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RU2006146060A - METHOD FOR PRODUCING GAS OIL BY CATALYTIC CRACKING OF FISCHER-TROPSH SYNTHESIS PRODUCT - Google Patents

METHOD FOR PRODUCING GAS OIL BY CATALYTIC CRACKING OF FISCHER-TROPSH SYNTHESIS PRODUCT Download PDF

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Publication number
RU2006146060A
RU2006146060A RU2006146060/042006146060/04A RU2006146060A RU2006146060A RU 2006146060 A RU2006146060 A RU 2006146060A RU 2006146060 A RU2006146060 A RU 2006146060A RU 2006146060 A RU2006146060 A RU 2006146060A
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Prior art keywords
gas oil
zsm
carbon atoms
stage
fischer
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RU2006146060/042006146060/04A
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Russian (ru)
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RU2388791C2 (en
Inventor
Ян Лодевейк Мария ДИРИКС
Original Assignee
Шелл Интернэшнл Рисерч Маатсхаппий Б.В.
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Priority claimed from PCT/EP2004/050931 external-priority patent/WO2004106462A1/en
Application filed by Шелл Интернэшнл Рисерч Маатсхаппий Б.В. filed Critical Шелл Интернэшнл Рисерч Маатсхаппий Б.В.
Publication of RU2006146060A publication Critical patent/RU2006146060A/en
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Publication of RU2388791C2 publication Critical patent/RU2388791C2/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/14—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts
    • C10G11/18—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised-bed" technique
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1022—Fischer-Tropsch products
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/1048—Middle distillates
    • C10G2300/1059—Gasoil having a boiling range of about 330 - 427 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4006—Temperature
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/06—Gasoil

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Claims (11)

1. Способ получения газойля, включающий1. The method of producing gas oil, including (a) выделение из продукта синтеза Фишера-Тропша первой фракции газойля и фракции, кипящей выше фракции газойля,(a) recovering from the Fischer-Tropsch synthesis product a first gas oil fraction and a fraction boiling above a gas oil fraction, (b) контактирование более тяжелой фракции с каталитической системой, содержащей катализатор, включающий кислотную матрицу и крупнопористое молекулярное сито, в вертикальном реакторе при температуре 450-650°С, времени контакта 1-10 с и соотношением между количеством катализатора и количеством масла 2-20 кг/кг.(b) contacting the heavier fraction with a catalyst system comprising a catalyst comprising an acid matrix and a large pore molecular sieve in a vertical reactor at a temperature of 450-650 ° C, a contact time of 1-10 s and the ratio between the amount of catalyst and the amount of oil 2-20 kg / kg (c) выделение из продукта со стадии (b) второй фракции газойля,(c) recovering from the product from step (b) a second fraction of gas oil, (d) объединение первой и второй фракций газойля.(d) combining the first and second gas oil fractions. 2. Способ по п.1, в котором сырье, используемое на стадии (b), характеризуется соотношением между количеством соединений, содержащих, по меньшей мере, 60 или более углеродных атомов, и количеством соединений, содержащих, по меньшей мере, 30 углеродных атомов, равным, по меньшей мере, 0,2, и в котором, по меньшей мере, 30 мас.% соединений содержат, по меньшей мере, 30 углеродных атомов.2. The method according to claim 1, in which the raw materials used in stage (b) are characterized by the ratio between the number of compounds containing at least 60 or more carbon atoms and the number of compounds containing at least 30 carbon atoms equal to at least 0.2, and in which at least 30 wt.% compounds contain at least 30 carbon atoms. 3. Способ по п.2, в котором, по меньшей мере, 50 мас.% соединений в сырье со стадии (b) содержат, по меньшей мере, 30 углеродных атомов.3. The method according to claim 2, in which at least 50 wt.% Of the compounds in the feed from step (b) contain at least 30 carbon atoms. 4. Способ по п.3, в котором массовое соотношение между количеством соединений, содержащих, по меньшей мере, 60 или более углеродных атомов, и количеством соединений, содержащих, по меньшей мере, 30 углеродных атомов в продукте синтеза Фишера-Тропша, представляющем сырье для стадии (b), составляет, по меньшей мере, 0,4.4. The method according to claim 3, in which the mass ratio between the number of compounds containing at least 60 or more carbon atoms, and the number of compounds containing at least 30 carbon atoms in the product of the Fischer-Tropsch synthesis, representing raw materials for stage (b), is at least 0.4. 5. Способ по любому из пп.1-4, в котором стадию (b) проводят при температуре ниже 600°С.5. The method according to any one of claims 1 to 4, in which stage (b) is carried out at a temperature below 600 ° C. 6. Способ по п.1, в котором кислотная матрица представляет собой оксид алюминия.6. The method according to claim 1, in which the acid matrix is an alumina. 7. Способ по п.1, в котором крупнопористое молекулярное сито представляет собой материал фожазитного (FAU) типа.7. The method according to claim 1, in which the large-pore molecular sieve is a material of faujasite (FAU) type. 8. Способ по п.1, в котором каталитическая система со стадии (b) также содержит цеолит бета, эрионит, ферриерит, ZSM-5, ZSM-11, ZSM-12, ZSM-22, ZSM-23 или ZSM-57.8. The method according to claim 1, in which the catalyst system from stage (b) also contains zeolite beta, erionite, ferrierite, ZSM-5, ZSM-11, ZSM-12, ZSM-22, ZSM-23 or ZSM-57. 9. Способ по п.8, в котором изо- и нормальные пентены и/или изо- и нормальные гексены подвергают олигомеризации с целью получения соединений, кипящих в температурном интервале кипения газойля, причем указанные соединения объединяют с газойлем, полученным на стадии (d).9. The method of claim 8, in which iso- and normal pentenes and / or iso-and normal hexenes are oligomerized to obtain compounds boiling in the temperature range of the boiling gas oil, and these compounds are combined with the gas oil obtained in stage (d) . 10. Способ по п.1, в котором продукт синтеза Фишера-Тропша, используемый в качестве сырья на стадии (а), получают с помощью процесса синтеза Фишера-Тропша с использованием кобальтового катализатора.10. The method according to claim 1, in which the product of the Fischer-Tropsch synthesis used as a raw material in stage (a), is obtained using the Fischer-Tropsch synthesis process using a cobalt catalyst. 11. Способ по п.10, в котором кобальтовый катализатор получают (аа) смешиванием с образованием смеси (1) оксида титана или его предшественника, (2) жидкости и (3) производного кобальта, который, по меньшей мере, частично нерастворим во взятом количестве жидкости; (bb) формованием и сушкой полученной смеси и (сс) прокаливанием полученной композиции.11. The method according to claim 10, in which the cobalt catalyst is obtained (aa) by mixing to form a mixture of (1) titanium oxide or its precursor, (2) a liquid and (3) a cobalt derivative that is at least partially insoluble in the taken amount of fluid; (bb) molding and drying the resulting mixture; and (cc) calcining the resulting composition.
RU2006146060/04A 2004-05-26 2005-05-25 Method of obtaining gas oil through catalytic cracking of fischer-tropsch synthesis product RU2388791C2 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
PCT/EP2004/050931 WO2004106462A1 (en) 2003-05-27 2004-05-26 Process to prepare a gasoline
EPPCT/EP2004/050931 2004-05-26
EP04106189 2004-11-30
EP04106189.6 2004-11-30

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RU2006146060A true RU2006146060A (en) 2008-07-10
RU2388791C2 RU2388791C2 (en) 2010-05-10

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US (1) US20070227946A1 (en)
EP (1) EP1753841A1 (en)
JP (1) JP4955541B2 (en)
CN (1) CN1965059B (en)
BR (1) BRPI0510476A (en)
RU (1) RU2388791C2 (en)
WO (1) WO2005118747A1 (en)

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Publication number Publication date
CN1965059B (en) 2010-06-16
RU2388791C2 (en) 2010-05-10
US20070227946A1 (en) 2007-10-04
WO2005118747A1 (en) 2005-12-15
EP1753841A1 (en) 2007-02-21
JP4955541B2 (en) 2012-06-20
JP2008500418A (en) 2008-01-10
CN1965059A (en) 2007-05-16
BRPI0510476A (en) 2007-11-06

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