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RU2016140366A - Микроструктурированные многослойные эластичные слоистые материалы с повышенной прочностью и эластичностью и способы их получения - Google Patents

Микроструктурированные многослойные эластичные слоистые материалы с повышенной прочностью и эластичностью и способы их получения Download PDF

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RU2016140366A
RU2016140366A RU2016140366A RU2016140366A RU2016140366A RU 2016140366 A RU2016140366 A RU 2016140366A RU 2016140366 A RU2016140366 A RU 2016140366A RU 2016140366 A RU2016140366 A RU 2016140366A RU 2016140366 A RU2016140366 A RU 2016140366A
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styrene
ethylene
elastic laminate
weight
layer
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RU2661214C2 (ru
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ВанДук ЛИ
Пэйгуан ЧЖО
Давис Данг Хоанг НХАН
Альфонс Карл ДЕМАРКО
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Кимберли-Кларк Ворлдвайд, Инк.
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/001—Combinations of extrusion moulding with other shaping operations
    • B29C48/0018—Combinations of extrusion moulding with other shaping operations combined with shaping by orienting, stretching or shrinking, e.g. film blowing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/16—Articles comprising two or more components, e.g. co-extruded layers
    • B29C48/18—Articles comprising two or more components, e.g. co-extruded layers the components being layers
    • B29C48/21—Articles comprising two or more components, e.g. co-extruded layers the components being layers the layers being joined at their surfaces
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00—Layered products comprising a layer of natural or synthetic rubber
    • B32B25/04—Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B25/08—Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00—Layered products comprising a layer of natural or synthetic rubber
    • B32B25/14—Layered products comprising a layer of natural or synthetic rubber comprising synthetic rubber copolymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/302—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising aromatic vinyl (co)polymers, e.g. styrenic (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/144—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers using layers with different mechanical or chemical conditions or properties, e.g. layers with different thermal shrinkage, layers under tension during bonding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/02—Physical, chemical or physicochemical properties
    • B32B7/022—Mechanical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/07—Flat, e.g. panels
    • B29C48/08—Flat, e.g. panels flexible, e.g. films
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2009/00—Use of rubber derived from conjugated dienes, as moulding material
    • B29K2009/06—SB polymers, i.e. butadiene-styrene polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2274/00—Thermoplastic elastomer material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/51—Elastic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/702—Amorphous
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/704—Crystalline
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/724—Permeability to gases, adsorption
    • B32B2307/7242—Non-permeable
    • B32B2307/7244—Oxygen barrier
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2555/00—Personal care
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31786—Of polyester [e.g., alkyd, etc.]
    • Y10T428/31797—Next to addition polymer from unsaturated monomers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31909—Next to second addition polymer from unsaturated monomers
    • Y10T428/31913—Monoolefin polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31931—Polyene monomer-containing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31938—Polymer of monoethylenically unsaturated hydrocarbon

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Laminated Bodies (AREA)

Claims (25)

1. Эластичный слоистый материал, содержащий:
первый термопластичный эластомерный слой пленки, обладающий необратимой деформацией менее 40% после 150% удлинения, при этом термопластичная эластомерная пленка содержит термопластичный эластомер на основе полиолефинов и стирольный блок-сополимер; и
первый слой пластика, прикрепленный к первой поверхности термопластичного эластомерного слоя пленки, при этом слой пластика обладает необратимой деформацией, превышающей необратимую деформацию эластомерного слоя пленки, и где слой пластика содержит один из полукристаллического и аморфного полимера.
2. Эластичный слоистый материал по п. 1, где термопластичный эластомер на основе полиолефинов содержит гомополимер или сополимер б-олефина с 1—12 атомами углерода.
3. Эластичный слоистый материал по п. 1, где стирольный блок-сополимер выбран из группы, состоящей из стирол-этилен-пропилен-стирола (SEPS), стирол-этилен-пропилен-стирол-этилен-пропилена (SEPSEP), стирол-этилен-бутилен-стирола (SEBS), стирол-этилен-бутилен-стирол-этилен-бутилена (SEBSEB), стирол-бутадиен-стирола (SBS), стирол-изопрен-стирола (SIS), стирол-изопрен-бутадиен-стирола (SIBS), стирол-этилен-этилен-пропилен-стирола (SEEPS), гидрогенизированного винил-полиизопрена/гидрогенизированного полиизопрена/полистирола и их комбинаций.
4. Эластичный слоистый материал по п. 1, дополнительно содержащий средство, повышающее прочность, где средство, повышающее прочность, представляет собой неорганическую глину.
5. Эластичный слоистый материал по п. 4, где термопластичный эластомерный слой пленки содержит более 50% по весу термопластичного эластомера на основе полиолефинов, от приблизительно 15% по весу до приблизительно 40% по весу стирольного блок-сополимера и от приблизительно 2% по весу до приблизительно 10% по весу средства, повышающего прочность.
6. Эластичный слоистый материал по п. 1, где термопластичный эластомерный слой пленки практически не содержит карбонат кальция.
7. Эластичный слоистый материал по п. 1, где полукристаллический или аморфный полимер выбран из группы, состоящей из полиолефинов, coполимеров на основе полиолефинов, сложных полиэфиров и их комбинаций.
8. Эластичный слоистый материал по п. 1, где слой пластика содержит от приблизительно 5% по весу до приблизительно 50% по весу полукристаллического или аморфного полимера.
9. Эластичный слоистый материал по п. 1, где термопластичный эластомерный слой пленки является непроницаемым для воздуха.
10. Эластичный слоистый материал по п. 1, дополнительно содержащий второй слой пластика, прикрепленный ко второй поверхности термопластичного эластомерного слоя пленки.
11. Эластичный слоистый материал по п. 1, дополнительно содержащий второй термопластичный эластомерный слой пленки, где второй термопластичный эластомерный слой пленки прикреплен к первому слою пластика, противоположному первому термопластичному эластомерному слою пленки.
12. Способ получения эластичного слоистого материала, при этом способ включает:
совместную экструзию первого термопластичного эластомерного слоя пленки с первым слоем пластика с получением эластичного слоистого материала, при этом термопластичный слой пленки обладает необратимой деформацией менее 40% после 150% удлинения и содержит термопластичный эластомер на основе полиолефинов, стирольный блок-сополимер и средство, повышающее прочность, при этом слой пластика обладает необратимой деформацией, превышающей необратимую деформацию эластомерного слоя пленки, и где слой пластика содержит один из полукристаллического или аморфного полимера;
растяжение эластичного слоистого материала в одном или обоих из машинного направления или поперечного направления; и
расслабление растянутого эластичного слоистого материала.
13. Способ по п. 12, где термопластичный эластомер на основе полиолефинов содержит гомополимер или сополимер α-олефина с 1—12 атомами углерода.
14. Способ по п. 12, где стирольный блок-сополимер выбирают из группы, состоящей из стирол-этилен-пропилен-стирола (SEPS), стирол-этилен-пропилен-стирол-этилен-пропилена (SEPSEP), стирол-этилен-бутилен-стирола (SEBS), стирол-этилен-бутилен-стирол-этилен-бутилена (SEBSEB), стирол-бутадиен-стирола (SBS), стирол-изопрен-стирола (SIS), стирол-изопрен-бутадиен-стирола (SIBS), стирол-этилен-этилен-пропилен-стирола (SEEPS), гидрогенизированного винил-полиизопрена/гидрогенизированного полиизопрена/полистирола и их комбинаций.
15. Способ по п. 12, где средство, повышающее прочность, представляет собой неорганическую глину.
16. Способ по п. 12, где термопластичный эластомерный слой пленки содержит более 50% по весу термопластичного эластомера на основе полиолефинов, от приблизительно 15% по весу до приблизительно 40% по весу стирольного блок-сополимера и от приблизительно 2% по весу до приблизительно 10% по весу средства, повышающего прочность.
17. Способ по п. 12, где полукристаллический или аморфный полимер выбирают из группы, состоящей из полиолефинов, coполимеров на основе полиолефинов, сложных полиэфиров и их комбинаций.
18. Способ по п. 12, где эластомерный слоистый материал растягивают на от приблизительно 100% до приблизительно 600% в машинном направлении или поперечном направлении.
19. Способ по п. 12, дополнительно включающий совместную экструзию второго слоя пластика с первым термопластичным эластомерным слоем пленки, противоположным первому слою пластика, при этом второй слой пластика содержит один из полукристаллического или аморфного полимера.
20. Способ по п. 12, дополнительно включающий совместную экструзию второго термопластичного эластомерного слоя пленки с первым слоем пластика, противоположным первому термопластичному эластомерному слою пленки.
RU2016140366A 2014-03-31 2015-03-06 Микроструктурированные многослойные эластичные слоистые материалы с повышенной прочностью и эластичностью и способы их получения RU2661214C2 (ru)

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Application Number Priority Date Filing Date Title
US14/230,741 2014-03-31
US14/230,741 US9802392B2 (en) 2014-03-31 2014-03-31 Microtextured multilayered elastic laminates with enhanced strength and elasticity and methods of making thereof
PCT/IB2015/051661 WO2015150937A1 (en) 2014-03-31 2015-03-06 Microtextured multilayered elastic laminates with enhanced strength and elasticity and methods of making thereof

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RU2016140366A true RU2016140366A (ru) 2018-04-13
RU2661214C2 RU2661214C2 (ru) 2018-07-13

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US (1) US9802392B2 (ru)
EP (1) EP3126140B2 (ru)
KR (1) KR102356219B1 (ru)
CN (1) CN106103088B (ru)
AU (1) AU2015242310B2 (ru)
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EP3126140A1 (en) 2017-02-08
US9802392B2 (en) 2017-10-31
US20150273802A1 (en) 2015-10-01
RU2661214C2 (ru) 2018-07-13
EP3126140B1 (en) 2021-01-13
MX2016012442A (es) 2016-12-20
WO2015150937A1 (en) 2015-10-08
BR112016021562B1 (pt) 2021-09-08
CN106103088A (zh) 2016-11-09
KR20160140741A (ko) 2016-12-07
MX360519B (es) 2018-11-05
CN106103088B (zh) 2019-07-05
KR102356219B1 (ko) 2022-01-28
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