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RU2018131350A - Насыпные катализаторы гидропереработки из смешанного оксида металла/углерода, содержащие никель, и их применение - Google Patents

Насыпные катализаторы гидропереработки из смешанного оксида металла/углерода, содержащие никель, и их применение Download PDF

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RU2018131350A
RU2018131350A RU2018131350A RU2018131350A RU2018131350A RU 2018131350 A RU2018131350 A RU 2018131350A RU 2018131350 A RU2018131350 A RU 2018131350A RU 2018131350 A RU2018131350 A RU 2018131350A RU 2018131350 A RU2018131350 A RU 2018131350A
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acid
tungsten
molybdenum
sum
molar ratio
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RU2018131350A
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RU2018131350A3 (ru
RU2728793C2 (ru
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Якоб Ари БЕРГВЕРФФ
Вилхелмус Клеменс Йозеф Верман
Рональд Ян ХЁЙБЕРТС
Сона ЭЙСБАУТС-ШПИЧКОВА
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Альбемарл Юроп Спрл
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Claims (28)

1. Предшественник насыпного катализатора на основе NiW, NiMo или NiMoW, имеющий состав, содержащий оксид никеля, а также оксид молибдена, или оксид вольфрама, или их смеси, а также органический компонент, полученный из органической добавки, где общее количество оксида молибдена и оксида вольфрама составляет по меньшей мере 30 масс.%, молярное отношение никеля к сумме молибдена и вольфрама выше чем 0,05, и молярное отношение углерода к сумме молибдена и вольфрама составляет от 1,5 до 10; и где органическая добавка выбрана из уксусной кислоты, аспарагиновой кислоты, лимонной кислоты, муравьиной кислоты, фумаровой кислоты, глюконовой кислоты, глютаминовой кислоты, глиоксиловой кислоты, кетоглутаровой кислоты, малеиновой кислоты, яблочной кислоты, щавелевоуксусной кислоты, пропионовой кислоты, пировиноградной кислоты, янтарной кислоты, фруктозы, глюкозы, лактозы, сахарозы, сорбита, ксилита, серина и их смесей.
2. Предшественник насыпного катализатора по п. 1, дополнительно имеющий площадь поверхности по БЭТ, при измерении посредством физической адсорбции N2, <40 м2/г.
3. Предшественник насыпного катализатора по п. 1, дополнительно содержащий Ni-кристаллы, определяемые посредством метода просвечивающей электронной микроскопии (TEM).
4. Предшественник насыпного катализатора по п. 1, дополнительно имеющий пик при 45° 2-тета на дифрактограмме, полученной дифракционным рентгеновским анализом (XRD) при применении рентгеновского излучения с длиной волны 1,54 Å.
5. Предшественник насыпного катализатора по п. 1, отличающийся отсутствием на его дифрактограмме, полученной дифракционным рентгеновским анализом (XRD) при применении рентгеновского излучения с длиной волны 1,54 Å, любых пиков с полной шириной на половине максимума в радианах (FWHM) менее чем 2° 2-тета в интервале 10-40° 2-тета.
6. Предшественник насыпного катализатора по п. 1, где молярное отношение углерода к сумме молибдена и вольфрама составляет от 1,5 до 7,0.
7. Предшественник насыпного катализатора по п. 1, дополнительно имеющий молярное отношение никеля к сумме молибдена и вольфрама от 0,10 до 1,05.
8. Предшественник насыпного катализатора по п. 6, где молярное отношение никеля к молибдену плюс вольфрам составляет от 0,20 до 0,75.
9. Предшественник насыпного катализатора по п. 1, дополнительно содержащий оксид никеля в количестве от 2 до 30 масс.%.
10. Предшественник насыпного катализатора по п. 1, где общее количество оксида молибдена и оксида вольфрама составляет от 40 до 80 масс.%.
11. Предшественник насыпного катализатора по п. 1, где количество углерода составляет от 10 до 30 масс.%.
12. Способ гидропереработки углеводородного сырья, содержащего органические соединения серы и азота, включающий стадию осуществления контакта углеводородного сырья с оксидным насыпным катализатором на основе NiW, NiMo или NiMoW, полученным из предшественника насыпного катализатора по любому из п.п. 1-11, причем данный катализатор содержит минимальную загрузку металла 2,0 моля в сумме молибдена и вольфрама на литр реактора, где молярное отношение никеля к сумме молибдена и вольфрама выше, чем 0,05, и молярное отношение углерода к сумме молибдена и вольфрама составляет от 1,5 до 10.
13. Способ по п. 12, где катализатор дополнительно имеет пик при 45° 2-тета на дифрактограмме, полученной дифракционным рентгеновским анализом (XRD) при применении рентгеновского излучения с длиной волны 1,54 Å.
14. Способ по п. 12, где катализатор дополнительно содержит Ni-кристаллы, определяемые посредством метода просвечивающей электронной микроскопии (TEM).
15. Способ по п. 12, где катализатор содержит неорганическое связующее, содержащее кремнезем, кремнезем-глинозем, глинозем, диоксид титана, глинозем, покрытый диоксидом титана, диоксид циркония, бентонит, аттапульгит или их смеси.
16. Способ по п. 12, где загрузка металла из молибдена и вольфрама на литр реактора составляет от 3,0 до 7,0.
17. Способ по п. 12, где молярное отношение углерода к сумме молибдена и вольфрама составляет от 1,5 до 7,0.
18. Способ по п. 12, где молярное отношение никеля к сумме молибдена и вольфрама составляет от 0,10 до 1,05.
19. Способ по п. 12, где молярное отношение никеля к сумме молибдена и вольфрама составляет от 0,20 до 0,75.
20. Способ получения предшественника катализатора, содержащего смешанный оксид металла и органическую фазу, по любому из п.п. 1-11, включающий
a. формирование раствора в протонсодержащей жидкости одного или нескольких растворимых металлсодержащих соединений, содержащих никель и молибден или вольфрам или их смесь и одно или несколько органических соединений, где молярное отношение никеля к сумме молибдена и вольфрама составляет более чем 0,05;
b. испарение протонсодержащей жидкости;
c. частичное разложение металлоорганической фазы с образованием предшественника катализатора из смешанного оксида металла и органической фазы, где молярное отношение углерода к сумме молибдена и вольфрама составляет от 1,5 до 10;
где одним или несколькими органическими соединениями являются уксусная кислота, аспарагиновая кислота, лимонная кислота, муравьиная кислота, фумаровая кислота, глюконовая кислота, гютаминовая кислота, глиоксиловая кислота, кетоглутаровая кислота, малеиновая кислота, яблочная кислота, щавелевоуксусная кислота, пропионовая кислота, пировиноградная кислота, янтарная кислота, фруктоза, глюкоза, лактоза, сахароза, сорбит, ксилит, серин и их смеси.
21. Способ по п. 20, где одно или несколько органических соединений являются органической кислотой или сахаром.
22. Способ получения оксидного катализатора, включающий формование предшественника насыпного катализатора по п. 20.
23. Способ по п. 22, где формование предшественника насыпного катализатора включает формование экструдата с применением неорганического связующего и воды и затем сушку экструдатов при температуре по меньшей мере 120°C.
24. Способ получения сульфидного катализатора, включающий сульфидирование насыпного катализатора по п. 20.
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Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2665484C1 (ru) * 2017-08-25 2018-08-30 Федеральное государственное бюджетное учреждение науки Ордена Трудового Красного Знамени Институт нефтехимического синтеза им. А.В. Топчиева Российской академии наук (ИНХС РАН) Способ получения катализатора и способ гидрирования нефтеполимерных смол в его присутствии
US11504699B2 (en) 2019-06-27 2022-11-22 King Fahd University Of Petroleum And Minerals Preparation of mesoporous silica supported NiMoS catalysts for hydrodesulfurization application
CN112844416A (zh) * 2019-10-25 2021-05-28 中国石油化工股份有限公司 一种加氢催化剂及其制备方法
CN111254461B (zh) * 2020-01-19 2021-08-27 安徽大学 一种光还原二氧化碳的氧化钨/碘氧铋异质结材料及其制备方法和应用
CN116917035A (zh) * 2021-02-22 2023-10-20 雪佛龙美国公司 多金属本体加氢加工催化剂
KR20240023395A (ko) 2021-06-22 2024-02-21 셰브런 유.에스.에이.인크. 다중-금속성 벌크 수소화처리 촉매
CN116060053B (zh) * 2021-10-29 2024-10-11 中国石油化工股份有限公司 待再生催化剂的再生方法以及待再生催化剂的活性恢复方法

Family Cites Families (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4094820A (en) 1977-03-11 1978-06-13 Union Oil Company Of California Manufacture of cobalt and/or nickel-molybdenum-alumina catalysts
DD145231A1 (de) 1979-08-06 1980-12-03 Karl Becker Katalysatorkombination fuer die einstufige hydrierung von kohlenwasserstoffgemischen
US5086027A (en) * 1990-12-18 1992-02-04 Exxon Research And Engineering Company Novel noble metal supported hydrotreating catalysts
US6635599B1 (en) * 1997-07-15 2003-10-21 Exxonmobil Research & Engineering Company Mixed metal catalyst, its preparation by co-precipitation, and its use
US6156695A (en) 1997-07-15 2000-12-05 Exxon Research And Engineering Company Nickel molybdotungstate hydrotreating catalysts
DK1150768T3 (da) 1999-01-15 2004-09-20 Akzo Nobel Nv En blandet metalkatalysatorsammensætning, dens fremstilling og anvendelse
US6534437B2 (en) * 1999-01-15 2003-03-18 Akzo Nobel N.V. Process for preparing a mixed metal catalyst composition
DE60134140D1 (de) 2000-07-12 2008-07-03 Albemarle Netherlands Bv Verfahren zur herstellung eines ein additiv enthaltenden mischmetallkatalysators
AU2001289625A1 (en) 2000-07-12 2002-01-21 Akzo Nobel N.V. Process for preparing an additive-based mixed metal catalyst
FR2841798B1 (fr) * 2002-07-03 2005-03-04 Inst Francais Du Petrole Catalyseur d'hydrotraitement contenant un compose organique azote et son utilisation
US20050109674A1 (en) * 2003-11-20 2005-05-26 Advanced Refining Technologies Llc Hydroconversion catalysts and methods of making and using same
US8394263B2 (en) 2005-10-26 2013-03-12 Albemarle Netherlands B.V. Bulk catalyst comprising metal oxidic particles and a process for the manufacture thereof
KR101353846B1 (ko) 2005-10-26 2014-01-20 알베마를 네덜란드 비.브이. 8족 금속 및 몰리브덴을 포함하는 벌크 수소화공정 촉매,그의 제조 및 용도
WO2007050636A2 (en) 2005-10-26 2007-05-03 Exxonmobil Research And Engineering Company Hydroprocessing using bulk bimetallic catalysts
JP5564179B2 (ja) 2005-10-26 2014-07-30 エクソンモービル リサーチ アンド エンジニアリング カンパニー 水熱調製されたバルク多元金属触媒を用いる水素処理
ES2758348T3 (es) 2005-10-26 2020-05-05 Albemarle Netherlands Bv Un catalizador en masa que comprende partículas de óxido metálico de níquel-wolframio y un método de preparación del mismo
US7951746B2 (en) 2006-10-11 2011-05-31 Exxonmobil Research And Engineering Company Bulk group VIII/group VIB metal catalysts and method of preparing same
JP5412286B2 (ja) 2006-10-11 2014-02-12 エクソンモービル リサーチ アンド エンジニアリング カンパニー バルク第ｖｉｉｉ族／ｖｉｂ族金属触媒に対する水素処理方法
CN101578352B (zh) * 2006-10-11 2014-04-16 埃克森美孚研究工程公司 本体第viii族/第vib族金属催化剂及其制备方法
JP5508856B2 (ja) 2006-12-19 2014-06-04 エクソンモービル リサーチ アンド エンジニアリング カンパニー 高活性の担持留出油水素処理触媒
US8343887B2 (en) * 2007-10-31 2013-01-01 Chevron U.S.A. Inc. Hydroconversion processes employing multi-metallic catalysts and method for making thereof
EP2222400B1 (en) 2007-12-04 2016-06-08 Albemarle Netherlands BV Bulk catalyst composition comprising bulk metal oxide particles and its preparation method
US9174206B2 (en) 2008-10-06 2015-11-03 Exxonmobile Research And Engineering Company Catalysts having increased stability
CN101722055B (zh) * 2008-10-28 2013-05-01 中国石油化工股份有限公司 硫化型催化剂的制备方法
BRPI1009565B1 (pt) * 2009-03-06 2018-05-02 Albemarle Europe Sprl "precursor de catalisador e catalisador de metal misto sulfídico bruto seus métodos de fabricação e uso em conversão de gás de síntese em álcool."
US7931799B2 (en) 2009-04-29 2011-04-26 Chevron U.S.A. Inc. Hydroconversion multi-metallic catalyst and method for making thereof
EA022003B1 (ru) * 2009-04-29 2015-10-30 Шеврон Ю.Эс.Эй. Инк. Полиметаллический катализатор для гидропереработки и способ его получения
IT1398288B1 (it) * 2009-09-30 2013-02-22 Eni Spa Ossidi misti di metalli di transizione, catalizzatori di idrotrattamento da essi ottenuti, e processo di preparazione comprendente procedimenti sol-gel
US10022712B2 (en) * 2010-06-01 2018-07-17 Exxonmobil Research And Engineering Company Hydroprocessing catalysts and their production
RU2012154275A (ru) * 2010-06-01 2014-07-20 ЭкссонМобил Рисерч энд Энджиниринг Компани Катализаторы гидрообработки и их получение
KR101796792B1 (ko) * 2011-02-09 2017-11-13 에스케이이노베이션 주식회사 촉매를 이용하여 수소화 처리 반응을 통해 황 및 수은이 포함된 탄화수소 원료로부터 이들을 동시에 제거하는 방법
ITMI20110510A1 (it) 2011-03-30 2012-10-01 Eni Spa Ossidi misti di metalli di transizione, catalizzatori di idrotrattamento da essi ottenuti, e processo di preparazione
US9776177B2 (en) * 2012-03-29 2017-10-03 Wayne State University Bimetal catalysts
US20130261362A1 (en) 2012-03-30 2013-10-03 Exxonmobil Research And Engineering Company Coprocessing of biofeeds with bulk mixed metal catalysts
CN104785274B (zh) 2015-04-13 2017-03-29 河北工业大学 一种大孔径本体型Ni‑Mo加氢脱氧催化剂的制备方法

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