[go: up one dir, main page]

RU2011118354A - CATALYTIC MATERIALS, PHOTOANODES AND PHOTOELECTRIC CELLS FOR ELECTROLYSIS OF WATER AND OTHER ELECTROCHEMICAL TECHNOLOGIES - Google Patents

CATALYTIC MATERIALS, PHOTOANODES AND PHOTOELECTRIC CELLS FOR ELECTROLYSIS OF WATER AND OTHER ELECTROCHEMICAL TECHNOLOGIES Download PDF

Info

Publication number
RU2011118354A
RU2011118354A RU2011118354/07A RU2011118354A RU2011118354A RU 2011118354 A RU2011118354 A RU 2011118354A RU 2011118354/07 A RU2011118354/07 A RU 2011118354/07A RU 2011118354 A RU2011118354 A RU 2011118354A RU 2011118354 A RU2011118354 A RU 2011118354A
Authority
RU
Russia
Prior art keywords
photoactive electrode
component
catalytic material
anionic
photoactive
Prior art date
Application number
RU2011118354/07A
Other languages
Russian (ru)
Inventor
Дэниел Г. НОСЕРА (US)
Дэниел Г. НОСЕРА
Мэттью В. КАНАН (US)
Мэттью В. КАНАН
Йогеш СУРЕНДРАНАТХ (US)
Йогеш СУРЕНДРАНАТХ
Стивен Й. РИС (US)
Стивен Й. РИС
Артур Дж. ЭССВАЙН (US)
Артур Дж. ЭССВАЙН
Original Assignee
Массачусетс Инститьют Оф Текнолоджи (Us)
Массачусетс Инститьют Оф Текнолоджи
Сан Каталитикс Корпорейшн (Us)
Сан Каталитикс Корпорейшн
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Массачусетс Инститьют Оф Текнолоджи (Us), Массачусетс Инститьют Оф Текнолоджи, Сан Каталитикс Корпорейшн (Us), Сан Каталитикс Корпорейшн filed Critical Массачусетс Инститьют Оф Текнолоджи (Us)
Publication of RU2011118354A publication Critical patent/RU2011118354A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C25B1/04—Hydrogen or oxygen by electrolysis of water
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0244—Coatings comprising several layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/34—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation
    • B01J37/348—Electrochemical processes, e.g. electrochemical deposition or anodisation
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/50—Processes
    • C25B1/55—Photoelectrolysis
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M14/00—Electrochemical current or voltage generators not provided for in groups H01M6/00 - H01M12/00; Manufacture thereof
    • H01M14/005—Photoelectrochemical storage cells
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/39—Photocatalytic properties
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/133—Renewable energy sources, e.g. sunlight

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Metallurgy (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Plasma & Fusion (AREA)
  • Toxicology (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)

Abstract

1. Способ формирования фотоанода, включающий: ! предоставление фотоактивного электрода; и ! побуждение металлического ионного компонента, первого типа анионных компонентов, содержащего гидроксидные и/или оксидные ионы, и второго типа анионных компонентов к формированию каталитического материала, связанного с фотоактивным электродом, посредством приложения напряжения к фотоактивному электроду. ! 2. Способ формирования фотоанода, включающий: ! предоставление фотоактивного электрода; и ! побуждение металлического ионного компонента и анионного компонента к формированию каталитического материала, связанного с фотоактивным электродом, посредством приложения напряжения к фотоактивному электроду, при этом напряжение прикладывают к фотоактивному электроду посредством воздействия на фотоактивный электрод электромагнитного излучения. ! 3. Способ формирования фотоанода, включающий: ! предоставление раствора, содержащего ионы кобальта и/или никеля и анионный компонент, содержащий фосфор и/или бор; ! предоставление фотоактивного электрода; и ! побуждение ионов кобальта и/или никеля и анионного компонента, содержащего фосфор и/или бор, к формированию каталитического материала, связанного с фотоактивным электродом, посредством приложения напряжения к фотоактивному электроду. ! 4. Способ получения кислорода из воды, включающий следующие этапы: ! предоставление фотоэлектрохимической ячейки, содержащей: ! фотоактивный электрод; ! электролит; и ! каталитический материал, полностью связанный с фотоактивным электродом, данный каталитический материал содержит металлический ионный компонент и анионный компонен 1. A method of forming a photoanode, including:! provision of a photoactive electrode; and! causing the metal ionic component, the first type of anionic components containing hydroxide and / or oxide ions, and the second type of anionic components to form a catalytic material associated with the photoactive electrode by applying a voltage to the photoactive electrode. ! 2. A method of forming a photoanode, including:! provision of a photoactive electrode; and! causing the metal ionic component and the anionic component to form a catalytic material associated with the photoactive electrode by applying a voltage to the photoactive electrode, wherein a voltage is applied to the photoactive electrode by exposing the photoactive electrode to electromagnetic radiation. ! 3. A method of forming a photoanode, including:! providing a solution containing cobalt and / or nickel ions and an anionic component containing phosphorus and / or boron; ! provision of a photoactive electrode; and! causing the cobalt and / or nickel ions and the phosphorus and / or boron anionic component to form a catalytic material associated with the photoactive electrode by applying a voltage to the photoactive electrode. ! 4. A method for obtaining oxygen from water, including the following steps:! provision of a photoelectrochemical cell containing:! photoactive electrode; ! electrolyte; and! catalytic material fully bonded to the photoactive electrode, this catalytic material contains a metallic ionic component and an anionic component

Claims (11)

1. Способ формирования фотоанода, включающий:1. The method of forming a photoanode, including: предоставление фотоактивного электрода; иprovision of a photoactive electrode; and побуждение металлического ионного компонента, первого типа анионных компонентов, содержащего гидроксидные и/или оксидные ионы, и второго типа анионных компонентов к формированию каталитического материала, связанного с фотоактивным электродом, посредством приложения напряжения к фотоактивному электроду.inducing a metal ionic component, a first type of anionic components containing hydroxide and / or oxide ions, and a second type of anionic components to form a catalytic material bonded to the photoactive electrode by applying voltage to the photoactive electrode. 2. Способ формирования фотоанода, включающий:2. A method of forming a photo anode, including: предоставление фотоактивного электрода; иprovision of a photoactive electrode; and побуждение металлического ионного компонента и анионного компонента к формированию каталитического материала, связанного с фотоактивным электродом, посредством приложения напряжения к фотоактивному электроду, при этом напряжение прикладывают к фотоактивному электроду посредством воздействия на фотоактивный электрод электромагнитного излучения.causing the metal ion component and the anion component to form a catalytic material bonded to the photoactive electrode by applying voltage to the photoactive electrode, wherein voltage is applied to the photoactive electrode by exposing the photoactive electrode to electromagnetic radiation. 3. Способ формирования фотоанода, включающий:3. A method of forming a photo anode, including: предоставление раствора, содержащего ионы кобальта и/или никеля и анионный компонент, содержащий фосфор и/или бор;providing a solution containing cobalt and / or nickel ions and an anionic component containing phosphorus and / or boron; предоставление фотоактивного электрода; иprovision of a photoactive electrode; and побуждение ионов кобальта и/или никеля и анионного компонента, содержащего фосфор и/или бор, к формированию каталитического материала, связанного с фотоактивным электродом, посредством приложения напряжения к фотоактивному электроду.inducing cobalt and / or nickel ions and an anionic component containing phosphorus and / or boron to form catalytic material bonded to the photoactive electrode by applying a voltage to the photoactive electrode. 4. Способ получения кислорода из воды, включающий следующие этапы:4. A method of producing oxygen from water, comprising the following steps: предоставление фотоэлектрохимической ячейки, содержащей:providing a photoelectrochemical cell containing: фотоактивный электрод;photoactive electrode; электролит; иelectrolyte; and каталитический материал, полностью связанный с фотоактивным электродом, данный каталитический материал содержит металлический ионный компонент и анионный компонент, и при этом каталитический материал содержит металлический ионный компонент, первый тип анионных компонентов, содержащий гидроксидные и/или оксидные ионы, и второй тип анионных компонентов; иa catalytic material fully bonded to the photoactive electrode, the catalytic material contains a metal ion component and an anion component, and the catalytic material contains a metal ion component, a first type of anionic components containing hydroxide and / or oxide ions, and a second type of anionic components; and облучение фотоэлектрохимической ячейки электромагнитным излучением, чтобы посредством этого получать кислород из воды.irradiating the photoelectrochemical cell with electromagnetic radiation to thereby obtain oxygen from water. 5. Фотоанод, содержащий:5. Photoanode containing: фотоактивный электрод; иphotoactive electrode; and каталитический материал, связанный с фотоактивным электродом и содержащий ионы кобальта и/или ионы никеля и анионный компонент, содержащий фосфор и/или бор.catalytic material associated with a photoactive electrode and containing cobalt ions and / or nickel ions and an anionic component containing phosphorus and / or boron. 6. Фотоанод, содержащий:6. Photoanode containing: фотоактивный электрод, содержащий фотоактивную композицию, иa photoactive electrode containing a photoactive composition, and каталитический материал, содержащий металлический ионный компонент, первый тип анионных компонентов и второй тип анионных компонентов, в котором металлический ионный компонент в состоянии окисления (n+x) и первый тип и/или второй тип анионных компонентов образуют по существу некристаллическую композицию и имеют величину Ksp, которая меньше, по меньшей мере в 103 раз, чем величина Ksp композиции, содержащей металлический ионный компонент в состоянии окисления (n) и первый тип и/или второй тип анионных компонентов.a catalytic material containing a metal ionic component, a first type of anionic components and a second type of anionic components, in which the metal ionic component in the oxidized state (n + x) and the first type and / or second type of anionic components form a substantially non-crystalline composition and have a K value sp , which is at least 10 3 times less than the K sp value of the composition containing the metal ionic component in the oxidized state (n) and the first type and / or second type of anionic components. 7. Фотоанод, содержащий:7. A photo anode containing: фотоактивный электрод, содержащий фотоактивную композицию, иa photoactive electrode containing a photoactive composition, and каталитический материал, содержащий металлический ионный компонент и анионный компонент, в котором металлический ионный компонент в состоянии окисления (n+x) и анионный компонент образуют по существу некристаллическую композицию и имеют величину Ksp, при pH менее чем 11, которая меньше по меньшей мере в 103 раз, чем величина Ksp композиции, содержащей металлический ионный компонент в состоянии окисления (n) и анионный компонент.a catalytic material containing a metal ionic component and an anionic component in which the metalic ionic component in the oxidized state (n + x) and the anionic component form a substantially non-crystalline composition and have a K sp value, at a pH of less than 11, which is less than at least 10 3 times the K sp value of the composition containing the metal ionic component in the oxidized state (n) and the anionic component. 8. Фотоанод, содержащий:8. A photo anode containing: фотоактивный электрод; иphotoactive electrode; and каталитический материал, содержащий металлический ионный компонент и анионный компонент, при этом каталитический материал сформирован приложением напряжения к фотоактивному электроду, и при этом каталитический материал содержит металлический ионный компонент, первый тип анионных компонентов, содержащий гидроксидные и/или оксидные ионы, и второй тип анионных компонентов.a catalytic material containing a metal ionic component and an anionic component, wherein the catalytic material is formed by applying a voltage to the photoactive electrode, and the catalytic material contains a metal ionic component, a first type of anionic components containing hydroxide and / or oxide ions, and a second type of anionic components . 9. Фотоэлектрохимическая ячейка, содержащая:9. A photoelectrochemical cell containing: фотоанод, содержащий фотоактивный электрод и каталитический материал, содержащий металлический ионный компонент и анионный компонент, при этом каталитический материал содержит металлический ионный компонент, первый тип анионных компонентов, содержащий гидроксидные и/или оксидные ионы, и второй тип анионных компонентов;a photoanode containing a photoactive electrode and a catalytic material containing a metal ionic component and an anionic component, the catalytic material containing a metal ionic component, a first type of anionic components containing hydroxide and / or oxide ions, and a second type of anionic components; второй электрод; иsecond electrode; and электролит.electrolyte. 10. Способ получения кислорода и/или водорода из воды, включающий следующие этапы:10. A method of producing oxygen and / or hydrogen from water, comprising the following steps: предоставление устройства, содержащего:providing a device comprising: фотоактивный электрод, содержащий каталитический материал;a photoactive electrode containing catalytic material; электролит; иelectrolyte; and воду при pH воды от примерно 3 до примерно 11;water at a pH of from about 3 to about 11; облучение устройства светом, чтобы получать кислород из воды, при этом общий кпд преобразования энергии устройством при облучении смоделированным излучением AM 1,5, составляет по меньшей мере примерно 1,0%.irradiating the device with light in order to obtain oxygen from water, with a total energy conversion efficiency of the device irradiated with simulated radiation of AM 1.5, at least about 1.0%. 11. Устройство для получения кислорода и/или водорода из воды, содержащее:11. A device for producing oxygen and / or hydrogen from water, containing: фотоактивную композицию; иphotoactive composition; and электролит, при pH от примерно 2 до примерно 12, находящийся в соприкосновении с возможностью протекания электрохимических реакций с фотоактивной композицией,an electrolyte, at a pH of from about 2 to about 12, in contact with the possibility of electrochemical reactions with the photoactive composition, при этом устройство функционирует с общей эффективностью преобразования энергии, при облучении смоделированным излучением AM 1,5, составляющей по меньшей мере примерно 1,0%. however, the device operates with a total energy conversion efficiency when irradiated with simulated radiation of AM 1.5 of at least about 1.0%.
RU2011118354/07A 2008-10-08 2009-10-08 CATALYTIC MATERIALS, PHOTOANODES AND PHOTOELECTRIC CELLS FOR ELECTROLYSIS OF WATER AND OTHER ELECTROCHEMICAL TECHNOLOGIES RU2011118354A (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US10389808P 2008-10-08 2008-10-08
US61/103,898 2008-10-08
US21800609P 2009-06-17 2009-06-17
US61/218,006 2009-06-17

Publications (1)

Publication Number Publication Date
RU2011118354A true RU2011118354A (en) 2012-11-20

Family

ID=41508326

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2011118354/07A RU2011118354A (en) 2008-10-08 2009-10-08 CATALYTIC MATERIALS, PHOTOANODES AND PHOTOELECTRIC CELLS FOR ELECTROLYSIS OF WATER AND OTHER ELECTROCHEMICAL TECHNOLOGIES

Country Status (11)

Country Link
US (1) US20100133111A1 (en)
EP (1) EP2350347A1 (en)
JP (1) JP2012505310A (en)
KR (1) KR20110084225A (en)
CN (1) CN102224279A (en)
AU (1) AU2009302811A1 (en)
BR (1) BRPI0920386A2 (en)
IL (1) IL212188A0 (en)
MX (1) MX2011003719A (en)
RU (1) RU2011118354A (en)
WO (1) WO2010042196A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2579782C1 (en) * 2014-11-28 2016-04-10 Федеральное государственное бюджетное образовательное учреждение высшего образования "Юго-Западный государственный университет" (ЮЗГУ) Photoelectrochemical cell

Families Citing this family (128)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2229471B1 (en) 2008-01-08 2015-03-11 Treadstone Technologies, Inc. Highly electrically conductive surfaces for electrochemical applications
KR20110033212A (en) * 2008-06-18 2011-03-30 메사추세츠 인스티튜트 오브 테크놀로지 Catalytic materials, electrodes and systems for the electrolysis of water, and other electrochemical techniques
US11214486B2 (en) 2009-02-20 2022-01-04 Marine Power Products Incorporated Desalination methods and devices using geothermal energy
US9206043B2 (en) 2009-02-20 2015-12-08 Marine Power Products Incorporated Method of and device for optimizing a hydrogen generating system
US9415363B2 (en) 2009-02-20 2016-08-16 Marine Power Products Corporation Method and apparatus for efficient on-demand production of H2 and O2 from water using waste heat and environmentally safe metals
US10145015B2 (en) 2012-12-05 2018-12-04 Marine Power Products Incorporated Hydrogen generating system and method using geothermal energy
TWI384310B (en) * 2009-04-13 2013-02-01 Univ Nat Cheng Kung Photovoltachromic device and the application thereof
WO2011028262A2 (en) 2009-08-27 2011-03-10 Sun Catalytix Corporation Compositions, electrodes, methods and systems for water electrolysis and other electrochemical techniques
US8192609B2 (en) * 2009-12-01 2012-06-05 Wisconsin Alumni Research Foundation Cobalt oxyfluoride catalysts for electrolytic dissociation of water
EP2507411A4 (en) * 2009-12-01 2015-07-29 Wisconsin Alumni Res Found BUFFER CATALYSTS BASED ON COBALT OXIDE
KR101220036B1 (en) * 2010-04-21 2013-01-21 한양대학교 산학협력단 Electrode for electrochemical device, method for fabricating the same and electrochemical device
WO2011132101A1 (en) * 2010-04-22 2011-10-27 Koninklijke Philips Electronics N.V. Beverage carbonator and method for producing such carbonated beverage
US8840772B2 (en) * 2010-05-17 2014-09-23 Honda Motor Co., Ltd. Solar fuel cell
US20120156577A1 (en) 2010-08-20 2012-06-21 Massachusetts Institute Of Technology Methods for forming electrodes for water electrolysis and other electrochemical techniques
US20120145265A1 (en) * 2010-12-09 2012-06-14 Mark Stephenson System for Conditioning Fluids Using Fermi Energy
US20130277209A1 (en) * 2010-12-28 2013-10-24 Kabushiki Kaisha Toyota Chuo Kenkyusho Photochemical reaction device
EP2663668A2 (en) 2011-01-12 2013-11-20 Ceramatec, Inc Electrochemical production of hydrogen
WO2012102118A1 (en) * 2011-01-28 2012-08-02 株式会社村田製作所 Photovoltaic device and hydrogen generating device
TWI553158B (en) 2011-02-09 2016-10-11 海運動力產品股份有限公司 Stability control of a hydrogen generating system and method
US9732431B2 (en) * 2011-03-28 2017-08-15 Aquahydrex Pty Ltd Cathode-driven or assisted solar cell
EP2694702A4 (en) * 2011-04-01 2014-10-15 California Inst Of Techn PROTON EXCHANGE MEMBRANE ELECTROLYSIS USING WATER VAPOR AS A STARTING PRODUCT
US9205420B2 (en) 2011-04-22 2015-12-08 President And Fellows Of Harvard College Nanostructures, systems, and methods for photocatalysis
WO2012154692A1 (en) * 2011-05-06 2012-11-15 Molycorp Minerals, Llc Lanthanide-mediated water splitting process for hydrogen and oxygen generation
US20120318679A1 (en) * 2011-05-17 2012-12-20 Massachusetts Institute Of Technology Methods and compositions comprising macrocycles, including halogenated macrocycles
CN103748783B (en) 2011-07-29 2017-02-15 康宁股份有限公司 Solar-redshift systems
US10208384B2 (en) * 2011-08-11 2019-02-19 Toyota Motor Engineering & Manufacturing North America, Inc. Efficient water oxidation catalysts and methods of oxygen and hydrogen production by photoelectrolysis
WO2013029186A1 (en) 2011-09-01 2013-03-07 Trudel Simon Electrocatalytic materials and methods for manufacturing same
US9755023B2 (en) * 2011-09-30 2017-09-05 The University Of Kentucky Research Foundation Photoelectrochemical cell including Ga(Sbx)N1-x semiconductor electrode
WO2013055788A1 (en) * 2011-10-12 2013-04-18 The Regents Of The University Of California Photoelectrode for solar water oxidation
US9593053B1 (en) * 2011-11-14 2017-03-14 Hypersolar, Inc. Photoelectrosynthetically active heterostructures
KR101251378B1 (en) * 2011-11-18 2013-04-05 권오주 Ceramic poles fluorescent lamp type electronic ballast using ceramic-glass composite electrode
CN103159297B (en) * 2011-12-13 2014-09-03 中国科学院大连化学物理研究所 Hydrogen-production and on-line separation device for decomposing water by optical electrolytic cell
CN102496465B (en) * 2011-12-16 2015-04-29 奇瑞汽车股份有限公司 Electrolyte for dye-sensitized solar cell and preparation method thereof, and solar cell
US20130186768A1 (en) * 2012-01-05 2013-07-25 Massachusetts Institute Of Technology Articles, devices, systems, and methods for solar energy storage and/or utilization
US8968534B2 (en) * 2012-01-31 2015-03-03 Toyota Motor Egineering & Manufacturing North America, Inc. Water oxidation catalyst
US10370595B2 (en) 2012-03-13 2019-08-06 Marine Power Products Incorporated System for and method of using on-site excess heat to convert CO2 emissions into hydrocarbons income at coal-fired power plants
WO2013152043A1 (en) * 2012-04-02 2013-10-10 California Institute Of Technology Solar fuels generator
ES2549636T3 (en) * 2012-04-05 2015-10-30 Commissariat à l'énergie atomique et aux énergies alternatives Method for preparing a catalyst that mediates the evolution of H2, said catalyst and uses thereof
JP6183620B2 (en) * 2012-10-31 2017-08-23 株式会社大阪ソーダ Zero gap type anode for salt electrolyzer, salt electrolyzer, and salt electrolysis method using the same
JP6067344B2 (en) * 2012-11-20 2017-01-25 株式会社東芝 Photochemical reaction system
TWI500211B (en) * 2012-12-14 2015-09-11 Hwang Bing Joe Photocatalyst galvanic cell system
US20140174905A1 (en) * 2012-12-20 2014-06-26 Sunpower Technologies Llc Photo-catalytic systems for the production of hydrogen
US8936734B2 (en) 2012-12-20 2015-01-20 Sunpower Technologies Llc System for harvesting oriented light—water splitting
WO2014103609A1 (en) * 2012-12-26 2014-07-03 富士フイルム株式会社 Semiconductor film, production method for semiconductor film, solar cell, light-emitting diode, thin film transistor, and electronic device
US20140209478A1 (en) * 2013-01-31 2014-07-31 Sunpower Technologies Llc Artificial Photosynthetic System Using Photocatalyst
US9567681B2 (en) 2013-02-12 2017-02-14 Treadstone Technologies, Inc. Corrosion resistant and electrically conductive surface of metallic components for electrolyzers
JP6249362B2 (en) * 2013-05-21 2017-12-20 パナソニックＩｐマネジメント株式会社 Method for reducing carbon dioxide, carbon dioxide reduction cell and carbon dioxide reduction device
CN105209664A (en) 2013-07-05 2015-12-30 松下知识产权经营株式会社 Method for reducing carbon dioxide
NL2011354C2 (en) * 2013-08-29 2015-03-03 Univ Leiden Process for preparing an anode material, an electrochemical cell and a process to convert water.
WO2015054656A1 (en) * 2013-10-10 2015-04-16 California Institute Of Technology Protecting the surface of a light absorber in a photoanode
US9512526B2 (en) 2013-12-19 2016-12-06 Toyota Motor Engineering & Manufacturing North America, Inc. Water oxidation catalyst including lithium cobalt germanate
CN104576068A (en) * 2014-03-06 2015-04-29 华东理工大学 Solar cell based on water-air system
WO2015146014A1 (en) * 2014-03-24 2015-10-01 株式会社 東芝 Photoelectrochemical reaction system
JP6258467B2 (en) * 2014-03-24 2018-01-10 株式会社東芝 Photoelectrochemical reaction system
JP6271311B2 (en) * 2014-03-24 2018-01-31 株式会社東芝 Electrochemical reactor
JP6614429B2 (en) * 2014-03-27 2019-12-04 国立研究開発法人理化学研究所 Catalyst for water splitting and method for producing oxygen and hydrogen using the same
US9469908B2 (en) * 2014-05-12 2016-10-18 The Trustees Of The University Of Pennsylvania Synergistic oxygen evolving activity of non-stoichiometric surfaces
EP3147385B1 (en) * 2014-05-20 2020-02-19 Kabushiki Kaisha Toshiba Photoelectrochemical reaction device
US9809889B2 (en) 2014-08-28 2017-11-07 Toyota Motor Engineering & Manufacturing North America, Inc. Water oxidation catalyst including cobalt molybdenum
US9999870B2 (en) * 2014-09-12 2018-06-19 Paul Gregory O'BRIEN Nanostructured solar selective catalytic supports
JP2016104897A (en) * 2014-12-01 2016-06-09 株式会社東芝 Photoelectrode, method of manufacturing the same, and photoelectrochemical reactor using the same
CA2971379A1 (en) * 2014-12-25 2016-06-30 Si Energy Company Limited Method and apparatus for synthesizing hydrocarbon
JP6559710B2 (en) * 2015-01-13 2019-08-14 富士フイルム株式会社 Hydrogen generation electrode
CN104833766B (en) * 2015-04-14 2016-08-24 中国科学院化学研究所 A kind of Fe-O active specy formed on nanometer bloodstone surface and its preparation method and application
CN107849680B (en) 2015-04-15 2020-11-13 踏石科技有限公司 A method for treating the surface of metal parts to achieve lower contact resistance
US10202695B2 (en) * 2015-05-21 2019-02-12 Palo Alto Research Center Incorporated Photoelectrolysis system and method
JP6768269B2 (en) 2015-07-31 2020-10-14 株式会社東芝 Photoelectrochemical reactor
JP6768273B2 (en) 2015-09-04 2020-10-14 株式会社東芝 Photoelectrochemical reactor
US10344388B2 (en) 2015-09-16 2019-07-09 Kabushiki Kaisha Toshiba CO2 reduction catalyst, CO2 reduction electrode, CO2 reduction reaction apparatus, and process for producing CO2 reduction catalyst
GB201518190D0 (en) * 2015-10-14 2015-11-25 Univ Dublin City Porphyrins as electrocatalysts and electrodes modified with same
EP3377675B1 (en) * 2015-11-18 2023-03-22 Enlighten Innovations Inc. Electrochemical production of hydrogen with dye-sensitized solar cell-based anode
US20170137950A1 (en) * 2015-11-18 2017-05-18 Ceramatec, Inc. Electrochemical production of hydrogen with dye-sensitized solar cell-based anode
KR101709021B1 (en) * 2015-12-16 2017-02-22 서울대학교산학협력단 Manufacturing method of photoelectrode for electrochemical hydrogen production
US10103416B2 (en) * 2016-03-09 2018-10-16 Saudi Arabian Oil Company System and method for power generation with a closed-loop photocatalytic solar device
JP6803587B2 (en) * 2016-03-09 2020-12-23 東京都公立大学法人 Hydrolytic photoelectrochemical cell, and hydrogen production equipment and hydrogen peroxide production equipment using it
CN105839138B (en) * 2016-05-10 2017-11-07 东北林业大学 A kind of preparation method of solid oxide electrolytic cell high temperature fused carbonate air electrode
JP6810338B2 (en) 2016-08-10 2021-01-06 富士通株式会社 Photochemical electrode and hydrogen generator
US10690604B2 (en) * 2016-08-25 2020-06-23 Purdue Research Foundation Sensors and methods of identifying a gas, and levitated spin-optomechanical systems
JP6989875B2 (en) * 2016-09-01 2022-01-12 昭和電工マテリアルズ株式会社 Nanocrystal manufacturing method and steel manufacturing method
WO2018058094A1 (en) 2016-09-26 2018-03-29 University Of Iowa Research Foundation Integrated membrane solar fuel production assembly
US10370766B2 (en) * 2016-10-27 2019-08-06 The Regents Of The University Of California Hybrid photo-electrochemical and photo-voltaic cells
CN106374000B (en) * 2016-10-28 2018-01-09 苏州大学 The preparation method and applications of black silicon photocathode
CN106770587B (en) * 2016-11-25 2019-03-26 深圳大学 A kind of Photoelectrochemistrbiosensor biosensor and preparation method thereof
CN106770566B (en) * 2016-11-25 2019-04-16 深圳大学 The detection method of Salmonella sensor, preparation method and salmonella concentration
EP3558498A4 (en) * 2016-12-21 2021-01-13 University of Iowa Research Foundation DEVICE AND METHOD FOR THREE-DIMENSIONAL PHOTOELECTRODIALYSIS
KR101884691B1 (en) * 2017-03-09 2018-08-30 성균관대학교 산학협력단 Catalyst for hydrogen evolution reaction
JP6744242B2 (en) 2017-03-10 2020-08-19 株式会社東芝 Chemical reaction system
KR101946029B1 (en) * 2017-05-16 2019-04-17 경북대학교 산학협력단 wastewater treatment, desalination and chemical production complex system
US10563312B2 (en) 2017-07-11 2020-02-18 University Of South Florida Photoelectrochemical cells
CN107829108B (en) * 2017-09-30 2020-04-28 华南理工大学 A FeOOH/CdS/Ti:Fe2O3 composite photoelectrode and its preparation method
WO2019160701A1 (en) * 2018-02-14 2019-08-22 The Board Of Trustees Of The Leland Stanford Junior University Highly sustained electrodes and electrolytes for salty alkaline and neutral water splitting
KR102085583B1 (en) * 2018-06-28 2020-03-06 울산과학기술원 Highly efficient photoelectrochemical cell, its manufacturing method and water splitting method
KR102166118B1 (en) 2018-08-31 2020-10-15 광주과학기술원 Manufacturing method for phtoelectro chemical cell photoanode with dispersed plasmon metal nano particles and the phtoelectro chemical cell photonaode
KR102180882B1 (en) 2018-09-12 2020-11-20 주식회사 보야스에너지 Synthesis method of water electrolysis catalyst using ultrasonic spray pyrolysis
KR102123988B1 (en) * 2018-10-04 2020-06-17 울산과학기술원 Solar-seawater battery system and unbiased spontaneous photo-charging method
CN113614287B (en) * 2018-12-18 2024-09-13 十二益公司 Electrolysis device and method of use
US11603598B2 (en) * 2019-03-14 2023-03-14 The Regents Of The University Of California Back-illuminated photoelectrochemical cell
CN110224033B (en) * 2019-06-17 2020-12-08 苏州大学 A kind of iron oxide photoanode system with embedded silicon pn junction and preparation method
CN110424022B (en) * 2019-06-26 2021-05-18 武汉科技大学 Nanorod alpha-iron oxide composite MIL-101 heterojunction photo-anode and preparation method thereof
CN110357223B (en) * 2019-08-06 2021-07-20 郑州航空工业管理学院 A kind of zinc-bismuth synergistically modified cerium oxide composite electrode and its preparation method and application
JP2022543662A (en) * 2019-08-08 2022-10-13 ナンオプテック コーポレイション Radiation-assisted electrolyzer cells and panels
CN110479328B (en) * 2019-08-16 2022-06-21 安徽师范大学 Fe-doped cobalt hydroxyphosphite nanosheet array structure material and preparation method and application thereof
KR20210040515A (en) * 2019-10-04 2021-04-14 성균관대학교산학협력단 Hydrogen evolution apparatus
KR102441295B1 (en) * 2020-02-19 2022-09-06 성균관대학교산학협력단 Hydrogen evolution apparatus
US11618955B2 (en) 2019-10-04 2023-04-04 Research & Business Foundation Sungkyunkwan University Hydrogen evolution apparatus
CN110904468B (en) * 2019-12-05 2021-07-13 河北大学 A kind of cerium-doped tungsten phosphide submicron ball composite material and its preparation method and application
CN111575736B (en) * 2020-05-09 2021-04-27 武汉科技大学 A kind of preparation method of TiO2/Au/CoPi composite nanotube array photoanode
US20210404072A1 (en) * 2020-06-24 2021-12-30 Jonathan Jan Hydrogen separation system and method therefor
AU2021344346A1 (en) * 2020-09-15 2023-04-27 The Regents Of The University Of Michigan Nanostructure-based atomic scale electrochemical reaction catalysis
US20230378572A1 (en) * 2020-10-08 2023-11-23 The Regents Of The University Of California Photo rechargeable electrochemical energy storage device
KR20220077874A (en) 2020-11-30 2022-06-09 주식회사 보야스에너지 Synthesis method of IrRuOx/ATO catalyst for proton exchange membrane water electrolysis
US20220250919A1 (en) * 2021-02-09 2022-08-11 Ionobell, Inc. Silicon material and method of manufacture
EP4301900A1 (en) * 2021-03-01 2024-01-10 Verdagy, Inc. Systems and methods to make hydrogen gas
CN113198481B (en) * 2021-05-06 2023-08-22 淮阴师范学院 A kind of preparation method of perovskite photocatalyst
US11591478B2 (en) 2021-05-25 2023-02-28 Ionobell, Inc. Silicon material and method of manufacture
KR102625069B1 (en) * 2021-07-30 2024-01-16 한국과학기술연구원 A high-efficiency photoelectrochemical electrode as a hydrogen generator composed of metal oxide-transition metal dichalcogenide bond based on 3D carbon fabric and its manufacturing method
KR20230018567A (en) * 2021-07-30 2023-02-07 한국과학기술연구원 Photoelectrochemical electrode as a hydrogen generator composed of a molybdenum disulfide based on 3D carbon fabric and its manufacturing method
WO2023056292A2 (en) 2021-09-28 2023-04-06 Verdagy, Inc. Systems and methods to make hydrogen gas with a steady-state ph differential
US11799075B2 (en) 2021-10-12 2023-10-24 Ionobell, Inc. Silicon battery and method for assembly
KR20230062374A (en) 2021-10-28 2023-05-09 주식회사 보야스에너지 Synthesis method of high-efficiency IrRuOx/ATO catalyst for water electrolysis
WO2023114211A2 (en) 2021-12-13 2023-06-22 Ionobell, Inc. Porous silicon material and method of manufacture
CN114457358B (en) * 2022-01-18 2023-04-25 安徽大学 A kind of Bi/TiO2 series electrocatalytic material and its preparation method and application
CN114853103B (en) * 2022-04-19 2023-10-31 南京理工大学 Locally heated salt solution water separation device based on homogeneous ion rejection
TWI818610B (en) * 2022-06-30 2023-10-11 國立中興大學 Photoelectrochemical device
WO2024010903A1 (en) 2022-07-08 2024-01-11 Ionobell, Inc. Electrode slurry and method of manufacture
WO2024049798A2 (en) * 2022-08-30 2024-03-07 Massachusetts Institute Of Technology Photoelectrochemical capture of acid gases
CN115505957B (en) * 2022-09-27 2024-06-21 四川轻化工大学 A nickel-nitrogen doped carbon material for electrocatalytic synthesis of hydrogen peroxide and a preparation method thereof
KR102602035B1 (en) * 2023-06-09 2023-11-14 한국에너지공과대학교 Non-aqueous solar power electrochemical cell using ammonia oxidation and hydrogen generation system containing the same

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4215182A (en) * 1979-05-29 1980-07-29 Institute Of Gas Technology Conversion of solar energy to chemical and electrical energy
GB2081307A (en) * 1980-07-08 1982-02-17 Engelhard Min & Chem Use of electrocatalytic anodes in photolysis
US4461691A (en) * 1983-02-10 1984-07-24 The United States Of America As Represented By The United States Department Of Energy Organic conductive films for semiconductor electrodes
JP2000325796A (en) * 1999-05-24 2000-11-28 Japan Organo Co Ltd Photocatalyst carrier and method for producing the same
AU2001238001A1 (en) * 2000-01-31 2001-08-07 Roe, A. Nicholas Photo-assisted electrolysis
US6887728B2 (en) * 2002-08-26 2005-05-03 University Of Hawaii Hybrid solid state/electrochemical photoelectrode for hydrogen production
US20050064289A1 (en) * 2003-07-03 2005-03-24 Tdk Corporation Electrode, electrochemical device, method for manufacturing electrode, and method for manufacturing electrochemical device
JP3995051B2 (en) * 2003-12-26 2007-10-24 関西ティー・エル・オー株式会社 Water electrolysis using organic photocatalyst
US7241950B2 (en) * 2004-03-03 2007-07-10 Gas Technology Institute Solar cell electrolysis of water to make hydrogen and oxygen
WO2007092570A2 (en) * 2006-02-07 2007-08-16 Battelle Memorial Institute Breathing air maintenance and recycle
US7481914B2 (en) * 2006-03-31 2009-01-27 General Electric Company Photoelectrolysis cells, and related devices and processes

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2579782C1 (en) * 2014-11-28 2016-04-10 Федеральное государственное бюджетное образовательное учреждение высшего образования "Юго-Западный государственный университет" (ЮЗГУ) Photoelectrochemical cell

Also Published As

Publication number Publication date
AU2009302811A1 (en) 2010-04-15
MX2011003719A (en) 2011-07-29
EP2350347A1 (en) 2011-08-03
JP2012505310A (en) 2012-03-01
BRPI0920386A2 (en) 2016-03-22
WO2010042196A1 (en) 2010-04-15
IL212188A0 (en) 2011-06-30
US20100133111A1 (en) 2010-06-03
KR20110084225A (en) 2011-07-21
CN102224279A (en) 2011-10-19

Similar Documents

Publication Publication Date Title
RU2011118354A (en) CATALYTIC MATERIALS, PHOTOANODES AND PHOTOELECTRIC CELLS FOR ELECTROLYSIS OF WATER AND OTHER ELECTROCHEMICAL TECHNOLOGIES
Fischer Photoelectrode, photovoltaic and photosynthetic microbial fuel cells
Poli et al. Graphite-protected CsPbBr3 perovskite photoanodes functionalised with water oxidation catalyst for oxygen evolution in water
Chen et al. Silicon decorated with amorphous cobalt molybdenum sulfide catalyst as an efficient photocathode for solar hydrogen generation
CN101629300B (en) Method for separating and preparing hydrogen by decomposing water in fuel cell through photocatalysis
Jin et al. An experimental and modeling/simulation-based evaluation of the efficiency and operational performance characteristics of an integrated, membrane-free, neutral pH solar-driven water-splitting system
CN102421942B (en) photoelectrochemical unit
KR100806168B1 (en) Photocatalytic Water Decomposition Hydrogen Energy Manufacturing Method Using Electromotive Force of Solar Cell
CN102329006B (en) Microbial photoelectrochemical system capable of simultaneously generating electricity and hydrogen and treating sewage
CN102284293B (en) Cu/Cu2O film material for reducing CO2 into organic fuel under catalysis
Baniasadi et al. Measured effects of light intensity and catalyst concentration on photocatalytic hydrogen and oxygen production with zinc sulfide suspensions
CN104498991B (en) A kind of NiO/CdSe/MoS2Lamellar composite type photocathode and preparation method thereof
JP6525816B2 (en) Process for oxidizing water, cell for oxidizing water, water oxidation catalyst, and electrode for electrochemical water oxidation
CN102534645A (en) Method for producing hydrogen by water electrolysis assisted with photocatalysis
Liang et al. Hydrogen generation promoted by photocatalytic oxidation of ascorbate and glucose at a cadmium sulfide electrode
CN107541747A (en) A kind of energy storage device integrating optical electro-chemical water decomposes the design method of battery
CN104630816A (en) Hydrogen production device and technology via photoelectric degradation of organic pollutant based on solar energy and sea water cell collaborative drive
DE102012003597A1 (en) Photovoltaic hybrid electrolysis cell
Andrade et al. Transient phenomenological modeling of photoelectrochemical cells for water splitting–Application to undoped hematite electrodes
KR102366774B1 (en) Photoelectrode for photoelectrochemical water treatment, manufacturing method of the same, and use of the same
Song et al. Efficient solar-driven water splitting performance of S-doped NiFe-LDH based electrolyzer directly coupled with Si photovoltaic cell
Lee et al. Reverse electrodialysis-assisted solar water splitting
Zou et al. Novel bio-solar hybrid photoelectrochemical synthesis for selective hydrogen peroxide production
Casallas et al. Experimental investigation and analysis of a novel photo-electrochemical hydrogen production cell with polymeric membrane photocathode
Yi et al. A two-step approach towards solar-driven water splitting

Legal Events

Date Code Title Description
FA93 Acknowledgement of application withdrawn (no request for examination)

Effective date: 20121009