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RU2018125264A - CATALYST COMPOSITION AND METHOD OF ISOMERIZATION - Google Patents

CATALYST COMPOSITION AND METHOD OF ISOMERIZATION Download PDF

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RU2018125264A
RU2018125264A RU2018125264A RU2018125264A RU2018125264A RU 2018125264 A RU2018125264 A RU 2018125264A RU 2018125264 A RU2018125264 A RU 2018125264A RU 2018125264 A RU2018125264 A RU 2018125264A RU 2018125264 A RU2018125264 A RU 2018125264A
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catalyst according
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RU2018125264A
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RU2739200C2 (en
RU2018125264A3 (en
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ДЕР ХАУ Менно Фейко ВАН
Рихард Беренд МАУЭР
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Шелл Интернэшнл Рисерч Маатсхаппий Б.В.
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/80—Mixtures of different zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/74—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/74—Noble metals
    • B01J29/7446—EUO-type, e.g. EU-1, TPZ-3 or ZSM-50
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/74—Noble metals
    • B01J29/7469—MTW-type, e.g. ZSM-12, NU-13, TPZ-12 or Theta-3
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/02—Monocyclic hydrocarbons
    • C07C15/067—C8H10 hydrocarbons
    • C07C15/073—Ethylbenzene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/02—Monocyclic hydrocarbons
    • C07C15/067—C8H10 hydrocarbons
    • C07C15/08—Xylenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2702—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously
    • C07C5/2708—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously with crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/20—After treatment, characterised by the effect to be obtained to introduce other elements in the catalyst composition comprising the molecular sieve, but not specially in or on the molecular sieve itself
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • C07C2529/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65 containing iron group metals, noble metals or copper
    • C07C2529/74—Noble metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/80—Mixtures of different zeolites
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Claims (15)

1. Композиция катализатора, которая содержит компонент, представляющий собой материал носителя, и компонент, представляющий собой металл(-ы), поддерживаемый компонентом, представляющим собой материал носителя, причем компонент, представляющий собой материал носителя, содержит (i) цеолит типа ZSM-12 в количестве от 2 до 20% мас. в пересчете на общую массу материала носителя, при этом цеолит типа ZSM-12 характеризуется молярным соотношением диоксида кремния к оксиду алюминия в диапазоне от 60 до 200; (ii) цеолит типа EU-1 в количестве от 2 до 30% мас. в пересчете на общую массу материала носителя, при этом цеолит типа EU-1 характеризуется молярным соотношением диоксида кремния к оксиду алюминия в диапазоне от 20 до 200; и неорганическое связующее в количестве в диапазоне от 55 до 96% мас. в пересчете на общую массу материала носителя; и при этом компонент, представляющий собой металл(-ы), содержит металл VIII группы в количестве по меньшей мере 0,01% мас. в пересчете на общую массу катализатора. 1. The catalyst composition, which contains a component representing a carrier material, and a component representing a metal (s) supported by a component representing a carrier material, and a component representing a carrier material, contains (i) zeolite type ZSM-12 in an amount of from 2 to 20% wt. in terms of the total mass of the carrier material, while the zeolite type ZSM-12 is characterized by a molar ratio of silicon dioxide to alumina in the range from 60 to 200; (ii) zeolite type EU-1 in an amount of from 2 to 30% wt. in terms of the total weight of the carrier material, while the EU-1 type zeolite is characterized by a molar ratio of silicon dioxide to alumina in the range from 20 to 200; and inorganic binder in an amount in the range from 55 to 96% wt. in terms of the total mass of carrier material; and wherein the component, which is a metal (s), contains a metal of group VIII in an amount of at least 0.01% wt. in terms of the total weight of the catalyst. 2. Катализатор по п. 1, отличающийся тем, что цеолит типа ZSM-12 присутствует в количестве в диапазоне от 2 до 15% мас. в пересчете на общую массу материала носителя.2. The catalyst according to claim 1, characterized in that the zeolite type ZSM-12 is present in an amount in the range from 2 to 15% wt. in terms of the total mass of carrier material. 3. Катализатор по п. 1 или 2, отличающийся тем, что цеолит типа EU-1 присутствует в количестве в диапазоне от 2 до 24% мас. в пересчете на общую массу материала носителя.3. The catalyst according to p. 1 or 2, characterized in that the zeolite type EU-1 is present in an amount in the range from 2 to 24% wt. in terms of the total mass of carrier material. 4. Катализатор по любому из пп. 1-3, отличающийся тем, что неорганическое связующее присутствует в количестве в диапазоне от 70 до 95% мас. в пересчете на общую массу материала носителя.4. The catalyst according to any one of paragraphs. 1-3, characterized in that the inorganic binder is present in an amount in the range from 70 to 95% wt. in terms of the total mass of carrier material. 5. Катализатор по любому из пп. 1-4, отличающийся тем, что неорганическое связующее состоит из оксида алюминия.5. The catalyst according to any one of paragraphs. 1-4, characterized in that the inorganic binder consists of aluminum oxide. 6. Катализатор по любому из пп. 1-5, отличающийся тем, что металл VIII группы представляет собой платину, которая присутствует в количестве в диапазоне от 0,1 до 0,6% мас. в пересчете на общую массу катализатора.6. The catalyst according to any one of paragraphs. 1-5, characterized in that the metal of group VIII is platinum, which is present in an amount in the range from 0.1 to 0.6% wt. in terms of the total weight of the catalyst. 7. Катализатор по любому из пп. 1-6, отличающийся тем, что цеолит типа ZSM-12 характеризуется молярным соотношением диоксида кремния к оксиду алюминия в диапазоне от 70 до 150. 7. The catalyst according to any one of paragraphs. 1-6, characterized in that the zeolite type ZSM-12 is characterized by a molar ratio of silicon dioxide to alumina in the range from 70 to 150. 8. Катализатор по любому из пп. 1-7, отличающийся тем, что цеолит типа EU-1 характеризуется молярным соотношением диоксида кремния к оксиду алюминия в диапазоне от 30 до 95. 8. The catalyst according to any one of paragraphs. 1-7, characterized in that the zeolite type EU-1 is characterized by a molar ratio of silicon dioxide to alumina in the range from 30 to 95. 9. Катализатор по любому из пп. 1-8, отличающийся тем, что цеолит типа ZSM-12 имеет средний размер частиц в диапазоне от 5 до 50 нм.9. The catalyst according to any one of paragraphs. 1-8, characterized in that the zeolite type ZSM-12 has an average particle size in the range from 5 to 50 nm. 10. Катализатор по любому из пп. 1-9, отличающийся тем, что цеолит типа EU-1 имеет средний размер частиц в диапазоне от 20 до 70 нм.10. The catalyst according to any one of paragraphs. 1-9, characterized in that the zeolite type EU-1 has an average particle size in the range from 20 to 70 nm. 11. Способ получения катализатора по любому из пп. 1-10, включающий в себя стадии, в которых: 11. The method of producing the catalyst according to any one of paragraphs. 1-10, which includes stages in which: (a) смешивают цеолит типа ZSM-12, цеолит типа EU-1, неорганическое связующее и металл группы VIII в любой возможной последовательности; и (a) a zeolite of type ZSM-12, a zeolite of type EU-1, an inorganic binder and a metal of group VIII are mixed in any possible sequence; and (b) прокаливают смесь, полученную на стадии (a).(b) calcining the mixture obtained in step (a). 12. Способ изомеризации алкилароматических соединений, включающий в себя приведение углеводородного сырья, содержащего алкилароматические соединения, в контакт с катализатором по любому из пп. 1-10.12. The method of isomerization of alkyl aromatic compounds, comprising bringing the hydrocarbon feed containing alkyl aromatic compounds into contact with the catalyst according to any one of claims. 1-10. 13. Способ по п. 12, отличающийся тем, что исходное сырье содержит этилбензол и ксилолы. 13. The method according to p. 12, characterized in that the feedstock contains ethylbenzene and xylenes.
RU2018125264A 2015-12-11 2016-12-08 Catalyst composition and isomerisation method RU2739200C2 (en)

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EP15199643 2015-12-11
EP15199643.6 2015-12-11
PCT/EP2016/080197 WO2017097880A1 (en) 2015-12-11 2016-12-08 Catalyst composition and isomerisation process

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CN113646287B (en) * 2019-03-29 2025-04-25 埃克森美孚化学专利公司 Novel zeolite, method for preparing the zeolite and use of the zeolite for converting aromatic hydrocarbons
RU2707179C1 (en) * 2019-08-02 2019-11-25 федеральное государственное автономное образовательное учреждение высшего образования "Российский государственный университет нефти и газа (национальный исследовательский университет) имени И.М. Губкина" Bizeolitic catalyst for isomerization of aromatic hydrocarbons c-8

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US3856872A (en) * 1973-09-13 1974-12-24 Mobil Oil Corp Xylene isomerization
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JP2015516878A (en) * 2012-04-02 2015-06-18 サウジ アラビアン オイル カンパニー Multimetallic zeolitic catalysts for transalkylation of heavy reformate to produce xylenes and petrochemical feedstocks
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RU2739200C2 (en) 2020-12-21
KR20180084082A (en) 2018-07-24
BR112018011634B1 (en) 2021-06-01
SA518391731B1 (en) 2021-09-12
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SG11201804523QA (en) 2018-06-28
CN108367281B (en) 2021-10-15
BR112018011634A2 (en) 2018-11-27
US20180369797A1 (en) 2018-12-27
EP3386633A1 (en) 2018-10-17
MY192190A (en) 2022-08-05
KR102683463B1 (en) 2024-07-09
RU2018125264A3 (en) 2020-03-19

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