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RU2021135364A - NEW PAENIBACILLUS STRAIN, ANTIFUNGAL COMPOUNDS AND METHODS OF THEIR APPLICATION - Google Patents

NEW PAENIBACILLUS STRAIN, ANTIFUNGAL COMPOUNDS AND METHODS OF THEIR APPLICATION Download PDF

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RU2021135364A
RU2021135364A RU2021135364A RU2021135364A RU2021135364A RU 2021135364 A RU2021135364 A RU 2021135364A RU 2021135364 A RU2021135364 A RU 2021135364A RU 2021135364 A RU2021135364 A RU 2021135364A RU 2021135364 A RU2021135364 A RU 2021135364A
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paenibacillus
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Джереми БОУ
Даниел М. ДЖУ
Патрик ШВИНТЕК
Коллин С. ТЕЙЛОР
Бьорн А. ТРАГ
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Байер Кропсайенс Лп
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
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    • A—HUMAN NECESSITIES
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    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
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    • A01N47/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —N=CX2 groups, e.g. isothiourea
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • G01N2333/24—Assays involving biological materials from specific organisms or of a specific nature from bacteria from Enterobacteriaceae (F), e.g. Citrobacter, Serratia, Proteus, Providencia, Morganella, Yersinia

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Claims (68)

1. Композиция, включающая соединение структуры (I):1. Composition comprising a compound of structure (I):
Figure 00000001
,
Figure 00000001
, где R1 и R2 каждый независимо представляет собой -CH(CH3)2 или -CH(CH3)CH2CH3;where R 1 and R 2 are each independently -CH(CH 3 ) 2 or -CH(CH 3 )CH 2 CH 3 ; R3 представляет собой -CH2C(O)NH2 или –(CH2)2C(O)NH2; иR 3 is -CH 2 C(O)NH 2 or -(CH 2 ) 2 C(O)NH 2 ; and n является целым числом от 13 до 20;n is an integer from 13 to 20; включая его соли, гидраты, сольваты, полиморфы, оптические изомеры, геометрические изомеры, энантиомеры, диастереомеры, ациклические аналоги и смеси.including its salts, hydrates, solvates, polymorphs, optical isomers, geometric isomers, enantiomers, diastereomers, acyclic analogs and mixtures. 2. Композиция по п. 1, где n представляет собой 14 или 16.2. Composition according to claim 1, where n is 14 or 16. 3. Композиция по п. 2, где соединение структуры (I) представляет собой3. The composition of claim 2, wherein the compound of structure (I) is
Figure 00000002
Figure 00000002
Figure 00000003
Figure 00000003
Figure 00000004
Figure 00000004
Figure 00000005
Figure 00000005
Figure 00000006
Figure 00000006
Figure 00000007
Figure 00000007
Figure 00000008
Figure 00000008
Figure 00000009
Figure 00000009
Figure 00000010
Figure 00000010
Figure 00000011
Figure 00000011
Figure 00000012
Figure 00000012
Figure 00000013
Figure 00000013
Figure 00000014
Figure 00000014
Figure 00000015
Figure 00000015
 4. Композиция, включающая соединение структуры (II):4. Composition comprising a compound of structure (II):
Figure 00000016
Figure 00000016
 где R1 представляет собой -CH2OH или -CH(OH)CH3;where R 1 represents -CH 2 OH or -CH(OH)CH 3 ; R2 представляет собой -CH2C(O)NH2 или -(CH2)2C(O)NH2; иR 2 is -CH 2 C(O)NH 2 or -(CH 2 ) 2 C(O)NH 2 ; and R3 представляет собой H или CH3;R 3 is H or CH 3 ; при условии, что, если R1 представляет собой -CH2OH, и R2 представляет собой -CH2C(O)NH2, то R3 представляет собой H;with the proviso that if R 1 is -CH 2 OH and R 2 is -CH 2 C(O)NH 2 then R 3 is H; включая его соли, гидраты, сольваты, полиморфы, оптические изомеры, геометрические изомеры, энантиомеры, диастереомеры, ациклические аналоги и смеси.including its salts, hydrates, solvates, polymorphs, optical isomers, geometric isomers, enantiomers, diastereomers, acyclic analogs and mixtures. 5. Композиция по п. 4, где соединение структуры (II) представляет собой5. The composition according to claim 4, where the compound of structure (II) is
Figure 00000017
Figure 00000017
Figure 00000018
Figure 00000018
Figure 00000019
Figure 00000019
Figure 00000020
Figure 00000020
Figure 00000021
Figure 00000021
Figure 00000022
Figure 00000022
Figure 00000023
Figure 00000023
Figure 00000024
Figure 00000024
Figure 00000025
Figure 00000025
 илиor
Figure 00000026
Figure 00000026
 6. Композиция, включающая соединение, как определено в любом из пп. 1-5, и приемлемый для применения в сельском хозяйстве носитель.6. A composition comprising a compound as defined in any one of paragraphs. 1-5 and an agriculturally acceptable carrier. 7. Композиция по п. 6, отличающаяся тем, что соединение входит в раствор с концентрацией по крайней мере 0,001 мг/мл.7. Composition according to claim 6, characterized in that the compound enters the solution at a concentration of at least 0.001 mg/ml. 8. Композиция, которая включает:8. Composition, which includes: а) по крайней мере один фусарицидин; иa) at least one fusaricidin; and б) по крайней мере один Paeniserine или по крайней мере один Paeniprolixinb) at least one Paeniserine or at least one Paeniprolixin в синергетически эффективном количестве.in a synergistically effective amount. 9. Композиция по п. 8, где фусарицидин представляет собой Фусарицидин A. 9. The composition of claim 8, wherein the fusaricidin is Fusaricidin A. 10. Композиция по п. 8 или 9, где Paeniserine представляет собой Paeniserine A1.10. Composition according to claim 8 or 9, wherein the Paeniserine is Paeniserine A1. 11. Композиция по п. 8 или 9, где Paeniprolixin представляет собой Paeniprolixin C1.11. Composition according to claim 8 or 9, wherein the Paeniprolixin is Paeniprolixin C1. 12. Способ обработки растения для борьбы с болезнью, включающий нанесение эффективного количества композиции по любому из пп. 1-11 на растение, часть растения и/или место выращивания растения.12. A method of treating a plant to control a disease, comprising applying an effective amount of a composition according to any one of paragraphs. 1-11 per plant, part of a plant and/or plant growing site. 13. Способ по п. 12, где композиция представляет собой продукт ферментации штамма вида Paenibacillus NRRL B-50972, штамма вида Paenibacillus NRRL B-67129 или их фунгицидного мутантного штамма.13. The method of claim 12, wherein the composition is a fermentation product of a Paenibacillus NRRL B-50972 strain, a Paenibacillus NRRL B-67129 strain, or a fungicidal mutant strain thereof. 14. Способ по п. 12, где способ включает нанесение композиции на части лиственных растений.14. The method of claim 12, wherein the method comprises applying the composition to parts of leafy plants. 15. Способ по п. 12, где композицию применяют в количестве от приблизительно 1×1010 до приблизительно 1×1012 колониеобразующих единиц (КОЕ) штамма вида Paenibacillus NRRL B-50972, штамма вида Paenibacillus NRRL B-67129 или их фунгицидного мутантного штамма на гектар.15. The method of claim 12 wherein the composition is used in an amount of from about 1 x 10 10 to about 1 x 10 12 colony forming units (CFU) of a Paenibacillus NRRL B-50972 strain, a Paenibacillus NRRL B-67129 strain, or a fungicidal mutant strain thereof per hectare. 16. Способ по п. 12, где композицию применяют в количестве от приблизительно 0,5 кг до приблизительно 5 кг твердых продуктов ферментации на гектар.16. The method of claim 12 wherein the composition is applied in an amount of from about 0.5 kg to about 5 kg of fermentation solids per hectare. 17. Способ по любому из пп. 12 - 16, где болезнь растений вызывается грибком.17. The method according to any one of paragraphs. 12-16 where the plant disease is caused by a fungus. 18. Способ по п. 17, где болезнью растений является мучнистая роса или ржавчинное заболевание.18. The method of claim 17 wherein the plant disease is powdery mildew or rust disease. 19. Способ по п. 18, где мучнистая роса является истинной мучнистой росой или псевдомучнистой росой.19. The method of claim 18 wherein the powdery mildew is true powdery mildew or pseudo powdery mildew. 20. Способ по п. 18, где ржавчинное заболевание является выбранным из группы, состоящей из листовой ржавчины пшеницы, листовой ржавчины ячменя, листовой ржавчины ржи, бурой листовой ржавчины, корончатой ржавчины и стеблевой ржавчины.20. The method of claim 18 wherein the rust disease is selected from the group consisting of wheat leaf rust, barley leaf rust, rye leaf rust, brown leaf rust, crown rust and stem rust. 21. Способ по п. 17, где грибок является выбранным из группы, состоящей из Alternaria alternata, Alternaria solani, Botrytis cinerea, Colletotrichum lagenarium, Fusarium culmorum, Phaeosphaeria nodorum, Zymoseptoria tritici, Phytophthora cryptogea, Phytophthora infestans, Pythium ultimum, Magnaporthe oryzae, Thanatephorus cucumeris, Ustilago segetum var. avenae, Uromyces appendiculatus и Puccinia triticina. 21. The method of claim. 17 wherein the fungus is selected from group consisting of Alternaria alternata, Alternaria solani, Botrytis cinerea , Colletotrichum lagenarium, Fusarium culmorum, Phaeosphaeria nodorum, Zymoseptoria tritici, Phytophthora cryptogea, Phytophthora infestans, Pythium ultimum, Magnaporthe oryzae, Thanatephorus cucumeris , Ustilago segetum var. avenae , Uromyces appendiculatus and Puccinia triticina. 22. Способ по любому из пп. 17-21, где композиция имеет остаточную активность, которая приводит к борьбе з грибком в течение по крайней мере 5 дней, по крайней мере 10 дней или по крайней мере 15 дней после нанесения на растение, часть растения и/или место выращивания растения.22. The method according to any one of paragraphs. 17-21, wherein the composition has residual activity that results in fungal control for at least 5 days, at least 10 days, or at least 15 days after application to the plant, plant part, and/or plant growing site. 23. Способ по любому из пп. 12-16, где болезнь растений вызывается бактериями.23. The method according to any one of paragraphs. 12-16 where the plant disease is caused by bacteria. 24. Способ по п. 23, где бактерии являются выбранными из группы, состоящей из Xanthomonas campestris, Pseudomonas syringae и Erwinia carotovora. 24. The method of claim 23 wherein the bacteria are selected from the group consisting of Xanthomonas campestris , Pseudomonas syringae and Erwinia carotovora. 25. Применение композиции по любому из пп. 1-11 для борьбы с фитопатогенными организмами у полезных растений.25. The use of a composition according to any one of paragraphs. 1-11 to control phytopathogenic organisms in useful plants. 26. Применение по п. 25, где композиция включает продукт ферментации штамма вида Paenibacillus NRRL B-50972, штамма вида Paenibacillus NRRL B-67129 или их фунгицидного мутантного штамма.26. Use according to claim 25, wherein the composition comprises a fermentation product of Paenibacillus species NRRL B-50972, Paenibacillus NRRL B-67129, or a fungicidal mutant strain thereof. 27. Применение по п. 25, где фитопатогенный организм является выбранным из группы, состоящей из Alternaria alternata, Alternaria solani, Botrytis cinerea, Colletotrichum lagenarium, Fusarium culmorum, Phaeosphaeria nodorum, Zymoseptoria tritici, Phytophthora cryptogea, Phytophthora infestans, Pythium ultimum, Magnaporthe oryzae, Thanatephorus cucumeris, Ustilago segetum var. avenae, Uromyces appendiculatus и Puccinia triticina.27. The use of claim. 25 wherein a phytopathogenic organism is selected from group consisting of Alternaria alternata, Alternaria solani, Botrytis cinerea , Colletotrichum lagenarium, Fusarium culmorum, Phaeosphaeria nodorum, Zymoseptoria tritici, Phytophthora cryptogea, Phytophthora infestans, Pythium ultimum, Magnaporthe oryzae , Thanatephorus cucumeris , Ustilago segetum var. avenae , Uromyces appendiculatus and Puccinia triticina . 28. Применение по п. 25, где фитопатогенный организм является выбранным из группы, состоящей из Xanthomonas campestris, Pseudomonas syringae и Erwinia carotovora. 28. Use according to claim 25, wherein the phytopathogenic organism is selected from the group consisting of Xanthomonas campestris , Pseudomonas syringae and Erwinia carotovora. 29. Применение по любому из пп. 25-28, где полезные растения являются выбранными из группы, состоящей из яблоней, бананов, цитрусовых, киви, дынь, персиков, грушей, ананасов, семечковых плодов, гранатов, капусты, цветной капусты, огурцев, тыквей, томатов, картошек, пшеницы, риса и сои.29. Application according to any one of paragraphs. 25-28, wherein the beneficial plants are selected from the group consisting of apple, banana, citrus, kiwi, melon, peach, pear, pineapple, pome fruit, pomegranate, cabbage, cauliflower, cucumber, pumpkin, tomato, potato, wheat, rice and soy.
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