RU2018142568A - Композиция для гидролитической стабилизации сложных полиэфиров - Google Patents
Композиция для гидролитической стабилизации сложных полиэфиров Download PDFInfo
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- RU2018142568A RU2018142568A RU2018142568A RU2018142568A RU2018142568A RU 2018142568 A RU2018142568 A RU 2018142568A RU 2018142568 A RU2018142568 A RU 2018142568A RU 2018142568 A RU2018142568 A RU 2018142568A RU 2018142568 A RU2018142568 A RU 2018142568A
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- Prior art keywords
- terephthalate
- use according
- formula
- polyester
- compound
- Prior art date
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- 229920000728 polyester Polymers 0.000 title claims 12
- 239000000203 mixture Substances 0.000 title claims 3
- 230000003301 hydrolyzing effect Effects 0.000 title 1
- 230000006641 stabilisation Effects 0.000 title 1
- 238000011105 stabilization Methods 0.000 title 1
- -1 polyethylene terephthalate Polymers 0.000 claims 13
- 150000001875 compounds Chemical class 0.000 claims 9
- 239000000463 material Substances 0.000 claims 8
- 239000000654 additive Substances 0.000 claims 4
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 claims 4
- WURBFLDFSFBTLW-UHFFFAOYSA-N benzil Chemical group C=1C=CC=CC=1C(=O)C(=O)C1=CC=CC=C1 WURBFLDFSFBTLW-UHFFFAOYSA-N 0.000 claims 3
- 229920001707 polybutylene terephthalate Polymers 0.000 claims 3
- 229920000139 polyethylene terephthalate Polymers 0.000 claims 3
- 239000005020 polyethylene terephthalate Substances 0.000 claims 3
- 239000000370 acceptor Substances 0.000 claims 2
- GXJPKIGCMGAHTL-UHFFFAOYSA-N dipropyl benzene-1,4-dicarboxylate Chemical compound CCCOC(=O)C1=CC=C(C(=O)OCCC)C=C1 GXJPKIGCMGAHTL-UHFFFAOYSA-N 0.000 claims 2
- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 claims 2
- 239000011112 polyethylene naphthalate Substances 0.000 claims 2
- 229920002215 polytrimethylene terephthalate Polymers 0.000 claims 2
- 229920001634 Copolyester Polymers 0.000 claims 1
- LQLQDKBJAIILIQ-UHFFFAOYSA-N Dibutyl terephthalate Chemical compound CCCCOC(=O)C1=CC=C(C(=O)OCCCC)C=C1 LQLQDKBJAIILIQ-UHFFFAOYSA-N 0.000 claims 1
- 239000004609 Impact Modifier Substances 0.000 claims 1
- 239000004594 Masterbatch (MB) Substances 0.000 claims 1
- 239000004698 Polyethylene Substances 0.000 claims 1
- 229920000331 Polyhydroxybutyrate Polymers 0.000 claims 1
- 239000006096 absorbing agent Substances 0.000 claims 1
- CWRYPZZKDGJXCA-UHFFFAOYSA-N acenaphthene Chemical compound C1=CC(CC2)=C3C2=CC=CC3=C1 CWRYPZZKDGJXCA-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 229920003232 aliphatic polyester Polymers 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 239000003242 anti bacterial agent Substances 0.000 claims 1
- 239000003963 antioxidant agent Substances 0.000 claims 1
- 239000002216 antistatic agent Substances 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 229920001577 copolymer Polymers 0.000 claims 1
- ONIHPYYWNBVMID-UHFFFAOYSA-N diethyl benzene-1,4-dicarboxylate Chemical compound CCOC(=O)C1=CC=C(C(=O)OCC)C=C1 ONIHPYYWNBVMID-UHFFFAOYSA-N 0.000 claims 1
- RXDQUKGEPHJIJN-UHFFFAOYSA-N diheptyl benzene-1,4-dicarboxylate Chemical compound CCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCC)C=C1 RXDQUKGEPHJIJN-UHFFFAOYSA-N 0.000 claims 1
- MLIPQTRXLNTCRS-UHFFFAOYSA-N dihexyl benzene-1,4-dicarboxylate Chemical compound CCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCC)C=C1 MLIPQTRXLNTCRS-UHFFFAOYSA-N 0.000 claims 1
- UBXIPPSTBVKKIK-UHFFFAOYSA-N dinonyl benzene-1,4-dicarboxylate Chemical compound CCCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCCC)C=C1 UBXIPPSTBVKKIK-UHFFFAOYSA-N 0.000 claims 1
- OEIWPNWSDYFMIL-UHFFFAOYSA-N dioctyl benzene-1,4-dicarboxylate Chemical compound CCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC)C=C1 OEIWPNWSDYFMIL-UHFFFAOYSA-N 0.000 claims 1
- SQQSFUNTQGNWKD-UHFFFAOYSA-N dipentyl benzene-1,4-dicarboxylate Chemical compound CCCCCOC(=O)C1=CC=C(C(=O)OCCCCC)C=C1 SQQSFUNTQGNWKD-UHFFFAOYSA-N 0.000 claims 1
- 239000000975 dye Substances 0.000 claims 1
- 239000000806 elastomer Substances 0.000 claims 1
- 229920001971 elastomer Polymers 0.000 claims 1
- 239000003063 flame retardant Substances 0.000 claims 1
- 239000012760 heat stabilizer Substances 0.000 claims 1
- 229910001385 heavy metal Inorganic materials 0.000 claims 1
- 230000007062 hydrolysis Effects 0.000 claims 1
- 238000006460 hydrolysis reaction Methods 0.000 claims 1
- 230000002209 hydrophobic effect Effects 0.000 claims 1
- 238000010147 laser engraving Methods 0.000 claims 1
- 239000004611 light stabiliser Substances 0.000 claims 1
- 239000006078 metal deactivator Substances 0.000 claims 1
- 230000003287 optical effect Effects 0.000 claims 1
- 150000002978 peroxides Chemical class 0.000 claims 1
- 239000000049 pigment Substances 0.000 claims 1
- 239000005015 poly(hydroxybutyrate) Substances 0.000 claims 1
- 229920000218 poly(hydroxyvalerate) Polymers 0.000 claims 1
- 229920001610 polycaprolactone Polymers 0.000 claims 1
- 229920000573 polyethylene Polymers 0.000 claims 1
- 239000002516 radical scavenger Substances 0.000 claims 1
- 239000003381 stabilizer Substances 0.000 claims 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 claims 1
- 229940070710 valerate Drugs 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/76—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring
- C07C69/80—Phthalic acid esters
- C07C69/82—Terephthalic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2467/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2467/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2469/00—Characterised by the use of polycarbonates; Derivatives of polycarbonates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2310/00—Masterbatches
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Polyesters Or Polycarbonates (AREA)
Claims (17)
1. Применение, по меньшей мере, одного соединения формулы (1)
где
R1 и R2 являются одинаковыми или различными и обозначают С1 – С10 алкил,
в качестве стабилизатора гидролиза в материалах сложных полиэфиров.
2. Применение по п. 1, где соединения формулы (1) представляют собой диметилтерефталат, диэтилтерефталат, дипропилтерефталат, дибутилтерефталат, дипентилтерефталат, дигексилтерефталат, дигептилтерефталат, диоктилтерефталат, динонилтерефталат или дидецилтерефталат.
3. Применение по п. 1 или 2, где соединение формулы (1), представляет собой диметилтерефталат.
4. Применение по любому из предшествующих пунктов, где сложный полиэфир в материалах сложных полиэфиров представляет собой полиэтилентерефталат, полиэтиленнафталат, полибутилентерефталат, политриметилентерефталат, дибензоилполиэтилентерефталат, дибензоилполибутилентерефталат, дибензоилполиэтиленнафталат или их смеси.
5. Применение по любому из предшествующих пунктов, где сложный полиэфир в материалах сложных полиэфиров представляет собой полиэтилентерефталат, полибутилентерефталат, полиэтиленнафталат и политриметилентерефталат и их смеси и их сложные сополиэфиры.
6. Применение по любому из предшествующих пунктов, где сложный полиэфир в материалах сложных полиэфиров представляет собой алифатические сложные полиэфиры, выбранные из группы, состоящей из полигидроксибутирата и его сополимера с полигидроксивалератом, полигидроксибутирата-валерата, поли(ε-капролактона).
7. Применение по любому из предшествующих пунктов, где доля соединения формулы (1) составляет от 0,1 до 20,0% масс. при расчете на массу материала стабилизированного сложного полиэфира.
8. Применение по любому из предшествующих пунктов, где доля соединения формулы (1) составляет от 1,0 до 10,0% масс. при расчете на массу материала стабилизированного сложного полиэфира.
9. Применение по любому из предшествующих пунктов, где доля соединения формулы (1) составляет от 1,5 до 5,0% масс. при расчете на массу материала стабилизированного сложного полиэфира.
10. Применение по любому из предшествующих пунктов, где соединение формулы (1) используют в комбинации с дополнительными добавками, выбранными из группы, состоящей из акцепторов радикалов, светостабилизаторов, термостабилизаторов, антипиренов, пигментов, красителей, антиоксидантов, противобактериальных средств, нейтрализаторов, антистатиков, антиадгезивов, оптических отбеливателей, дезактиваторов тяжелых металлов, гидрофобных добавок, пероксидов, акцепторов воды, акцепторов кислот, гидроталькитов, эластомеров, модификаторов ударопрочности, добавок для лазерной гравировки, технологических добавок и их смесей.
11. Применение по любому из предшествующих пунктов, где соединение формулы (1) используют в комбинации с УФ-поглотителями.
12. Применение по любому из предшествующих пунктов, где соединение формулы (1) используют в виде маточной смеси.
13. Применение по любому из предшествующих пунктов, где материал сложного полиэфира имеет форму пленки или листа.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP16168305.7 | 2016-05-04 | ||
| EP16168305.7A EP3241866A1 (en) | 2016-05-04 | 2016-05-04 | Composition for polyester hydrolytic stabilization |
| PCT/EP2017/059848 WO2017190993A1 (en) | 2016-05-04 | 2017-04-26 | Composition for hydrolytic stabilization of polyester |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| RU2018142568A true RU2018142568A (ru) | 2020-06-04 |
| RU2018142568A3 RU2018142568A3 (ru) | 2020-08-26 |
| RU2763499C2 RU2763499C2 (ru) | 2021-12-29 |
Family
ID=55913508
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2018142568A RU2763499C2 (ru) | 2016-05-04 | 2017-04-26 | Композиция для гидролитической стабилизации сложных полиэфиров |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US10808101B2 (ru) |
| EP (2) | EP3241866A1 (ru) |
| JP (1) | JP7113759B2 (ru) |
| KR (1) | KR102404837B1 (ru) |
| CN (1) | CN109153816B (ru) |
| BR (1) | BR112018070575B1 (ru) |
| CA (1) | CA3022923A1 (ru) |
| ES (1) | ES2861312T3 (ru) |
| MX (1) | MX2018012428A (ru) |
| RU (1) | RU2763499C2 (ru) |
| SG (1) | SG11201808508TA (ru) |
| TW (1) | TWI769156B (ru) |
| WO (1) | WO2017190993A1 (ru) |
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| EP2221336A1 (en) * | 2009-02-19 | 2010-08-25 | Mitsubishi Plastics, Inc. | Biaxially oriented polyester film with favorable light shielding properties, having hydrolysis resistance |
| KR20120014888A (ko) * | 2009-03-13 | 2012-02-20 | 바스프 에스이 | 폴리에스테르 및 폴리아미드의 안정화된 블렌드 |
| GB0915687D0 (en) * | 2009-09-08 | 2009-10-07 | Dupont Teijin Films Us Ltd | Polyester films |
| US8658285B2 (en) * | 2010-06-09 | 2014-02-25 | Toray Plastics (America), Inc. | Optically clear UV and hydrolysis resistant polyester film |
| US20130320594A1 (en) * | 2011-02-18 | 2013-12-05 | Keith Bechard | Methods for recycling post-consumer mixed rigid plastics |
| GB2488787A (en) * | 2011-03-07 | 2012-09-12 | Dupont Teijin Films Us Ltd | Stabilised polyester films |
| EP2738204B1 (en) * | 2012-11-29 | 2019-01-09 | Solvay Specialty Polymers USA, LLC. | Polyester compositions with improved crystallization rate |
| CN103694655B (zh) * | 2013-12-09 | 2015-12-02 | 方万漂 | 耐湿热聚对苯二甲酸丁二醇酯 |
| CN104045980B (zh) * | 2014-05-24 | 2016-01-27 | 池州万维化工有限公司 | 一种抗水解pet色母粒及其制备方法和用途 |
-
2016
- 2016-05-04 EP EP16168305.7A patent/EP3241866A1/en not_active Withdrawn
-
2017
- 2017-04-26 US US16/098,467 patent/US10808101B2/en active Active
- 2017-04-26 BR BR112018070575-6A patent/BR112018070575B1/pt active IP Right Grant
- 2017-04-26 SG SG11201808508TA patent/SG11201808508TA/en unknown
- 2017-04-26 EP EP17719586.4A patent/EP3452542B1/en active Active
- 2017-04-26 CA CA3022923A patent/CA3022923A1/en active Pending
- 2017-04-26 MX MX2018012428A patent/MX2018012428A/es unknown
- 2017-04-26 KR KR1020187035206A patent/KR102404837B1/ko active Active
- 2017-04-26 JP JP2018557133A patent/JP7113759B2/ja active Active
- 2017-04-26 WO PCT/EP2017/059848 patent/WO2017190993A1/en not_active Ceased
- 2017-04-26 RU RU2018142568A patent/RU2763499C2/ru active
- 2017-04-26 CN CN201780027346.2A patent/CN109153816B/zh active Active
- 2017-04-26 ES ES17719586T patent/ES2861312T3/es active Active
- 2017-05-02 TW TW106114528A patent/TWI769156B/zh active
Also Published As
| Publication number | Publication date |
|---|---|
| EP3452542B1 (en) | 2021-02-24 |
| EP3241866A1 (en) | 2017-11-08 |
| RU2018142568A3 (ru) | 2020-08-26 |
| WO2017190993A1 (en) | 2017-11-09 |
| BR112018070575B1 (pt) | 2022-09-27 |
| CN109153816B (zh) | 2021-05-14 |
| MX2018012428A (es) | 2019-03-01 |
| US20190153195A1 (en) | 2019-05-23 |
| ES2861312T3 (es) | 2021-10-06 |
| EP3452542A1 (en) | 2019-03-13 |
| CA3022923A1 (en) | 2017-11-09 |
| TWI769156B (zh) | 2022-07-01 |
| KR20190005922A (ko) | 2019-01-16 |
| JP7113759B2 (ja) | 2022-08-05 |
| CN109153816A (zh) | 2019-01-04 |
| JP2019515102A (ja) | 2019-06-06 |
| US10808101B2 (en) | 2020-10-20 |
| TW201811888A (zh) | 2018-04-01 |
| SG11201808508TA (en) | 2018-10-30 |
| BR112018070575A2 (pt) | 2019-02-12 |
| RU2763499C2 (ru) | 2021-12-29 |
| KR102404837B1 (ko) | 2022-06-07 |
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