RU2017108971A - Способ получения синтез-газа - Google Patents
Способ получения синтез-газа Download PDFInfo
- Publication number
- RU2017108971A RU2017108971A RU2017108971A RU2017108971A RU2017108971A RU 2017108971 A RU2017108971 A RU 2017108971A RU 2017108971 A RU2017108971 A RU 2017108971A RU 2017108971 A RU2017108971 A RU 2017108971A RU 2017108971 A RU2017108971 A RU 2017108971A
- Authority
- RU
- Russia
- Prior art keywords
- reaction zone
- hydrocarbon
- solid material
- carbon
- hydrogen
- Prior art date
Links
- 230000015572 biosynthetic process Effects 0.000 title claims 2
- 238000003786 synthesis reaction Methods 0.000 title claims 2
- 238000004519 manufacturing process Methods 0.000 title 1
- 238000006243 chemical reaction Methods 0.000 claims 15
- 238000000034 method Methods 0.000 claims 10
- 150000002430 hydrocarbons Chemical class 0.000 claims 7
- 239000004215 Carbon black (E152) Substances 0.000 claims 5
- 229930195733 hydrocarbon Natural products 0.000 claims 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 4
- 229910052739 hydrogen Inorganic materials 0.000 claims 4
- 239000001257 hydrogen Substances 0.000 claims 4
- 239000011343 solid material Substances 0.000 claims 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 3
- 229910004298 SiO 2 Inorganic materials 0.000 claims 3
- 229910052799 carbon Inorganic materials 0.000 claims 3
- 239000007789 gas Substances 0.000 claims 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 3
- 229910002092 carbon dioxide Inorganic materials 0.000 claims 2
- 239000001569 carbon dioxide Substances 0.000 claims 2
- 238000005979 thermal decomposition reaction Methods 0.000 claims 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 1
- 229910002091 carbon monoxide Inorganic materials 0.000 claims 1
- 239000003245 coal Substances 0.000 claims 1
- 239000000571 coke Substances 0.000 claims 1
- 229910052878 cordierite Inorganic materials 0.000 claims 1
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 claims 1
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 claims 1
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 1
- 230000003993 interaction Effects 0.000 claims 1
- 229910052863 mullite Inorganic materials 0.000 claims 1
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims 1
- 230000002441 reversible effect Effects 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/40—Carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
- C01B3/24—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
- C01B3/28—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using moving solid particles
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
- C01B3/24—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B5/00—Water
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0211—Processes for making hydrogen or synthesis gas containing a reforming step containing a non-catalytic reforming step
- C01B2203/0216—Processes for making hydrogen or synthesis gas containing a reforming step containing a non-catalytic reforming step containing a non-catalytic steam reforming step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0211—Processes for making hydrogen or synthesis gas containing a reforming step containing a non-catalytic reforming step
- C01B2203/0222—Processes for making hydrogen or synthesis gas containing a reforming step containing a non-catalytic reforming step containing a non-catalytic carbon dioxide reforming step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0238—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a carbon dioxide reforming step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0266—Processes for making hydrogen or synthesis gas containing a decomposition step
- C01B2203/0272—Processes for making hydrogen or synthesis gas containing a decomposition step containing a non-catalytic decomposition step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0838—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/141—Feedstock
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
- Carbon And Carbon Compounds (AREA)
Claims (9)
1. Способ получения синтез-газа (5), в котором углеводород (2) в первой реакционной зоне (Z1) термически разлагают на водород и углерод и образующийся водород из первой реакционной зоны (Z1) направляют во вторую реакционную зону (Z2) для осуществления в ней взаимодействия типа обратимой конверсии водяного газа с диоксидом углерода (4) с получением воды и монооксида углерода, отличающийся тем, что необходимую для термического разложения углеводорода (2) энергию подают в первую реакционную зону (Z1) из второй реакционной зоны (Z2).
2. Способ по п. 1, отличающийся тем, что тепловую энергию во второй реакционной зоне (Z2) производят посредством окисления водорода и/или посредством электрической энергии.
3. Способ по п. 1, отличающийся тем, что неразложившийся или неполностью разложившийся в первой реакционной зоне (Z1) углеводород направляют во вторую реакционную зону (Z2), в которой его подвергают взаимодействию с водой с получением водорода и диоксида углерода.
4. Способ по п. 1, отличающийся тем, что обе реакционные зоны (Z1, Z2) соединены посредством состоящего из гранулированного твердого материала подвижного слоя (W), который перемещается от второй реакционной зоны (Z2) к первой реакционной зоне (Z1).
5. Способ по п. 4, отличающийся тем, что гранулированный твердый материал возвращают в повторный цикл.
6. Способ по п. 4, отличающийся тем, что выходящий из второй реакционной зоны (Z2) газ направляют противотоком к подвижному слою (W) и охлаждают путем непосредственного теплообмена с ним.
7. Способ по п. 4, отличающийся тем, что углеводород (2) подают в первую реакционную зону (Z1) противотоком к подвижному слою (W) и нагревают путем непосредственного теплообмена с ним.
8. Способ по п. 4, отличающийся тем, что осажденный на гранулированном твердом материале углерод отделяют (А) после первой реакционной зоны (Z1) и удаляют из подвижного слоя (W).
9. Способ по одному из пп. 1-8, отличающийся тем, что в качестве гранулированного твердого материала используют корунд (Al2O3), или кварцевое стекло (SiO2), или муллит (Al2O3⋅SiO2), или кордиерит ((Mg,Fe)2(AI2Si)[AI2Si4O18]), или стеатит (SiO2⋅MgO⋅AI2O3), или уголь, или кокс, или углерод, полученный в способе посредством термического разложения углеводорода.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP14002872 | 2014-08-19 | ||
| EP14002872.1 | 2014-08-19 | ||
| PCT/EP2015/001675 WO2016026562A1 (de) | 2014-08-19 | 2015-08-13 | Verfahren zur erzeugung von synthesegas |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2017108971A true RU2017108971A (ru) | 2018-09-20 |
| RU2017108971A3 RU2017108971A3 (ru) | 2019-02-07 |
Family
ID=51399497
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2017108971A RU2017108971A (ru) | 2014-08-19 | 2015-08-13 | Способ получения синтез-газа |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US10099923B2 (ru) |
| EP (1) | EP3194333B1 (ru) |
| JP (1) | JP2017530926A (ru) |
| KR (1) | KR20170042734A (ru) |
| CN (1) | CN106573782A (ru) |
| AR (1) | AR102047A1 (ru) |
| AU (1) | AU2015306471A1 (ru) |
| CA (1) | CA2958101A1 (ru) |
| RU (1) | RU2017108971A (ru) |
| TW (1) | TW201609526A (ru) |
| WO (1) | WO2016026562A1 (ru) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101955602B1 (ko) * | 2017-09-05 | 2019-03-07 | 한국화학연구원 | 2단 유동층 가스화기 |
| DE102018222463A1 (de) * | 2018-12-20 | 2020-06-25 | Basf Se | Verfahren und Vorrichtung zur Herstellung von Wasserstoff, Kohlenmonoxid und einem kohlenstoffhaltigen Produkt |
| US12529151B2 (en) * | 2020-03-31 | 2026-01-20 | Osaka Gas Co., Ltd. | Electrolysis cell unit, electrolysis cell device, hydrocarbon production system, and production method and use method of electrolysis cell unit |
| DE102020211407A1 (de) * | 2020-09-10 | 2022-03-10 | Caphenia Gmbh | Verfahren und Vorrichtung zur Herstellung von Synthesegas |
| CN115724398A (zh) * | 2021-09-01 | 2023-03-03 | 中国石油大学(北京) | 一种负碳还原铁合成气的生产方法以及气基竖炉生产还原铁的方法 |
| US20240391765A1 (en) | 2021-10-06 | 2024-11-28 | Basf Se | Use of carbonaceous carrier material in bed reactors |
| EP4472921A1 (en) | 2022-02-01 | 2024-12-11 | TotalEnergies OneTech | Process to conduct a reverse water-gas shift reaction in an electrified fluidized bed reactor |
| DE102022123944A1 (de) * | 2022-09-19 | 2024-03-21 | Sergej Belik | Reaktoranordnung und Verfahren zur thermischen Spaltung von Kohlenwasserstoff |
| WO2024238552A1 (en) * | 2023-05-15 | 2024-11-21 | Molten Industries Inc. | Synthesis gas production by reverse water gas shift reaction using carbon dioxide and pyrolysis-derived hydrogen |
| WO2025090992A1 (en) * | 2023-10-27 | 2025-05-01 | Molten Industries Inc. | Integrated thermal energy storage for hydrocarbon pyrolysis |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4265868A (en) * | 1978-02-08 | 1981-05-05 | Koppers Company, Inc. | Production of carbon monoxide by the gasification of carbonaceous materials |
| KR101570882B1 (ko) | 2009-08-04 | 2015-11-23 | 에스케이이노베이션 주식회사 | 메탄의 열분해 및 이산화탄소 전환 반응을 포함하는 탄소 함유 물질의 가스화 방법 |
| DE102011106645A1 (de) | 2011-07-05 | 2013-01-10 | Linde Aktiengesellschaft | Verfahren zur Erzeugung von Koks |
| DE102011106642A1 (de) * | 2011-07-05 | 2013-01-10 | Linde Ag | Verfahren zur Synthesegaserzeugung |
| DE102013021418A1 (de) * | 2012-12-18 | 2014-06-18 | Basf Se | Verfahren zum Speichern elektrischer Energie und zur kohlenstoffdioxidarmen Energiegewinnung |
| EP2935098B1 (de) * | 2012-12-21 | 2018-02-14 | Basf Se | Parallele herstellung von wasserstoff, kohlenstoffmonoxid und einem kohlenstoffhaltigen produkt |
-
2015
- 2015-08-10 AR ARP150102569A patent/AR102047A1/es unknown
- 2015-08-12 TW TW104126272A patent/TW201609526A/zh unknown
- 2015-08-13 US US15/504,982 patent/US10099923B2/en not_active Expired - Fee Related
- 2015-08-13 CN CN201580044514.XA patent/CN106573782A/zh active Pending
- 2015-08-13 EP EP15754117.8A patent/EP3194333B1/de not_active Not-in-force
- 2015-08-13 KR KR1020177007225A patent/KR20170042734A/ko not_active Withdrawn
- 2015-08-13 RU RU2017108971A patent/RU2017108971A/ru not_active Application Discontinuation
- 2015-08-13 AU AU2015306471A patent/AU2015306471A1/en not_active Abandoned
- 2015-08-13 JP JP2017510330A patent/JP2017530926A/ja active Pending
- 2015-08-13 CA CA2958101A patent/CA2958101A1/en not_active Abandoned
- 2015-08-13 WO PCT/EP2015/001675 patent/WO2016026562A1/de not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| US10099923B2 (en) | 2018-10-16 |
| AU2015306471A1 (en) | 2017-03-23 |
| EP3194333B1 (de) | 2018-07-18 |
| US20170275161A1 (en) | 2017-09-28 |
| KR20170042734A (ko) | 2017-04-19 |
| EP3194333A1 (de) | 2017-07-26 |
| CN106573782A (zh) | 2017-04-19 |
| WO2016026562A1 (de) | 2016-02-25 |
| RU2017108971A3 (ru) | 2019-02-07 |
| TW201609526A (zh) | 2016-03-16 |
| CA2958101A1 (en) | 2016-02-25 |
| JP2017530926A (ja) | 2017-10-19 |
| AR102047A1 (es) | 2017-02-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FA92 | Acknowledgement of application withdrawn (lack of supplementary materials submitted) |
Effective date: 20190603 |