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RU2008136771A - COMPOSITIONS WITH IMPROVED INHIBITING ACTION FOR UREASES AND CONTAINING THEIR UREA FERTILIZERS - Google Patents

COMPOSITIONS WITH IMPROVED INHIBITING ACTION FOR UREASES AND CONTAINING THEIR UREA FERTILIZERS Download PDF

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RU2008136771A
RU2008136771A RU2008136771/15A RU2008136771A RU2008136771A RU 2008136771 A RU2008136771 A RU 2008136771A RU 2008136771/15 A RU2008136771/15 A RU 2008136771/15A RU 2008136771 A RU2008136771 A RU 2008136771A RU 2008136771 A RU2008136771 A RU 2008136771A
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acid
triamide
thio
composition according
phosphoric acid
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RU2008136771/15A
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RU2433985C2 (en
RU2433985C9 (en
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Александер ВИССЕМАЙЕР (DE)
Александер Виссемайер
Патрик ДЕК (DE)
Патрик ДЕК
Оливер ХУТТЕНЛОХ (DE)
Оливер ХУТТЕНЛОХ
Михаэль МАУС (DE)
Михаэль МАУС
Грегор ПАСДА (DE)
Грегор Пасда
Ральф-Томас РАН (DE)
Ральф-Томас РАН
Вольфганг ВАЙГЕЛЬТ (DE)
Вольфганг ВАЙГЕЛЬТ
Вольфрам ЦЕРУЛЛА (DE)
Вольфрам Церулла
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Басф Се (De)
Басф Се
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    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/90—Mixtures of one or more fertilisers with additives not having a specially fertilising activity for affecting the nitrification of ammonium compounds or urea in the soil
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05C—NITROGENOUS FERTILISERS
    • C05C9/00—Fertilisers containing urea or urea compounds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P60/00—Technologies relating to agriculture, livestock or agroalimentary industries
    • Y02P60/20—Reduction of greenhouse gas [GHG] emissions in agriculture, e.g. CO2
    • Y02P60/21—Dinitrogen oxide [N2O], e.g. using aquaponics, hydroponics or efficiency measures
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S71/00—Chemistry: fertilizers
    • Y10S71/902—Nitrification inhibition

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Soil Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Fertilizers (AREA)
  • Medicinal Preparation (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)

Abstract

1. Композиция, содержащая, по меньшей мере, два различных триамида (тио)фосфорной кислоты со структурами согласно следующей формуле (I), ! , ! в которой ! Х означает кислород или серу, ! R1 означает группу алкила, имеющего от 1 до 10 атомов углерода, циклоалкила, имеющего от 3 до 10 атомов углерода, арила, имеющего от 6 до 10 атомов углерода или диалкиламинокарбонила и ! R2 означает водород, или ! R1 и R2 вместе со связывающим их атомом азота образуют 5- или 6-членное насыщенное или ненасыщенный гетероциклический остаток, который, при необходимости может содержать еще 1 или 2 других гетероатома, выбираемых из группы, состоящей из азота, кислорода и серы, ! которые отличаются, по меньшей мере, в одном из остатков R1 или R2. ! 2. Композиция по п.1, отличающаяся тем, что в случае триамида (тио)фосфорной кислоты речь идет о триамиде N-алкил(тио)фосфорной кислоты и/или триамиде N-алкилфосфорной кислоты. ! 3. Композиция по одному из пп.1 или 2, отличающаяся тем, что в случае триамида (тио)фосфорной кислоты речь идет о триамиде N-н-бутилтиофосфорной кислоты. ! 4. Композиция по п.3, отличающаяся тем, что она кроме триамида N-н-бутилтиофосфорной кислоты содержит еще, по меньшей мере, одно производное, выбираемое из группы, состоящей из триамида N-циклогексилфосфорной кислоты, N-пентилфосфорной кислоты, N-изо-бутилфосфорной кислоты и N-пропилфосфорной кислоты, и триамида N-циклогексилтиофосфорной кислоты, N-пентилтиофосфорной кислоты, N-изо-бутилтиофосфорной кислоты и N-пропилтиофосфорной кислоты. ! 5. Композиция по п.4, отличающаяся тем, что содержание триамида N-н-бутилтиофосфорной кислоты составляет от 40 до 95 мас.%, в расчете на общую массу всех содержащихся в компози1. A composition containing at least two different triamides of (thio) phosphoric acid with structures according to the following formula (I),! ! wherein ! X means oxygen or sulfur! R1 means an alkyl group having from 1 to 10 carbon atoms, cycloalkyl having from 3 to 10 carbon atoms, aryl having from 6 to 10 carbon atoms or dialkylaminocarbonyl and! R2 means hydrogen, or! R1 and R2 together with the nitrogen atom bonding them form a 5- or 6-membered saturated or unsaturated heterocyclic residue, which, if necessary, may contain 1 or 2 other heteroatoms selected from the group consisting of nitrogen, oxygen and sulfur,! which differ in at least one of the residues R1 or R2. ! 2. The composition according to claim 1, characterized in that in the case of triamide (thio) phosphoric acid we are talking about triamide N-alkyl (thio) phosphoric acid and / or triamide N-alkylphosphoric acid. ! 3. The composition according to one of claims 1 or 2, characterized in that in the case of triamide (thio) phosphoric acid we are talking about triamide N-n-butylthiophosphoric acid. ! 4. The composition according to claim 3, characterized in that in addition to N-n-butylthiophosphoric triamide, it also contains at least one derivative selected from the group consisting of N-cyclohexylphosphoric triamide, N-pentylphosphoric acid, N- isobutylphosphoric acid and N-propylphosphoric acid, and triamide N-cyclohexylthiophosphoric acid, N-pentylthiophosphoric acid, N-isobutylthiophosphoric acid and N-propylthiophosphoric acid. ! 5. The composition according to claim 4, characterized in that the content of N-n-butylthiophosphoric triamide is from 40 to 95 wt.%, Calculated on the total weight of all contained in the composition

Claims (10)

1. Композиция, содержащая, по меньшей мере, два различных триамида (тио)фосфорной кислоты со структурами согласно следующей формуле (I),1. A composition containing at least two different triamides of (thio) phosphoric acid with structures according to the following formula (I),
Figure 00000001
,
Figure 00000001
, в которойwherein Х означает кислород или серу,X is oxygen or sulfur, R1 означает группу алкила, имеющего от 1 до 10 атомов углерода, циклоалкила, имеющего от 3 до 10 атомов углерода, арила, имеющего от 6 до 10 атомов углерода или диалкиламинокарбонила иR 1 means an alkyl group having from 1 to 10 carbon atoms, cycloalkyl having from 3 to 10 carbon atoms, aryl having from 6 to 10 carbon atoms or dialkylaminocarbonyl and R2 означает водород, илиR 2 means hydrogen, or R1 и R2 вместе со связывающим их атомом азота образуют 5- или 6-членное насыщенное или ненасыщенный гетероциклический остаток, который, при необходимости может содержать еще 1 или 2 других гетероатома, выбираемых из группы, состоящей из азота, кислорода и серы,R 1 and R 2 together with the nitrogen atom bonding them form a 5- or 6-membered saturated or unsaturated heterocyclic residue, which, if necessary, may contain 1 or 2 other heteroatoms selected from the group consisting of nitrogen, oxygen and sulfur, которые отличаются, по меньшей мере, в одном из остатков R1 или R2.which differ in at least one of the residues R 1 or R 2 . 2. Композиция по п.1, отличающаяся тем, что в случае триамида (тио)фосфорной кислоты речь идет о триамиде N-алкил(тио)фосфорной кислоты и/или триамиде N-алкилфосфорной кислоты.2. The composition according to claim 1, characterized in that in the case of triamide (thio) phosphoric acid we are talking about triamide N-alkyl (thio) phosphoric acid and / or triamide N-alkylphosphoric acid. 3. Композиция по одному из пп.1 или 2, отличающаяся тем, что в случае триамида (тио)фосфорной кислоты речь идет о триамиде N-н-бутилтиофосфорной кислоты.3. The composition according to one of claims 1 or 2, characterized in that in the case of triamide (thio) phosphoric acid we are talking about triamide N-n-butylthiophosphoric acid. 4. Композиция по п.3, отличающаяся тем, что она кроме триамида N-н-бутилтиофосфорной кислоты содержит еще, по меньшей мере, одно производное, выбираемое из группы, состоящей из триамида N-циклогексилфосфорной кислоты, N-пентилфосфорной кислоты, N-изо-бутилфосфорной кислоты и N-пропилфосфорной кислоты, и триамида N-циклогексилтиофосфорной кислоты, N-пентилтиофосфорной кислоты, N-изо-бутилтиофосфорной кислоты и N-пропилтиофосфорной кислоты.4. The composition according to claim 3, characterized in that in addition to the triamide of N-n-butylthiophosphoric acid, it contains at least one derivative selected from the group consisting of N-cyclohexylphosphoric triamide, N-pentylphosphoric acid, N- isobutylphosphoric acid and N-propylphosphoric acid, and triamide N-cyclohexylthiophosphoric acid, N-pentylthiophosphoric acid, N-isobutylthiophosphoric acid and N-propylthiophosphoric acid. 5. Композиция по п.4, отличающаяся тем, что содержание триамида N-н-бутилтиофосфорной кислоты составляет от 40 до 95 мас.%, в расчете на общую массу всех содержащихся в композиции триамидов (тио)фосфорной кислоты.5. The composition according to claim 4, characterized in that the content of N-n-butylthiophosphoric triamide is from 40 to 95 wt.%, Based on the total weight of all (thio) phosphoric acid triamides contained in the composition. 6. Способ получения композиций по п.1, отличающийся тем, что тиофосфорилхлорид подвергают взаимодействию со смесью, по меньшей мере, двух различных первичных и/или вторичных аминов и затем с аммиаком.6. The method of producing compositions according to claim 1, characterized in that the thiophosphoryl chloride is reacted with a mixture of at least two different primary and / or secondary amines and then with ammonia. 7. Применение композиций по п.1 при внесении содержащих мочевину удобрений.7. The use of compositions according to claim 1 when making fertilizers containing urea. 8. Содержащее мочевину удобрение, отличающееся тем, что оно включает композицию по п.1.8. A urea-containing fertilizer, characterized in that it includes the composition according to claim 1. 9. Содержащее мочевину удобрение по п.8, отличающееся тем, что общее содержание триамидов (тио)фосфорной кислоты в расчете на содержащуюся мочевину составляет между 0,001 и 0,5 мас.%.9. The urea-containing fertilizer of claim 8, wherein the total content of triamides (thio) phosphoric acid per urea is between 0.001 and 0.5 wt.%. 10. Применение содержащего мочевину удобрения по п.8 в сельском хозяйстве или в садоводстве. 10. The use of urea-containing fertilizer according to claim 8 in agriculture or in horticulture.
RU2008136771/21A 2006-02-16 2007-02-07 Compositions with improved urease inhibiting action and urea-containing fertilisers containing said compositions RU2433985C9 (en)

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EP06110039.2 2006-02-16

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JP (2) JP5502330B2 (en)
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AU (1) AU2007216551B2 (en)
BR (1) BRPI0707795B1 (en)
CA (1) CA2639995C (en)
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