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RU2008140311A - Маложелезистое высокопропускающее флоат-стекло для применения в солнечных элементах и способ его изготовления - Google Patents

Маложелезистое высокопропускающее флоат-стекло для применения в солнечных элементах и способ его изготовления Download PDF

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RU2008140311A
RU2008140311A RU2008140311/03A RU2008140311A RU2008140311A RU 2008140311 A RU2008140311 A RU 2008140311A RU 2008140311/03 A RU2008140311/03 A RU 2008140311/03A RU 2008140311 A RU2008140311 A RU 2008140311A RU 2008140311 A RU2008140311 A RU 2008140311A
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glass
oxide
redox
feo
glass substrate
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RU2443642C2 (ru
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Ксения А. ЛЭНДА (US)
Ксения А. ЛЭНДА
Скотт В. ТОМСЕН (US)
Скотт В. ТОМСЕН
Ричард ХУЛЬМ (US)
Ричард ХУЛЬМ
Леонид М. ЛЭНДА (US)
Леонид М. ЛЭНДА
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Гардиан Индастриз Корп. (Us)
Гардиан Индастриз Корп.
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    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00Glass compositions
    • C03C3/04Glass compositions containing silica
    • C03C3/076Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/083Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound
    • C03C3/085Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal
    • C03C3/087Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal containing calcium oxide, e.g. common sheet or container glass
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3668Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having electrical properties
    • C03C17/3678Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having electrical properties specially adapted for use in solar cells
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C4/00Compositions for glass with special properties
    • C03C4/0092Compositions for glass with special properties for glass with improved high visible transmittance, e.g. extra-clear glass
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C4/00Compositions for glass with special properties
    • C03C4/10Compositions for glass with special properties for infrared transmitting glass
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10FINORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F77/00Constructional details of devices covered by this subclass
    • H10F77/10Semiconductor bodies
    • H10F77/16Material structures, e.g. crystalline structures, film structures or crystal plane orientations
    • H10F77/169Thin semiconductor films on metallic or insulating substrates
    • H10F77/1692Thin semiconductor films on metallic or insulating substrates the films including only Group IV materials
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10FINORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F77/00Constructional details of devices covered by this subclass
    • H10F77/70Surface textures, e.g. pyramid structures
    • H10F77/707Surface textures, e.g. pyramid structures of the substrates or of layers on substrates, e.g. textured ITO layer on a glass substrate
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/90Other aspects of coatings
    • C03C2217/94Transparent conductive oxide layers [TCO] being part of a multilayer coating
    • C03C2217/944Layers comprising zinc oxide
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy

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  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Sustainable Development (AREA)
  • Glass Compositions (AREA)

Abstract

1. Способ изготовления стекла, содержащего ! Ингредиент мас.% SiO2 67-75% Na2O 10-20% CaO 5-15% общее железо (выраженное как Fe2O3) от 0,001 до 0,1% %FeO от 0 до 0,005 ! где данное стекло имеет пропускание в видимой области, по меньшей мере, приблизительно 90%, величину проходящего а* цвета от -1,0 до +1,0, величину проходящего b* цвета от -0,50 до +1,5, %ПС, по меньшей мере, 89,5%, причем в способе используют редокс шихты от +26 до +40 при изготовлении упомянутого стекла. ! 2. Способ по п.1, где редокс шихты составляет от +27 до +35. ! 3. Способ по п.1, где редокс шихты составляет от +28 до +33. ! 4. Способ по п.1, где данное стекло содержит ! %FeO ≤0,004% редокс стекла ≤0,06 ИК пропускание (%ИК) ≥90% ! 5. Способ по п.1, где в данном способе дополнительно используют надлежащие материалы в шихте, используемой при изготовлении данного стекла, так что стекло содержит, по меньшей мере, 0,27% SO3. ! 6. Способ по п.5, где стекло содержит от 0,30 до 0,50% SO3. ! 7. Способ по п.5, где стекло содержит, по меньшей мере, 0,32% SO3. ! 8. Способ по п.1, где стеклянная подложка имеет %ПС, по меньшей мере, 90% и содержит ! %FeO ≤0,004% редокс стекла ≤0,06 ! 9. Способ по п.1, где стеклянная подложка содержит не более 2 ч./млн, по меньшей мере, двух соединений из оксида эрбия, оксида никеля, оксида кобальта, оксида неодима, оксида хрома и селена. ! 10. Способ по п.1, где стеклянная подложка содержит не более 2 ч./млн, по меньшей мере, четырех соединений из оксида эрбия, оксида никеля, оксида кобальта, оксида неодима, оксида хрома и селена. !11. Способ по п.1, где стеклянная подложка содержит не более 2 ч./млн, по меньшей мере, пяти соединений из оксида эрбия, оксида никеля, оксида кобальта, оксида неодима, оксида хрома и селена. ! 12. Способ по

Claims (27)

1. Способ изготовления стекла, содержащего
Ингредиент мас.% SiO2 67-75% Na2O 10-20% CaO 5-15% общее железо (выраженное как Fe2O3) от 0,001 до 0,1% %FeO от 0 до 0,005
где данное стекло имеет пропускание в видимой области, по меньшей мере, приблизительно 90%, величину проходящего а* цвета от -1,0 до +1,0, величину проходящего b* цвета от -0,50 до +1,5, %ПС, по меньшей мере, 89,5%, причем в способе используют редокс шихты от +26 до +40 при изготовлении упомянутого стекла.
2. Способ по п.1, где редокс шихты составляет от +27 до +35.
3. Способ по п.1, где редокс шихты составляет от +28 до +33.
4. Способ по п.1, где данное стекло содержит
%FeO ≤0,004% редокс стекла ≤0,06 ИК пропускание (%ИК) ≥90%
5. Способ по п.1, где в данном способе дополнительно используют надлежащие материалы в шихте, используемой при изготовлении данного стекла, так что стекло содержит, по меньшей мере, 0,27% SO3.
6. Способ по п.5, где стекло содержит от 0,30 до 0,50% SO3.
7. Способ по п.5, где стекло содержит, по меньшей мере, 0,32% SO3.
8. Способ по п.1, где стеклянная подложка имеет %ПС, по меньшей мере, 90% и содержит
%FeO ≤0,004% редокс стекла ≤0,06
9. Способ по п.1, где стеклянная подложка содержит не более 2 ч./млн, по меньшей мере, двух соединений из оксида эрбия, оксида никеля, оксида кобальта, оксида неодима, оксида хрома и селена.
10. Способ по п.1, где стеклянная подложка содержит не более 2 ч./млн, по меньшей мере, четырех соединений из оксида эрбия, оксида никеля, оксида кобальта, оксида неодима, оксида хрома и селена.
11. Способ по п.1, где стеклянная подложка содержит не более 2 ч./млн, по меньшей мере, пяти соединений из оксида эрбия, оксида никеля, оксида кобальта, оксида неодима, оксида хрома и селена.
12. Способ по п.1, где стеклянная подложка содержит не более 2 ч./млн, по меньшей мере, каждого соединения из оксида эрбия, оксида никеля, оксида кобальта, оксида неодима, оксида хрома и селена.
13. Способ по п.1, где стекло содержит от 0 до 0,07% оксида церия.
14. Способ по п.1, где стекло содержит от 0 до 0,05% оксида церия.
15. Способ по п.1, где стекло содержит от 0 до менее чем 0,01% оксида сурьмы.
16. Солнечный элемент, содержащий
стеклянную подложку;
первый и второй проводящие слои с, по меньшей мере, фотоэлектрической пленкой, расположенной между ними;
где стеклянная подложка имеет следующий состав:
Ингредиент мас.% SiO2 67-75% Na2O 10-20% CaO 5-15% общее железо (выраженное как Fe2O3) ≤0,1% %FeO ≤0,005 редокс стекла ≤0,08 оксид сурьмы от 0 до менее чем 0,01% оксид церия от 0 до 0,07%
где данное стекло имеет пропускание в видимой области, по меньшей мере, 90%, ПС пропускание, по меньшей мере, 90%; величину проходящего а* цвета от -1,0 до +1,0, величину проходящего b* цвета от -0,5 до +1,5.
17. Солнечный элемент по п.16, где стеклянная подложка содержит
%FeO ≤0,003% редокс стекла ≤0,06
18. Солнечный элемент по п.16, где стеклянная подложка имеет %ПС, по меньшей мере, 91% и содержит
%FeO ≤0,002%
редокс стекла ≤0,04
19. Солнечный элемент по п.16, где стекло содержит, по меньшей мере, 0,27% SO3, более предпочтительно от 0,30 до 0,50% SO3.
20. Солнечный элемент по п.16, где стеклянная подложка содержит не более 2 ч./млн, по меньшей мере, двух, более предпочтительно, по меньшей мере, трех, даже более предпочтительно, по меньшей мере, четырех, и наиболее предпочтительно, по меньшей мере, пяти соединений из оксида эрбия, оксида никеля, оксида кобальта, оксида неодима, оксида хрома и селена.
21. Солнечный элемент по п.16, где стекло содержит от 0 до 0,05% оксида церия, более предпочтительно, не больше, чем 0,01% оксида церия.
22. Стекло, содержащее
Ингредиент мас.% SiO2 67-75% Na2O 10-20% CaO 5-15% общее железо (выраженное как Fe2O3) ≤0,1% %FeO ≤0,005 редокс стекла ≤0,08 оксид сурьмы от 0 до менее чем 0,01% оксид церия от 0 до 0,07%
где данное стекло имеет пропускание в видимой области, по меньшей мере, 90%, ПС пропускание, по меньшей мере, 90%; величину проходящего а* цвета от -1,0 до +1,0, величину проходящего b* цвета от -0,5 до +1,5.
23. Стекло по п.22, где данное стекло содержит
%FeO ≤0,003% редокс стекла ≤0,06
24. Стекло по п.22, где данное стекло имеет %ПС, по меньшей мере, 91% и содержит
%FeO ≤0,002% редокс стекла ≤0,04
25. Стекло по п.22, где данное стекло содержит, по меньшей мере, 0,27% SO3, более предпочтительно от 0,30 до 0,50% SO3.
26. Стекло по п.22, где данное стекло содержит не более 2 ч./млн, по меньшей мере, двух, более предпочтительно, по меньшей мере, трех, даже более предпочтительно, по меньшей мере, четырех, и наиболее предпочтительно, по меньшей мере, пяти соединений из оксида эрбия, оксида никеля, оксида кобальта, оксида неодима, оксида хрома и селена.
27. Стекло по п.22, где данное стекло содержит от 0 до 0,05% оксида церия, более предпочтительно, не больше, чем 0,01% оксида церия.
RU2008140311/03A 2006-03-13 2007-01-22 Маложелезистое высокопропускающее флоат-стекло для применения в солнечных элементах и способ его изготовления RU2443642C2 (ru)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US11/373,490 US8648252B2 (en) 2006-03-13 2006-03-13 Solar cell using low iron high transmission glass and corresponding method
US11/373,490 2006-03-13
US11/581,784 2006-10-17
US11/581,784 US7557053B2 (en) 2006-03-13 2006-10-17 Low iron high transmission float glass for solar cell applications and method of making same

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RU2443642C2 RU2443642C2 (ru) 2012-02-27

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EP (1) EP1993961A1 (ru)
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Families Citing this family (89)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7700870B2 (en) * 2005-05-05 2010-04-20 Guardian Industries Corp. Solar cell using low iron high transmission glass with antimony and corresponding method
US20070207912A1 (en) * 2006-03-02 2007-09-06 Guardian Industries Corp. Method of making glass including use of boron oxide for reducing glass refining time
US8648252B2 (en) * 2006-03-13 2014-02-11 Guardian Industries Corp. Solar cell using low iron high transmission glass and corresponding method
US7557053B2 (en) * 2006-03-13 2009-07-07 Guardian Industries Corp. Low iron high transmission float glass for solar cell applications and method of making same
US20080178932A1 (en) * 2006-11-02 2008-07-31 Guardian Industries Corp. Front electrode including transparent conductive coating on patterned glass substrate for use in photovoltaic device and method of making same
US20080105293A1 (en) * 2006-11-02 2008-05-08 Guardian Industries Corp. Front electrode for use in photovoltaic device and method of making same
US20080105298A1 (en) * 2006-11-02 2008-05-08 Guardian Industries Corp. Front electrode for use in photovoltaic device and method of making same
US20080302414A1 (en) * 2006-11-02 2008-12-11 Den Boer Willem Front electrode for use in photovoltaic device and method of making same
US20080105299A1 (en) * 2006-11-02 2008-05-08 Guardian Industries Corp. Front electrode with thin metal film layer and high work-function buffer layer for use in photovoltaic device and method of making same
US8012317B2 (en) * 2006-11-02 2011-09-06 Guardian Industries Corp. Front electrode including transparent conductive coating on patterned glass substrate for use in photovoltaic device and method of making same
US8203073B2 (en) * 2006-11-02 2012-06-19 Guardian Industries Corp. Front electrode for use in photovoltaic device and method of making same
US8076571B2 (en) * 2006-11-02 2011-12-13 Guardian Industries Corp. Front electrode for use in photovoltaic device and method of making same
US7964788B2 (en) * 2006-11-02 2011-06-21 Guardian Industries Corp. Front electrode for use in photovoltaic device and method of making same
US8334452B2 (en) * 2007-01-08 2012-12-18 Guardian Industries Corp. Zinc oxide based front electrode doped with yttrium for use in photovoltaic device or the like
US20080169021A1 (en) * 2007-01-16 2008-07-17 Guardian Industries Corp. Method of making TCO front electrode for use in photovoltaic device or the like
US20080223430A1 (en) * 2007-03-14 2008-09-18 Guardian Industries Corp. Buffer layer for front electrode structure in photovoltaic device or the like
US20080308145A1 (en) * 2007-06-12 2008-12-18 Guardian Industries Corp Front electrode including transparent conductive coating on etched glass substrate for use in photovoltaic device and method of making same
US20080308146A1 (en) * 2007-06-14 2008-12-18 Guardian Industries Corp. Front electrode including pyrolytic transparent conductive coating on textured glass substrate for use in photovoltaic device and method of making same
FR2921357B1 (fr) * 2007-09-21 2011-01-21 Saint Gobain Composition de verre silico-sodo-calcique
US7888594B2 (en) * 2007-11-20 2011-02-15 Guardian Industries Corp. Photovoltaic device including front electrode having titanium oxide inclusive layer with high refractive index
US20090194157A1 (en) * 2008-02-01 2009-08-06 Guardian Industries Corp. Front electrode having etched surface for use in photovoltaic device and method of making same
US20090194155A1 (en) * 2008-02-01 2009-08-06 Guardian Industries Corp. Front electrode having etched surface for use in photovoltaic device and method of making same
US8671717B2 (en) * 2008-03-06 2014-03-18 Guardian Industries Corp. Photovoltaic device having low iron high transmission glass with lithium oxide for reducing seed free time and corresponding method
KR101477282B1 (ko) * 2008-05-13 2014-12-31 한국전자통신연구원 방송 정보 획득 방법
US8022291B2 (en) * 2008-10-15 2011-09-20 Guardian Industries Corp. Method of making front electrode of photovoltaic device having etched surface and corresponding photovoltaic device
US8304358B2 (en) * 2008-11-21 2012-11-06 Ppg Industries Ohio, Inc. Method of reducing redox ratio of molten glass and the glass made thereby
KR101030356B1 (ko) * 2008-12-08 2011-04-20 삼성전기주식회사 반도체 패키지의 제조 방법
US20100154867A1 (en) * 2008-12-19 2010-06-24 E. I. Du Pont De Nemours And Company Mechanically reliable solar cell modules
FR2942623B1 (fr) * 2009-02-27 2012-05-25 Saint Gobain Feuille de verre
US20100255980A1 (en) 2009-04-03 2010-10-07 Guardian Industires Corp. Low iron high transmission glass with boron oxide for improved optics, durability and refining, and corresponding method
EP2440501A2 (en) 2009-06-12 2012-04-18 Air Products and Chemicals, Inc. Furnace and process for controlling the oxidative state of molten materials
US8858748B2 (en) * 2009-08-27 2014-10-14 Guardian Industries Corp. Electrochromic devices, assemblies incorporating electrochromic devices, and/or methods of making the same
CN102019165B (zh) * 2009-09-09 2013-09-18 中国科学院生态环境研究中心 一种复合金属氧化物除砷吸附剂及其制备方法
US8833950B2 (en) 2010-01-19 2014-09-16 Guardian Industries Corp. Secondary reflector panel (SRP) with heat-treatable coating for concentrated solar power applications, and/or methods of making the same
US20110180130A1 (en) * 2010-01-22 2011-07-28 Guardian Industries Corp. Highly-conductive and textured front transparent electrode for a-si thin-film solar cells, and/or method of making the same
US8939606B2 (en) 2010-02-26 2015-01-27 Guardian Industries Corp. Heatable lens for luminaires, and/or methods of making the same
US10294672B2 (en) 2010-04-26 2019-05-21 Guardian Glass, LLC Multifunctional photovoltaic skylight with dynamic solar heat gain coefficient and/or methods of making the same
US9151879B2 (en) 2010-04-26 2015-10-06 Guardian Industries Corp. Multi-functional photovoltaic skylight and/or methods of making the same
US8609455B2 (en) 2010-04-26 2013-12-17 Guardian Industries Corp. Patterned glass cylindrical lens arrays for concentrated photovoltaic systems, and/or methods of making the same
US9423533B2 (en) * 2010-04-26 2016-08-23 Guardian Industries Corp. Patterned glass cylindrical lens arrays for concentrated photovoltaic systems, and/or methods of making the same
US9574352B2 (en) 2010-04-26 2017-02-21 Guardian Industries Corp. Multifunctional static or semi-static photovoltaic skylight and/or methods of making the same
CN103153892B (zh) * 2010-05-20 2016-05-18 法国圣戈班玻璃厂 用于高温应用的玻璃基材
US20110290295A1 (en) 2010-05-28 2011-12-01 Guardian Industries Corp. Thermoelectric/solar cell hybrid coupled via vacuum insulated glazing unit, and method of making the same
KR100990875B1 (ko) * 2010-07-02 2010-11-01 군산대학교산학협력단 무알카리 알루미나 붕규산염계 디스플레이 파유리를 원료로 하는 태양전지용 저철분 판유리 뱃지조성물
US8664132B2 (en) 2010-09-03 2014-03-04 Ppg Industries Ohio, Inc. High transmittance glass
US8693097B2 (en) 2010-09-03 2014-04-08 Guardian Industries Corp. Temperable three layer antireflective coating, coated article including temperable three layer antireflective coating, and/or method of making the same
US9796619B2 (en) 2010-09-03 2017-10-24 Guardian Glass, LLC Temperable three layer antirefrlective coating, coated article including temperable three layer antirefrlective coating, and/or method of making the same
US8354586B2 (en) 2010-10-01 2013-01-15 Guardian Industries Corp. Transparent conductor film stack with cadmium stannate, corresponding photovoltaic device, and method of making same
US9566765B2 (en) 2010-10-08 2017-02-14 Guardian Industries Corp. Radiation curable adhesives for reflective laminated solar panels, laminated solar panels including radiation curable adhesives, and/or associated methods
US20120087029A1 (en) 2010-10-08 2012-04-12 Guardian Industries Corp. Mirrors for concentrating solar power (CSP) or concentrating photovoltaic (CPV) applications, and/or methods of making the same
US20120090246A1 (en) 2010-10-15 2012-04-19 Guardian Industries Corp. Refrigerator/freezer door, and/or method of making the same
US8541792B2 (en) 2010-10-15 2013-09-24 Guardian Industries Corp. Method of treating the surface of a soda lime silica glass substrate, surface-treated glass substrate, and device incorporating the same
US9312417B2 (en) 2010-10-22 2016-04-12 Guardian Industries Corp. Photovoltaic modules, and/or methods of making the same
US8834664B2 (en) 2010-10-22 2014-09-16 Guardian Industries Corp. Photovoltaic modules for use in vehicle roofs, and/or methods of making the same
US8668990B2 (en) 2011-01-27 2014-03-11 Guardian Industries Corp. Heat treatable four layer anti-reflection coating
US8247686B2 (en) 2011-05-31 2012-08-21 Primestar Solar, Inc. Multi-layer N-type stack for cadmium telluride based thin film photovoltaic devices and methods of making
US8241930B2 (en) 2011-05-31 2012-08-14 Primestar Solar, Inc. Methods of forming a window layer in a cadmium telluride based thin film photovoltaic device
US8188562B2 (en) 2011-05-31 2012-05-29 Primestar Solar, Inc. Multi-layer N-type stack for cadmium telluride based thin film photovoltaic devices and methods of making
WO2013004470A2 (fr) * 2011-07-04 2013-01-10 Agc Glass Europe Feuille de verre flotte a haute transmission energetique
CN102351424A (zh) * 2011-07-21 2012-02-15 长春理工大学 薄膜太阳能电池衬底用稀土掺杂硼酸盐发光玻璃
US8742655B2 (en) 2011-07-22 2014-06-03 Guardian Industries Corp. LED lighting systems with phosphor subassemblies, and/or methods of making the same
US9845943B2 (en) 2011-07-22 2017-12-19 Guardian Glass, LLC Heat management subsystems for LED lighting systems, LED lighting systems including heat management subsystems, and/or methods of making the same
US8992045B2 (en) 2011-07-22 2015-03-31 Guardian Industries Corp. LED lighting systems and/or methods of making the same
US8540394B2 (en) 2011-07-22 2013-09-24 Guardian Industries Corp. Collimating lenses for LED lighting systems, LED lighting systems including collimating lenses, and/or methods of making the same
US9202958B2 (en) 2011-11-03 2015-12-01 Guardian Industries Corp. Photovoltaic systems and associated components that are used on buildings and/or associated methods
US9556069B2 (en) 2011-12-28 2017-01-31 Centre Luxembourgeois De Recherches Pour Le Verre Et La Ceramique (C.R.V.C.) Sarl Mirror with optional protective paint layer, and/or methods of making the same
US9341748B2 (en) 2011-12-28 2016-05-17 Guardian Industries Corp. Mirror for use in humid environments, and/or method of making the same
US9082914B2 (en) 2012-01-13 2015-07-14 Gaurdian Industries Corp. Photovoltaic module including high contact angle coating on one or more outer surfaces thereof, and/or methods of making the same
US20130196139A1 (en) 2012-01-30 2013-08-01 Mark A. Lewis Coated article with antireflection coating including fullerene structures, and/or methods of making the same
US9054245B2 (en) 2012-03-02 2015-06-09 First Solar, Inc. Doping an absorber layer of a photovoltaic device via diffusion from a window layer
EP2834557A2 (en) 2012-04-02 2015-02-11 Guardian Industries Corp. Heatable lens for luminaires, and/or methods of making the same
DE112013002119T5 (de) 2012-04-18 2014-12-31 Guardian Industries Corp. Verbesserte photovoltaische Module zur Verwendung in Fahrzeugdächern und/oder Verfahren zu ihrer Herstellung
US10059622B2 (en) 2012-05-07 2018-08-28 Guardian Glass, LLC Anti-reflection glass with tin oxide nanoparticles
US8608525B1 (en) 2012-06-05 2013-12-17 Guardian Industries Corp. Coated articles and/or devices with optical out-coupling layer stacks (OCLS), and/or methods of making the same
US9332862B2 (en) 2012-11-30 2016-05-10 Guardian Industries Corp. Refrigerator door/window
US9181455B2 (en) 2012-12-03 2015-11-10 Guardian Industries Corp. Method of making hydrophobic coated article, coated article including hydrophobic coatings, and/or sol compositions for use in the same
EP2752386B1 (en) 2012-12-13 2019-08-28 Guardian Glass, LLC Method of making coated article including anti-reflection coating with porosity differences in two layers, and products containing the same
EP2752387B1 (en) 2012-12-13 2018-06-27 Guardian Glass, LLC Method of making coated article including anti-reflection coating with double coating layers including mesoporous materials, and products containing the same
US20140186613A1 (en) 2012-12-27 2014-07-03 Guardian Industries Corp. Anti-reflection coatings with self-cleaning properties, substrates including such coatings, and related methods
US9263701B2 (en) 2013-03-14 2016-02-16 Guardian Industries Corp. Coated article and/or device with optical out-coupling layer stack (OCLS) including vacuum deposited index match layer over scattering matrix, and/or associated methods
US20140309099A1 (en) * 2013-04-15 2014-10-16 Ppg Industries Ohio, Inc. Low iron, high redox ratio, and high iron, high redox ratio, soda-lime-silica glasses and methods of making same
EP3049589A1 (en) 2013-09-24 2016-08-03 Guardian Industries Corp. Multifunctional photovoltaic skylight with dynamic solar heat gain coefficient and/or methods of making the same
EP2873653A1 (fr) * 2013-11-18 2015-05-20 AGC Glass Europe Feuille de verre à haute transmission aux rayonnements infrarouges
KR20170033351A (ko) 2014-07-17 2017-03-24 에이쥐씨 글래스 유럽 적외선에서 높은 투과율을 갖는 유리 시트
GB201505091D0 (en) 2015-03-26 2015-05-06 Pilkington Group Ltd Glass
WO2018178278A1 (en) * 2017-03-30 2018-10-04 Agc Glass Europe Glass for autonomous car
CN109399924A (zh) * 2018-11-28 2019-03-01 四川华晶玻璃有限公司 一种高白料玻璃及其生产工艺
TW202035311A (zh) * 2019-01-29 2020-10-01 美商康寧公司 在玻璃組成物之處理期間減少鉻氧化態的方法
CN115052844A (zh) 2020-02-03 2022-09-13 维特罗平板玻璃有限责任公司 具有高可见光透射率的钠钙硅玻璃

Family Cites Families (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4510344A (en) * 1983-12-19 1985-04-09 Atlantic Richfield Company Thin film solar cell substrate
DE3528087C2 (de) * 1984-08-06 1995-02-09 Showa Aluminum Corp Substrat für Solarzellen aus amorphem Silicium
US5214008A (en) * 1992-04-17 1993-05-25 Guardian Industries Corp. High visible, low UV and low IR transmittance green glass composition
JP2504378B2 (ja) 1993-10-22 1996-06-05 株式会社日立製作所 太陽電池基板の製造方法
CZ279603B6 (cs) 1993-11-03 1995-05-17 Vysoká Škola Chemicko-Technologická Křišťálové bezolovnaté sklo s indexem lomu vyšším než 1,52
JP3431776B2 (ja) * 1995-11-13 2003-07-28 シャープ株式会社 太陽電池用基板の製造方法および太陽電池用基板加工装置
JPH10335684A (ja) * 1997-05-30 1998-12-18 Canon Inc 光電気変換体の製造方法
JP3079506B2 (ja) 1997-08-06 2000-08-21 東洋ガラス株式会社 紫外線吸収無色透明ガラス
US6222117B1 (en) * 1998-01-05 2001-04-24 Canon Kabushiki Kaisha Photovoltaic device, manufacturing method of photovoltaic device, photovoltaic device integrated with building material and power-generating apparatus
JP4010053B2 (ja) 1998-04-15 2007-11-21 旭硝子株式会社 太陽電池用カバーガラス及びその製造方法並びに太陽電池
WO2000012441A1 (fr) 1998-08-26 2000-03-09 Nihon Yamamura Glass Co., Ltd. Verre sodo-calcique transparent incolore absorbant les ultraviolets
US6461736B1 (en) 1998-09-04 2002-10-08 Nippon Sheet Glass Co., Ltd. Light-colored glass of high transmittance and method for production thereof, glass plate with electrically conductive film and method for production thereof, and glass article
EP1013620A1 (fr) * 1998-12-22 2000-06-28 Glaverbel Verre sodo-calcique à nuance bleue
US6235666B1 (en) * 1999-03-29 2001-05-22 Guardian Industries Corporation Grey glass composition and method of making same
EP2261183B1 (en) 2000-03-06 2015-02-25 Nippon Sheet Glass Company, Limited High transmittance glass sheet and method of manufacture the same
US6796146B2 (en) * 2000-06-02 2004-09-28 Guardian Industries Corp. Method for manufacturing patterned glass products
US6372327B1 (en) * 2000-06-02 2002-04-16 Guardian Industries Corp. Method and apparatus for manufacturing patterned glass products which simulate glue chipped glass
US6521558B2 (en) * 2001-01-23 2003-02-18 Guardian Industries Corp. Grey glass composition including erbium
US6573207B2 (en) * 2001-01-23 2003-06-03 Guardian Industries Corp. Grey glass composition including erbium
US6498118B1 (en) * 2001-06-27 2002-12-24 Guardian Industries Corp. Grey glass composition including erbium and holmium
KR100847618B1 (ko) * 2001-09-05 2008-07-21 니혼 이타가라스 가부시키가이샤 고 투과 글래스판 및 고 투과 글래스판의 제조방법
US6716780B2 (en) * 2001-09-26 2004-04-06 Guardian Industries Corp. Grey glass composition including erbium, holmium, and/or yttrium
US7037869B2 (en) * 2002-01-28 2006-05-02 Guardian Industries Corp. Clear glass composition
US7144837B2 (en) * 2002-01-28 2006-12-05 Guardian Industries Corp. Clear glass composition with high visible transmittance
US7169722B2 (en) * 2002-01-28 2007-01-30 Guardian Industries Corp. Clear glass composition with high visible transmittance
US6610622B1 (en) * 2002-01-28 2003-08-26 Guardian Industries Corp. Clear glass composition
US7151065B2 (en) * 2003-07-21 2006-12-19 Guardian Industries Corp. Grey glass composition
US7601660B2 (en) * 2004-03-01 2009-10-13 Guardian Industries Corp. Clear glass composition
US7700869B2 (en) 2005-02-03 2010-04-20 Guardian Industries Corp. Solar cell low iron patterned glass and method of making same
US7700870B2 (en) 2005-05-05 2010-04-20 Guardian Industries Corp. Solar cell using low iron high transmission glass with antimony and corresponding method
US7557053B2 (en) 2006-03-13 2009-07-07 Guardian Industries Corp. Low iron high transmission float glass for solar cell applications and method of making same
US8648252B2 (en) * 2006-03-13 2014-02-11 Guardian Industries Corp. Solar cell using low iron high transmission glass and corresponding method

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US7557053B2 (en) 2009-07-07
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WO2007106223A1 (en) 2007-09-20
RU2443642C2 (ru) 2012-02-27
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US20090217978A1 (en) 2009-09-03
US7893350B2 (en) 2011-02-22

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