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RU2016131959A - COMPOSITE MATERIAL BASED ON TITANIUM ALLOYS AND METHOD FOR PRODUCING IT - Google Patents

COMPOSITE MATERIAL BASED ON TITANIUM ALLOYS AND METHOD FOR PRODUCING IT Download PDF

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Publication number
RU2016131959A
RU2016131959A RU2016131959A RU2016131959A RU2016131959A RU 2016131959 A RU2016131959 A RU 2016131959A RU 2016131959 A RU2016131959 A RU 2016131959A RU 2016131959 A RU2016131959 A RU 2016131959A RU 2016131959 A RU2016131959 A RU 2016131959A
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Russia
Prior art keywords
titanium alloy
modified region
layer
composite material
material based
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RU2016131959A
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Russian (ru)
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RU2647963C2 (en
Inventor
Гавриил Александрович Агарков
Михаил Германович Близник
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Общество с ограниченной ответственностью "ТБ композит"
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Priority to RU2016131959A priority Critical patent/RU2647963C2/en
Publication of RU2016131959A publication Critical patent/RU2016131959A/en
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/02Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working in inert or controlled atmosphere or vacuum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/02Physical, chemical or physicochemical properties
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/16Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of other metals or alloys based thereon
    • C22F1/18High-melting or refractory metals or alloys based thereon
    • C22F1/183High-melting or refractory metals or alloys based thereon of titanium or alloys based thereon
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/06Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Chemical Vapour Deposition (AREA)
  • Powder Metallurgy (AREA)

Claims (8)

1. Композиционный материал на основе титанового сплава с модифицированной областью, отличающийся тем, что модифицированная область состоит из лицевого слоя с керамической структурой, слоя с металлокерамической структурой и слоя с переходной структурой от слоя с металлокерамической структурой к титановому сплаву основного металла, содержит азот в виде насыщенного твердого раствора внедрения и керамические частицы TiNx и/или TiCx и/или TixNyCz, причем лицевой слой с керамической структурой имеет толщину от 0,08 мм до 0,5 мм, твердость не менее 62 HRC с массовой долей керамических частиц более 15%, величиной не более 1,0 мкм, расположенных в титановой матрице с величиной зерен не более 240 мкм, слой с металлокерамической структурой имеет толщину от 0,5 до 24 мм, твердость от 50 HRC до 74 HRC с величиной керамических частиц менее 1,0 мкм и массовой долей от 2 до 14%, расположенных в титановой матрице с величиной зерен не более 500 мкм, слой с переходной структурой имеет толщину от 5 до 10% от толщины металлокерамического слоя, твердость от 60 до 30 HRC, снижающуюся при переходе от слоя с металлокерамической структурой к титановому сплаву основного металла.1. A composite material based on a titanium alloy with a modified region, characterized in that the modified region consists of a front layer with a ceramic structure, a layer with a cermet structure and a layer with a transition structure from a layer with a cermet structure to a titanium alloy of the base metal, contains nitrogen in the form saturated interstitial solid solution and ceramic particles TiN x and / or TiC x and / or Ti x N y C z , the front layer with a ceramic structure having a thickness of 0.08 mm to 0.5 mm, a hardness of at least 62 HRC with a mass fraction of ceramic particles of more than 15%, a value of not more than 1.0 microns, located in a titanium matrix with a grain size of not more than 240 microns, a layer with a cermet structure has a thickness of 0.5 to 24 mm, hardness from 50 HRC to 74 HRC with a ceramic particle size of less than 1.0 μm and a mass fraction of 2 to 14% located in a titanium matrix with a grain size of not more than 500 μm, the layer with the transition structure has a thickness of 5 to 10% of the thickness of the cermet layer, hardness of 60 up to 30 HRC, decreasing upon transition from a layer with a cermet stream ture to the titanium alloy of the base metal. 2. Композиционный материал на основе титанового сплава с модифицированной областью по п. 1, отличающийся тем, что модифицированная область дополнительно содержит TiBx, TiyBx.2. A composite material based on a titanium alloy with a modified region according to claim 1, characterized in that the modified region further comprises TiB x , Ti y B x . 3. Композиционный материал на основе титанового сплава с модифицированной областью по п. 2, отличающийся тем, что массовая доля TiBx, TiyBx в лицевом слое с керамической структурой более 10%, в слое с металлокерамической структурой от 2 до 10%.3. A composite material based on a titanium alloy with a modified region according to claim 2, characterized in that the mass fraction of TiB x , Ti y B x in the front layer with a ceramic structure is more than 10%, in the layer with a cermet structure from 2 to 10%. 4. Способ изготовления композиционного материала на основе титанового сплава с модифицированной областью, включающий нагрев поверхности титанового сплава высококонцентрированным движущимся источником тепловой энергии в газовой атмосфере, содержащей модифицирующие компоненты, отличающийся тем, что нагрев производится плазменной погруженной дугой прямого действия при удельном тепловом потоке в центре пятна нагрева сжатой дугой от 104 до 105 Вт/см2, силе тока 50-450 А, напряжении дуги от 20 до 40 В, и скорости перемещения источника тепловой энергии относительно поверхности титанового сплава от 0,003 до 0,01 м/с, а газовая атмосфера образована смесью аргона с добавлением азота и/или газа содержащего углерод.4. A method of manufacturing a composite material based on a titanium alloy with a modified region, comprising heating the surface of a titanium alloy with a highly concentrated moving source of thermal energy in a gas atmosphere containing modifying components, characterized in that the heating is performed by a direct-acting plasma submerged arc with a specific heat flux in the center of the spot heating with a compressed arc from 10 4 to 10 5 W / cm 2 , current strength of 50-450 A, arc voltage from 20 to 40 V, and the speed of movement of the heat source ergii relative to the surface of the titanium alloy from 0.003 to 0.01 m / s, and the gas atmosphere is formed by a mixture of argon with the addition of nitrogen and / or gas containing carbon. 5. Способ изготовления композиционного материала на основе титанового сплава с модифицированной областью по п. 4, отличающийся тем, что формирование модифицированной области выполняется с перекрытием проходов на 45-60% от их ширины.5. A method of manufacturing a composite material based on a titanium alloy with a modified region according to claim 4, characterized in that the formation of the modified region is performed with overlapping passages by 45-60% of their width. 6. Способ изготовления композиционного материала на основе титанового сплава с модифицированной областью по п. 4, отличающийся тем, что после переплава проводят термообработку.6. A method of manufacturing a composite material based on a titanium alloy with a modified region according to claim 4, characterized in that heat treatment is carried out after remelting. 7. Способ изготовления композиционного материала на основе титанового сплава с модифицированной областью по п. 6, отличающийся тем, что термообработка проводится отжигом при температуре 800-850°C.7. A method of manufacturing a composite material based on a titanium alloy with a modified region according to claim 6, characterized in that the heat treatment is carried out by annealing at a temperature of 800-850 ° C. 8. Способ изготовления композиционного материала на основе титанового сплава с модифицированной областью по п. 6, отличающийся тем, что термообработка проводится отпуском при температуре 600-650°C, снижающим термические напряжения после переплава металла.8. A method of manufacturing a composite material based on a titanium alloy with a modified region according to claim 6, characterized in that the heat treatment is carried out by tempering at a temperature of 600-650 ° C, which reduces thermal stresses after remelting the metal.
RU2016131959A 2016-08-03 2016-08-03 Composite material on base of titanium alloy and procedure for its manufacture RU2647963C2 (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110372410A (en) * 2019-07-31 2019-10-25 成都工业学院 A kind of metal-ceramic composite material and preparation method thereof
CN114799216A (en) * 2022-04-14 2022-07-29 武汉大学 Heat treatment method of titanium alloy
CN115927910A (en) * 2022-12-08 2023-04-07 湖南湘投轻材科技股份有限公司 Titanium-based composite material brake disc and preparation method thereof
CN116000313A (en) * 2022-12-15 2023-04-25 西安交通大学 Treatment method for improving wear-resistant and hydrophobic properties of titanium alloy surface

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2731398C1 (en) * 2020-04-28 2020-09-02 Ооо "Нпп Титан-Композит" Multilayer cermet composite material and method of its production

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5334264A (en) * 1992-06-30 1994-08-02 Board Of Supervisors Of Louisiana State University And Agricultural And Mechanical College Titanium plasma nitriding intensified by thermionic emission source
DE102004033342A1 (en) * 2004-07-09 2006-02-02 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Process for producing wear-resistant and fatigue-resistant edge layers in titanium alloys and components produced therewith
JP2008195994A (en) * 2007-02-09 2008-08-28 Kyoto Institute Of Technology Surface modification method for titanium products and surface modified titanium products
RU2427666C1 (en) * 2009-12-21 2011-08-27 Государственное образовательное учреждение высшего профессионального образования "Сибирский государственный аэрокосмический университет имени академика М.Ф. Решетнева" (СибГАУ) Procedure for strengthening surface of items of titanium alloys
RU2562185C1 (en) * 2014-05-21 2015-09-10 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Уфимский государственный авиационный технический университет" Modification method of surface of items from titanium alloys in vacuum

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110372410A (en) * 2019-07-31 2019-10-25 成都工业学院 A kind of metal-ceramic composite material and preparation method thereof
CN110372410B (en) * 2019-07-31 2021-08-24 成都工业学院 A kind of metal-ceramic composite material and preparation method thereof
CN114799216A (en) * 2022-04-14 2022-07-29 武汉大学 Heat treatment method of titanium alloy
CN115927910A (en) * 2022-12-08 2023-04-07 湖南湘投轻材科技股份有限公司 Titanium-based composite material brake disc and preparation method thereof
CN115927910B (en) * 2022-12-08 2024-05-28 湖南湘投轻材科技股份有限公司 Titanium-based composite material brake disc and preparation method thereof
CN116000313A (en) * 2022-12-15 2023-04-25 西安交通大学 Treatment method for improving wear-resistant and hydrophobic properties of titanium alloy surface

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