RU2019119373A - Свободная от хрома композиция покрытия с антикоррозийным эффектом для металлических подложек - Google Patents
Свободная от хрома композиция покрытия с антикоррозийным эффектом для металлических подложек Download PDFInfo
- Publication number
- RU2019119373A RU2019119373A RU2019119373A RU2019119373A RU2019119373A RU 2019119373 A RU2019119373 A RU 2019119373A RU 2019119373 A RU2019119373 A RU 2019119373A RU 2019119373 A RU2019119373 A RU 2019119373A RU 2019119373 A RU2019119373 A RU 2019119373A
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- Prior art keywords
- coating composition
- iii
- tris
- iron
- coating
- Prior art date
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- 239000008199 coating composition Substances 0.000 title claims 11
- 239000000758 substrate Substances 0.000 title claims 10
- 238000005260 corrosion Methods 0.000 title claims 2
- 229910052751 metal Inorganic materials 0.000 claims 8
- 239000002184 metal Substances 0.000 claims 8
- 239000007983 Tris buffer Substances 0.000 claims 6
- 238000000576 coating method Methods 0.000 claims 6
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 claims 5
- 239000011248 coating agent Substances 0.000 claims 5
- 229910052757 nitrogen Inorganic materials 0.000 claims 5
- 150000001875 compounds Chemical class 0.000 claims 4
- 239000012990 dithiocarbamate Substances 0.000 claims 4
- 238000000034 method Methods 0.000 claims 4
- 239000000203 mixture Substances 0.000 claims 3
- PMVSDNDAUGGCCE-TYYBGVCCSA-L Ferrous fumarate Chemical compound [Fe+2].[O-]C(=O)\C=C\C([O-])=O PMVSDNDAUGGCCE-TYYBGVCCSA-L 0.000 claims 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims 2
- 239000011230 binding agent Substances 0.000 claims 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- 239000003431 cross linking reagent Substances 0.000 claims 2
- 239000003822 epoxy resin Substances 0.000 claims 2
- 229920000647 polyepoxide Polymers 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 2
- 229910000838 Al alloy Inorganic materials 0.000 claims 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims 1
- 239000004593 Epoxy Substances 0.000 claims 1
- VSWDORGPIHIGNW-UHFFFAOYSA-N Pyrrolidine dithiocarbamic acid Chemical compound SC(=S)N1CCCC1 VSWDORGPIHIGNW-UHFFFAOYSA-N 0.000 claims 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims 1
- 125000003277 amino group Chemical group 0.000 claims 1
- 238000007743 anodising Methods 0.000 claims 1
- 230000007797 corrosion Effects 0.000 claims 1
- 239000003085 diluting agent Substances 0.000 claims 1
- MZGNSEAPZQGJRB-UHFFFAOYSA-N dimethyldithiocarbamic acid Chemical compound CN(C)C(S)=S MZGNSEAPZQGJRB-UHFFFAOYSA-N 0.000 claims 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- WGPCJVLKOFIRMS-UHFFFAOYSA-K n,n-diethylcarbamodithioate;iron(3+) Chemical compound [Fe+3].CCN(CC)C([S-])=S.CCN(CC)C([S-])=S.CCN(CC)C([S-])=S WGPCJVLKOFIRMS-UHFFFAOYSA-K 0.000 claims 1
- 125000004433 nitrogen atom Chemical group N* 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- 229920003002 synthetic resin Polymers 0.000 claims 1
- 239000000057 synthetic resin Substances 0.000 claims 1
- 235000002906 tartaric acid Nutrition 0.000 claims 1
- 239000011975 tartaric acid Substances 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/39—Thiocarbamic acids; Derivatives thereof, e.g. dithiocarbamates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/002—Priming paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
- C09D5/086—Organic or non-macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/48—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 not containing phosphates, hexavalent chromium compounds, fluorides or complex fluorides, molybdates, tungstates, vanadates or oxalates
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0091—Complexes with metal-heteroatom-bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Laminated Bodies (AREA)
Claims (25)
1. Водная не содержащая хрома композиция покрытия, включающая в себя
(A) по меньшей мере одно связующее вещество, содержащее
(A1) по меньшей мере одну синтетическую смолу и
(A2) по меньшей мере одно сшивающее средство,
отличающаяся тем, что она дополнительно содержит
(B) по меньшей мере одно комплексное соединение железо(III)-трис(N,N-дитиокарбамат) общей формулы (I)
[R1-N(-R2)- C(=S)- S]3Fe+III (I)
где
(i) R1 и R2 независимо представляет собой одновалентный линейный, разветвленный или циклический алифатический углеводородный радикал с 1-10 атомами углерода, или
(ii) R1 представляет собой двухвалентный линейный или разветвленный алифатический углеводородный радикал с 1-10 атомами углерода, R2 представляет собой ковалентную связь, и R1 связан посредством этой ковалентной связи с атомом азота в формуле (I),
в которой содержание воды в композиции покрытия составляет по меньшей мере 50,0 мас.% по общему содержанию жидких разбавителей, присутствующих в композиции покрытия.
2. Композиция покрытия по п. 1, отличающаяся тем, что комплексное соединение железо(III)-трис(N,N-дитиокарбамат) (B) имеет растворимость в воде при 20°C менее чем 0,1 моль/л.
3. Композиция покрытия по п. 1 или 2, отличающаяся тем, что комплексное соединение железо(III)-трис(N,N-дитиокарбамат) (B) присутствует в количестве 0,01-25 мас.% по содержанию нелетучих веществ в композиции покрытия, как определено в стандарте DIN EN ISO 3251 (июнь 2008 г.).
4. Композиция покрытия по любому из пп. 1-3, отличающаяся тем, что по меньшей мере одно комплексное соединение железо(III)-трис(N,N-дитиокарбамат) (B) выбирается из группы, состоящей из: железо(III)-трис(диметилдитиокарбамат), железо(III)-трис(диэтилдитиокарбамат) и железо(III)-трис(пирролидиндитиокарбамат).
5. Композиция покрытия по любому из пп. 1-4, отличающаяся тем, что связующее вещество (A) содержит по меньшей мере одну эпоксидную смолу (A1) и по меньшей мере одно сшивающее средство (A2), имеющее по меньшей мере одну функциональную аминогруппу.
6. Композиция покрытия по п. 5, отличающаяся тем, что по меньшей мере одна эпоксидная смола (A1) имеет массу эпоксидного эквивалента в диапазоне 100-300, определяемую в соответствии со стандартом DIN EN ISO 3001 (ноябрь 1999 г.).
7. Способ по меньшей мере частичного нанесения покрытия металлической подложки грунтовочным слоем, содержащим по меньшей мере стадию (1):
(1) по меньшей мере частичное контактирование металлической подложки с композицией покрытия по любому из пп. 1-6.
8. Способ по меньшей мере частичного нанесения покрытия металлической подложки многослойным покрытием, содержащий по меньшей мере стадии (1) и (2), а именно:
(1) по меньшей мере частичное контактирование металлической подложки с композицией покрытия по любому из пп. 1-6 для по меньшей мере частичного нанесения грунтовочного слоя на подложку, и
(2) нанесение по меньшей мере одного дополнительного слоя, предпочтительно верхнего покрывающего слоя или прозрачного покрывающего слоя, на грунтовочный слой, нанесенный на стадии (1).
9. Способ по п. 7 или 8, отличающийся тем, что перед стадией (1) металлическая подложка предварительно обрабатывается анодированием серной и винной кислотами (TSA) в соответствии со стандартом DIN EN 4704.
10. Способ по любому из пп. 7-9, отличающийся тем, что металлическая подложка представляет собой алюминиевый сплав группы 2XXX или 7XXX.
11. Применение композиции покрытия по любому из пп. 1-7 для защиты от коррозии металлических подложек, в частности в области производства самолетов.
12. Металлическая подложка, покрытая по меньшей мере частично композицией покрытия по любому из пп. 1-7.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP16201311.4 | 2016-11-30 | ||
| EP16201311 | 2016-11-30 | ||
| PCT/EP2017/080762 WO2018099942A1 (en) | 2016-11-30 | 2017-11-29 | Chromium-free coating composition with anti-corrosive effect for metallic substrates |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| RU2019119373A true RU2019119373A (ru) | 2021-01-11 |
| RU2019119373A3 RU2019119373A3 (ru) | 2021-02-03 |
| RU2753337C2 RU2753337C2 (ru) | 2021-08-13 |
Family
ID=57539006
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2019119373A RU2753337C2 (ru) | 2016-11-30 | 2017-11-29 | Свободная от хрома композиция покрытия с антикоррозийным эффектом для металлических подложек |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US11186730B2 (ru) |
| EP (1) | EP3548567B1 (ru) |
| CN (1) | CN109983085B (ru) |
| CA (1) | CA3043275A1 (ru) |
| ES (1) | ES2812709T3 (ru) |
| RU (1) | RU2753337C2 (ru) |
| WO (1) | WO2018099942A1 (ru) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA3043275A1 (en) | 2016-11-30 | 2018-06-07 | Akzo Nobel Coatings International B.V. | Chromium-free coating composition with anti-corrosive effect for metallic substrates |
| CN115279842A (zh) * | 2020-03-30 | 2022-11-01 | 阿克佐诺贝尔国际涂料股份有限公司 | 可高温固化的涂料组合物 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4560716A (en) * | 1983-08-30 | 1985-12-24 | Kabushiki Kaisha Toyota Chuo Kenkyusho | Rust preventing epoxy resin compositions |
| JPH0565450A (ja) | 1991-09-06 | 1993-03-19 | Honda Motor Co Ltd | 塩化ビニルプラスチゾル組成物 |
| JP3669844B2 (ja) | 1998-08-13 | 2005-07-13 | 日本ペイント株式会社 | リン酸系前処理を含むノンクロム防錆方法 |
| MXPA05009076A (es) * | 2003-02-25 | 2005-10-19 | Chemetall Gmbh | Metodos para recubrir superficies metalicas con una composicion rica en silano. |
| DE102005005858A1 (de) | 2005-02-08 | 2006-08-17 | Henkel Kgaa | Verfahren zur Beschichtung von Metallblech, insbesondere Zinkblech |
| US7686980B2 (en) * | 2005-09-30 | 2010-03-30 | Teledyne Scientific & Imaging, Llc | Corrosion inhibitors, methods of production and uses thereof |
| US8691028B2 (en) * | 2006-05-10 | 2014-04-08 | The Boeing Company | Article having a hexavalent-chromium-free, corrosion-inhibiting organic conversion coating thereon, and its preparation |
| DE102006039633A1 (de) | 2006-08-24 | 2008-03-13 | Henkel Kgaa | Chromfreies, thermisch härtbares Korrosionsschutzmittel |
| EP2118342A4 (en) * | 2007-03-05 | 2010-11-03 | Crosslink | CORROSION RESISTANT COATINGS WITH MODIFIED METAL SALTS OF CORROSION RESISTANT ORGANIC ANIONS |
| US20090297818A1 (en) * | 2008-05-29 | 2009-12-03 | Jeld-Wen, Inc. | Primer compositions and methods of making the same |
| US20100243108A1 (en) | 2009-03-31 | 2010-09-30 | Ppg Industries Ohio, Inc. | Method for treating and/or coating a substrate with non-chrome materials |
| JP5490086B2 (ja) | 2011-12-22 | 2014-05-14 | Ｂａｓｆジャパン株式会社 | クロムフリー塗料組成物及びこれを塗装して得られる塗膜 |
| EP3058041A1 (de) | 2013-10-16 | 2016-08-24 | BASF Coatings GmbH | Wässrige beschichtungszusammensetzung zum aufbringen einer decklackschicht |
| US20150322271A1 (en) | 2014-05-09 | 2015-11-12 | Prc-Desoto International, Inc. | Chromate free pretreatment primer |
| US20170096564A1 (en) | 2014-06-05 | 2017-04-06 | Basf Coatings Gmbh | Coating composition with anticorrosion effect |
| CA3043275A1 (en) | 2016-11-30 | 2018-06-07 | Akzo Nobel Coatings International B.V. | Chromium-free coating composition with anti-corrosive effect for metallic substrates |
-
2017
- 2017-11-29 CA CA3043275A patent/CA3043275A1/en active Pending
- 2017-11-29 RU RU2019119373A patent/RU2753337C2/ru active
- 2017-11-29 WO PCT/EP2017/080762 patent/WO2018099942A1/en not_active Ceased
- 2017-11-29 ES ES17805198T patent/ES2812709T3/es active Active
- 2017-11-29 EP EP17805198.3A patent/EP3548567B1/en active Active
- 2017-11-29 CN CN201780072432.5A patent/CN109983085B/zh active Active
- 2017-11-29 US US16/463,770 patent/US11186730B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US20190375947A1 (en) | 2019-12-12 |
| EP3548567A1 (en) | 2019-10-09 |
| CN109983085A (zh) | 2019-07-05 |
| WO2018099942A1 (en) | 2018-06-07 |
| EP3548567B1 (en) | 2020-07-22 |
| ES2812709T3 (es) | 2021-03-18 |
| CA3043275A1 (en) | 2018-06-07 |
| CN109983085B (zh) | 2021-04-23 |
| RU2753337C2 (ru) | 2021-08-13 |
| RU2019119373A3 (ru) | 2021-02-03 |
| US11186730B2 (en) | 2021-11-30 |
| BR112019010550A2 (pt) | 2019-09-17 |
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