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RU2010125110A - Низкоэмиссионное покрытие с низким коэффициентом солнечного теплопритока и улучшенными химическими и механическими характеристиками и способ его изготовления - Google Patents

Низкоэмиссионное покрытие с низким коэффициентом солнечного теплопритока и улучшенными химическими и механическими характеристиками и способ его изготовления Download PDF

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RU2010125110A
RU2010125110A RU2010125110/03A RU2010125110A RU2010125110A RU 2010125110 A RU2010125110 A RU 2010125110A RU 2010125110/03 A RU2010125110/03 A RU 2010125110/03A RU 2010125110 A RU2010125110 A RU 2010125110A RU 2010125110 A RU2010125110 A RU 2010125110A
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layer
protective layer
emission coating
dielectric layer
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RU2492150C2 (ru
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Питер МАШВИТЦ (US)
Питер Машвитц
Кит ГРАББ (US)
Кит ГРАББ
Доминик КОСТЕР (BE)
Доминик Костер
Даньель ДЕКРУПЕ (BE)
Даньель ДЕКРУПЕ
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Эй-Джи-Си Флет Гласс Норт Эмерике, Инк. (Us)
Эй-Джи-Си Флет Гласс Норт Эмерике, Инк.
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    • C—CHEMISTRY; METALLURGY
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    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
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    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
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    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
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    • B32B17/10036—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
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    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
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    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
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    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
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    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
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    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
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    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3652—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the coating stack containing at least one sacrificial layer to protect the metal from oxidation
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    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3657—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having optical properties
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    • C03C2218/00—Methods for coating glass
    • C03C2218/10—Deposition methods
    • C03C2218/15—Deposition methods from the vapour phase
    • C03C2218/154—Deposition methods from the vapour phase by sputtering
    • C03C2218/156—Deposition methods from the vapour phase by sputtering by magnetron sputtering
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    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12535—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
    • Y10T428/12542—More than one such component
    • Y10T428/12549—Adjacent to each other
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    • Y10T428/12576—Boride, carbide or nitride component
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Abstract

1. Низкоэмиссионное покрытие на подложке, включающее, в порядке от подложки наружу: ! первый диэлектрический слой, ! первый затравочный слой, ! первый слой серебра, ! первый защитный слой, ! второй диэлектрический слой, ! второй затравочный слой, ! второй слой серебра, ! второй защитный слой, ! третий диэлектрический слой, и ! при необходимости, верхний слой покрытия. ! 2. Низкоэмиссионное покрытие по п.1, в котором по меньшей мере один из первого диэлектрического слоя, второго диэлектрического слоя или третьего диэлектрического слоя имеет субстехиометрический состав. ! 3. Низкоэмиссионное покрытие по п.1, в котором по меньшей мере один из первого защитного слоя или второго защитного слоя является поглощающим защитным слоем. ! 4. Низкоэмиссионное покрытие по п.1, в котором первый защитный слой и второй защитный слой каждый по отдельности содержат материал, выбранный из группы, состоящей из металла, сплава, силицида, поглощающего оксида и нитрида. !5. Низкоэмиссионное покрытие по п.4, в котором первый защитный слой и второй защитный слой каждый по отдельности содержат материал, выбранный из группы, состоящей из Ti, TiN, Si, NiCr, NiCrOx, Cr, Zr, Mo, W и ZrSi. ! 6. Низкоэмиссионное покрытие по п.5, в котором по меньшей мере один из первого защитного слоя и второго защитного слоя содержит NiCr. ! 7. Низкоэмиссионное покрытие по п.5, в котором по меньшей мере один из первого защитного слоя и второго защитного слоя содержит NiCrOx. ! 8. Низкоэмиссионное покрытие по п.1, в котором по меньшей мере один из первого или второго защитного слоев способен уменьшить пропускание покрытия. ! 9. Низкоэмиссионное покрытие по п.1, в котором по меньшей мере один из первого ил

Claims (38)

1. Низкоэмиссионное покрытие на подложке, включающее, в порядке от подложки наружу:
первый диэлектрический слой,
первый затравочный слой,
первый слой серебра,
первый защитный слой,
второй диэлектрический слой,
второй затравочный слой,
второй слой серебра,
второй защитный слой,
третий диэлектрический слой, и
при необходимости, верхний слой покрытия.
2. Низкоэмиссионное покрытие по п.1, в котором по меньшей мере один из первого диэлектрического слоя, второго диэлектрического слоя или третьего диэлектрического слоя имеет субстехиометрический состав.
3. Низкоэмиссионное покрытие по п.1, в котором по меньшей мере один из первого защитного слоя или второго защитного слоя является поглощающим защитным слоем.
4. Низкоэмиссионное покрытие по п.1, в котором первый защитный слой и второй защитный слой каждый по отдельности содержат материал, выбранный из группы, состоящей из металла, сплава, силицида, поглощающего оксида и нитрида.
5. Низкоэмиссионное покрытие по п.4, в котором первый защитный слой и второй защитный слой каждый по отдельности содержат материал, выбранный из группы, состоящей из Ti, TiN, Si, NiCr, NiCrOx, Cr, Zr, Mo, W и ZrSi.
6. Низкоэмиссионное покрытие по п.5, в котором по меньшей мере один из первого защитного слоя и второго защитного слоя содержит NiCr.
7. Низкоэмиссионное покрытие по п.5, в котором по меньшей мере один из первого защитного слоя и второго защитного слоя содержит NiCrOx.
8. Низкоэмиссионное покрытие по п.1, в котором по меньшей мере один из первого или второго защитного слоев способен уменьшить пропускание покрытия.
9. Низкоэмиссионное покрытие по п.1, в котором по меньшей мере один из первого или второго защитного слоев способен увеличить поглощение покрытия.
10. Низкоэмиссионное покрытие по п.1, в котором второй слой серебра толще первого слоя серебра.
11. Низкоэмиссионное покрытие по п.1, в котором первый защитный слой толще второго защитного слоя.
12. Низкоэмиссионное покрытие по п.10, в котором отношение толщины первого слоя серебра к толщине второго слоя серебра составляет примерно от 0,8 до 1,2.
13. Низкоэмиссионное покрытие по п.11, в котором отношение толщины первого защитного слоя к толщине второго защитного слоя составляет примерно от 1,2 до 2,0.
14. Низкоэмиссионное покрытие по п.1, в котором первый затравочный слой толще второго затравочного слоя.
15. Низкоэмиссионное покрытие по п.14, в котором отношение толщины первого затравочного слоя к толщине второго затравочного слоя составляет примерно от 1,2 до 2,0.
16. Низкоэмиссионное покрытие по п.1, в котором коэффициент преломления третьего диэлектрического слоя ниже коэффициентов преломления как второго диэлектрического слоя, так и первого диэлектрического слоя.
17. Низкоэмиссионное покрытие по п.7, в котором каждое из упомянутых защитных слоев характеризуется отношением "кислород:кВт", равным 2:1.
18. Низкоэмиссионное покрытие по п.1, в котором каждый из первого диэлектрического слоя, второго диэлектрического слоя и третьего диэлектрического по отдельности содержит материал, выбранный из группы, включающей оксид, нитрид, оксинитрид или их комбинации.
19. Низкоэмиссионное покрытие по п.18, в котором по меньшей мере один из первого диэлектрического слоя, второго диэлектрического слоя и третьего диэлектрического слоя содержит оксид.
20. Низкоэмиссионное покрытие по п.19, в котором оксид содержит до примерно 20 мас.% элемента, выбранного из группы, состоящей из Al и В.
21. Низкоэмиссионное покрытие по п.20, в котором оксид содержит до примерно 10 мас.% элемента, выбранного из группы, состоящей из Al и В.
22. Низкоэмиссионное покрытие по п.15, в котором по меньшей мере один из первого диэлектрического слоя, второго диэлектрического слоя и третьего диэлектрического слоя содержит нитрид или оксинитрид.
23. Низкоэмиссионное покрытие по п.1, в котором по меньшей мере один из затравочных слоев содержит ZnAlOx.
24. Низкоэмиссионное покрытие по п.1, в котором подложка выполнена из стекла.
25. Автомобильное стекло, включающее низкоэмиссионное покрытие по п.1.
26. Способ изготовления низкоэмиссионной многослойной системы, имеющей низкий коэффициент солнечного теплопритока, при осуществлении которого наносят на подложку покрытие по п.1.
27. Способ по п.26, в котором используют магнетронное распыление.
28. Низкоэмиссионное покрытие на подложке, включающее, в порядке от подложки наружу:
первый диэлектрический слой, содержащий SiAlOxNy,
первый затравочный слой, содержащий ZnAlOx,
первый слой, отражающий инфракрасное излучение, содержащий Ag,
первый поглощающий защитный слой, содержащий NiCr,
второй диэлектрический слой, содержащий SiAlOxNy,
второй затравочный слой, содержащий ZnAlOx,
второй слой, отражающий инфракрасное излучение, содержащий Ag,
второй поглощающий защитный слой, содержащий NiCr,
третий диэлектрический слой, содержащий SiAlOxNy, и
при необходимости, верхний слой покрытия.
29. Низкоэмиссионное покрытие на подложке, включающее, в порядке от подложки наружу:
первый диэлектрический слой, содержащий SiAlOxNy,
первый затравочный слой, содержащий ZnAlOx,
первый слой, отражающий инфракрасное излучение, содержащий Ag,
первый поглощающий защитный слой, содержащий NiCrOx,
второй диэлектрический слой, содержащий SiAlOxNy,
второй затравочный слой, содержащий ZnAlOx,
второй слой, отражающий инфракрасное излучение, содержащий Ag,
второй поглощающий защитный слой, содержащий NiCrOx,
третий диэлектрический слой, содержащий SiAlOxNy, и
при необходимости, верхний слой покрытия.
30. Низкоэмиссионная многослойная система, включающая по меньшей мере один поглощающий защитный слой и характеризующаяся коэффициентом солнечного теплопритока менее примерно 0,31.
31. Низкоэмиссионная многослойная система по п.30, характеризующаяся коэффициентом солнечного теплопритока примерно от 0,22 до 0,25.
32. Низкоэмиссионная многослойная система по п.30, в которой пропускание света, измеренное в стеклопакете, составляет примерно от 42% до 46%.
33. Низкоэмиссионная многослойная система по п.30, в которой пропускание света, измеренное в стеклопакете, составляет примерно от 58% до 62%.
34. Низкоэмиссионная многослойная система по п.30, характеризующаяся улучшенной механической или химической стойкостью.
35. Низкоэмиссионная многослойная система по п.30, характеризующаяся устойчивостью к закалке или термическому упрочнению.
36. Низкоэмиссионная многослойная система по п.35, у которой оптические свойства не ухудшаются после закалки или термического упрочнения.
37. Низкоэмиссионная многослойная система по п.30, цветовое пропускание которой характеризуется отрицательным а* и отрицательным b*.
38. Низкоэмиссионная многослойная система по п.30, цветовое пропускание которой характеризуется отрицательным а* и положительным b*.
RU2010125110/03A 2007-11-23 2008-11-21 Низкоэмиссионное покрытие с низким коэффициентом солнечного теплопритока и улучшенными химическими и механическими характеристиками и способ его изготовления RU2492150C2 (ru)

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AU2008326700A1 (en) 2009-05-28
MX2010005639A (es) 2010-09-09
NZ586362A (en) 2012-10-26
US7901781B2 (en) 2011-03-08
AU2008326700B2 (en) 2013-05-02
CA2706395A1 (en) 2009-05-28
CN101925552B (zh) 2013-10-30
EP2231540A1 (en) 2010-09-29
CN101925552A (zh) 2010-12-22
CA2706395C (en) 2016-03-15
US20110135955A1 (en) 2011-06-09
JP2011504450A (ja) 2011-02-10
JP2015221747A (ja) 2015-12-10
KR20100097175A (ko) 2010-09-02
RU2492150C2 (ru) 2013-09-10
US9067822B2 (en) 2015-06-30
US20090136765A1 (en) 2009-05-28
BRPI0819822A2 (pt) 2015-05-26
EP2231540B1 (en) 2023-11-01
MY169599A (en) 2019-04-22
BRPI0819822B1 (pt) 2019-11-05
WO2009067263A1 (en) 2009-05-28
HK1152289A1 (en) 2012-02-24

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