RU2018101471A - Композитное покрытие на основе углеродных нанотрубок и способ его получения - Google Patents
Композитное покрытие на основе углеродных нанотрубок и способ его получения Download PDFInfo
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- 239000002041 carbon nanotube Substances 0.000 title claims 25
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims 24
- 229910021393 carbon nanotube Inorganic materials 0.000 title claims 24
- 239000011248 coating agent Substances 0.000 title claims 10
- 238000000576 coating method Methods 0.000 title claims 10
- 239000002131 composite material Substances 0.000 title claims 9
- 238000004519 manufacturing process Methods 0.000 title 1
- 229910052751 metal Inorganic materials 0.000 claims 17
- 239000002184 metal Substances 0.000 claims 17
- 239000002243 precursor Substances 0.000 claims 14
- 238000000034 method Methods 0.000 claims 12
- 125000002524 organometallic group Chemical group 0.000 claims 12
- 239000011241 protective layer Substances 0.000 claims 5
- 239000000919 ceramic Substances 0.000 claims 4
- 239000000463 material Substances 0.000 claims 4
- 229910044991 metal oxide Inorganic materials 0.000 claims 4
- 150000004706 metal oxides Chemical class 0.000 claims 4
- 238000005229 chemical vapour deposition Methods 0.000 claims 3
- 239000010410 layer Substances 0.000 claims 3
- 239000000203 mixture Substances 0.000 claims 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims 2
- 229910016036 BaF 2 Inorganic materials 0.000 claims 2
- 229910004261 CaF 2 Inorganic materials 0.000 claims 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 2
- 229910006404 SnO 2 Inorganic materials 0.000 claims 2
- 229910010413 TiO 2 Inorganic materials 0.000 claims 2
- 238000000151 deposition Methods 0.000 claims 2
- 230000008021 deposition Effects 0.000 claims 2
- 239000002082 metal nanoparticle Substances 0.000 claims 2
- SHWZFQPXYGHRKT-FDGPNNRMSA-N (z)-4-hydroxypent-3-en-2-one;nickel Chemical compound [Ni].C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O SHWZFQPXYGHRKT-FDGPNNRMSA-N 0.000 claims 1
- 239000004215 Carbon black (E152) Substances 0.000 claims 1
- 239000000956 alloy Substances 0.000 claims 1
- 229910045601 alloy Inorganic materials 0.000 claims 1
- 230000003197 catalytic effect Effects 0.000 claims 1
- FJDJVBXSSLDNJB-LNTINUHCSA-N cobalt;(z)-4-hydroxypent-3-en-2-one Chemical compound [Co].C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O FJDJVBXSSLDNJB-LNTINUHCSA-N 0.000 claims 1
- 230000000694 effects Effects 0.000 claims 1
- 230000002708 enhancing effect Effects 0.000 claims 1
- 230000008020 evaporation Effects 0.000 claims 1
- 238000001704 evaporation Methods 0.000 claims 1
- 239000000945 filler Substances 0.000 claims 1
- 229930195733 hydrocarbon Natural products 0.000 claims 1
- 150000002430 hydrocarbons Chemical class 0.000 claims 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 1
- 229910052742 iron Inorganic materials 0.000 claims 1
- LZKLAOYSENRNKR-LNTINUHCSA-N iron;(z)-4-oxoniumylidenepent-2-en-2-olate Chemical compound [Fe].C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O LZKLAOYSENRNKR-LNTINUHCSA-N 0.000 claims 1
- 239000011777 magnesium Substances 0.000 claims 1
- AKTIAGQCYPCKFX-FDGPNNRMSA-L magnesium;(z)-4-oxopent-2-en-2-olate Chemical compound [Mg+2].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O AKTIAGQCYPCKFX-FDGPNNRMSA-L 0.000 claims 1
- 239000002105 nanoparticle Substances 0.000 claims 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 1
- 229910052759 nickel Inorganic materials 0.000 claims 1
- 230000003287 optical effect Effects 0.000 claims 1
- 230000005855 radiation Effects 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
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Claims (23)
1. Композитное покрытие на основе углеродных нанотрубок (УНТ), содержащее слой углеродных нанотрубок, отличающееся тем, что углеродные нанотрубки содержат металлоксидные оболочки, покрывающие углеродные нанотрубки.
2. Композитное покрытие на основе углеродных нанотрубок по п. 1, где углеродные нанотрубки являются неориентированными.
3. Композитное покрытие на основе углеродных нанотрубок по п. 1 или 2, где углеродные нанотрубки имеют средний диаметр в диапазоне от 0,3 до 150 нм.
4. Композитное покрытие на основе углеродных нанотрубок по любому из пп. 1-3, где металлоксидные оболочки содержат или состоят из MgO.
5. Композитное покрытие на основе углеродных нанотрубок по любому из пп. 1-4, содержащее керамический защитный слой в виде слоя поверх указанных углеродных нанотрубок с покрытием и/или в виде заполнителя в указанном слое углеродных нанотрубок.
6. Композитное покрытие на основе углеродных нанотрубок по п. 5, где керамический защитный слой состоит из материала, отличного от материала указанных металлоксидных оболочек.
7. Композитное покрытие на основе углеродных нанотрубок по п. 5 или 6, где указанный керамический защитный слой состоит из материала, выбранного из группы, содержащей Al2O3, Si2O, Si3N4, MgF2, SiOxNx, AlN, AlNO, MgO, ZnO, SnO2, NiO, ZrO2, Cr2O3, MoO2, RuO2, CoOx, CuOx, VOx, FeOx, MnOx, TiO2, CaF2, BaF2, тройные и/или сложные оксиды, включающие один или более видов элементов из вышеуказанных, и их смеси.
8. Оптическое черное покрытие, содержащее композитное покрытие на основе углеродных нанотрубок по любому из пп. 1-7.
9. Способ получения углеродных нанотрубок с помощью химического осаждения из газовой фазы, включающий:
обеспечение в реакционной камере основы, имеющей на поверхности наночастицы металла и/или карбида металла, содержащие первый катализирующий рост УНТ металл, выбранный из группы, содержащей Fe, Со, Ni и их смеси;
введение неорганического, металлорганического или органометаллического прекурсора в реакционную камеру совместно с прекурсором УНТ, при этом неорганический, металлорганический или органометаллический прекурсор выбран для осаждения второго металла;
выращивание УНТ из прекурсора УНТ, при этом второй металл, полученный из неорганического, металлорганического или органометаллического прекурсора, усиливает катализирующую рост УНТ активность первого металла.
10. Способ по п. 9, где прекурсор УНТ включает углеводород, предпочтительно спирт.
11. Способ по п. 9 или 10, где второй металл образует с первым металлом фазу сплава или карбида, вызывающую усиление катализирующей рост УНТ активности.
12. Способ по любому из пп. 9-11, где рост УНТ проводят в температурном диапазоне от 300 до 600°С, предпочтительно в температурном диапазоне от 350°С до 500°С, даже более предпочтительно в диапазоне от 350 до 450°С.
13. Способ по п. 12, где рост УНТ не индуцирован ни плазмой, ни излучением.
14. Способ по любому из пп. 9-13, где второй металл образует металлоксидную оболочку, покрывающую УНТ.
15. Способ по любому из пп. 9-14, где второй металл представляет собой Mg.
16. Способ по любому из пп. 9-14, включающий осаждение керамического защитного слоя поверх УНТ.
17. Способ по п. 16, где защитный слой состоит из материала, выбранного из группы, содержащей Al2O3, Si2O, Si3N4, SiOxNx, AlN, AlNO, MgO, ZnO, SnO2, NiO, ZrO2, Cr2O3, MoO2, RuO2, CoOx, CuOx, VOx, FeOx, MnOx, TiO2, CaF2, BaF2, MgF2, тройные и/или сложные оксиды, включающие один или более видов элементов из вышеуказанных, и их смеси.
18. Способ по любому из пп. 9-17, где наночастицы металла и/или карбида металла осаждают из металлорганического или органометаллического прекурсора первого металла.
19. Способ по любому из пп. 9-18, где химическое осаждение из газовой фазы включает химическое осаждение из газовой фазы с испарением импульсным распылением, при этом наночастицы металла и/или карбида металла осаждают из раствора первого прекурсора, содержащего металлорганический или органометаллический прекурсор первого металла, растворенный в растворителе, второй металл осаждают из раствора второго прекурсора, содержащего металлорганический или органометаллический прекурсор, выбранный для осаждения второго металла, растворенный в спирте, служащем в качестве прекурсора УНТ.
20. Способ по п. 19, где прекурсор первого металла содержит ацетилацетонат кобальта, и/или ацетилацетонат никеля, и/или ацетилацетонат железа, и где прекурсор, выбранный для осаждения второго металла, содержит ацетилацетонат магния.
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| LU92758A LU92758B1 (en) | 2015-06-29 | 2015-06-29 | Carbon-nanotube-based composite coating and production method thereof |
| LU92758 | 2015-06-29 | ||
| PCT/EP2016/065016 WO2017001406A2 (en) | 2015-06-29 | 2016-06-28 | Carbon-nanotube-based composite coating and production method thereof |
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| RU2018101471A true RU2018101471A (ru) | 2019-07-30 |
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| LU92758B1 (en) | 2015-06-29 | 2016-12-30 | Luxembourg Inst Of Science And Tech (List) | Carbon-nanotube-based composite coating and production method thereof |
| DE102017206386A1 (de) * | 2017-04-13 | 2018-10-18 | Robert Bosch Gmbh | Verfahren zum Schutz einer MEMS-Einheit vor Infrarot-Untersuchungen sowie MEMS-Einheit |
| CN110031107B (zh) * | 2018-01-11 | 2022-08-16 | 清华大学 | 黑体辐射源及黑体辐射源的制备方法 |
| CN110031116A (zh) * | 2018-01-11 | 2019-07-19 | 清华大学 | 腔式黑体辐射源 |
| CN110031108A (zh) * | 2018-01-11 | 2019-07-19 | 清华大学 | 黑体辐射源及黑体辐射源的制备方法 |
| CN110031104A (zh) * | 2018-01-11 | 2019-07-19 | 清华大学 | 面源黑体 |
| CN110031106B (zh) * | 2018-01-11 | 2021-04-02 | 清华大学 | 黑体辐射源 |
| CN111670486B (zh) | 2018-01-29 | 2024-08-09 | 麻省理工学院 | 背栅场效应晶体管及其制造方法 |
| WO2019236974A1 (en) | 2018-06-08 | 2019-12-12 | Massachusetts Institute Of Technology | Systems, devices, and methods for gas sensing |
| US11062067B2 (en) | 2018-09-10 | 2021-07-13 | Massachusetts Institute Of Technology | Systems and methods for designing integrated circuits |
| WO2020068812A1 (en) | 2018-09-24 | 2020-04-02 | Massachusetts Institute Of Technology | Tunable doping of carbon nanotubes through engineered atomic layer deposition |
| WO2020113205A1 (en) | 2018-11-30 | 2020-06-04 | Massachusetts Institute Of Technology | Rinse - removal of incubated nanotubes through selective exfoliation |
| CN110282974B (zh) * | 2019-06-28 | 2020-12-29 | 华南理工大学 | 定向排布磁性碳纤维石墨烯复合膜及其制备方法和应用 |
| KR102396863B1 (ko) * | 2020-11-17 | 2022-05-10 | 한국전기연구원 | 황 담지 탄소나노튜브 전극의 제조 방법，이로부터 제조되는 황 담지 탄소나노튜브 전극 및 이를 포함하는 리튬황 전지 |
| CN114671710B (zh) * | 2022-03-10 | 2023-04-07 | 西北工业大学 | 一种双周期多层TaC/HfC超高温陶瓷抗烧蚀涂层及制备方法 |
| LU507534B1 (en) * | 2024-06-20 | 2025-12-22 | Luxembourg Inst Science & Tech List | Composite material |
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| AU2002254367B2 (en) | 2001-03-26 | 2007-12-06 | Eikos, Inc. | Coatings containing carbon nanotubes |
| AU2003235592A1 (en) | 2002-01-11 | 2003-07-30 | The Trustees Of Boston College | Reinforced carbon nanotubes |
| US7459013B2 (en) * | 2004-11-19 | 2008-12-02 | International Business Machines Corporation | Chemical and particulate filters containing chemically modified carbon nanotube structures |
| CN100434210C (zh) * | 2005-01-17 | 2008-11-19 | 武汉科技大学 | 一种碳包覆金属纳米粒子及其制备方法 |
| RU2310601C2 (ru) * | 2005-10-19 | 2007-11-20 | Химический факультет МГУ им. М.В. Ломоносова | Способ получения углеродных нанотрубок с инкапсулированными частицами никеля и кобальта и установка для синтеза материалов на основе углеродных нанотрубок и наночастиц никеля или кобальта |
| DE102006033037A1 (de) | 2006-07-14 | 2008-01-24 | Universität Bielefeld | Einstufiges Verfahren zur Aufbringung einer Metallschicht auf ein Substrat |
| TWI343929B (en) * | 2007-03-27 | 2011-06-21 | Nat Univ Tsing Hua | Tio2-coated cnt, tio2-coated cnt reinforcing polymer composite and methods of preparation thereof |
| US9078942B2 (en) * | 2007-05-14 | 2015-07-14 | Northwestern University | Titanium dioxide, single-walled carbon nanotube composites |
| CN102317200B (zh) * | 2009-02-17 | 2014-04-09 | 应用纳米结构方案公司 | 包括纤维上的碳纳米管的复合材料 |
| US8246860B2 (en) * | 2009-10-23 | 2012-08-21 | Tsinghua University | Carbon nanotube composite, method for making the same, and electrochemical capacitor using the same |
| DE102009054427B4 (de) * | 2009-11-25 | 2014-02-13 | Kme Germany Ag & Co. Kg | Verfahren zum Aufbringen von Gemengen aus Kohlenstoff und Metallpartikeln auf ein Substrat, nach dem Verfahren erhältliches Substrat und dessen Verwendung |
| EP2531558B1 (en) * | 2010-02-02 | 2018-08-22 | Applied NanoStructured Solutions, LLC | Carbon nanotube-infused fiber materials containing parallel-aligned carbon nanotubes, methods for production thereof, and composite materials derived therefrom |
| CA2712051A1 (en) * | 2010-08-12 | 2012-02-12 | The Governors Of The University Of Alberta | Method of fabricating a carbon nanotube array |
| GB2501872B8 (en) * | 2012-05-03 | 2022-08-17 | Dyson Technology Ltd | Coated Structured Surfaces |
| WO2014063149A1 (en) | 2012-10-19 | 2014-04-24 | Georgia Tech Research Corporation | Multilayer coatings formed on aligned arrays of carbon nanotubes |
| US10847810B2 (en) | 2013-10-22 | 2020-11-24 | Cornell University | Nanostructures for lithium air batteries |
| LU92758B1 (en) | 2015-06-29 | 2016-12-30 | Luxembourg Inst Of Science And Tech (List) | Carbon-nanotube-based composite coating and production method thereof |
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| IL256232B (en) | 2022-02-01 |
| ES2928795T3 (es) | 2022-11-22 |
| US12024635B2 (en) | 2024-07-02 |
| WO2017001406A3 (en) | 2017-04-27 |
| IL256232A (en) | 2018-02-28 |
| US20180179391A1 (en) | 2018-06-28 |
| EP3313942A2 (en) | 2018-05-02 |
| LU92758B1 (en) | 2016-12-30 |
| WO2017001406A2 (en) | 2017-01-05 |
| EP3313942B1 (en) | 2022-08-17 |
| RU2727604C2 (ru) | 2020-07-22 |
| US20220220317A1 (en) | 2022-07-14 |
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