machine according to claim 1, characterized in that said tablet is formed in such a way that at least 50%, preferably at least 60%, more preferably at least 80% by weight of one or more detergent active substances enter the washing solution during the first 10 minutes, preferably during the first 5 minutes and more preferably during the first 3 minutes of the washing process. 5. Многофазная детергентная таблетка по любому из предшествующих пунктов, отличающаяся тем, что одно или более детергентных активных веществ выбирают из ферментов, отбеливателей, активаторов отбеливания, катализаторов отбеливания, поверхностно-активных веществ, хелатирующих агентов, ингибиторов роста кристаллов и их смесей. 5. A multiphase detergent tablet according to any one of the preceding paragraphs, characterized in that one or more detergent active substances is selected from enzymes, bleaches, bleaching activators, bleaching catalysts, surfactants, chelating agents, crystal growth inhibitors and mixtures thereof. 6. Многофазная детергентная таблетка по любому из предшествующих пунктов, отличающаяся тем, что разрушающий агент выбирают из дезинтегрирующих агентов, вспенивающих агентов и их смесей. 6. Multiphase detergent tablet according to any one of the preceding paragraphs, characterized in that the destructive agent is selected from disintegrating agents, foaming agents and mixtures thereof. 7. Многофазная детергентная таблетка по любому из предшествующих пунктов, отличающаяся тем, что первая и/или вторая фазы содержат связующее. 7. Multiphase detergent tablet according to any one of the preceding paragraphs, characterized in that the first and / or second phases contain a binder. 8. Многофазная детергентная таблетка по п.7, отличающаяся тем, что связующее выбирают из группы, состоящей из сахара и производных сахара, крахмала и производных крахмала, неорганических и органических полимеров. 8. Multiphase detergent tablet according to claim 7, characterized in that the binder is selected from the group consisting of sugar and derivatives of sugar, starch and derivatives of starch, inorganic and organic polymers. 9. Многофазная детергентная таблетка по любому из предшествующих пунктов, отличающаяся тем, что дополнительно содержит барьерный слой между первой и второй фазами. 9. Multiphase detergent tablet according to any one of the preceding paragraphs, characterized in that it further comprises a barrier layer between the first and second phases. 10. Многофазная детергентная таблетка по п.9, отличающаяся тем, что барьерный слой содержит связующее, используемое в жидкой форме. 10. Multiphase detergent tablet according to claim 9, characterized in that the barrier layer contains a binder used in liquid form. 11. Способ мытья в моечной машине, включающий загрузку в моечную машину одной или более многофазных детергентных таблеток, отличающийся тем, что используют многофазные детергентные таблетки по любому из предшествующих пунктов. 11. A method of washing in a washing machine, comprising loading into the washer one or more multiphase detergent tablets, characterized in that the multiphase detergent tablets according to any one of the preceding paragraphs are used. 12. Способ по п.11, отличающийся тем, что многофазная детергентная таблетка растворяется или разрушается менее чем за 15 мин в посудомоечной машине. 12. The method according to claim 11, characterized in that the multiphase detergent tablet is dissolved or destroyed in less than 15 minutes in a dishwasher. Приоритет по пунктам:
17.07.1998 - по пп. 1-8, 11-12;
17.05.1999 - по пп. 9-10.Priority on points:
07.17.1998 - according to paragraphs 1-8, 11-12;
05/17/1999 - according to paragraphs 9-10.
RU2001104452/04A 1998-07-17 1999-07-09 Multiphase detergent tablet and a method of washing in washing machine RU2208628C2 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
GB9815525.2 1998-07-17
GBGB9815525.2A GB9815525D0 (en) 1998-07-17 1998-07-17 Detergent tablet
GB9911264.1 1999-05-17
GB9911264A GB2339792B (en) 1998-07-17 1999-05-17 Detergent tablet

Publications (2)

Publication Number Publication Date
RU2001104452A RU2001104452A (en) 2003-01-27
RU2208628C2 true RU2208628C2 (en) 2003-07-20

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RU2001104452/04A RU2208628C2 (en) 1998-07-17 1999-07-09 Multiphase detergent tablet and a method of washing in washing machine

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EP (2) EP0979866B1 (en)
JP (1) JP2002520479A (en)
CN (1) CN1309692A (en)
AT (4) ATE338808T1 (en)
AU (1) AU4964499A (en)
BR (1) BR9912157A (en)
CA (1) CA2333468C (en)
DE (5) DE29911484U1 (en)
DK (1) DK0979866T3 (en)
ES (4) ES2272825T3 (en)
FI (1) FI4408U1 (en)
FR (1) FR2782090B1 (en)
IE (1) IES990572A2 (en)
IT (2) ITMI991511A1 (en)
NL (1) NL1012585C1 (en)
PL (1) PL346179A1 (en)
PT (1) PT979866E (en)
RU (1) RU2208628C2 (en)
SK (1) SK602001A3 (en)
TR (1) TR200100096T2 (en)
WO (1) WO2000004124A2 (en)

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DE69900833T2 (en) * 1998-07-17 2002-10-31 The Procter & Gamble Company, Cincinnati detergent tablet
GB9815525D0 (en) * 1998-07-17 1998-09-16 Procter & Gamble Detergent tablet
DE29911484U1 (en) * 1998-07-17 2000-02-24 The Procter & Gamble Co., Cincinnati, Ohio Detergent tablet
ATE211503T1 (en) * 1998-07-17 2002-01-15 Procter & Gamble METHOD FOR PRODUCING DETERGENT TABLETS
ATE242312T1 (en) * 1998-07-17 2003-06-15 Procter & Gamble DETERGENT TABLET
DE19922578C2 (en) * 1999-05-17 2003-12-24 Benckiser Nv Process for the production of a multilayer tablet, in particular detergent tablet, and product which can be produced thereafter
ATE318299T1 (en) * 2000-06-09 2006-03-15 Procter & Gamble METHOD FOR TREATING TISSUE WITH A DETERGENT MOLDED BODY CONTAINING AN ION EXCHANGE RESIN
DE10053416A1 (en) † 2000-10-27 2002-05-08 Bsh Bosch Siemens Hausgeraete Process for the mechanical cleaning of textiles or solid objects
DE20320615U1 (en) * 2002-02-26 2005-01-13 Rational Ag Detergents for cooking utensils in tabular form
DE102011107684A1 (en) * 2011-07-13 2013-01-17 Budich International Gmbh Chlorinated detergent tablet for toilets
CN102965223B (en) * 2012-11-26 2014-01-08 吴金龙 Nano-multifunctional washing sheet
EP4034621A1 (en) 2019-09-23 2022-08-03 Ecolab USA Inc. Color changing detergent compositions and methods of use
EP3825392A1 (en) 2019-11-21 2021-05-26 Dalli-Werke GmbH & Co. KG Detergent tablet comprising an effervescent system
EP4166638A1 (en) 2021-10-13 2023-04-19 CLARO Products GmbH Cleaning tablet for cleaning spectacles

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WO1997003177A1 (en) * 1995-07-13 1997-01-30 Joh. A. Benckiser Gmbh Dish washer product in tablet form

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