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RU2008129100A - PACKAGE OF ADDITIVES FOR HIGH TEMPERATURE SYNTHETIC GREASES - Google Patents

PACKAGE OF ADDITIVES FOR HIGH TEMPERATURE SYNTHETIC GREASES Download PDF

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Publication number
RU2008129100A
RU2008129100A RU2008129100/04A RU2008129100A RU2008129100A RU 2008129100 A RU2008129100 A RU 2008129100A RU 2008129100/04 A RU2008129100/04 A RU 2008129100/04A RU 2008129100 A RU2008129100 A RU 2008129100A RU 2008129100 A RU2008129100 A RU 2008129100A
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Russia
Prior art keywords
synthetic
ester
lubricant according
metal borates
borated
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RU2008129100/04A
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Russian (ru)
Inventor
Дейл Д. КАРР (US)
Дейл Д. КАРР
Томас Г. ШЕФЕР (US)
Томас Г. ШЕФЕР
Джеффри А. ХАТТЕР (US)
Джеффри А. ХАТТЕР
Original Assignee
Хатко Корпорейшн (Us)
Хатко Корпорейшн
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Publication of RU2008129100A publication Critical patent/RU2008129100A/en

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
    • C10M141/12—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic compound containing atoms of elements not provided for in groups C10M141/02 - C10M141/10
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
    • C10M159/12—Reaction products
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/06—Mixtures of thickeners and additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/087—Boron oxides, acids or salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/283—Esters of polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/283—Esters of polyhydroxy compounds
    • C10M2207/2835—Esters of polyhydroxy compounds used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064—Di- and triaryl amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064—Di- and triaryl amines
    • C10M2215/065—Phenyl-Naphthyl amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/223—Five-membered rings containing nitrogen and carbon only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/045—Polyureas; Polyurethanes
    • C10M2217/0456—Polyureas; Polyurethanes used as thickening agents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
    • C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
    • C10M2219/066—Thiocarbamic type compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
    • C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/047—Thioderivatives not containing metallic elements
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/04—Groups 2 or 12
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/14—Group 7
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/02—Pour-point; Viscosity index
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/08—Resistance to extreme temperature
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/10—Form in which the lubricant is applied to the material being lubricated semi-solid; greasy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2060/00—Chemical after-treatment of the constituents of the lubricating composition
    • C10N2060/14—Chemical after-treatment of the constituents of the lubricating composition by boron or a compound containing boron

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

1. Пакет присадок для сложнополиолэфирной исходной смеси, подходящей для высокотемпературного применения, содержащий: ! по меньшей мере, один олигомерный ароматический аминный антиоксидант и ! по меньшей мере, один борированный агент против предельного сжатия/истирания. ! 2. Пакет присадок по п.1, в котором олигомерный ароматический аминный антиоксидант является продуктом взаимодействия алкилированного дифениламина, алкилированного фенилнафтиламина и сложноэфирной исходной смеси. ! 3. Пакет присадок по п.1, в котором борированный агент против предельного сжатия/истирания представляет собой, по меньшей мере, одно из борированного амина, тетрабората калия, боратов щелочноземельных металлов группы 2а, стабильных боратов переходных металлов, включая цинк, медь и олово, и борной кислоты. ! 4. Пакет присадок по п.1, в котором олигомерный ароматический аминный антиоксидант является продуктом взаимодействия алкилированного дифениламина, алкилированного фенилнафтиламина и сложноэфирной исходной смеси, и борированный агент против предельного сжатия/истирания представляет собой, по меньшей мере, одно из борированного амина, тетрабората калия, боратов щелочноземельных металлов группы 2а, стабильных боратов переходных металлов, включая цинк, медь и олово, и борной кислоты. ! 5. Синтетическая жидкая смазка на основе сложного эфира, содержащая ! (А) сложноэфирную исходную смесь, которая является продуктом взаимодействия: ! (i) пентаэритрита и ! (ii) смеси монокарбоновых кислот, включающей, по меньшей мере, 60 мас.% изо-С9-кислоты; и ! (В) эффективного количества пакета присадок, включающего: ! по меньшей мере, один олигомерный аромат�1. An additive package for a polyester ester feed mixture suitable for high temperature applications, comprising:! at least one oligomeric aromatic amine antioxidant and! at least one borated agent against ultimate compression / abrasion. ! 2. The additive package according to claim 1, in which the oligomeric aromatic amine antioxidant is a product of the interaction of alkylated diphenylamine, alkylated phenylnaphthylamine and ester starting mixture. ! 3. The additive package according to claim 1, in which the borated anti-compression / abrasion agent is at least one of a borated amine, potassium tetraborate, group 2a alkaline earth metal borates, stable transition metal borates, including zinc, copper and tin , and boric acid. ! 4. The additive package according to claim 1, in which the oligomeric aromatic amine antioxidant is the product of the interaction of alkylated diphenylamine, alkylated phenylnaphthylamine and ester starting mixture, and the boron anti-compression / abrasion agent is at least one of the boron amine, potassium tetraborate , alkaline earth metal borates of group 2a, stable transition metal borates, including zinc, copper and tin, and boric acid. ! 5. A synthetic ester based fluid lubricant containing! (A) ester starting mixture, which is the product of the interaction:! (i) pentaerythritol and! (ii) a mixture of monocarboxylic acids, comprising at least 60 wt.% iso-C9 acid; and! (B) an effective amount of an additive package including:! at least one oligomeric flavor�

Claims (26)

1. Пакет присадок для сложнополиолэфирной исходной смеси, подходящей для высокотемпературного применения, содержащий:1. An additive package for a polyester ester feed mixture suitable for high temperature applications, comprising: по меньшей мере, один олигомерный ароматический аминный антиоксидант иat least one oligomeric aromatic amine antioxidant and по меньшей мере, один борированный агент против предельного сжатия/истирания.at least one borated agent against ultimate compression / abrasion. 2. Пакет присадок по п.1, в котором олигомерный ароматический аминный антиоксидант является продуктом взаимодействия алкилированного дифениламина, алкилированного фенилнафтиламина и сложноэфирной исходной смеси.2. The additive package according to claim 1, in which the oligomeric aromatic amine antioxidant is a product of the interaction of alkylated diphenylamine, alkylated phenylnaphthylamine and ester starting mixture. 3. Пакет присадок по п.1, в котором борированный агент против предельного сжатия/истирания представляет собой, по меньшей мере, одно из борированного амина, тетрабората калия, боратов щелочноземельных металлов группы 2а, стабильных боратов переходных металлов, включая цинк, медь и олово, и борной кислоты.3. The additive package according to claim 1, wherein the borated anti-compression / abrasion agent is at least one of a borated amine, potassium tetraborate, group 2a alkaline earth metal borates, stable transition metal borates, including zinc, copper and tin , and boric acid. 4. Пакет присадок по п.1, в котором олигомерный ароматический аминный антиоксидант является продуктом взаимодействия алкилированного дифениламина, алкилированного фенилнафтиламина и сложноэфирной исходной смеси, и борированный агент против предельного сжатия/истирания представляет собой, по меньшей мере, одно из борированного амина, тетрабората калия, боратов щелочноземельных металлов группы 2а, стабильных боратов переходных металлов, включая цинк, медь и олово, и борной кислоты.4. The additive package according to claim 1, wherein the oligomeric aromatic amine antioxidant is a reaction product of an alkylated diphenylamine, an alkylated phenylnaphthylamine and an ester starting mixture, and the boron anti-compression / abrasion agent is at least one of a boron amine, potassium tetraborate , alkaline earth metal borates of group 2a, stable transition metal borates, including zinc, copper and tin, and boric acid. 5. Синтетическая жидкая смазка на основе сложного эфира, содержащая5. Synthetic ester-based liquid lubricant containing (А) сложноэфирную исходную смесь, которая является продуктом взаимодействия:(A) ester starting mixture, which is the product of the interaction: (i) пентаэритрита и(i) pentaerythritol; and (ii) смеси монокарбоновых кислот, включающей, по меньшей мере, 60 мас.% изо-С9-кислоты; и(ii) a mixture of monocarboxylic acids, comprising at least 60 wt.% iso-C 9 acids; and (В) эффективного количества пакета присадок, включающего:(B) an effective amount of an additive package including: по меньшей мере, один олигомерный ароматический аминный антиоксидант иat least one oligomeric aromatic amine antioxidant and по меньшей мере, один борированный агент против предельного сжатия/истирания,at least one borated anti-ultimate compression / abrasion agent, причем жидкая смазка имеет вязкость при 40°C, по меньшей мере, примерно 120 сСт.moreover, the liquid lubricant has a viscosity at 40 ° C of at least about 120 cSt. 6. Синтетическая жидкая смазка по п.5, в которой пакет присадок присутствует в количестве 5-15 мас.% по отношению к общей массе смазки.6. The synthetic liquid lubricant according to claim 5, in which the additive package is present in an amount of 5-15 wt.% In relation to the total weight of the lubricant. 7. Синтетическая жидкая смазка по п.5, в которой антиоксидант присутствует в количестве примерно 1-10 мас.% по отношению к общей массе смазки.7. The synthetic liquid lubricant according to claim 5, in which the antioxidant is present in an amount of about 1-10 wt.% In relation to the total weight of the lubricant. 8. Синтетическая жидкая смазка по п.5, в которой борированный агент против истирания присутствует в количестве примерно 0,1-5 мас.% по отношению к общей массе смазки.8. The synthetic liquid lubricant according to claim 5, in which the borated anti-abrasion agent is present in an amount of about 0.1-5 wt.% With respect to the total weight of the lubricant. 9. Синтетическая жидкая смазка по п.5, в которой борированный агент против предельного сжатия выбран из группы, состоящей из борированных аминов, тетрабората калия, боратов щелочных металлов группы 1а, боратов щелочноземельных металлов группы 2а, стабильных боратов переходных металлов, таких как цинк, медь и олово, и борной кислоты.9. The synthetic liquid lubricant according to claim 5, wherein the borated anti-compression agent is selected from the group consisting of borated amines, potassium tetraborate, group 1a alkali metal borates, group 2a alkaline earth metal borates, stable transition metal borates such as zinc, copper and tin, and boric acid. 10. Синтетическая жидкая смазка по п.5, в которой олигомерный ароматический амин является продуктом взаимодействия алкилированного дифениламина, алкилированного фенилнафтиламина и сложноэфирной исходной смеси.10. The synthetic liquid lubricant according to claim 5, in which the oligomeric aromatic amine is the product of the interaction of alkylated diphenylamine, alkylated phenylnaphthylamine and ester starting mixture. 11. Синтетическая жидкая смазка по п.5, в которой олигомерный ароматический аминный антиоксидант является продуктом взаимодействия алкилированного дифениламина, алкилированного фенилнафтиламина и сложноэфирной исходной смеси, и борированным агентом против предельного сжатия/истирания является, по меньшей мере, одно из борированного амина, тетрабората калия, боратов щелочных металлов группы 1а, боратов щелочноземельных металлов группы 2а, стабильных боратов переходных металлов, таких как цинк, медь и олово, и борной кислоты.11. The synthetic liquid lubricant according to claim 5, in which the oligomeric aromatic amine antioxidant is the product of the interaction of an alkylated diphenylamine, an alkylated phenylnaphthylamine and an ester starting mixture, and at least one of the boronated amine, potassium tetraborate, is a boronated anti-compression / abrasion agent. alkali metal borates of group 1a; alkaline earth metal borates of group 2a; stable transition metal borates such as zinc, copper and tin, and boric acid. 12. Синтетическая жидкая смазка по п.5, в которой полиол представляет собой, по меньшей мере, 85 мас.% пентаэритрита.12. The synthetic liquid lubricant according to claim 5, in which the polyol is at least 85 wt.% Pentaerythritol. 13. Синтетическая жидкая смазка по п.5, в которой полиол представляет собой, по меньшей мере, 98 мас.% пентаэритрита.13. The synthetic liquid lubricant according to claim 5, in which the polyol is at least 98 wt.% Pentaerythritol. 14. Синтетическая жидкая смазка по п.5, в которой кислота с неразветвленной цепью представляет собой смесь, включающую, по меньшей мере, 75 мас.% изо-С9-кислоты и остальное до 100 мас.% С7 и С8-10 кислот с неразветвленной цепью.14. The synthetic liquid lubricant according to claim 5, in which the straight chain acid is a mixture comprising at least 75 wt.% Iso-C 9 acids and the rest is up to 100 wt.% C 7 and C 8-10 straight chain acids. 15. Синтетическая жидкая смазка по п.5, дополнительно включающая эффективное количество ингибитора коррозии.15. The synthetic liquid lubricant according to claim 5, further comprising an effective amount of a corrosion inhibitor. 16. Синтетическая жидкая смазка по п.5, в которой ингибитором коррозии является бензотриазол.16. The synthetic fluid lubricant according to claim 5, wherein the corrosion inhibitor is benzotriazole. 17. Синтетическая жидкая смазка по п.5, в которой остальное количество до 100% монокарбоновой кислоты представляет собой обычные С7-С10-кислоты.17. The synthetic fluid lubricant according to claim 5, wherein the remaining amount of up to 100% monocarboxylic acid is a conventional C 7 -C 10 acid. 18. Синтетическая жидкая смазка по п.17, в которой кислотная смесь представляет собой, по меньшей мере, примерно 66% изо-С9-кислоты.18. The synthetic liquid lubricant according to 17, in which the acidic mixture is at least about 66% iso-C 9 acid. 19. Синтетическая жидкая смазка на основе сложного эфира, содержащая19. A synthetic ester-based fluid lubricant containing (А) сложноэфирную исходную смесь, которая является продуктом взаимодействия:(A) ester starting mixture, which is the product of the interaction: (i) дипентаэритрита и(i) dipentaerythritol; and (ii) смеси монокарбоновых кислот, включающей, по меньшей мере, примерно 60 мас.% изо-С9-кислоты и С7 и С8-10 кислот с неразветвленной цепью; и(ii) a mixture of monocarboxylic acids, comprising at least about 60% by weight of iso-C 9 acid and C 7 and C 8-10 straight chain acids; and (В) эффективное количество пакета присадок, включающего:(B) an effective amount of an additive package including: по меньшей мере, один олигомерный ароматический аминный антиоксидант иat least one oligomeric aromatic amine antioxidant and борированный агент против предельного сжатия/истирания,borated agent against ultimate compression / abrasion, причем жидкая смазка имеет вязкость при 40°C, по меньшей мере, примерно 120 сСт.moreover, the liquid lubricant has a viscosity at 40 ° C of at least about 120 cSt. 20. Синтетическая жидкая смазка на основе сложного эфира по п.19, в которой дипентаэритрит представляет собой, по меньшей мере, примерно 85 мас.% дипентаэритрита.20. The synthetic ester-based fluid lubricant according to claim 19, wherein the dipentaerythritol is at least about 85% by weight of dipentaerythritol. 21. Синтетическая жидкая смазка на основе сложного эфира по п.19, в которой антиоксидант присутствует в количестве примерно 3-8 мас.% по отношению к общей массе смазки.21. The synthetic ester-based liquid lubricant according to claim 19, wherein the antioxidant is present in an amount of about 3-8 wt.% With respect to the total weight of the lubricant. 22. Синтетическая жидкая смазка на основе сложного эфира по п.19, в которой борированный агент против истирания присутствует в количестве примерно 0,5-4 мас.% по отношению к общей массе смазки.22. The synthetic ester-based fluid lubricant according to claim 19, wherein the boron anti-abrasion agent is present in an amount of about 0.5-4 wt.% With respect to the total weight of the lubricant. 23. Синтетическая жидкая смазка на основе сложного эфира по п.5, дополнительно включающая загуститель с образованием густой смазки.23. The synthetic ester-based fluid lubricant according to claim 5, further comprising a thickener to form a thick lubricant. 24. Синтетическая жидкая смазка на основе сложного эфира по п.22, в которой загустителем является полимочевина.24. The synthetic ester-based fluid lubricant according to claim 22, wherein the thickener is polyurea. 25. Синтетическая жидкая смазка на основе сложного эфира по п.19, дополнительно включающая загуститель с образованием густой смазки.25. The synthetic ester-based fluid lubricant according to claim 19, further comprising a thickener to form a thick lubricant. 26. Синтетическая жидкая смазка на основе сложного эфира по п.25, в которой загустителем является полимочевина, присутствующая в количестве примерно 20-25 мас.% от общей массы смазки. 26. The synthetic ester-based liquid lubricant according to claim 25, wherein the thickening agent is polyurea, present in an amount of about 20-25 wt.% Of the total weight of the lubricant.
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