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RU2019110727A - Двухкомпонентные адгезивные композиции без растворителей и способы их получения - Google Patents

Двухкомпонентные адгезивные композиции без растворителей и способы их получения Download PDF

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RU2019110727A
RU2019110727A RU2019110727A RU2019110727A RU2019110727A RU 2019110727 A RU2019110727 A RU 2019110727A RU 2019110727 A RU2019110727 A RU 2019110727A RU 2019110727 A RU2019110727 A RU 2019110727A RU 2019110727 A RU2019110727 A RU 2019110727A
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polyol
component
phosphate
composition according
isocyanate
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RU2019110727A
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RU2019110727A3 (ru
RU2739841C2 (ru
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Чэньянь БАЙ
Май ЧЭНЬ
Амира Аврил МАРИН
Джозеф Джеймс ЦУПАНЧИК
Иньчжун ГО
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Дау Глоубл Текнолоджиз Ллк
Ром Энд Хаас Компани
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    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
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    • C08G18/08—Processes
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    • C08G18/40—High-molecular-weight compounds
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    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
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    • C08G18/4216—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols from mixtures or combinations of aromatic dicarboxylic acids and aliphatic dicarboxylic acids and dialcohols
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    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4236—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups
    • C08G18/4238—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups derived from dicarboxylic acids and dialcohols
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    • C08G18/40—High-molecular-weight compounds
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    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4833—Polyethers containing oxyethylene units
    • C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
    • C08G18/4841—Polyethers containing oxyethylene units and other oxyalkylene units containing oxyethylene end groups
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/50—Polyethers having heteroatoms other than oxygen
    • C08G18/5075—Polyethers having heteroatoms other than oxygen having phosphorus
    • C08G18/5081—Polyethers having heteroatoms other than oxygen having phosphorus having phosphorus bound to oxygen only
    • C08G18/5084—Phosphate compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/721—Two or more polyisocyanates not provided for in one single group C08G18/73 - C08G18/80
    • C08G18/725—Combination of polyisocyanates of C08G18/78 with other polyisocyanates
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    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
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    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
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    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
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    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
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Claims (15)

1. Двухкомпонентная адгезивная композиция без растворителей, содержащая
полиольный компонент, содержащий соединение с фосфатной функциональной группой и по меньшей мере один полиол, выбранный из сложного полиэфира, простого полиэфира и их комбинаций; и
изоцианатный компонент, содержащий изоцианатный форполимер, который является продуктом реакции по меньшей мере одного изоцианатного мономера и по меньшей мере одного полиола, выбранного из сложного полиэфира, простого полиэфира и их комбинаций.
2. Композиция по п. 1, отличающаяся тем, что соединение с фосфатной функциональной группой имеет структуру I
Figure 00000001
3. Композиция по п. 2, отличающаяся тем, что соединение с фосфатной функциональной группой представляет собой полиол с фосфатной функциональной группой, содержащий две или более гидроксильные группы и одну или более структур I.
4. Композиция по п. 3, отличающаяся тем, что полиол с фосфатной функциональной группой является продуктом реакции полиола и полифосфорной кислоты.
5. Композиция по п. 3, отличающаяся тем, что полиол с фосфатной функциональной группой имеет молекулярную массу по меньшей мере 90, и она не должна превышать 4000 г/моль.
6. Композиция по п. 1, отличающаяся тем, что количество соединения с фосфатной функциональной группой в полиольном компоненте составляет по меньшей мере 0,2% мас. и не должно превышать 10% мас. относительно массы полиольного компонента.
7. Композиция по п. 1, отличающаяся тем, что изоцианатный мономер выбирают из ароматических изоцианатов, алифатических изоцианатов, модифицированных карбодиимидом изоцианатов и их комбинаций.
8. Композиция по п. 1, отличающаяся тем, что по меньшей мере один компонент из изоцианатного компонента и полиольного компонента дополнительно содержит биополиол.
9. Композиция по п. 8, отличающаяся тем, что биополиол является касторовым маслом.
10. Композиция по п. 1, отличающаяся тем, что массовое отношение изоцианатного компонента к полиольному компоненту составляет от 1:1 до 5:1.
11. Адгезивная композиция, которая является продуктом реакции отверждения полиольного компонента и изоцианатного компонента по п. 1.
12. Слоистая пленка, содержащая слой адгезивной композиции по п. 11.
RU2019110727A 2016-09-19 2016-09-19 Двухкомпонентные адгезивные композиции без растворителей и способы их получения RU2739841C2 (ru)

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US (1) US11608457B2 (ru)
EP (1) EP3516004A4 (ru)
JP (1) JP7030111B2 (ru)
CN (2) CN119220214A (ru)
AR (1) AR109638A1 (ru)
BR (1) BR112019005190B1 (ru)
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BR112020019574A2 (pt) * 2018-03-28 2021-01-05 Dow Global Technologies Llc Composições adesivas de dois componentes com base em isocianatos modificados com éster de fosfato isocianatos e métodos para produzir as mesmas
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