RU2009132002A - METAL COMPOSITIONS - Google Patents
METAL COMPOSITIONS Download PDFInfo
- Publication number
- RU2009132002A RU2009132002A RU2009132002/02A RU2009132002A RU2009132002A RU 2009132002 A RU2009132002 A RU 2009132002A RU 2009132002/02 A RU2009132002/02 A RU 2009132002/02A RU 2009132002 A RU2009132002 A RU 2009132002A RU 2009132002 A RU2009132002 A RU 2009132002A
- Authority
- RU
- Russia
- Prior art keywords
- powder
- binder
- cobalt
- binder metal
- elements
- Prior art date
Links
- 229910052751 metal Inorganic materials 0.000 title claims abstract 37
- 239000002184 metal Substances 0.000 title claims abstract 37
- 239000000203 mixture Substances 0.000 title claims abstract 32
- 239000000843 powder Substances 0.000 claims abstract 56
- 239000011230 binding agent Substances 0.000 claims abstract 38
- 239000010941 cobalt Substances 0.000 claims abstract 21
- 229910017052 cobalt Inorganic materials 0.000 claims abstract 21
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract 21
- 229910052742 iron Inorganic materials 0.000 claims abstract 16
- 239000000463 material Substances 0.000 claims abstract 15
- 229910052759 nickel Inorganic materials 0.000 claims abstract 13
- 239000000956 alloy Substances 0.000 claims abstract 7
- 229910045601 alloy Inorganic materials 0.000 claims abstract 7
- 229910052782 aluminium Inorganic materials 0.000 claims abstract 6
- 230000000737 periodic effect Effects 0.000 claims abstract 6
- 229910052804 chromium Inorganic materials 0.000 claims abstract 5
- 229910052748 manganese Inorganic materials 0.000 claims abstract 5
- 238000005260 corrosion Methods 0.000 claims abstract 3
- 230000007797 corrosion Effects 0.000 claims abstract 3
- 229920006395 saturated elastomer Polymers 0.000 claims abstract 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 27
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 19
- 238000000034 method Methods 0.000 claims 4
- 239000000126 substance Substances 0.000 claims 4
- 231100000331 toxic Toxicity 0.000 claims 3
- 230000002588 toxic effect Effects 0.000 claims 3
- 238000005275 alloying Methods 0.000 claims 2
- INZDTEICWPZYJM-UHFFFAOYSA-N 1-(chloromethyl)-4-[4-(chloromethyl)phenyl]benzene Chemical compound C1=CC(CCl)=CC=C1C1=CC=C(CCl)C=C1 INZDTEICWPZYJM-UHFFFAOYSA-N 0.000 claims 1
- QIJNJJZPYXGIQM-UHFFFAOYSA-N 1lambda4,2lambda4-dimolybdacyclopropa-1,2,3-triene Chemical compound [Mo]=C=[Mo] QIJNJJZPYXGIQM-UHFFFAOYSA-N 0.000 claims 1
- 229910039444 MoC Inorganic materials 0.000 claims 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- 239000011651 chromium Substances 0.000 claims 1
- 238000000576 coating method Methods 0.000 claims 1
- 239000000428 dust Substances 0.000 claims 1
- 239000011572 manganese Substances 0.000 claims 1
- 206010035653 pneumoconiosis Diseases 0.000 claims 1
- 208000005069 pulmonary fibrosis Diseases 0.000 claims 1
- 229910052761 rare earth metal Inorganic materials 0.000 claims 1
- 238000005245 sintering Methods 0.000 claims 1
- 208000011580 syndromic disease Diseases 0.000 claims 1
- 239000010936 titanium Substances 0.000 claims 1
- 229910052719 titanium Inorganic materials 0.000 claims 1
- 230000002110 toxicologic effect Effects 0.000 claims 1
- 231100000759 toxicological effect Toxicity 0.000 claims 1
- MTPVUVINMAGMJL-UHFFFAOYSA-N trimethyl(1,1,2,2,2-pentafluoroethyl)silane Chemical compound C[Si](C)(C)C(F)(F)C(F)(F)F MTPVUVINMAGMJL-UHFFFAOYSA-N 0.000 claims 1
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 claims 1
- 229910052727 yttrium Inorganic materials 0.000 claims 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
- C22C29/02—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
- C22C29/06—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
- C22C29/02—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
- C22C29/06—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds
- C22C29/067—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds comprising a particular metallic binder
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
- C22C29/02—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
- C22C29/06—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds
- C22C29/08—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds based on tungsten carbide
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/06—Metallic material
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/06—Metallic material
- C23C4/067—Metallic material containing free particles of non-metal elements, e.g. carbon, silicon, boron, phosphorus or arsenic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Powder Metallurgy (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
Abstract
1. Композиция, содержащая, по меньшей мере, один порошок высокопрочного материала и, по меньшей мере, 2 порошка связующего металла, отличающаяся тем, что в первом порошке связующего металла содержится кобальт и он предварительно легирован одним или несколькими элементами из группы 3-8 периодической таблицы элементов, которые являются элементами четвертого периода, и содержится, по меньшей мере, один дальнейший порошок связующего металла из группы одноэлементных порошков Fe, Ni, Al, Mn, Cr или их сплавы друг с другом и дальнейшие порошки связующего металла, не содержащие кобальта в предварительно не легированной форме. ! 2. Композиция, содержащая, по меньшей мере, один порошок высокопрочного материала и, по меньшей мере, 2 порошка связующего металла, отличающийся тем, что в первом порошке связующего металла содержится кобальт и он предварительно легирован одним или несколькими элементами из группы 3-8 периодической таблицы элементов, и содержится, по меньшей мере, один дальнейший порошок связующего металла из группы одноэлементных порошков Fe, Ni, Al, Mn, Cr или их сплавы друг с другом и дальнейшие порошки связующего металла, не содержащие кобальта в предварительно не легированной форме, при этом свободный коррозионный потенциал между высокопрочным материалом и первым порошком связующего металла, измеряемый в насыщенной воздухом воде при нормальном давлении и комнатной температуре, составляет менее 0,300 Вольт, причем высокопрочный материал имеет положительную полярность. ! 3. Композиция, содержащая, по меньшей мере, один порошок высокопрочного материала и, по меньшей мере, 2 порошка связующего металла, отличающаяся тем, что � 1. A composition containing at least one powder of high-strength material and at least 2 powders of a binder metal, characterized in that the first powder of a binder metal contains cobalt and it is pre-alloyed with one or more elements from the group 3-8 periodic tables of elements, which are elements of the fourth period, and contains at least one further powder of a binder metal from the group of single-element powders of Fe, Ni, Al, Mn, Cr or their alloys with each other and further powders of a binder metal that do not contain cobalt in pre-doped form. ! 2. A composition containing at least one powder of a high-strength material and at least 2 powders of a binder metal, characterized in that the first powder of a binder metal contains cobalt and is pre-alloyed with one or more elements from group 3-8 of periodic table of elements, and contains at least one further powder of a binder metal from the group of single-element powders of Fe, Ni, Al, Mn, Cr or their alloys with each other and further powders of a binder metal that do not contain cobalt in a pre-alloyed form, when the free corrosion potential between the high-strength material and the first binder metal powder, measured in air-saturated water at normal pressure and room temperature, is less than 0.300 volts, with the high strength material having a positive polarity. ! 3. Composition containing at least one powder of high-strength material and at least 2 powder of a binder metal, characterized in that �
Claims (23)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102007004937.6 | 2007-01-26 | ||
| DE102007004937A DE102007004937B4 (en) | 2007-01-26 | 2007-01-26 | metal formulations |
| PCT/EP2008/050845 WO2008090208A1 (en) | 2007-01-26 | 2008-01-25 | Metal formulations |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2009132002A true RU2009132002A (en) | 2011-03-10 |
| RU2483833C2 RU2483833C2 (en) | 2013-06-10 |
Family
ID=39325106
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2009132002/02A RU2483833C2 (en) | 2007-01-26 | 2008-01-25 | Metal compositions |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US20100077887A1 (en) |
| EP (1) | EP2126148A1 (en) |
| JP (1) | JP2010516896A (en) |
| KR (1) | KR20090107554A (en) |
| CN (1) | CN101589166B (en) |
| BR (1) | BRPI0807178A2 (en) |
| CA (1) | CA2674928A1 (en) |
| DE (1) | DE102007004937B4 (en) |
| MX (1) | MX2009007484A (en) |
| RU (1) | RU2483833C2 (en) |
| WO (1) | WO2008090208A1 (en) |
| ZA (1) | ZA200904268B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2608112C2 (en) * | 2011-09-06 | 2017-01-13 | Х.К. Штарк Гмбх | Cermet powder |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102179511A (en) * | 2011-04-21 | 2011-09-14 | 北京矿冶研究总院 | Preparation method of porous MCrAlY alloy powder for thermal spraying |
| ES2628422T3 (en) * | 2011-05-27 | 2017-08-02 | H.C. Starck Gmbh | FeNi binder with universal applicability |
| DE102013220040A1 (en) | 2013-10-02 | 2015-04-02 | H.C. Starck Gmbh | Sintered spray powder based on molybdenum carbide |
| CN104400080B (en) * | 2014-09-23 | 2017-04-05 | 宁波市荣科迈特数控刀具有限公司 | A kind of depth drill |
| CN104625078B (en) * | 2015-02-14 | 2018-01-09 | 江苏和鹰机电科技有限公司 | Hard alloy cutter for cutting carbon fiber or glass fibre and preparation method thereof |
| CN104831216A (en) * | 2015-05-09 | 2015-08-12 | 芜湖鼎恒材料技术有限公司 | Ni-Co-Mo-Mn nanocoating material and preparation method thereof |
| CN104831213A (en) * | 2015-05-09 | 2015-08-12 | 安徽鼎恒再制造产业技术研究院有限公司 | Ni-Co-Mo-Mn material and preparation method thereof |
| KR20190021816A (en) * | 2017-08-24 | 2019-03-06 | 주식회사 포스코 | Metal alloy powder and method for producing the same |
| EP3748025A4 (en) * | 2018-01-31 | 2021-10-27 | Hitachi Metals, Ltd. | CEMENTED CARBIDE AND CEMENTED CARBIDE COMPOSITE ROLLER FOR LAMINATION |
| CN109280838B (en) * | 2018-11-30 | 2020-11-06 | 宇龙精机科技(浙江)有限公司 | Titanium-cobalt alloy and preparation method thereof |
| CN111826569A (en) * | 2020-07-21 | 2020-10-27 | 广东正信硬质材料技术研发有限公司 | Wear-resistant high-hardness hard alloy drilling tool and preparation method thereof |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2349052A (en) * | 1941-12-15 | 1944-05-16 | Joseph O Ollier | Manufacture of cemented hard metals, in particular for tool elements |
| US2986807A (en) * | 1958-09-03 | 1961-06-06 | Union Carbide Corp | Metal bonded refractory |
| US3515540A (en) * | 1964-12-16 | 1970-06-02 | Du Pont | Mixed cobalt/tungsten carbide powders |
| SU398670A1 (en) * | 1971-09-16 | 1973-09-27 | Всесоюзный научно исследовательский , проектный институт тугоплавких металлов , твердых сплавов | 1 P'G '"' METAL-CERAMIC HARD ALLOY ^^ * ^ = ' |
| RU2021385C1 (en) * | 1991-06-11 | 1994-10-15 | Институт проблем сверхпластичности металлов РАН | Hard alloy |
| US5423899A (en) * | 1993-07-16 | 1995-06-13 | Newcomer Products, Inc. | Dispersion alloyed hard metal composites and method for producing same |
| IL110663A (en) * | 1994-08-15 | 1997-09-30 | Iscar Ltd | Tungsten-based cemented carbide powder mix and cemented carbide products made therefrom |
| US5541006A (en) * | 1994-12-23 | 1996-07-30 | Kennametal Inc. | Method of making composite cermet articles and the articles |
| SE518810C2 (en) * | 1996-07-19 | 2002-11-26 | Sandvik Ab | Cemented carbide body with improved high temperature and thermomechanical properties |
| DE19640788C1 (en) * | 1996-10-02 | 1997-11-20 | Fraunhofer Ges Forschung | Coating powder used e.g. in thermal spraying |
| US6170917B1 (en) * | 1997-08-27 | 2001-01-09 | Kennametal Inc. | Pick-style tool with a cermet insert having a Co-Ni-Fe-binder |
| DE19822663A1 (en) | 1998-05-20 | 1999-12-02 | Starck H C Gmbh Co Kg | Sintered metal and alloy powders for powder metallurgical applications and processes for their production and their use |
| DE19962015A1 (en) * | 1999-12-22 | 2001-06-28 | Starck H C Gmbh Co Kg | Compound powder mixtures used, e.g., for particle blasting, are produced using one powder type of a metal with a high melting point, hard material or ceramic together with a bonding metal |
| SE522571C2 (en) * | 2001-02-08 | 2004-02-17 | Sandvik Ab | Carbide sealing rings for drinking water applications |
| AT4928U1 (en) * | 2001-03-29 | 2002-01-25 | Plansee Tizit Ag | METHOD FOR PRODUCING A HARD METAL APPROACH |
| AU2003227056A1 (en) * | 2002-03-29 | 2003-10-13 | Umicore | Pre-alloyed bond powders |
| US6911063B2 (en) * | 2003-01-13 | 2005-06-28 | Genius Metal, Inc. | Compositions and fabrication methods for hardmetals |
| DE10356470B4 (en) * | 2003-12-03 | 2009-07-30 | Kennametal Inc. | Zirconium and niobium-containing cemented carbide bodies and process for its preparation and its use |
| JP3853322B2 (en) * | 2004-01-30 | 2006-12-06 | トーカロ株式会社 | Powder composite material for thermal spraying, thermal spray coating member and method for producing the member |
| CN100526490C (en) * | 2006-04-14 | 2009-08-12 | 韶关学院 | Hard alloy sintered by high-entropy alloy binder and compound carbide and preparation method thereof |
| US20090277301A1 (en) * | 2006-07-12 | 2009-11-12 | H.C. Starck Gmbh | Metallic powder mixtures |
-
2007
- 2007-01-26 DE DE102007004937A patent/DE102007004937B4/en not_active Expired - Fee Related
-
2008
- 2008-01-25 JP JP2009546760A patent/JP2010516896A/en active Pending
- 2008-01-25 MX MX2009007484A patent/MX2009007484A/en active IP Right Grant
- 2008-01-25 WO PCT/EP2008/050845 patent/WO2008090208A1/en not_active Ceased
- 2008-01-25 US US12/524,600 patent/US20100077887A1/en not_active Abandoned
- 2008-01-25 EP EP08708184A patent/EP2126148A1/en not_active Withdrawn
- 2008-01-25 KR KR1020097017802A patent/KR20090107554A/en not_active Ceased
- 2008-01-25 BR BRPI0807178-0A patent/BRPI0807178A2/en not_active IP Right Cessation
- 2008-01-25 CA CA002674928A patent/CA2674928A1/en not_active Abandoned
- 2008-01-25 RU RU2009132002/02A patent/RU2483833C2/en not_active IP Right Cessation
- 2008-01-25 CN CN2008800030635A patent/CN101589166B/en not_active Expired - Fee Related
-
2009
- 2009-06-18 ZA ZA200904268A patent/ZA200904268B/en unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2608112C2 (en) * | 2011-09-06 | 2017-01-13 | Х.К. Штарк Гмбх | Cermet powder |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101589166B (en) | 2013-06-26 |
| MX2009007484A (en) | 2009-07-22 |
| WO2008090208A1 (en) | 2008-07-31 |
| EP2126148A1 (en) | 2009-12-02 |
| ZA200904268B (en) | 2010-08-25 |
| DE102007004937A1 (en) | 2008-07-31 |
| DE102007004937B4 (en) | 2008-10-23 |
| JP2010516896A (en) | 2010-05-20 |
| RU2483833C2 (en) | 2013-06-10 |
| US20100077887A1 (en) | 2010-04-01 |
| BRPI0807178A2 (en) | 2014-05-27 |
| CA2674928A1 (en) | 2008-07-31 |
| KR20090107554A (en) | 2009-10-13 |
| CN101589166A (en) | 2009-11-25 |
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