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RU2011106608A - METHOD FOR DISPOSAL OF WASTE WITH PRODUCTION OF FIRE-RESISTANT BUILDING MATERIAL AND COMPOSITION FOR PRODUCTION OF FIRE-RESISTANT BUILDING MATERIAL - Google Patents

METHOD FOR DISPOSAL OF WASTE WITH PRODUCTION OF FIRE-RESISTANT BUILDING MATERIAL AND COMPOSITION FOR PRODUCTION OF FIRE-RESISTANT BUILDING MATERIAL Download PDF

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RU2011106608A
RU2011106608A RU2011106608/03A RU2011106608A RU2011106608A RU 2011106608 A RU2011106608 A RU 2011106608A RU 2011106608/03 A RU2011106608/03 A RU 2011106608/03A RU 2011106608 A RU2011106608 A RU 2011106608A RU 2011106608 A RU2011106608 A RU 2011106608A
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waste
fire
building material
resistant building
modifier
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RU2011106608/03A
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Russian (ru)
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RU2469976C2 (en
Inventor
Елена Валентиновна Зелинская (RU)
Елена Валентиновна Зелинская
Федор Анатольевич Шутов (RU)
Федор Анатольевич Шутов
Наталья Анатольевна Толмачева (RU)
Наталья Анатольевна Толмачева
Екатерина Олеговна Сутурина (RU)
Екатерина Олеговна Сутурина
Вячеслав Валерьевич Барахтенко (RU)
Вячеслав Валерьевич Барахтенко
Александр Евгеньевич Бурдонов (RU)
Александр Евгеньевич Бурдонов
Сергей Александрович Пронин (RU)
Сергей Александрович Пронин
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Государственное образовательное учреждение высшего профессионального образования "Иркутский государственный технический университе
Государственное образовательное учреждение высшего профессионального образования "Иркутский государственный технический университет" (ГОУ ИрГТУ)
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Priority to RU2011106608/03A priority Critical patent/RU2469976C2/en
Priority to PCT/RU2012/000116 priority patent/WO2012115537A1/en
Publication of RU2011106608A publication Critical patent/RU2011106608A/en
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Publication of RU2469976C2 publication Critical patent/RU2469976C2/en

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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02—Macromolecular compounds
    • C04B26/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing halogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/0026—Recovery of plastics or other constituents of waste material containing plastics by agglomeration or compacting
    • B29B17/0042—Recovery of plastics or other constituents of waste material containing plastics by agglomeration or compacting for shaping parts, e.g. multilayered parts with at least one layer containing regenerated plastic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/022—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/92—Measuring, controlling or regulating
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/006—Waste materials as binder
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J11/00—Recovery or working-up of waste materials
    • C08J11/04—Recovery or working-up of waste materials of polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92504—Controlled parameter
    • B29C2948/92514—Pressure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92504—Controlled parameter
    • B29C2948/92704—Temperature
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92819—Location or phase of control
    • B29C2948/92857—Extrusion unit
    • B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2027/00—Use of polyvinylhalogenides or derivatives thereof as moulding material
    • B29K2027/06—PVC, i.e. polyvinylchloride
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00034—Physico-chemical characteristics of the mixtures
    • C04B2111/00129—Extrudable mixtures
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20—Resistance against chemical, physical or biological attack
    • C04B2111/28—Fire resistance, i.e. materials resistant to accidental fires or high temperatures
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2327/06—Homopolymers or copolymers of vinyl chloride
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock
    • Y02P20/143—Feedstock the feedstock being recycled material, e.g. plastics
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/62—Plastics recycling; Rubber recycling
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/91—Use of waste materials as fillers for mortars or concrete

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Health & Medical Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

1. Способ утилизации отходов с получением огнестойкого строительного материала, включающий подготовку композиции для получения огнестойкого строительного материала на основе отходов и модифицирующих добавок путем смешения ингредиентов, экструзию и охлаждение, отличающийся тем, что в качестве отходов используют промышленные отходы поливинилхлорида ПВХ и золу уноса от сжигания угля на теплоэлектростанциях, в качестве модифицирующих добавок используют термосветостабилизатор, модификатор текучести, смазку, модификатор ударопрочности, подготовку композиции для получения огнестойкого строительного материала осуществляют в турбосмесителе в две стадии: сначала проводят смешение промышленных отходов поливинилхлорида ПВХ и модифицирующих добавок, а затем вводят золу уноса от сжигания угля на теплоэлектростанциях и перемешивают до получения однородной массы; при этом экструзию проводят при температуре 175-195°С и давлении 15-25 МПа. ! 2. Способ по п.1, отличающийся тем, что в качестве термостабилизатора используют AKSTAB. ! 3. Способ по п.1, отличающийся тем, что в качестве модификатора текучести используют AKDENIZ. ! 4. Способ по п.1, отличающийся тем, что в качестве смазки используют стеариновую кислоту. ! 5. Способ по п.1, отличающийся тем, что в качестве модификатора ударопрочности используют Tyrin. ! 6. Композиция для получения огнестойкого строительного материала на основе отходов и модифицирующих добавок, отличающаяся тем, что в качестве отходов используют промышленные отходы поливинилхлорида ПВХ и золу уноса от сжигания угля на теплоэлектростанциях, а в качестве модифицирующих добавок используют термосветостабилизат 1. The method of waste disposal to obtain a fire-resistant building material, including the preparation of a composition for producing a fire-resistant building material based on waste and modifying additives by mixing the ingredients, extrusion and cooling, characterized in that industrial waste PVC and fly ash are used as waste coal at thermal power plants, as modifying additives use a heat and light stabilizer, a fluidity modifier, a lubricant, an impact modifier the preparation of the composition for the production of fire-resistant building material is carried out in a turbo mixer in two stages: first, industrial wastes of PVC polyvinyl chloride and modifying additives are mixed, and then fly ash from coal burning at thermal power plants is introduced and mixed until a homogeneous mass is obtained; while extrusion is carried out at a temperature of 175-195 ° C and a pressure of 15-25 MPa. ! 2. The method according to claim 1, characterized in that AKSTAB is used as thermostabilizer. ! 3. The method according to claim 1, characterized in that AKDENIZ is used as a flow modifier. ! 4. The method according to claim 1, characterized in that stearic acid is used as a lubricant. ! 5. The method according to claim 1, characterized in that Tyrin is used as an impact resistance modifier. ! 6. Composition for producing fire-resistant building material based on waste and modifying additives, characterized in that industrial waste polyvinyl chloride PVC and fly ash from coal combustion at thermal power plants are used as waste, and heat and light stabilization is used as modifying additives

Claims (6)

1. Способ утилизации отходов с получением огнестойкого строительного материала, включающий подготовку композиции для получения огнестойкого строительного материала на основе отходов и модифицирующих добавок путем смешения ингредиентов, экструзию и охлаждение, отличающийся тем, что в качестве отходов используют промышленные отходы поливинилхлорида ПВХ и золу уноса от сжигания угля на теплоэлектростанциях, в качестве модифицирующих добавок используют термосветостабилизатор, модификатор текучести, смазку, модификатор ударопрочности, подготовку композиции для получения огнестойкого строительного материала осуществляют в турбосмесителе в две стадии: сначала проводят смешение промышленных отходов поливинилхлорида ПВХ и модифицирующих добавок, а затем вводят золу уноса от сжигания угля на теплоэлектростанциях и перемешивают до получения однородной массы; при этом экструзию проводят при температуре 175-195°С и давлении 15-25 МПа.1. The method of waste disposal to obtain a fire-resistant building material, including the preparation of a composition for producing a fire-resistant building material based on waste and modifying additives by mixing the ingredients, extrusion and cooling, characterized in that industrial waste PVC and fly ash are used as waste coal at thermal power plants, as modifying additives use a heat and light stabilizer, a fluidity modifier, a lubricant, an impact modifier the preparation of the composition for the production of fire-resistant building material is carried out in a turbo mixer in two stages: first, industrial wastes of PVC polyvinyl chloride and modifying additives are mixed, and then fly ash from coal burning at thermal power plants is introduced and mixed until a homogeneous mass is obtained; while extrusion is carried out at a temperature of 175-195 ° C and a pressure of 15-25 MPa. 2. Способ по п.1, отличающийся тем, что в качестве термостабилизатора используют AKSTAB.2. The method according to claim 1, characterized in that AKSTAB is used as thermostabilizer. 3. Способ по п.1, отличающийся тем, что в качестве модификатора текучести используют AKDENIZ.3. The method according to claim 1, characterized in that AKDENIZ is used as a flow modifier. 4. Способ по п.1, отличающийся тем, что в качестве смазки используют стеариновую кислоту.4. The method according to claim 1, characterized in that stearic acid is used as a lubricant. 5. Способ по п.1, отличающийся тем, что в качестве модификатора ударопрочности используют Tyrin.5. The method according to claim 1, characterized in that Tyrin is used as an impact resistance modifier. 6. Композиция для получения огнестойкого строительного материала на основе отходов и модифицирующих добавок, отличающаяся тем, что в качестве отходов используют промышленные отходы поливинилхлорида ПВХ и золу уноса от сжигания угля на теплоэлектростанциях, а в качестве модифицирующих добавок используют термосветостабилизатор AKSTAB, модификатор текучести AKDENIZ, смазку - стеариновую кислоту, модификатор ударопрочности Tyrin при следующем соотношении ингредиентов, мас.ч.:6. Composition for the production of fire-resistant building material based on waste and modifying additives, characterized in that industrial waste polyvinyl chloride PVC and fly ash from coal combustion at thermal power plants are used as waste, and AKSTAB thermal light stabilizer, AKDENIZ fluidity modifier, lubricant are used as modifying additives - stearic acid, impact modifier Tyrin in the following ratio of ingredients, parts by weight: промышленные отходы поливинилхлорида ПВХPVC industrial waste 100,0100.0 термосветостабилизатор AKSTABthermal light stabilizer AKSTAB 3,0-7,03.0-7.0 модификатор текучести AKDENIZflow modifier AKDENIZ 2,5-12,02.5-12.0 смазка - стеариновая кислотаlubricant - stearic acid 0,1-0,50.1-0.5 модификатор ударопрочности Tyrinimpact modifier Tyrin 1,0-3,01.0-3.0 зола уноса от сжигания угля на теплоэлектростанцияхfly ash from coal combustion at thermal power plants 50,0-170,050.0-170.0
RU2011106608/03A 2011-02-22 2011-02-22 Method to recycle wastes with production of fire-resistant construction material and composition for production of fire-resistant construction material RU2469976C2 (en)

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RU2011106608/03A RU2469976C2 (en) 2011-02-22 2011-02-22 Method to recycle wastes with production of fire-resistant construction material and composition for production of fire-resistant construction material
PCT/RU2012/000116 WO2012115537A1 (en) 2011-02-22 2012-02-20 Method for waste recycling to afford a fireproof constructive material

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RU2469976C2 RU2469976C2 (en) 2012-12-20

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WO2017150961A1 (en) * 2016-03-04 2017-09-08 Moncada Uribe Jorge Frame made from recycled materials, for the production of furniture
RU2679017C1 (en) * 2017-11-20 2019-02-05 Федеральное государственное бюджетное образовательное учреждение высшего образования "Владимирский Государственный Университет имени Александра Григорьевича и Николая Григорьевича Столетовых" (ВлГУ) Method of processing polymer wastes and glass breakage with obtaining facing and finishing materials
RU2705120C1 (en) * 2019-06-10 2019-11-05 Федеральное государственное бюджетное образовательное учреждение высшего образования "Санкт-Петербургский государственный лесотехнический университет имени С.М. Кирова" Method of producing construction material from a mixture of milled domestic polyethylene and ash from burning waste water sludge
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