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RU2018132354A - 4-амино-6-(гетероциклические)пиколинаты и 6-амино-2-(гетероциклические)пиримидин-4-карбоксилаты и их использование в качестве гербицидов - Google Patents

4-амино-6-(гетероциклические)пиколинаты и 6-амино-2-(гетероциклические)пиримидин-4-карбоксилаты и их использование в качестве гербицидов Download PDF

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RU2018132354A
RU2018132354A RU2018132354A RU2018132354A RU2018132354A RU 2018132354 A RU2018132354 A RU 2018132354A RU 2018132354 A RU2018132354 A RU 2018132354A RU 2018132354 A RU2018132354 A RU 2018132354A RU 2018132354 A RU2018132354 A RU 2018132354A
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Джозеф Д. ЭККЕЛЬБАРДЖЕР
Джеффри Б. ЭПП
Стефен Крэйг ФИЛДЗ
Линдси Г. ФИШЕР
Натали К. ДЖАМПЬЕТРО
Катерине А. ГЮНТЕНСПБЕРГЕР
Кристиан Т. ЛОУ
Джефф ПЕТКУС
Джошуа Рот
Норберт М. САЧИВИ
Пол Ричард ШМИТЦЕР
Томас Л. СИДДАЛЛ
Ник Х. ВАН
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ДАУ АГРОСАЙЕНСИЗ ЭлЭлСи
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Claims (42)

1     1. Соединение формулы (I):
Figure 00000001
,
где X представляет собой CF;
R1 представляет собой OR1′, где R1′ представляет собой водород, C1-C8 алкил или C7-C10 арилалкил;
R2 представляет собой галоген, C1-C4 алкил, C1-C4 галогеналкил, C2-C4 алкенил, C2-C4 галогеналкенил, C2-C4 алкинил, C1-C4 алкокси, C1-C4 галогеналкокси, C1-C4 алкилтио, C1-C4 галогеналкилтио, амино, C1-C4 алкиламино, C2-C4 галогеналкиламино, формил, C1-C3 алкилкарбонил, C1-C3 галогеналкилкарбонил, циано или группу формулы -CR17=CR18-SiR19R20R21, где R17 представляет собой водород, F или Cl; R18 представляет собой водород, F, Cl, C1-C4 алкил или C1-C4 галогеналкил; и R19, R20 и R21 независимо представляют собой C1-C10 алкил, C3-C6 циклоалкил, фенил, замещенный фенил, C1-C10 алкокси или OH;
R3 и R4 независимо представляют собой водород, C1-C6 алкил, C1-C6 галогеналкил, C3-C6 алкенил, C3-C6 галогеналкенил, C3-C6 алкинил, формил, C1-C3 алкилкарбонил, C1-C3 галогеналкилкарбонил, C1-C6 алкоксикарбонил, C1-C6 алкилкарбамил, C1-C6 алкилсульфонил, C1-C6 триалкилсилил, C1-C6 диалкилфосфонил, или R3 и R4, взятые вместе с N, представляют собой 5- или 6-членное насыщенное кольцо, или R3 и R4, взятые вместе, представляют собой =CR3′(R4′), где R3′ и R4′ независимо представляют собой водород, C1-C6 алкил, C3-C6 алкенил, C3-C6 алкинил, C1-C6 алкокси или C1-C6 алкиламино, или R3′ и R4′, взятые вместе с =C, представляют собой 5- или 6-членное насыщенное кольцо;
A представляет собой одну из групп A1-A36
Figure 00000002
Figure 00000003
Figure 00000003
Figure 00000004
R5 представляет собой водород, галоген, C1-C4 алкил, C1-C4 галогеналкил, циклопропил, галогенциклопропил, C2-C4 алкенил, C2-C4 галогеналкенил, C2-C4 алкинил, C1-C3 алкокси, C1-C3 галогеналкокси, C1-C3 алкилтио, C1-C3 галогеналкилтио, амино, C1-C4 алкиламино, C2-C4 галогеналкиламино, OH или CN;
R6, R6′ и R6″ независимо представляют собой водород, галоген, C1-C4 алкил, C1-C4 галогеналкил, циклопропил, галогенциклопропил, C2-C4 алкенил, C2-C4 галогеналкенил, C2-C4 алкинил, C1-C3 алкокси, C1-C3 галогеналкокси, C1-C3 алкилтио, C1-C3 галогеналкилтио, амино, C1-C4 алкиламино или C2-C4 галогеналкиламино, OH, CN или NO2;
R7 и R7’ независимо представляют собой водород, галоген, C1-C4 алкил, C1-C4 галогеналкил, циклопропил, галогенциклопропил, C2-C4 алкенил, C2-C4 галогеналкенил, C2-C4 алкинил, C1-C3 алкокси, C1-C3 галогеналкокси,C1-C3 алкилтио, C1-C3 галогеналкилтио, амино, C1-C4 алкиламино, C2-C4 галогеналкиламино или фенил;
R8 представляет собой водород, C1-C6 алкил, C1-C6 галогеналкил, C3-C6 алкенил, C3-C6 галогеналкенил, C3-C6 алкинил, формил, C1-C3 алкилкарбонил, C1-C3 галогеналкилкарбонил, C1-C6 алкоксикарбонил, C1-C6 алкилкарбамил, C1-C6 алкилсульфонил, C1-C6 триалкилсилил или фенил;
или его N-оксид или сельскохозяйственно приемлемая соль.
2     2. Соединение по п. 1,
где
R1 представляет собой OR1’, где R1’ представляет собой водород, C1-C8 алкил или C7-C10 арилалкил;
R2 представляет собой галоген, C1-C4 алкил, C1-C4 галогеналкил, C2-C4-алкенил, C2-C4 галогеналкенил, C2-C4 алкинил, C1-C4-алкокси, C1-C4 галогеналкокси, C1-C4 алкилтио или C1-C4 галогеналкилтио;
R3 и R4 представляют собой водород, C1-C6 алкил, C1-C6 галогеналкил, C3-C6 алкенил, C3-C6 галогеналкенил, C3-C6 алкинил, формил, C1-C3 алкилкарбонил, C1-C3 галогеналкилкарбонил, или R3 и R4, взятые вместе, представляют собой =CR3′(R4′), где R3′ и R4′ независимо представляют собой водород, C1-C6 алкил, C3-C6 алкенил, C3-C6 алкинил, C1-C6 алкокси или C1-C6 алкиламино;
A представляет собой A1, A2, A3, A7, A8, A9, A10, A11, A12, A13, A14, A15, A21, A22, A23, A24, A27, A28, A29, A30, A31 или A32;
R5 представляет собой водород, галоген, C1-C4 алкил, C1-C4 галогеналкил, C2-C4 алкенил, C2-C4 галогеналкенил, C2-C4 алкинил, C1-C3 алкокси, C1-C3 галогеналкокси, C1-C3 алкилтио, C1-C3 галогеналкилтио, амино, C1-C4 алкиламино или C2-C4 галогеналкиламино;
R6, R6’ и R6’’ независимо представляют собой водород, галоген, C1-C4 алкил, C1-C4 галогеналкил, циклопропил, галогенциклопропил, C2-C4 алкенил, C2-C4 галогеналкенил, C2-C4 алкинил, C1-C3 алкокси, C1-C3 галогеналкокси, CN или NO2;
R7 и R7’ независимо представляют собой водород, галоген, C1-C4 алкил, C1-C4 галогеналкил, C1-C3 алкокси, C1-C3 галогеналкокси, C1-C3 алкилтио, циклопропил, амино или C1-C4 алкиламино;
R8 представляет собой водород, C1-C6 алкил, C1-C4 галогеналкил, C3-C6 алкенил, C3-C6 галогеналкенил, формил, C1-C3 алкилкарбонил, C1-C3 галогеналкилкарбонил, C1-C6 алкоксикарбонил или C1-C6 алкилкарбамил.
3. Соединение по п. 1 или 2, где R2 представляет собой галоген, C2-C4-алкенил, C2-C4 галогеналкенил или C1-C4-алкокси.
4. Соединение по любому из пп. 1-3, где R2 представляет собой Cl, метокси, винил или 1-пропенил.
5. Соединение по любому из пп. 1-4, где R3 и R4 представляют собой водород.
6. Соединение по любому из пп. 1-5, где A представляет собой A1, A2, A3, A7, A8, A9, A10, A13, A14 или A15.
7. Соединение по любому из пп. 1-6, где A представляет собой A1, A2, A3, A13, A14 или A15.
8. Соединение по любому из пп. 1-7, где A представляет собой A15.
9. Соединение по любому из пп. 1-8, где R5 представляет собой водород или F.
10. Соединение по любому из пп. 1-9, где R5 представляет собой F.
11. Соединение по любому из пп. 1-10, где R6 представляет собой водород или F.
12. Соединение по любому из пп. 1-11, где R6″ представляет собой водород, галоген, C1-C4 алкил, C1-C4 галогеналкил, циклопропил, C2-C4 алкинил, CN или NO2.
13. Соединение по любому из пп. 1-12, где R6, R6′ и R6″ все представляют собой водород.
14. Соединение по любому из пп. 1-13, где соединение представляет собой 4-амино-3-хлор-5-фтор-6-(7-фтор-1H-индол-6-ил)пиколиновую кислоту.
15. Соединение по любому из пп. 1-13, где соединение представляет собой метил 4-амино-3-хлор-5-фтор-6-(7-фтор-1H-индол-6-ил)пиколинат.
16. Гербицидная композиция, включающая соединение по любому из пп. 1-15 и сельскохозяйственно приемлемый адъювант или носитель.
17. Композиция по п. 16, дополнительно включающая дополнительный пестицид.
18. Композиция по п. 16 или 17, дополнительно включающая антидод для гербицида.
19. Способ борьбы с нежелательной растительностью, который включает нанесение на растительность или площадь вблизи растительности, или внесение в почву или воду для предотвращения появления или роста растительности соединения по любому из пп. 1-15 или гербицидной композиции по любому из пп. 16-18.
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