RU2019107043A - Смола с низким содержанием натрия - Google Patents
Смола с низким содержанием натрия Download PDFInfo
- Publication number
- RU2019107043A RU2019107043A RU2019107043A RU2019107043A RU2019107043A RU 2019107043 A RU2019107043 A RU 2019107043A RU 2019107043 A RU2019107043 A RU 2019107043A RU 2019107043 A RU2019107043 A RU 2019107043A RU 2019107043 A RU2019107043 A RU 2019107043A
- Authority
- RU
- Russia
- Prior art keywords
- resin
- batch
- copolymer
- quaternary ammonium
- ammonium groups
- Prior art date
Links
- 239000011347 resin Substances 0.000 title claims 6
- 229920005989 resin Polymers 0.000 title claims 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 title claims 2
- 229910052708 sodium Inorganic materials 0.000 title claims 2
- 239000011734 sodium Substances 0.000 title claims 2
- 239000008187 granular material Substances 0.000 claims 5
- 229920001577 copolymer Polymers 0.000 claims 4
- 125000001453 quaternary ammonium group Chemical group 0.000 claims 4
- 229920002554 vinyl polymer Polymers 0.000 claims 4
- 239000000178 monomer Substances 0.000 claims 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 claims 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 2
- 238000006243 chemical reaction Methods 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- 230000000379 polymerizing effect Effects 0.000 claims 2
- 239000012508 resin bead Substances 0.000 claims 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 1
- 125000003118 aryl group Chemical group 0.000 claims 1
- 239000003729 cation exchange resin Substances 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims 1
- 229920000058 polyacrylate Polymers 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/20—Manufacture of shaped structures of ion-exchange resins
- C08J5/22—Films, membranes or diaphragms
- C08J5/2287—After-treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J49/00—Regeneration or reactivation of ion-exchangers; Apparatus therefor
- B01J49/50—Regeneration or reactivation of ion-exchangers; Apparatus therefor characterised by the regeneration reagents
- B01J49/57—Regeneration or reactivation of ion-exchangers; Apparatus therefor characterised by the regeneration reagents for anionic exchangers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F257/00—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00
- C08F257/02—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00 on to polymers of styrene or alkyl-substituted styrenes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
- B01J39/08—Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
- B01J39/16—Organic material
- B01J39/18—Macromolecular compounds
- B01J39/20—Macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/04—Processes using organic exchangers
- B01J41/05—Processes using organic exchangers in the strongly basic form
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/08—Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/12—Macromolecular compounds
- B01J41/14—Macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J49/00—Regeneration or reactivation of ion-exchangers; Apparatus therefor
- B01J49/05—Regeneration or reactivation of ion-exchangers; Apparatus therefor of fixed beds
- B01J49/07—Regeneration or reactivation of ion-exchangers; Apparatus therefor of fixed beds containing anionic exchangers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J49/00—Regeneration or reactivation of ion-exchangers; Apparatus therefor
- B01J49/05—Regeneration or reactivation of ion-exchangers; Apparatus therefor of fixed beds
- B01J49/09—Regeneration or reactivation of ion-exchangers; Apparatus therefor of fixed beds of mixed beds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/44—Preparation of metal salts or ammonium salts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/20—Manufacture of shaped structures of ion-exchange resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Manufacturing & Machinery (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Developing Agents For Electrophotography (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Claims (7)
1. Партия гранул смолы,
где гранулы смолы содержат один или более виниловых полимеров с четвертичными аммонийными группами;
катионообменная смола, если присутствует в партии гранул смолы, содержится в количестве от 0 до 0,5% по массе в пересчете на массу партии гранул смолы;
90 мольных % четвертичных аммонийных групп или более ассоциированы с гидроксидным анионом;
натрий, если присутствует, содержится в количестве 0-100 ppb по массе в пересчете на массу партии гранул смолы.
2. Партия гранул смолы по п. 1, отличающаяся тем, что указанный виниловый полимер представляет собой ароматический виниловый полимер, полученный способом, включающим полимеризацию мономеров, содержащих стирол и дивинилбензол с получением предварительного сополимера, и последующую обработку предварительного сополимера по одной или более химическим реакциям для присоединения четвертичных аммонийных групп к предварительному сополимеру.
3. Партия гранул смолы по п. 1, отличающаяся тем, что указанный виниловый полимер представляет собой акриловый полимер, полученный способом, включающим полимеризацию мономеров, содержащих один или более акриловых мономеров с получением предварительного сополимера, и последующую обработку предварительного сополимера по одной или более химическим реакциям для присоединения четвертичных аммонийных групп к предварительному сополимеру.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201662381203P | 2016-08-30 | 2016-08-30 | |
| US62/381,203 | 2016-08-30 | ||
| US201762460954P | 2017-02-20 | 2017-02-20 | |
| US62/460,954 | 2017-02-20 | ||
| PCT/US2017/048544 WO2018044703A1 (en) | 2016-08-30 | 2017-08-25 | Low-sodium resin |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2019107043A true RU2019107043A (ru) | 2020-09-14 |
| RU2019107043A3 RU2019107043A3 (ru) | 2020-12-04 |
Family
ID=59930754
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2019107043A RU2019107043A (ru) | 2016-08-30 | 2017-08-25 | Смола с низким содержанием натрия |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US20210277161A1 (ru) |
| EP (1) | EP3507013A1 (ru) |
| JP (1) | JP2019526668A (ru) |
| KR (1) | KR20190046873A (ru) |
| CN (1) | CN109661269A (ru) |
| RU (1) | RU2019107043A (ru) |
| WO (1) | WO2018044703A1 (ru) |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2591573A (en) * | 1947-07-05 | 1952-04-01 | Rohm & Haas | Resinous insoluble reaction products of tertiary amines with haloalkylated vinyl aromatic hydrocarbon copolymers |
| US2669713A (en) * | 1950-10-27 | 1954-02-16 | Dow Chemical Co | Method of regenerating anion exchange resins |
| US2697079A (en) * | 1951-12-05 | 1954-12-14 | Koppers Co Inc | Ion-exchange resins containing quaternary ammonium hydroxide groups |
| US2697080A (en) * | 1951-12-05 | 1954-12-14 | Koppers Co Inc | Ion-exchange resins containing quaternary ammonium hydroxide groups |
| US3385787A (en) | 1967-04-03 | 1968-05-28 | Crane Co | Condensate purification process |
| US4025467A (en) | 1975-06-13 | 1977-05-24 | Rohm And Haas Company | Strong anion exchange resins free of active chloride and method of preparation |
| JPS58177140A (ja) * | 1982-04-12 | 1983-10-17 | Showa Denko Kk | 液体クロマトグラフイ−用多孔質充填剤及びその製造方法 |
| US5962183A (en) * | 1995-11-27 | 1999-10-05 | Clariant Finance (Bvi) Limited | Metal ion reduction in photoresist compositions by chelating ion exchange resin |
| WO1998027461A1 (en) * | 1996-12-17 | 1998-06-25 | Clariant International Ltd. | A method for reducing metal ion contaminants in photoresist compositions containing an organic polar solvent by ion exchange |
| US20080035564A1 (en) * | 2006-08-09 | 2008-02-14 | Solmetex, Inc. | Sorbent For Selective Removal Of Contaminants From Fluids |
| JP2010042395A (ja) * | 2008-03-05 | 2010-02-25 | Mitsubishi Chemicals Corp | アニオン交換樹脂、マクロポーラス型アニオン交換樹脂の製造方法、脱塩装置、発電所用復水脱塩装置、および懸濁性金属腐蝕生成物の除去方法 |
| US20110138935A1 (en) * | 2008-08-12 | 2011-06-16 | Wako Pure Chemical Industries, Ltd. | Polymer for filler for preprocessing column |
-
2017
- 2017-08-25 KR KR1020197007556A patent/KR20190046873A/ko not_active Ceased
- 2017-08-25 CN CN201780052306.3A patent/CN109661269A/zh active Pending
- 2017-08-25 RU RU2019107043A patent/RU2019107043A/ru unknown
- 2017-08-25 EP EP17771913.5A patent/EP3507013A1/en not_active Withdrawn
- 2017-08-25 WO PCT/US2017/048544 patent/WO2018044703A1/en not_active Ceased
- 2017-08-25 US US16/321,671 patent/US20210277161A1/en not_active Abandoned
- 2017-08-25 JP JP2019511399A patent/JP2019526668A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| EP3507013A1 (en) | 2019-07-10 |
| WO2018044703A1 (en) | 2018-03-08 |
| US20210277161A1 (en) | 2021-09-09 |
| JP2019526668A (ja) | 2019-09-19 |
| RU2019107043A3 (ru) | 2020-12-04 |
| CN109661269A (zh) | 2019-04-19 |
| KR20190046873A (ko) | 2019-05-07 |
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