RU2011103674A - Способ эксплуатации реактора для высокотемпературной конверсии - Google Patents
Способ эксплуатации реактора для высокотемпературной конверсии Download PDFInfo
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- RU2011103674A RU2011103674A RU2011103674/05A RU2011103674A RU2011103674A RU 2011103674 A RU2011103674 A RU 2011103674A RU 2011103674/05 A RU2011103674/05 A RU 2011103674/05A RU 2011103674 A RU2011103674 A RU 2011103674A RU 2011103674 A RU2011103674 A RU 2011103674A
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- Prior art keywords
- catalyst
- synthesis gas
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- zinc
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- 238000006243 chemical reaction Methods 0.000 title claims abstract 7
- 238000000034 method Methods 0.000 title claims abstract 7
- 230000015572 biosynthetic process Effects 0.000 claims abstract 12
- 239000003054 catalyst Substances 0.000 claims abstract 12
- 239000007789 gas Substances 0.000 claims abstract 10
- 238000003786 synthesis reaction Methods 0.000 claims abstract 10
- 239000000203 mixture Substances 0.000 claims abstract 9
- 229910052792 caesium Inorganic materials 0.000 claims abstract 7
- 229910052700 potassium Inorganic materials 0.000 claims abstract 7
- 229910052701 rubidium Inorganic materials 0.000 claims abstract 7
- 229910052708 sodium Inorganic materials 0.000 claims abstract 7
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract 6
- 229910002091 carbon monoxide Inorganic materials 0.000 claims abstract 6
- 239000011701 zinc Substances 0.000 claims abstract 6
- 229910052802 copper Inorganic materials 0.000 claims abstract 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical class [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract 4
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract 4
- 150000001340 alkali metals Chemical class 0.000 claims abstract 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract 4
- 229910052799 carbon Inorganic materials 0.000 claims abstract 4
- 239000001257 hydrogen Substances 0.000 claims abstract 4
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract 4
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims abstract 4
- 239000001301 oxygen Substances 0.000 claims abstract 4
- 229910052760 oxygen Inorganic materials 0.000 claims abstract 4
- 229910052725 zinc Inorganic materials 0.000 claims abstract 4
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract 3
- 229910052719 titanium Inorganic materials 0.000 claims abstract 3
- 229910052726 zirconium Inorganic materials 0.000 claims abstract 3
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract 2
- JYMITAMFTJDTAE-UHFFFAOYSA-N aluminum zinc oxygen(2-) Chemical compound [O-2].[Al+3].[Zn+2] JYMITAMFTJDTAE-UHFFFAOYSA-N 0.000 claims abstract 2
- 239000006227 byproduct Substances 0.000 claims abstract 2
- 229930195733 hydrocarbon Natural products 0.000 claims abstract 2
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract 2
- 229910052738 indium Inorganic materials 0.000 claims abstract 2
- 229910052596 spinel Inorganic materials 0.000 claims abstract 2
- 239000011029 spinel Substances 0.000 claims abstract 2
- 239000011787 zinc oxide Substances 0.000 claims abstract 2
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/48—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/005—Spinels
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of zinc, cadmium or mercury
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
- C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0405—Purification by membrane separation
- C01B2203/041—In-situ membrane purification during hydrogen production
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1076—Copper or zinc-based catalysts
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1094—Promotors or activators
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
1. Способ обогащения синтез-газа по водороду, при этом упомянутый выше синтез-газ содержит водород, монооксид углерода, а также пар, путем конверсии монооксида углерода и пара над катализатором, при котором упомянутый выше синтез-газ имеет молярное соотношение кислорода и углерода от 1,69 до 2,25 и при котором упомянутый выше катализатор содержит оксиды цинка и алюминия совместно с одним или более промоторами, а также при котором конверсия монооксида углерода и пара проводится в условиях высокотемпературной конверсии, где синтез-газ имеет температуру от 300°С до 400°С, и давление составляет от 2,3 до 6,5 МПа, а также при котором катализатор содержит в своей активной форме смесь цинк-алюминийоксидной шпинели и оксида цинка в комбинации с промотором в виде щелочного металла, выбранного из группы, состоящей из Na, К, Rb, Cs и их смесей, при этом упомянутый выше катализатор имеет молярное соотношение Zn/Al в пределах от 0,5 до 1,0 и содержание щелочного металла в пределах от 0,4 до 8,0 мас.% в пересчете на массу окисленного катализатора. ! 2. Способ по п.1, при котором упомянутые выше промоторы выбираются из Na, К, Rb, Cs, Cu, Ti, Zr, редкоземельных элементов, а также их смесей. ! 3. Способ по п.2, при котором упомянутые выше промоторы выбираются из Na, К, Rb, Cs, Сu, а также их смесей. ! 4. Применение катализатора, содержащего оксиды цинка и алюминия совместно с одним или более промоторами, при эксплуатации реактора для конверсии при условиях, в которых синтез-газ, поступающий в реактор, имеет молярное соотношение кислорода и углерода от 1,69 до 2,25, для подавления образования углеводородного побочного продукта. ! 5. Применение по п.4, при котором вышеупомянутые промо
Claims (5)
1. Способ обогащения синтез-газа по водороду, при этом упомянутый выше синтез-газ содержит водород, монооксид углерода, а также пар, путем конверсии монооксида углерода и пара над катализатором, при котором упомянутый выше синтез-газ имеет молярное соотношение кислорода и углерода от 1,69 до 2,25 и при котором упомянутый выше катализатор содержит оксиды цинка и алюминия совместно с одним или более промоторами, а также при котором конверсия монооксида углерода и пара проводится в условиях высокотемпературной конверсии, где синтез-газ имеет температуру от 300°С до 400°С, и давление составляет от 2,3 до 6,5 МПа, а также при котором катализатор содержит в своей активной форме смесь цинк-алюминийоксидной шпинели и оксида цинка в комбинации с промотором в виде щелочного металла, выбранного из группы, состоящей из Na, К, Rb, Cs и их смесей, при этом упомянутый выше катализатор имеет молярное соотношение Zn/Al в пределах от 0,5 до 1,0 и содержание щелочного металла в пределах от 0,4 до 8,0 мас.% в пересчете на массу окисленного катализатора.
2. Способ по п.1, при котором упомянутые выше промоторы выбираются из Na, К, Rb, Cs, Cu, Ti, Zr, редкоземельных элементов, а также их смесей.
3. Способ по п.2, при котором упомянутые выше промоторы выбираются из Na, К, Rb, Cs, Сu, а также их смесей.
4. Применение катализатора, содержащего оксиды цинка и алюминия совместно с одним или более промоторами, при эксплуатации реактора для конверсии при условиях, в которых синтез-газ, поступающий в реактор, имеет молярное соотношение кислорода и углерода от 1,69 до 2,25, для подавления образования углеводородного побочного продукта.
5. Применение по п.4, при котором вышеупомянутые промоторы выбираются из Na, К, Rb, Cs, Cu, Ti, Zr, редкоземельных элементов, а также их смесей.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DKPA200800935 | 2008-07-03 | ||
| DKPA200800935 | 2008-07-03 | ||
| PCT/EP2009/004288 WO2010000387A1 (en) | 2008-07-03 | 2009-06-15 | Process for operating hts reactor |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2011103674A true RU2011103674A (ru) | 2012-08-10 |
| RU2516546C2 RU2516546C2 (ru) | 2014-05-20 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2011103674/05A RU2516546C2 (ru) | 2008-07-03 | 2009-06-15 | Способ эксплуатации реактора для высокотемпературной конверсии |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US8404156B2 (ru) |
| EP (2) | EP2924002B1 (ru) |
| KR (1) | KR101529906B1 (ru) |
| CN (1) | CN102083745B (ru) |
| BR (1) | BRPI0915369B8 (ru) |
| CA (1) | CA2729736C (ru) |
| ES (2) | ES2728916T3 (ru) |
| MX (1) | MX2010014351A (ru) |
| PL (2) | PL2300359T3 (ru) |
| RU (1) | RU2516546C2 (ru) |
| WO (1) | WO2010000387A1 (ru) |
| ZA (1) | ZA201009233B (ru) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL2008313C2 (en) | 2012-02-17 | 2013-09-02 | Stichting Energie | Water gas shift process. |
| GB201501952D0 (en) * | 2015-02-05 | 2015-03-25 | Johnson Matthey Plc | Process |
| GB201519139D0 (en) | 2015-10-29 | 2015-12-16 | Johnson Matthey Plc | Process |
| UA123999C2 (uk) | 2015-10-29 | 2021-07-07 | Джонсон Метті Паблік Лімітед Компані | Каталізатор конверсії водяного газу |
| GB201519133D0 (en) | 2015-10-29 | 2015-12-16 | Johnson Matthey Plc | Process |
| MY191228A (en) * | 2016-02-02 | 2022-06-09 | Haldor Tops?E As | Atr based ammonia process and plant |
| GB201603298D0 (en) * | 2016-02-25 | 2016-04-13 | Johnson Matthey Plc | Process |
| AR107702A1 (es) * | 2016-02-29 | 2018-05-23 | Haldor Topsoe As | Renovación con baja cantidad de vapor / carbono |
| EA201992025A1 (ru) * | 2017-03-07 | 2020-03-06 | Хальдор Топсёэ А/С | Способ получения мочевины с контролируемым избытком coи/или nh |
| KR102772890B1 (ko) * | 2017-07-13 | 2025-02-27 | 토프쉐 에이/에스 | 암모니아 합성 가스의 제조를 위한 방법 및 촉매 |
| CN108435182B (zh) * | 2017-08-16 | 2021-01-15 | 西安向阳航天材料股份有限公司 | 一种铜系低温变换催化剂的制备方法 |
| PL235786B1 (pl) * | 2017-09-29 | 2020-10-19 | Grupa Azoty Spolka Akcyjna | Promotowany katalizator cynkowy parowej konwersji tlenku węgla i sposób jego otrzymywania |
| PL234182B1 (pl) * | 2017-09-29 | 2020-01-31 | Inst Nowych Syntez Chemicznych | Promotowany katalizator cynkowy parowej konwersji tlenku węgla i sposób jego otrzymywania |
| DK181937B1 (en) | 2020-10-08 | 2025-04-04 | Petroleo Brasileiro Sa Petrobras | Methods for preparing high temperature water gas shifting catalyst, catalyst and process for reducing carbon monoxide |
| EP4251561A1 (en) | 2020-11-24 | 2023-10-04 | Topsoe A/S | Improved water gas shift catalyst |
| WO2022112311A1 (en) | 2020-11-24 | 2022-06-02 | Topsoe A/S | Process for producing hydrogen from co-rich gases |
| EP4251560B1 (en) | 2020-11-24 | 2024-11-06 | Topsoe A/S | Method of starting-up a water gas shift reactor |
| CN116981513A (zh) * | 2020-12-09 | 2023-10-31 | 巴西石油公司 | 通过高温水煤气变换制备催化剂的方法和降低一氧化碳含量的方法 |
| US20240116756A1 (en) | 2022-10-06 | 2024-04-11 | Air Products And Chemicals, Inc. | Process and System for Water-Gas Shift Conversion of Synthesis Gas with High CO Concentration |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2567866B1 (fr) * | 1984-07-20 | 1987-01-02 | Shell Int Research | Procede de preparation d'un gaz riche en hydrogene |
| GB8817480D0 (en) | 1988-07-22 | 1988-08-24 | Ici Plc | Hydrogen |
| EP0361648B1 (en) * | 1988-07-22 | 1993-04-07 | Imperial Chemical Industries Plc | Hydrogen production including a shift reaction process |
| GB9225372D0 (en) * | 1992-12-04 | 1993-01-27 | British Petroleum Co Plc | Oxide compositions |
| ATE251592T1 (de) * | 2000-04-27 | 2003-10-15 | Haldor Topsoe As | Verfahren zur herstellung eines wasserstoffreichen gases |
| GB0121680D0 (en) * | 2001-09-08 | 2001-10-31 | Ici Plc | Catalysts |
| US6627572B1 (en) * | 2002-03-22 | 2003-09-30 | Sud-Chemie Inc. | Water gas shift catalyst |
| US20040105804A1 (en) * | 2002-11-29 | 2004-06-03 | Industrial Technology Research Institute | Catalyst for water-gas shift reaction and method for converting carbon monoxide and water to hydrogen and carbon dioxide |
| ES2381105T3 (es) * | 2003-02-05 | 2012-05-23 | Haldor Topsoe A/S | Procedimiento para el tratamiento de gas de síntesis |
| JP2004321924A (ja) * | 2003-04-24 | 2004-11-18 | Toyota Central Res & Dev Lab Inc | 水性ガスシフト反応用触媒 |
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2009
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- 2009-06-15 BR BRPI0915369A patent/BRPI0915369B8/pt active Search and Examination
- 2009-06-15 CN CN200980125774.4A patent/CN102083745B/zh active Active
- 2009-06-15 EP EP15166788.8A patent/EP2924002B1/en active Active
- 2009-06-15 CA CA2729736A patent/CA2729736C/en active Active
- 2009-06-15 EP EP09772087.4A patent/EP2300359B1/en active Active
- 2009-06-15 KR KR1020107029413A patent/KR101529906B1/ko active Active
- 2009-06-15 PL PL09772087T patent/PL2300359T3/pl unknown
- 2009-06-15 WO PCT/EP2009/004288 patent/WO2010000387A1/en not_active Ceased
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- 2009-06-15 RU RU2011103674/05A patent/RU2516546C2/ru active
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Also Published As
| Publication number | Publication date |
|---|---|
| US20110101279A1 (en) | 2011-05-05 |
| CN102083745B (zh) | 2014-04-02 |
| ES2549382T3 (es) | 2015-10-27 |
| KR101529906B1 (ko) | 2015-06-18 |
| US8404156B2 (en) | 2013-03-26 |
| PL2924002T3 (pl) | 2019-09-30 |
| BRPI0915369B8 (pt) | 2020-02-04 |
| KR20110039422A (ko) | 2011-04-18 |
| MX2010014351A (es) | 2011-05-03 |
| CA2729736A1 (en) | 2010-01-07 |
| ZA201009233B (en) | 2012-04-25 |
| BRPI0915369A2 (pt) | 2015-11-03 |
| EP2300359A1 (en) | 2011-03-30 |
| EP2300359B1 (en) | 2015-08-26 |
| EP2924002B1 (en) | 2019-04-24 |
| BRPI0915369B1 (pt) | 2019-09-24 |
| EP2924002A1 (en) | 2015-09-30 |
| WO2010000387A1 (en) | 2010-01-07 |
| CN102083745A (zh) | 2011-06-01 |
| CA2729736C (en) | 2015-09-15 |
| PL2300359T3 (pl) | 2016-01-29 |
| ES2728916T3 (es) | 2019-10-29 |
| AU2009266113A1 (en) | 2010-01-07 |
| RU2516546C2 (ru) | 2014-05-20 |
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