RU2008140311A - Маложелезистое высокопропускающее флоат-стекло для применения в солнечных элементах и способ его изготовления - Google Patents
Маложелезистое высокопропускающее флоат-стекло для применения в солнечных элементах и способ его изготовления Download PDFInfo
- Publication number
- RU2008140311A RU2008140311A RU2008140311/03A RU2008140311A RU2008140311A RU 2008140311 A RU2008140311 A RU 2008140311A RU 2008140311/03 A RU2008140311/03 A RU 2008140311/03A RU 2008140311 A RU2008140311 A RU 2008140311A RU 2008140311 A RU2008140311 A RU 2008140311A
- Authority
- RU
- Russia
- Prior art keywords
- glass
- oxide
- redox
- feo
- glass substrate
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract 30
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims abstract 12
- 238000004519 manufacturing process Methods 0.000 title claims abstract 7
- 229910052742 iron Inorganic materials 0.000 title claims abstract 5
- 239000005329 float glass Substances 0.000 title 1
- 239000011521 glass Substances 0.000 claims abstract 58
- VQCBHWLJZDBHOS-UHFFFAOYSA-N erbium(iii) oxide Chemical compound O=[Er]O[Er]=O VQCBHWLJZDBHOS-UHFFFAOYSA-N 0.000 claims abstract 18
- PLDDOISOJJCEMH-UHFFFAOYSA-N neodymium(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Nd+3].[Nd+3] PLDDOISOJJCEMH-UHFFFAOYSA-N 0.000 claims abstract 18
- 239000000758 substrate Substances 0.000 claims abstract 14
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract 12
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 claims abstract 9
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 claims abstract 9
- 229910000423 chromium oxide Inorganic materials 0.000 claims abstract 9
- 229910000428 cobalt oxide Inorganic materials 0.000 claims abstract 9
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 claims abstract 9
- 150000001875 compounds Chemical class 0.000 claims abstract 9
- 229910000480 nickel oxide Inorganic materials 0.000 claims abstract 9
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 claims abstract 9
- 229910052711 selenium Inorganic materials 0.000 claims abstract 9
- 239000011669 selenium Substances 0.000 claims abstract 9
- 238000002834 transmittance Methods 0.000 claims abstract 8
- 239000000203 mixture Substances 0.000 claims abstract 5
- 239000004615 ingredient Substances 0.000 claims abstract 4
- 239000000463 material Substances 0.000 claims abstract 2
- 229910000420 cerium oxide Inorganic materials 0.000 claims 8
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims 8
- 229910004298 SiO 2 Inorganic materials 0.000 claims 3
- 229910000410 antimony oxide Inorganic materials 0.000 claims 3
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 claims 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 abstract 1
- 229910052681 coesite Inorganic materials 0.000 abstract 1
- 229910052906 cristobalite Inorganic materials 0.000 abstract 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 229910052682 stishovite Inorganic materials 0.000 abstract 1
- 229910052905 tridymite Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/083—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound
- C03C3/085—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal
- C03C3/087—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal containing calcium oxide, e.g. common sheet or container glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3668—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having electrical properties
- C03C17/3678—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having electrical properties specially adapted for use in solar cells
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/0092—Compositions for glass with special properties for glass with improved high visible transmittance, e.g. extra-clear glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/10—Compositions for glass with special properties for infrared transmitting glass
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10F77/00—Constructional details of devices covered by this subclass
- H10F77/10—Semiconductor bodies
- H10F77/16—Material structures, e.g. crystalline structures, film structures or crystal plane orientations
- H10F77/169—Thin semiconductor films on metallic or insulating substrates
- H10F77/1692—Thin semiconductor films on metallic or insulating substrates the films including only Group IV materials
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10F77/00—Constructional details of devices covered by this subclass
- H10F77/70—Surface textures, e.g. pyramid structures
- H10F77/707—Surface textures, e.g. pyramid structures of the substrates or of layers on substrates, e.g. textured ITO layer on a glass substrate
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/90—Other aspects of coatings
- C03C2217/94—Transparent conductive oxide layers [TCO] being part of a multilayer coating
- C03C2217/944—Layers comprising zinc oxide
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Sustainable Development (AREA)
- Glass Compositions (AREA)
Abstract
1. Способ изготовления стекла, содержащего ! Ингредиент мас.% SiO2 67-75% Na2O 10-20% CaO 5-15% общее железо (выраженное как Fe2O3) от 0,001 до 0,1% %FeO от 0 до 0,005 ! где данное стекло имеет пропускание в видимой области, по меньшей мере, приблизительно 90%, величину проходящего а* цвета от -1,0 до +1,0, величину проходящего b* цвета от -0,50 до +1,5, %ПС, по меньшей мере, 89,5%, причем в способе используют редокс шихты от +26 до +40 при изготовлении упомянутого стекла. ! 2. Способ по п.1, где редокс шихты составляет от +27 до +35. ! 3. Способ по п.1, где редокс шихты составляет от +28 до +33. ! 4. Способ по п.1, где данное стекло содержит ! %FeO ≤0,004% редокс стекла ≤0,06 ИК пропускание (%ИК) ≥90% ! 5. Способ по п.1, где в данном способе дополнительно используют надлежащие материалы в шихте, используемой при изготовлении данного стекла, так что стекло содержит, по меньшей мере, 0,27% SO3. ! 6. Способ по п.5, где стекло содержит от 0,30 до 0,50% SO3. ! 7. Способ по п.5, где стекло содержит, по меньшей мере, 0,32% SO3. ! 8. Способ по п.1, где стеклянная подложка имеет %ПС, по меньшей мере, 90% и содержит ! %FeO ≤0,004% редокс стекла ≤0,06 ! 9. Способ по п.1, где стеклянная подложка содержит не более 2 ч./млн, по меньшей мере, двух соединений из оксида эрбия, оксида никеля, оксида кобальта, оксида неодима, оксида хрома и селена. ! 10. Способ по п.1, где стеклянная подложка содержит не более 2 ч./млн, по меньшей мере, четырех соединений из оксида эрбия, оксида никеля, оксида кобальта, оксида неодима, оксида хрома и селена. !11. Способ по п.1, где стеклянная подложка содержит не более 2 ч./млн, по меньшей мере, пяти соединений из оксида эрбия, оксида никеля, оксида кобальта, оксида неодима, оксида хрома и селена. ! 12. Способ по
Claims (27)
1. Способ изготовления стекла, содержащего
где данное стекло имеет пропускание в видимой области, по меньшей мере, приблизительно 90%, величину проходящего а* цвета от -1,0 до +1,0, величину проходящего b* цвета от -0,50 до +1,5, %ПС, по меньшей мере, 89,5%, причем в способе используют редокс шихты от +26 до +40 при изготовлении упомянутого стекла.
2. Способ по п.1, где редокс шихты составляет от +27 до +35.
3. Способ по п.1, где редокс шихты составляет от +28 до +33.
4. Способ по п.1, где данное стекло содержит
5. Способ по п.1, где в данном способе дополнительно используют надлежащие материалы в шихте, используемой при изготовлении данного стекла, так что стекло содержит, по меньшей мере, 0,27% SO3.
6. Способ по п.5, где стекло содержит от 0,30 до 0,50% SO3.
7. Способ по п.5, где стекло содержит, по меньшей мере, 0,32% SO3.
8. Способ по п.1, где стеклянная подложка имеет %ПС, по меньшей мере, 90% и содержит
9. Способ по п.1, где стеклянная подложка содержит не более 2 ч./млн, по меньшей мере, двух соединений из оксида эрбия, оксида никеля, оксида кобальта, оксида неодима, оксида хрома и селена.
10. Способ по п.1, где стеклянная подложка содержит не более 2 ч./млн, по меньшей мере, четырех соединений из оксида эрбия, оксида никеля, оксида кобальта, оксида неодима, оксида хрома и селена.
11. Способ по п.1, где стеклянная подложка содержит не более 2 ч./млн, по меньшей мере, пяти соединений из оксида эрбия, оксида никеля, оксида кобальта, оксида неодима, оксида хрома и селена.
12. Способ по п.1, где стеклянная подложка содержит не более 2 ч./млн, по меньшей мере, каждого соединения из оксида эрбия, оксида никеля, оксида кобальта, оксида неодима, оксида хрома и селена.
13. Способ по п.1, где стекло содержит от 0 до 0,07% оксида церия.
14. Способ по п.1, где стекло содержит от 0 до 0,05% оксида церия.
15. Способ по п.1, где стекло содержит от 0 до менее чем 0,01% оксида сурьмы.
16. Солнечный элемент, содержащий
стеклянную подложку;
первый и второй проводящие слои с, по меньшей мере, фотоэлектрической пленкой, расположенной между ними;
где стеклянная подложка имеет следующий состав:
где данное стекло имеет пропускание в видимой области, по меньшей мере, 90%, ПС пропускание, по меньшей мере, 90%; величину проходящего а* цвета от -1,0 до +1,0, величину проходящего b* цвета от -0,5 до +1,5.
17. Солнечный элемент по п.16, где стеклянная подложка содержит
18. Солнечный элемент по п.16, где стеклянная подложка имеет %ПС, по меньшей мере, 91% и содержит
19. Солнечный элемент по п.16, где стекло содержит, по меньшей мере, 0,27% SO3, более предпочтительно от 0,30 до 0,50% SO3.
20. Солнечный элемент по п.16, где стеклянная подложка содержит не более 2 ч./млн, по меньшей мере, двух, более предпочтительно, по меньшей мере, трех, даже более предпочтительно, по меньшей мере, четырех, и наиболее предпочтительно, по меньшей мере, пяти соединений из оксида эрбия, оксида никеля, оксида кобальта, оксида неодима, оксида хрома и селена.
21. Солнечный элемент по п.16, где стекло содержит от 0 до 0,05% оксида церия, более предпочтительно, не больше, чем 0,01% оксида церия.
22. Стекло, содержащее
где данное стекло имеет пропускание в видимой области, по меньшей мере, 90%, ПС пропускание, по меньшей мере, 90%; величину проходящего а* цвета от -1,0 до +1,0, величину проходящего b* цвета от -0,5 до +1,5.
23. Стекло по п.22, где данное стекло содержит
24. Стекло по п.22, где данное стекло имеет %ПС, по меньшей мере, 91% и содержит
25. Стекло по п.22, где данное стекло содержит, по меньшей мере, 0,27% SO3, более предпочтительно от 0,30 до 0,50% SO3.
26. Стекло по п.22, где данное стекло содержит не более 2 ч./млн, по меньшей мере, двух, более предпочтительно, по меньшей мере, трех, даже более предпочтительно, по меньшей мере, четырех, и наиболее предпочтительно, по меньшей мере, пяти соединений из оксида эрбия, оксида никеля, оксида кобальта, оксида неодима, оксида хрома и селена.
27. Стекло по п.22, где данное стекло содержит от 0 до 0,05% оксида церия, более предпочтительно, не больше, чем 0,01% оксида церия.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/373,490 US8648252B2 (en) | 2006-03-13 | 2006-03-13 | Solar cell using low iron high transmission glass and corresponding method |
| US11/373,490 | 2006-03-13 | ||
| US11/581,784 | 2006-10-17 | ||
| US11/581,784 US7557053B2 (en) | 2006-03-13 | 2006-10-17 | Low iron high transmission float glass for solar cell applications and method of making same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2008140311A true RU2008140311A (ru) | 2010-04-20 |
| RU2443642C2 RU2443642C2 (ru) | 2012-02-27 |
Family
ID=38134589
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2008140311/03A RU2443642C2 (ru) | 2006-03-13 | 2007-01-22 | Маложелезистое высокопропускающее флоат-стекло для применения в солнечных элементах и способ его изготовления |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US7557053B2 (ru) |
| EP (1) | EP1993961A1 (ru) |
| BR (1) | BRPI0709394A2 (ru) |
| CA (1) | CA2641929A1 (ru) |
| RU (1) | RU2443642C2 (ru) |
| WO (1) | WO2007106223A1 (ru) |
Families Citing this family (89)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7700870B2 (en) * | 2005-05-05 | 2010-04-20 | Guardian Industries Corp. | Solar cell using low iron high transmission glass with antimony and corresponding method |
| US20070207912A1 (en) * | 2006-03-02 | 2007-09-06 | Guardian Industries Corp. | Method of making glass including use of boron oxide for reducing glass refining time |
| US8648252B2 (en) * | 2006-03-13 | 2014-02-11 | Guardian Industries Corp. | Solar cell using low iron high transmission glass and corresponding method |
| US7557053B2 (en) * | 2006-03-13 | 2009-07-07 | Guardian Industries Corp. | Low iron high transmission float glass for solar cell applications and method of making same |
| US20080178932A1 (en) * | 2006-11-02 | 2008-07-31 | Guardian Industries Corp. | Front electrode including transparent conductive coating on patterned glass substrate for use in photovoltaic device and method of making same |
| US20080105293A1 (en) * | 2006-11-02 | 2008-05-08 | Guardian Industries Corp. | Front electrode for use in photovoltaic device and method of making same |
| US20080105298A1 (en) * | 2006-11-02 | 2008-05-08 | Guardian Industries Corp. | Front electrode for use in photovoltaic device and method of making same |
| US20080302414A1 (en) * | 2006-11-02 | 2008-12-11 | Den Boer Willem | Front electrode for use in photovoltaic device and method of making same |
| US20080105299A1 (en) * | 2006-11-02 | 2008-05-08 | Guardian Industries Corp. | Front electrode with thin metal film layer and high work-function buffer layer for use in photovoltaic device and method of making same |
| US8012317B2 (en) * | 2006-11-02 | 2011-09-06 | Guardian Industries Corp. | Front electrode including transparent conductive coating on patterned glass substrate for use in photovoltaic device and method of making same |
| US8203073B2 (en) * | 2006-11-02 | 2012-06-19 | Guardian Industries Corp. | Front electrode for use in photovoltaic device and method of making same |
| US8076571B2 (en) * | 2006-11-02 | 2011-12-13 | Guardian Industries Corp. | Front electrode for use in photovoltaic device and method of making same |
| US7964788B2 (en) * | 2006-11-02 | 2011-06-21 | Guardian Industries Corp. | Front electrode for use in photovoltaic device and method of making same |
| US8334452B2 (en) * | 2007-01-08 | 2012-12-18 | Guardian Industries Corp. | Zinc oxide based front electrode doped with yttrium for use in photovoltaic device or the like |
| US20080169021A1 (en) * | 2007-01-16 | 2008-07-17 | Guardian Industries Corp. | Method of making TCO front electrode for use in photovoltaic device or the like |
| US20080223430A1 (en) * | 2007-03-14 | 2008-09-18 | Guardian Industries Corp. | Buffer layer for front electrode structure in photovoltaic device or the like |
| US20080308145A1 (en) * | 2007-06-12 | 2008-12-18 | Guardian Industries Corp | Front electrode including transparent conductive coating on etched glass substrate for use in photovoltaic device and method of making same |
| US20080308146A1 (en) * | 2007-06-14 | 2008-12-18 | Guardian Industries Corp. | Front electrode including pyrolytic transparent conductive coating on textured glass substrate for use in photovoltaic device and method of making same |
| FR2921357B1 (fr) * | 2007-09-21 | 2011-01-21 | Saint Gobain | Composition de verre silico-sodo-calcique |
| US7888594B2 (en) * | 2007-11-20 | 2011-02-15 | Guardian Industries Corp. | Photovoltaic device including front electrode having titanium oxide inclusive layer with high refractive index |
| US20090194157A1 (en) * | 2008-02-01 | 2009-08-06 | Guardian Industries Corp. | Front electrode having etched surface for use in photovoltaic device and method of making same |
| US20090194155A1 (en) * | 2008-02-01 | 2009-08-06 | Guardian Industries Corp. | Front electrode having etched surface for use in photovoltaic device and method of making same |
| US8671717B2 (en) * | 2008-03-06 | 2014-03-18 | Guardian Industries Corp. | Photovoltaic device having low iron high transmission glass with lithium oxide for reducing seed free time and corresponding method |
| KR101477282B1 (ko) * | 2008-05-13 | 2014-12-31 | 한국전자통신연구원 | 방송 정보 획득 방법 |
| US8022291B2 (en) * | 2008-10-15 | 2011-09-20 | Guardian Industries Corp. | Method of making front electrode of photovoltaic device having etched surface and corresponding photovoltaic device |
| US8304358B2 (en) * | 2008-11-21 | 2012-11-06 | Ppg Industries Ohio, Inc. | Method of reducing redox ratio of molten glass and the glass made thereby |
| KR101030356B1 (ko) * | 2008-12-08 | 2011-04-20 | 삼성전기주식회사 | 반도체 패키지의 제조 방법 |
| US20100154867A1 (en) * | 2008-12-19 | 2010-06-24 | E. I. Du Pont De Nemours And Company | Mechanically reliable solar cell modules |
| FR2942623B1 (fr) * | 2009-02-27 | 2012-05-25 | Saint Gobain | Feuille de verre |
| US20100255980A1 (en) | 2009-04-03 | 2010-10-07 | Guardian Industires Corp. | Low iron high transmission glass with boron oxide for improved optics, durability and refining, and corresponding method |
| EP2440501A2 (en) | 2009-06-12 | 2012-04-18 | Air Products and Chemicals, Inc. | Furnace and process for controlling the oxidative state of molten materials |
| US8858748B2 (en) * | 2009-08-27 | 2014-10-14 | Guardian Industries Corp. | Electrochromic devices, assemblies incorporating electrochromic devices, and/or methods of making the same |
| CN102019165B (zh) * | 2009-09-09 | 2013-09-18 | 中国科学院生态环境研究中心 | 一种复合金属氧化物除砷吸附剂及其制备方法 |
| US8833950B2 (en) | 2010-01-19 | 2014-09-16 | Guardian Industries Corp. | Secondary reflector panel (SRP) with heat-treatable coating for concentrated solar power applications, and/or methods of making the same |
| US20110180130A1 (en) * | 2010-01-22 | 2011-07-28 | Guardian Industries Corp. | Highly-conductive and textured front transparent electrode for a-si thin-film solar cells, and/or method of making the same |
| US8939606B2 (en) | 2010-02-26 | 2015-01-27 | Guardian Industries Corp. | Heatable lens for luminaires, and/or methods of making the same |
| US10294672B2 (en) | 2010-04-26 | 2019-05-21 | Guardian Glass, LLC | Multifunctional photovoltaic skylight with dynamic solar heat gain coefficient and/or methods of making the same |
| US9151879B2 (en) | 2010-04-26 | 2015-10-06 | Guardian Industries Corp. | Multi-functional photovoltaic skylight and/or methods of making the same |
| US8609455B2 (en) | 2010-04-26 | 2013-12-17 | Guardian Industries Corp. | Patterned glass cylindrical lens arrays for concentrated photovoltaic systems, and/or methods of making the same |
| US9423533B2 (en) * | 2010-04-26 | 2016-08-23 | Guardian Industries Corp. | Patterned glass cylindrical lens arrays for concentrated photovoltaic systems, and/or methods of making the same |
| US9574352B2 (en) | 2010-04-26 | 2017-02-21 | Guardian Industries Corp. | Multifunctional static or semi-static photovoltaic skylight and/or methods of making the same |
| CN103153892B (zh) * | 2010-05-20 | 2016-05-18 | 法国圣戈班玻璃厂 | 用于高温应用的玻璃基材 |
| US20110290295A1 (en) | 2010-05-28 | 2011-12-01 | Guardian Industries Corp. | Thermoelectric/solar cell hybrid coupled via vacuum insulated glazing unit, and method of making the same |
| KR100990875B1 (ko) * | 2010-07-02 | 2010-11-01 | 군산대학교산학협력단 | 무알카리 알루미나 붕규산염계 디스플레이 파유리를 원료로 하는 태양전지용 저철분 판유리 뱃지조성물 |
| US8664132B2 (en) | 2010-09-03 | 2014-03-04 | Ppg Industries Ohio, Inc. | High transmittance glass |
| US8693097B2 (en) | 2010-09-03 | 2014-04-08 | Guardian Industries Corp. | Temperable three layer antireflective coating, coated article including temperable three layer antireflective coating, and/or method of making the same |
| US9796619B2 (en) | 2010-09-03 | 2017-10-24 | Guardian Glass, LLC | Temperable three layer antirefrlective coating, coated article including temperable three layer antirefrlective coating, and/or method of making the same |
| US8354586B2 (en) | 2010-10-01 | 2013-01-15 | Guardian Industries Corp. | Transparent conductor film stack with cadmium stannate, corresponding photovoltaic device, and method of making same |
| US9566765B2 (en) | 2010-10-08 | 2017-02-14 | Guardian Industries Corp. | Radiation curable adhesives for reflective laminated solar panels, laminated solar panels including radiation curable adhesives, and/or associated methods |
| US20120087029A1 (en) | 2010-10-08 | 2012-04-12 | Guardian Industries Corp. | Mirrors for concentrating solar power (CSP) or concentrating photovoltaic (CPV) applications, and/or methods of making the same |
| US20120090246A1 (en) | 2010-10-15 | 2012-04-19 | Guardian Industries Corp. | Refrigerator/freezer door, and/or method of making the same |
| US8541792B2 (en) | 2010-10-15 | 2013-09-24 | Guardian Industries Corp. | Method of treating the surface of a soda lime silica glass substrate, surface-treated glass substrate, and device incorporating the same |
| US9312417B2 (en) | 2010-10-22 | 2016-04-12 | Guardian Industries Corp. | Photovoltaic modules, and/or methods of making the same |
| US8834664B2 (en) | 2010-10-22 | 2014-09-16 | Guardian Industries Corp. | Photovoltaic modules for use in vehicle roofs, and/or methods of making the same |
| US8668990B2 (en) | 2011-01-27 | 2014-03-11 | Guardian Industries Corp. | Heat treatable four layer anti-reflection coating |
| US8247686B2 (en) | 2011-05-31 | 2012-08-21 | Primestar Solar, Inc. | Multi-layer N-type stack for cadmium telluride based thin film photovoltaic devices and methods of making |
| US8241930B2 (en) | 2011-05-31 | 2012-08-14 | Primestar Solar, Inc. | Methods of forming a window layer in a cadmium telluride based thin film photovoltaic device |
| US8188562B2 (en) | 2011-05-31 | 2012-05-29 | Primestar Solar, Inc. | Multi-layer N-type stack for cadmium telluride based thin film photovoltaic devices and methods of making |
| WO2013004470A2 (fr) * | 2011-07-04 | 2013-01-10 | Agc Glass Europe | Feuille de verre flotte a haute transmission energetique |
| CN102351424A (zh) * | 2011-07-21 | 2012-02-15 | 长春理工大学 | 薄膜太阳能电池衬底用稀土掺杂硼酸盐发光玻璃 |
| US8742655B2 (en) | 2011-07-22 | 2014-06-03 | Guardian Industries Corp. | LED lighting systems with phosphor subassemblies, and/or methods of making the same |
| US9845943B2 (en) | 2011-07-22 | 2017-12-19 | Guardian Glass, LLC | Heat management subsystems for LED lighting systems, LED lighting systems including heat management subsystems, and/or methods of making the same |
| US8992045B2 (en) | 2011-07-22 | 2015-03-31 | Guardian Industries Corp. | LED lighting systems and/or methods of making the same |
| US8540394B2 (en) | 2011-07-22 | 2013-09-24 | Guardian Industries Corp. | Collimating lenses for LED lighting systems, LED lighting systems including collimating lenses, and/or methods of making the same |
| US9202958B2 (en) | 2011-11-03 | 2015-12-01 | Guardian Industries Corp. | Photovoltaic systems and associated components that are used on buildings and/or associated methods |
| US9556069B2 (en) | 2011-12-28 | 2017-01-31 | Centre Luxembourgeois De Recherches Pour Le Verre Et La Ceramique (C.R.V.C.) Sarl | Mirror with optional protective paint layer, and/or methods of making the same |
| US9341748B2 (en) | 2011-12-28 | 2016-05-17 | Guardian Industries Corp. | Mirror for use in humid environments, and/or method of making the same |
| US9082914B2 (en) | 2012-01-13 | 2015-07-14 | Gaurdian Industries Corp. | Photovoltaic module including high contact angle coating on one or more outer surfaces thereof, and/or methods of making the same |
| US20130196139A1 (en) | 2012-01-30 | 2013-08-01 | Mark A. Lewis | Coated article with antireflection coating including fullerene structures, and/or methods of making the same |
| US9054245B2 (en) | 2012-03-02 | 2015-06-09 | First Solar, Inc. | Doping an absorber layer of a photovoltaic device via diffusion from a window layer |
| EP2834557A2 (en) | 2012-04-02 | 2015-02-11 | Guardian Industries Corp. | Heatable lens for luminaires, and/or methods of making the same |
| DE112013002119T5 (de) | 2012-04-18 | 2014-12-31 | Guardian Industries Corp. | Verbesserte photovoltaische Module zur Verwendung in Fahrzeugdächern und/oder Verfahren zu ihrer Herstellung |
| US10059622B2 (en) | 2012-05-07 | 2018-08-28 | Guardian Glass, LLC | Anti-reflection glass with tin oxide nanoparticles |
| US8608525B1 (en) | 2012-06-05 | 2013-12-17 | Guardian Industries Corp. | Coated articles and/or devices with optical out-coupling layer stacks (OCLS), and/or methods of making the same |
| US9332862B2 (en) | 2012-11-30 | 2016-05-10 | Guardian Industries Corp. | Refrigerator door/window |
| US9181455B2 (en) | 2012-12-03 | 2015-11-10 | Guardian Industries Corp. | Method of making hydrophobic coated article, coated article including hydrophobic coatings, and/or sol compositions for use in the same |
| EP2752386B1 (en) | 2012-12-13 | 2019-08-28 | Guardian Glass, LLC | Method of making coated article including anti-reflection coating with porosity differences in two layers, and products containing the same |
| EP2752387B1 (en) | 2012-12-13 | 2018-06-27 | Guardian Glass, LLC | Method of making coated article including anti-reflection coating with double coating layers including mesoporous materials, and products containing the same |
| US20140186613A1 (en) | 2012-12-27 | 2014-07-03 | Guardian Industries Corp. | Anti-reflection coatings with self-cleaning properties, substrates including such coatings, and related methods |
| US9263701B2 (en) | 2013-03-14 | 2016-02-16 | Guardian Industries Corp. | Coated article and/or device with optical out-coupling layer stack (OCLS) including vacuum deposited index match layer over scattering matrix, and/or associated methods |
| US20140309099A1 (en) * | 2013-04-15 | 2014-10-16 | Ppg Industries Ohio, Inc. | Low iron, high redox ratio, and high iron, high redox ratio, soda-lime-silica glasses and methods of making same |
| EP3049589A1 (en) | 2013-09-24 | 2016-08-03 | Guardian Industries Corp. | Multifunctional photovoltaic skylight with dynamic solar heat gain coefficient and/or methods of making the same |
| EP2873653A1 (fr) * | 2013-11-18 | 2015-05-20 | AGC Glass Europe | Feuille de verre à haute transmission aux rayonnements infrarouges |
| KR20170033351A (ko) | 2014-07-17 | 2017-03-24 | 에이쥐씨 글래스 유럽 | 적외선에서 높은 투과율을 갖는 유리 시트 |
| GB201505091D0 (en) | 2015-03-26 | 2015-05-06 | Pilkington Group Ltd | Glass |
| WO2018178278A1 (en) * | 2017-03-30 | 2018-10-04 | Agc Glass Europe | Glass for autonomous car |
| CN109399924A (zh) * | 2018-11-28 | 2019-03-01 | 四川华晶玻璃有限公司 | 一种高白料玻璃及其生产工艺 |
| TW202035311A (zh) * | 2019-01-29 | 2020-10-01 | 美商康寧公司 | 在玻璃組成物之處理期間減少鉻氧化態的方法 |
| CN115052844A (zh) | 2020-02-03 | 2022-09-13 | 维特罗平板玻璃有限责任公司 | 具有高可见光透射率的钠钙硅玻璃 |
Family Cites Families (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4510344A (en) * | 1983-12-19 | 1985-04-09 | Atlantic Richfield Company | Thin film solar cell substrate |
| DE3528087C2 (de) * | 1984-08-06 | 1995-02-09 | Showa Aluminum Corp | Substrat für Solarzellen aus amorphem Silicium |
| US5214008A (en) * | 1992-04-17 | 1993-05-25 | Guardian Industries Corp. | High visible, low UV and low IR transmittance green glass composition |
| JP2504378B2 (ja) | 1993-10-22 | 1996-06-05 | 株式会社日立製作所 | 太陽電池基板の製造方法 |
| CZ279603B6 (cs) | 1993-11-03 | 1995-05-17 | Vysoká Škola Chemicko-Technologická | Křišťálové bezolovnaté sklo s indexem lomu vyšším než 1,52 |
| JP3431776B2 (ja) * | 1995-11-13 | 2003-07-28 | シャープ株式会社 | 太陽電池用基板の製造方法および太陽電池用基板加工装置 |
| JPH10335684A (ja) * | 1997-05-30 | 1998-12-18 | Canon Inc | 光電気変換体の製造方法 |
| JP3079506B2 (ja) | 1997-08-06 | 2000-08-21 | 東洋ガラス株式会社 | 紫外線吸収無色透明ガラス |
| US6222117B1 (en) * | 1998-01-05 | 2001-04-24 | Canon Kabushiki Kaisha | Photovoltaic device, manufacturing method of photovoltaic device, photovoltaic device integrated with building material and power-generating apparatus |
| JP4010053B2 (ja) | 1998-04-15 | 2007-11-21 | 旭硝子株式会社 | 太陽電池用カバーガラス及びその製造方法並びに太陽電池 |
| WO2000012441A1 (fr) | 1998-08-26 | 2000-03-09 | Nihon Yamamura Glass Co., Ltd. | Verre sodo-calcique transparent incolore absorbant les ultraviolets |
| US6461736B1 (en) | 1998-09-04 | 2002-10-08 | Nippon Sheet Glass Co., Ltd. | Light-colored glass of high transmittance and method for production thereof, glass plate with electrically conductive film and method for production thereof, and glass article |
| EP1013620A1 (fr) * | 1998-12-22 | 2000-06-28 | Glaverbel | Verre sodo-calcique à nuance bleue |
| US6235666B1 (en) * | 1999-03-29 | 2001-05-22 | Guardian Industries Corporation | Grey glass composition and method of making same |
| EP2261183B1 (en) | 2000-03-06 | 2015-02-25 | Nippon Sheet Glass Company, Limited | High transmittance glass sheet and method of manufacture the same |
| US6796146B2 (en) * | 2000-06-02 | 2004-09-28 | Guardian Industries Corp. | Method for manufacturing patterned glass products |
| US6372327B1 (en) * | 2000-06-02 | 2002-04-16 | Guardian Industries Corp. | Method and apparatus for manufacturing patterned glass products which simulate glue chipped glass |
| US6521558B2 (en) * | 2001-01-23 | 2003-02-18 | Guardian Industries Corp. | Grey glass composition including erbium |
| US6573207B2 (en) * | 2001-01-23 | 2003-06-03 | Guardian Industries Corp. | Grey glass composition including erbium |
| US6498118B1 (en) * | 2001-06-27 | 2002-12-24 | Guardian Industries Corp. | Grey glass composition including erbium and holmium |
| KR100847618B1 (ko) * | 2001-09-05 | 2008-07-21 | 니혼 이타가라스 가부시키가이샤 | 고 투과 글래스판 및 고 투과 글래스판의 제조방법 |
| US6716780B2 (en) * | 2001-09-26 | 2004-04-06 | Guardian Industries Corp. | Grey glass composition including erbium, holmium, and/or yttrium |
| US7037869B2 (en) * | 2002-01-28 | 2006-05-02 | Guardian Industries Corp. | Clear glass composition |
| US7144837B2 (en) * | 2002-01-28 | 2006-12-05 | Guardian Industries Corp. | Clear glass composition with high visible transmittance |
| US7169722B2 (en) * | 2002-01-28 | 2007-01-30 | Guardian Industries Corp. | Clear glass composition with high visible transmittance |
| US6610622B1 (en) * | 2002-01-28 | 2003-08-26 | Guardian Industries Corp. | Clear glass composition |
| US7151065B2 (en) * | 2003-07-21 | 2006-12-19 | Guardian Industries Corp. | Grey glass composition |
| US7601660B2 (en) * | 2004-03-01 | 2009-10-13 | Guardian Industries Corp. | Clear glass composition |
| US7700869B2 (en) | 2005-02-03 | 2010-04-20 | Guardian Industries Corp. | Solar cell low iron patterned glass and method of making same |
| US7700870B2 (en) | 2005-05-05 | 2010-04-20 | Guardian Industries Corp. | Solar cell using low iron high transmission glass with antimony and corresponding method |
| US7557053B2 (en) | 2006-03-13 | 2009-07-07 | Guardian Industries Corp. | Low iron high transmission float glass for solar cell applications and method of making same |
| US8648252B2 (en) * | 2006-03-13 | 2014-02-11 | Guardian Industries Corp. | Solar cell using low iron high transmission glass and corresponding method |
-
2006
- 2006-10-17 US US11/581,784 patent/US7557053B2/en not_active Expired - Fee Related
-
2007
- 2007-01-22 RU RU2008140311/03A patent/RU2443642C2/ru not_active IP Right Cessation
- 2007-01-22 EP EP07749006A patent/EP1993961A1/en not_active Withdrawn
- 2007-01-22 WO PCT/US2007/001565 patent/WO2007106223A1/en not_active Ceased
- 2007-01-22 BR BRPI0709394-2A patent/BRPI0709394A2/pt not_active IP Right Cessation
- 2007-01-22 CA CA002641929A patent/CA2641929A1/en not_active Abandoned
-
2009
- 2009-05-05 US US12/453,275 patent/US7893350B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| BRPI0709394A2 (pt) | 2011-07-05 |
| US20070209698A1 (en) | 2007-09-13 |
| US7557053B2 (en) | 2009-07-07 |
| CA2641929A1 (en) | 2007-09-20 |
| WO2007106223A1 (en) | 2007-09-20 |
| RU2443642C2 (ru) | 2012-02-27 |
| EP1993961A1 (en) | 2008-11-26 |
| US20090217978A1 (en) | 2009-09-03 |
| US7893350B2 (en) | 2011-02-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| RU2008140311A (ru) | Маложелезистое высокопропускающее флоат-стекло для применения в солнечных элементах и способ его изготовления | |
| RU2008140316A (ru) | Солнечный элемент, использующий ультрапрозрачное стекло с низким содержанием железа, и соответствующий способ | |
| CN101462825B (zh) | 超白浮法玻璃 | |
| KR101517257B1 (ko) | 실리카-소다-석회 유리 시트 | |
| US6235667B1 (en) | Vitrifiable mixture for quality glasses | |
| US7700870B2 (en) | Solar cell using low iron high transmission glass with antimony and corresponding method | |
| US7700869B2 (en) | Solar cell low iron patterned glass and method of making same | |
| US9324894B2 (en) | Glass sheet with high energy transmission | |
| US8671717B2 (en) | Photovoltaic device having low iron high transmission glass with lithium oxide for reducing seed free time and corresponding method | |
| JP5694935B2 (ja) | ガラスを得るための方法及び得られたガラス | |
| RU2008113375A (ru) | Состав поглощающего ультрафиолетовый свет серого стекла | |
| RU2010147651A (ru) | Стекловолокна и композитные материалы с органической и/или неорганической матрицей, содержащие указанные волокна | |
| CN104024170A (zh) | 玻璃 | |
| RU2013114782A (ru) | Стекло с высокой пропускающей способностью | |
| KR20140064713A (ko) | 광전지용 기판 | |
| US10683231B2 (en) | Glasses | |
| RU2008107698A (ru) | Композиция зеленого стекла и ее применение | |
| JP2023532745A (ja) | 環境配慮型ガラス材料 | |
| US20180099895A1 (en) | Glasses | |
| US8318621B2 (en) | Silico-sodo-calcic glass sheet | |
| RU2009118597A (ru) | Натриево-кальциево-силикатное стекло, пропускающее ультрафиолет | |
| US20180099896A1 (en) | Novel glasses | |
| US20180099897A1 (en) | Glasses | |
| CN107651836A (zh) | 钾钡晶质玻璃器皿 | |
| CN103508669A (zh) | 一种抗紫外线光伏玻璃及其应用 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | The patent is invalid due to non-payment of fees |
Effective date: 20150123 |