RU2013113873A

RU2013113873A - ASSOCIATIVE THICKENER FOR WATER COMPOSITIONS

Info

Publication number: RU2013113873A
Application number: RU2013113873/04A
Authority: RU
Inventors: Хольгер Тюрк; Фолькер ВЕНДЕЛЬ; Анна КРИСТАДОРО; Раби АЛ-ХЕЛЛАНИ; Бернд Брухманн
Original assignee: Басф Се
Priority date: 2010-09-01
Filing date: 2011-08-25
Publication date: 2014-10-10
Also published as: KR20140001825A; WO2012028527A1; BR112013004660A2; JP2013537921A; CN103124754A; AU2011298459A1; MX2013002262A; EP2611845A1; CA2810099A1

Abstract

1. Соединение, содержащее по меньшей мере одну группу общей формулы (I),причем Rнезависимо друг от друга являются алкилом с 4-40 атомами углерода, циклоалкилом с 3-10 атомами углерода, арилом с 6-30 атомами углерода, арилалкилом с 7-40 атомами углерода, алкиларилом с 7-40 атомами углерода или -(R-O)-R;R, Rнезависимо друг от друга обозначают алкилен с 2-10 атомами углерода, арилен с 6-10 атомами углерода или арилалкилен с 7-10 атомами углерода;Rатом водорода (Н), алкил с 1-40 атомами углерода, циклоалкил с 3-10 атомами углерода, арил с 6-30 атомами углерода, арилалкил с 7-40 атомами углерода или алкиларил с 7-40 атомами углерода;n: от 1 до 200;m: от 1 до 6;р: от 0 до 200,* соединение концевой группы с остальным соединением,при условии, что для р=0 эта концевая группа вместо соединения через атом кислорода (О) может также быть присоединена к остальному соединению через NR, где Rвыбирается из Н и алкила с 1-30 атомами углерода.2. Соединение по п.1, причем Rпредставляет собой -(R-O)-R, Rалкилен с 2-5 атомами углерода, Rалкилен с 2-5 атомами углерода, Rалкил с 12-30 атомами углерода или арилалкил с 7-30 атомами углерода, а р=0.3. Соединение по п.1, причем m составляет от 2 до 5.4. Соединение по п.1, причем это соединение выбирается из уретанов, мочевин, сложных эфиров, амидов и карбонатов.5. Соединение по п.4, причем это соединение представляет собой простой полиэфируретан и включает в себя соответственно в форме содержащихся в полимереа. по меньшей мере один простой полиэфирполиол иb. по меньшей мере один полиизоцианат.6. Соединение по п.5, причем по меньшей мере один простой полиэфирполиол а. имеет среднечисленную молекулярную массу Mв диапазоне от 4000 до 10000 г/моль.7. Соединение по п.1, причем по меньш�1. A compound containing at least one group of general formula (I), and R independently of each other are alkyl with 4-40 carbon atoms, cycloalkyl with 3-10 carbon atoms, aryl with 6-30 carbon atoms, arylalkyl with 7- 40 carbon atoms, alkylaryl with 7-40 carbon atoms or - (RO) -R; R, R independently of each other denote alkylene with 2-10 carbon atoms, arylene with 6-10 carbon atoms or arylalkylene with 7-10 carbon atoms; Hydrogen atom (H), alkyl with 1-40 carbon atoms, cycloalkyl with 3-10 carbon atoms, aryl with 6-30 carbon atoms, arylalkyl with 7-40 carbon atoms or alkylaryl with 7-40 carbon atoms; n: from 1 up to 200; m: from 1 to 6; p: from 0 to 200, * connection of the end group with the rest of the connection, provided that for p = 0 this end group, instead of being connected through the oxygen atom (O), can also be attached to the rest a compound via NR, where R is selected from H and alkyl with 1-30 carbon atoms. 2. A compound according to claim 1, wherein R is - (RO) -R, R alkylene with 2-5 carbon atoms, R alkylene with 2-5 carbon atoms, R alkyl with 12-30 carbon atoms or arylalkyl with 7-30 carbon atoms, and p = 0.3. A compound according to claim 1, wherein m is from 2 to 5.4. A compound according to claim 1, wherein the compound is selected from urethanes, ureas, esters, amides and carbonates. A compound according to claim 4, which compound is a polyether urethane and includes, respectively, in the form of those contained in the polymer. at least one polyether polyol; and b. at least one polyisocyanate. 6. A compound according to claim 5, wherein at least one polyether polyol a. has a number average molecular weight M ranging from 4000 to 10000 g / mol. 7. Connection according to claim 1, and at least

Claims

1. The compound containing at least one group of General formula (I)

,

moreover, R ¹ independently from each other are alkyl with 4-40 carbon atoms, cycloalkyl with 3-10 carbon atoms, aryl with 6-30 carbon atoms, arylalkyl with 7-40 carbon atoms, alkylaryl with 7-40 carbon atoms or - ( R ² —O) _n —R ³ ;

R ² , R ⁴ independently from each other are alkylene with 2-10 carbon atoms, arylene with 6-10 carbon atoms or arylalkylene with 7-10 carbon atoms;

R ^{3 is} a hydrogen atom (H), alkyl with 1-40 carbon atoms, cycloalkyl with 3-10 carbon atoms, aryl with 6-30 carbon atoms, arylalkyl with 7-40 carbon atoms or alkylaryl with 7-40 carbon atoms;

n: from 1 to 200;

m: 1 to 6;

p: from 0 to 200,

* connection of the end group with the rest of the connection,

provided that for p = 0 this end group, instead of being connected via an oxygen atom (O), can also be attached to the rest of the compound via NR ⁵ , where R ⁵ is selected from H and alkyl with 1-30 carbon atoms.

2. The compound according to claim 1, wherein R ¹ is - (R ² -O) _n -R ³ , R ^{2 is} alkylene with 2-5 carbon atoms, R ^{4 is} alkylene with 2-5 carbon atoms, R ^{3 is} alkyl with 12 -30 carbon atoms or arylalkyl with 7-30 carbon atoms, and p = 0.

3. The compound according to claim 1, wherein m is from 2 to 5.

4. The compound according to claim 1, wherein this compound is selected from urethanes, ureas, esters, amides and carbonates.

5. The compound according to claim 4, wherein this compound is a polyether urethane and includes, respectively, in the form contained in the polymer

but. at least one polyether polyol and

b. at least one polyisocyanate.

6. The compound according to claim 5, wherein at least one polyether polyol a. has a number average molecular weight M _n in the range from 4000 to 10000 g / mol.

7. The compound according to claim 1, wherein at least one end group of the general formula (I) is bonded to the rest of the compound via a structural moiety selected from esters, amides, imides, urethanes, ureas, amines, ethers.

8. The compound according to one of claims 1 to 7, wherein at least one end group of the general formula (I) is connected to the rest of the compound through a structural fragment selected from urethanes and urea.

9. An aqueous composition containing at least one compound according to one of claims 1 to 8.

10. The aqueous composition according to claim 9, containing at least one salt or surfactant, or both.