RU2019105713A - Способ изготовления чувствительных к давлению клеевых композиций на водной основе - Google Patents
Способ изготовления чувствительных к давлению клеевых композиций на водной основе Download PDFInfo
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- RU2019105713A RU2019105713A RU2019105713A RU2019105713A RU2019105713A RU 2019105713 A RU2019105713 A RU 2019105713A RU 2019105713 A RU2019105713 A RU 2019105713A RU 2019105713 A RU2019105713 A RU 2019105713A RU 2019105713 A RU2019105713 A RU 2019105713A
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- Prior art keywords
- ester
- polyol
- conjugate
- unsaturated monomer
- emulsion polymer
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims 8
- 239000000853 adhesive Substances 0.000 title claims 4
- 230000001070 adhesive effect Effects 0.000 title claims 4
- 238000004519 manufacturing process Methods 0.000 title claims 2
- 238000000034 method Methods 0.000 claims 8
- 229920005862 polyol Polymers 0.000 claims 5
- 239000004908 Emulsion polymer Substances 0.000 claims 4
- 239000002253 acid Substances 0.000 claims 4
- 150000002148 esters Chemical class 0.000 claims 4
- 239000000178 monomer Substances 0.000 claims 4
- 150000003077 polyols Chemical class 0.000 claims 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims 2
- -1 glycerol ester Chemical class 0.000 claims 2
- 239000002383 tung oil Substances 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical group CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims 1
- 239000004820 Pressure-sensitive adhesive Substances 0.000 claims 1
- 239000000654 additive Substances 0.000 claims 1
- 230000000996 additive effect Effects 0.000 claims 1
- 239000002318 adhesion promoter Substances 0.000 claims 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 claims 1
- 239000012736 aqueous medium Substances 0.000 claims 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 239000003999 initiator Substances 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 230000003472 neutralizing effect Effects 0.000 claims 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims 1
- 239000004014 plasticizer Substances 0.000 claims 1
- 238000006116 polymerization reaction Methods 0.000 claims 1
- 230000000379 polymerizing effect Effects 0.000 claims 1
- 239000012966 redox initiator Substances 0.000 claims 1
- 239000002562 thickening agent Substances 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/062—Copolymers with monomers not covered by C09J133/06
- C09J133/064—Copolymers with monomers not covered by C09J133/06 containing anhydride, COOH or COOM groups, with M being metal or onium-cation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J191/00—Adhesives based on oils, fats or waxes; Adhesives based on derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/38—Pressure-sensitive adhesives [PSA]
- C09J7/381—Pressure-sensitive adhesives [PSA] based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C09J7/385—Acrylic polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1808—C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
- C09J2301/408—Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the adhesive layer
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
- C09J2301/414—Additional features of adhesives in the form of films or foils characterized by the presence of essential components presence of a copolymer
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2433/00—Presence of (meth)acrylic polymer
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Polymerisation Methods In General (AREA)
- Graft Or Block Polymers (AREA)
- Polymerization Catalysts (AREA)
Claims (13)
1. Способ изготовления клеевой композиции на водной основе, включающий:
диспергирование по меньшей мере одного ненасыщенного мономера в водной среде для образования эмульгированной смеси;
введение по меньшей мере одного инициатора в эмульгированную смесь, тем самым полимеризуя по меньшей мере один ненасыщенный мономер и образуя эмульсионный полимер; и
введение по меньшей мере одного сложного эфира полиола сопряженной кислоты в эмульсионный полимер по завершении полимеризации по меньшей мере одного ненасыщенного мономера, тем самым образуя клеевую композицию.
2. Способ по п. 1, отличающийся тем, что, по меньшей мере, одна сопряженная кислота содержит алифатическую карбоновую кислоту, содержащую по меньшей мере три сопряженные углерод-углеродные двойные связи.
3. Способ по п. 1, отличающийся тем, что по меньшей мере одна сопряженная кислота получена из тунгового масла.
4. Способ по п. 1, отличающийся тем, что, по меньшей мере, один сложный эфир полиола сопряженной кислоты представляет собой сложный эфир глицерина.
5. Способ по п. 1, отличающийся тем, что по меньшей мере один сложный эфир полиола сопряженной кислоты представляет собой тунговое масло.
6. Способ по п. 1, отличающийся тем, что, по меньшей мере, один сложный эфир полиола сопряженной кислоты составляет от 0,01 до 5% мас. клеевой композиции.
7. Способ по п. 1, дополнительно включающий введение инициаторов окисления-восстановления в эмульсионный полимер вместе со сложным эфиром полиола сопряженной кислоты.
8. Способ по п. 1, отличающийся тем, что, по меньшей мере, один ненасыщенный мономер выбран из группы, состоящей из 2-этилгексилакрилата, этилакрилата, бутилакрилата, метил(мет)акрилата, акриловой кислоты и смесей двух или более из них.
9. Способ по п. 1, дополнительно включающий введение в эмульсионный полимер по меньшей мере одной добавки, выбранной из группы, состоящей из загустителя, нейтрализующего агента, пластификатора, вещества для повышения клейкости, усилителя адгезии и комбинаций двух или более из них.
10. Чувствительный к давлению клей на водной основе, содержащий композицию, приготовленную согласно п. 1.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/CN2016/094830 WO2018027891A1 (en) | 2016-08-12 | 2016-08-12 | Method for making water-based pressure sensitive adhesive compositions |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| RU2019105713A3 RU2019105713A3 (ru) | 2020-08-28 |
| RU2019105713A true RU2019105713A (ru) | 2020-08-28 |
| RU2738816C2 RU2738816C2 (ru) | 2020-12-17 |
Family
ID=61161544
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2019105713A RU2738816C2 (ru) | 2016-08-12 | 2016-08-12 | Способ изготовления чувствительной к давлению клеевой композиции на водной основе |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US20190225844A1 (ru) |
| EP (1) | EP3497177B1 (ru) |
| JP (2) | JP6954991B2 (ru) |
| CN (1) | CN109790436B (ru) |
| AR (1) | AR109202A1 (ru) |
| BR (1) | BR112019002572B1 (ru) |
| MX (1) | MX2019001540A (ru) |
| RU (1) | RU2738816C2 (ru) |
| TW (1) | TWI812593B (ru) |
| WO (1) | WO2018027891A1 (ru) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2021173301A2 (en) * | 2020-02-27 | 2021-09-02 | Illinois Tool Works Inc. | Heat transfer label and process for the use thereof |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2889236A (en) * | 1956-07-17 | 1959-06-02 | Monsanto Chemicals | Latex base exterior protective coating compositions |
| JPS536193B1 (ru) * | 1967-12-11 | 1978-03-06 | ||
| US3547847A (en) * | 1968-08-13 | 1970-12-15 | Celanese Corp | Aqueous emulsion copolymers of vinyl alkanoates,alkyl acrylates,drying oil and another unsaturated compound |
| US4057527A (en) * | 1974-06-17 | 1977-11-08 | Borden, Inc. | Aqueous acrylate contact adhesive dispersions |
| JPS58225173A (ja) * | 1982-06-22 | 1983-12-27 | Sunstar Giken Kk | 水性接着剤組成物の製法 |
| JPS61101513A (ja) * | 1984-10-24 | 1986-05-20 | Nippon Synthetic Chem Ind Co Ltd:The | 不飽和ポリエステルの硬化方法 |
| DE69124354T3 (de) * | 1990-12-21 | 2003-04-24 | Rohm And Haas Co., Philadelphia | Lufthärtende Polymerzusammensetzung |
| US5326644A (en) * | 1993-02-05 | 1994-07-05 | Avery Dennison Corporation | Repulpable pressure-sensitive adhesive compositions |
| JP3006646B2 (ja) * | 1993-05-12 | 2000-02-07 | 昭和高分子株式会社 | アクリル系感圧接着剤 |
| CN1043314C (zh) * | 1995-04-13 | 1999-05-12 | 华中理工大学 | 铸造用改性水溶性有机粘结剂的制造方法 |
| RU2201948C1 (ru) * | 2001-09-04 | 2003-04-10 | Мясников Дмитрий Николаевич | Полимерная композиция для липкой пленки |
| EP1420054A1 (en) * | 2002-11-18 | 2004-05-19 | Rohm And Haas Company | Curable adhesive compositions |
| JP4147476B2 (ja) * | 2003-04-25 | 2008-09-10 | Ｄｉｃ株式会社 | 酸化重合性組成物 |
| US7863485B2 (en) * | 2004-12-10 | 2011-01-04 | Omnitech Environmental, Llc | Additive and vehicle for inks, paints, coatings and adhesives |
| US20060235131A1 (en) * | 2005-04-15 | 2006-10-19 | Hughes Kathleen A | Process for preparing aqueous dispersions of multistage emulsion polymers |
| US7566759B2 (en) * | 2005-10-27 | 2009-07-28 | Georgia-Pacific Chemicals Llc | Non-aqueous coating formulation of low volatility |
| BRPI0701521A2 (pt) * | 2007-04-05 | 2008-11-18 | Petroflex Ind E Com S A | copolÍmeros de estireno e butadieno, processo para a preparaÇço dos mesmos e composiÇÕes adesivas de alta coesço |
| US8796351B2 (en) * | 2007-05-21 | 2014-08-05 | Avery Dennison Corporation | Pressure sensitive adhesives made from renewable resources and related methods |
| JP5607337B2 (ja) * | 2009-10-27 | 2014-10-15 | リンテック株式会社 | 水分散型アクリル系粘着剤組成物、粘着シート及びその製造方法 |
| WO2013086014A1 (en) * | 2011-12-07 | 2013-06-13 | State Of Oregon Acting By And Through The State Board Of Higher Education On Behalf Of Oregon State University | Vegetable oil-based pressure-sensitive adhesives |
| CN102732200B (zh) * | 2012-07-13 | 2014-08-06 | 中物院成都科学技术发展中心 | 植物油基胶粘剂、复合人造板的制造方法以及复合人造板 |
| KR20150140984A (ko) * | 2014-06-09 | 2015-12-17 | 진봉진 | 천연 페놀계 고분자의 제조방법 |
-
2016
- 2016-08-12 MX MX2019001540A patent/MX2019001540A/es unknown
- 2016-08-12 JP JP2019507215A patent/JP6954991B2/ja active Active
- 2016-08-12 CN CN201680089639.9A patent/CN109790436B/zh active Active
- 2016-08-12 EP EP16912346.0A patent/EP3497177B1/en active Active
- 2016-08-12 BR BR112019002572-3A patent/BR112019002572B1/pt active IP Right Grant
- 2016-08-12 US US16/324,834 patent/US20190225844A1/en not_active Abandoned
- 2016-08-12 WO PCT/CN2016/094830 patent/WO2018027891A1/en not_active Ceased
- 2016-08-12 RU RU2019105713A patent/RU2738816C2/ru active
-
2017
- 2017-07-18 TW TW106124026A patent/TWI812593B/zh active
- 2017-07-28 AR ARP170102155A patent/AR109202A1/es active IP Right Grant
-
2021
- 2021-09-30 JP JP2021161589A patent/JP7344261B2/ja active Active
Also Published As
| Publication number | Publication date |
|---|---|
| JP7344261B2 (ja) | 2023-09-13 |
| BR112019002572A2 (pt) | 2019-05-21 |
| AR109202A1 (es) | 2018-11-07 |
| EP3497177A4 (en) | 2020-01-29 |
| MX2019001540A (es) | 2019-05-09 |
| WO2018027891A1 (en) | 2018-02-15 |
| RU2019105713A3 (ru) | 2020-08-28 |
| TWI812593B (zh) | 2023-08-21 |
| EP3497177B1 (en) | 2024-01-17 |
| CN109790436B (zh) | 2022-11-01 |
| JP2022003137A (ja) | 2022-01-11 |
| EP3497177A1 (en) | 2019-06-19 |
| BR112019002572B1 (pt) | 2022-04-19 |
| CN109790436A (zh) | 2019-05-21 |
| US20190225844A1 (en) | 2019-07-25 |
| JP6954991B2 (ja) | 2021-10-27 |
| RU2738816C2 (ru) | 2020-12-17 |
| TW201809019A (zh) | 2018-03-16 |
| JP2019528346A (ja) | 2019-10-10 |
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