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RU2011122264A - STABILIZING FOR HALOGENED POLYMERS, NOT CONTAINING HEAVY METALS - Google Patents

STABILIZING FOR HALOGENED POLYMERS, NOT CONTAINING HEAVY METALS Download PDF

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RU2011122264A
RU2011122264A RU2011122264/05A RU2011122264A RU2011122264A RU 2011122264 A RU2011122264 A RU 2011122264A RU 2011122264/05 A RU2011122264/05 A RU 2011122264/05A RU 2011122264 A RU2011122264 A RU 2011122264A RU 2011122264 A RU2011122264 A RU 2011122264A
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polymer according
optionally substituted
polymer
parts
amount
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RU2011122264/05A
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RU2528994C2 (en
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Бернхард ПЕЛЬЦЛЬ
Михель ШИЛЛЕР
Херндрик Виллем ХУЙСМАН
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Хемсон Полимер-Эддитив Аг
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1. Галогенсодержащий полимер, содержащий композицию стабилизатора на основе изоцианурата, не содержащую тяжелых металлов, включающую в качестве основных компонентов по меньшей мере один изоцианурат, по меньшей мере один дигидропиридин и по меньшей мере одну перхлоратную соль, причем изоцианурат содержится в количестве от 0,5 до 1,5 частей на 100 частей смолы, дигидропиридин - в количестве от 0,1 до 0,5 частей на 100 частей смолы и перхлоратная соль - в количестве от 0,05 до 0,25 частей на 100 частей смолы, и каждый из других стабилизирующих компонентов, которые могут содержаться, содержится в меньшем количестве, чем указанные основные компоненты.1. A halogen-containing polymer containing an isocyanurate-based stabilizer composition not containing heavy metals, comprising as main components at least one isocyanurate, at least one dihydropyridine and at least one perchlorate salt, the isocyanurate being contained in an amount of from 0.5 up to 1.5 parts per 100 parts of resin, dihydropyridine in an amount of from 0.1 to 0.5 parts per 100 parts of resin and perchlorate salt in an amount of from 0.05 to 0.25 parts per 100 parts of resin, and each of other stabilizing components which may be contained, is contained in a smaller amount than these main components. 2. Полимер по п.1, где по меньшей мере один изоцианурат выбран из соединений формулы (I)2. The polymer according to claim 1, where at least one isocyanurate selected from compounds of formula (I)
Figure 00000001
Figure 00000001
 где R1, R2 и R3 независимо друг от друга означают атом водорода, возможно замещенный C1-C18 алкил, возможно замещенный С2-С6 алкенил, возможно замещенный C1-C4 алкокси, возможно замещенный C5-C8 циклоалкил, возможно замещенный С3-С8 алкилциклоалкил или возможно замещенный С5-С10 арил, и Х независимо друг от друга выбраны из S или О.where R 1 , R 2 and R 3 independently represent a hydrogen atom, optionally substituted C 1 -C 18 alkyl, optionally substituted C 2 -C 6 alkenyl, optionally substituted C 1 -C 4 alkoxy, optionally substituted C 5 -C 8 cycloalkyl, optionally substituted C 3 -C 8 alkylcycloalkyl or optionally substituted C 5 -C 10 aryl, and X are independently selected from S or O. 3. Полимер по п.2, где R1, R2 и R3 независимо друг от друга являются группами -СН3, -СН2СН3, -СН2СН2СН3, -CH2OH, -CH2CH2OH, -CH2CH2CH3, -CH2CH2CH2OH or -СН2(С2Н3О).3. The polymer according to claim 2, where R1, R 2 and R 3 independently of one another are —CH 3 , —CH 2 CH 3 , —CH 2 CH 2 CH 3 , —CH 2 OH, —CH 2 CH 2 groups OH, -CH 2 CH 2 CH 3 , -CH 2 CH 2 CH 2 OH 2 or -CH 2 (C 2 H 3 O). 4. Полимер по п.2, где Х=О.4. The polymer according to claim 2, where X = O. 5. Полимер по п.1, где изоцианурат выбран из группы, состоящей из5. The polymer according to claim 1, where the isocyanurate is selected from the group consisting of
Figure 00000002
Figure 00000003
Figure 00000002
Figure 00000003
Figure 00000004
,
Figure 00000005
Figure 00000004
,
Figure 00000005
 6. Полимер по п.1, где по меньшей мере один дигидропиридин выбран из соединений формул II и III6. The polymer according to claim 1, where at least one dihydropyridine is selected from compounds of formulas II and III
Figure 00000006
Figure 00000006
Figure 00000007
Figure 00000007
 где R4, R5, R6, R7 и R8 независимо друг от друга представляют собой атом водорода, возможно замещенный C1-C18 алкил, возможно замещенный С2-С6 алкенил, возможно замещенный С1-С4алкокси, возможно замещенный С5-С8 циклоалкил или возможно замещенный C5-C10 арил; Y представляет собой C1-C18 алкил, причем один или более атомов углерода могут быть заменены атомами О или S; и n является целым числом от 1 до 5.where R 4 , R 5 , R 6 , R 7 and R 8 independently represent a hydrogen atom, possibly substituted C 1 -C 18 alkyl, optionally substituted C 2 -C 6 alkenyl, optionally substituted C 1 -C 4 alkoxy optionally substituted C 5 -C 8 cycloalkyl or optionally substituted C 5 -C 10 aryl; Y represents C 1 -C 18 alkyl, wherein one or more carbon atoms may be replaced by O or S atoms; and n is an integer from 1 to 5. 7. Полимер по п.6, где R4, R5, R6, R7 и R8 независимо друг от друга выбраны из -СН3, -C2H5, -C8H17, -С16Н33, -C17H35, -C18H37, -C6H5, -ОСН3, -OC2H5, -OC12H25.7. The polymer according to claim 6, where R 4 , R 5 , R 6 , R 7 and R 8 are independently selected from —CH 3 , —C 2 H 5 , —C 8 H 17 , —C 16 H 33 , -C 17 H 35 , -C 18 H 37 , -C 6 H 5 , -OCH 3 , -OC 2 H 5 , -OC 12 H 25 . 8. Полимер по п.6, где Y выбран из (CH2)x, (CH2)x-O-(CH2)y and (CH2)x-S-(CH2)y, причем х и y независимо друг от друга являются целым числом от 1 до 10.8. The polymer according to claim 6, where Y is selected from (CH 2 ) x , (CH 2 ) x -O- (CH 2 ) y and (CH 2 ) x -S- (CH 2 ) y , wherein x and y independently from each other are an integer from 1 to 10. 9. Полимер по п.6, где дигидропиридин выбран из группы, состоящей из:9. The polymer according to claim 6, where the dihydropyridine is selected from the group consisting of:
Figure 00000008
Figure 00000008
Figure 00000009
,
Figure 00000010
Figure 00000009
,
Figure 00000010
Figure 00000011
Figure 00000011
Figure 00000012
Figure 00000012
Figure 00000013
Figure 00000013
Figure 00000014
Figure 00000014
Figure 00000015
и
Figure 00000015
and
Figure 00000016
Figure 00000016
 10. Полимер по п.1, где по меньшей мере один перхлорат выбран из соединений с общими формулами (IV) и (V)10. The polymer according to claim 1, where at least one perchlorate is selected from compounds with General formulas (IV) and (V)
Figure 00000017
Figure 00000017
Figure 00000018
Figure 00000018
 где М обозначает Li, Na, К, Mg, Са или Al; k является целым числом от 1 до 3; х является целым числом от 1 до 6; z является числом в диапазоне от 0,01 до 2.where M is Li, Na, K, Mg, Ca or Al; k is an integer from 1 to 3; x is an integer from 1 to 6; z is a number in the range of 0.01 to 2. 11. Полимер по п.10, где перхлорат выбран из группы, состоящей из NaClO4, Ca(ClO4)2, Mg(ClO4)2 и Al(ClO4)3.11. The polymer of claim 10, where the perchlorate is selected from the group consisting of NaClO 4 , Ca (ClO 4 ) 2 , Mg (ClO 4 ) 2 and Al (ClO 4 ) 3 . 12. Полимер по п.1, где композиция стабилизатора содержится в количестве от примерно 0,01 до примерно 10,0 частей на 100 частей смолы.12. The polymer according to claim 1, where the stabilizer composition is contained in an amount of from about 0.01 to about 10.0 parts per 100 parts of resin. 13. Полимер по п.12, где композиция стабилизатора содержится в количестве от примерно 0,05 до примерно 8,0 частей на 100 частей смолы.13. The polymer of claim 12, wherein the stabilizer composition is contained in an amount of from about 0.05 to about 8.0 parts per 100 parts of resin. 14. Полимер по п.1, дополнительно содержащий по меньшей мере один состабилизатор.14. The polymer according to claim 1, additionally containing at least one stabilizer. 15. Полимер по п.1, дополнительно содержащий первичные стабилизаторы, цеолиты, антиоксиданты, наполнители, пластификаторы, красители, пигменты, антистатические агенты, поверхностно-активные вещества, пенообразователи, модификаторы ударопрочности и/или УФ-стабилизаторы.15. The polymer according to claim 1, additionally containing primary stabilizers, zeolites, antioxidants, fillers, plasticizers, dyes, pigments, antistatic agents, surfactants, foaming agents, impact modifiers and / or UV stabilizers. 16. Полимер по п.1, где галогенсодержащим полимером является ПВХ.16. The polymer according to claim 1, where the halogen-containing polymer is PVC. 17. Полимер по п.1, где композиция стабилизатора не содержит урацилов и/или аминокротонатов.17. The polymer according to claim 1, where the stabilizer composition does not contain uracils and / or aminocrotonates. 18. Применение композиции стабилизатора по любому из пунктов с 1 по 17 для стабилизации галогенсодержащих полимеров.18. The use of the stabilizer composition according to any one of paragraphs 1 to 17 for the stabilization of halogen-containing polymers. 19. Применение по п.18, где стабилизация представляет собой стабилизацию против воздействия света.19. The application of claim 18, wherein the stabilization is stabilization against exposure to light. 20. Применение по п.18 или 19, где галогенсодержащим полимером является ПВХ.20. The application of claim 18 or 19, wherein the halogen-containing polymer is PVC. 21. Формованное изделие, содержащее галогенсодержащий полимер по любому из пп.1-17.21. A molded product containing a halogen-containing polymer according to any one of claims 1 to 17. 22. Формованное изделие по п.21, которое может быть оконным профилем, трубой, покрытием для пола, полосой кровельного материала, кабелем и пленкой. 22. The molded product according to item 21, which may be a window profile, pipe, flooring, strip of roofing material, cable and film.
RU2011122264/05A 2008-11-26 2009-11-26 Heavy metal-free stabiliser composition for halogenated polymers RU2528994C2 (en)

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DE102008058901A DE102008058901A1 (en) 2008-11-26 2008-11-26 Heavy metal-free stabilizer composition for halogen-containing polymers
DE102008058901.2 2008-11-26
PCT/EP2009/065926 WO2010060966A1 (en) 2008-11-26 2009-11-26 Heavy metal-free stabilizer composition for halogenated polymers

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EP (1) EP2361282B1 (en)
CN (1) CN102292391A (en)
AU (1) AU2009318987B2 (en)
BR (1) BRPI0922833B1 (en)
DE (1) DE102008058901A1 (en)
ES (1) ES2670223T3 (en)
PL (1) PL2361282T3 (en)
RU (1) RU2528994C2 (en)
TR (1) TR201806132T4 (en)
UA (1) UA104441C2 (en)
WO (1) WO2010060966A1 (en)

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AU2012241926B2 (en) 2011-04-11 2015-09-03 Chemson Polymer-Additive Ag Hydroquinone compounds for reducing photoblueing of halogen-containing polymers

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