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RU2004119970A - Фильтр с потоком по стенкам для очистки выхлопных газов дизельного двигателя, система выхлопных газов дизельного двигателя, включающая указанный фильтр, и способ каталитической очистки выхлопных газов сгорания дизельного топлива - Google Patents

Фильтр с потоком по стенкам для очистки выхлопных газов дизельного двигателя, система выхлопных газов дизельного двигателя, включающая указанный фильтр, и способ каталитической очистки выхлопных газов сгорания дизельного топлива Download PDF

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Publication number
RU2004119970A
RU2004119970A RU2004119970/15A RU2004119970A RU2004119970A RU 2004119970 A RU2004119970 A RU 2004119970A RU 2004119970/15 A RU2004119970/15 A RU 2004119970/15A RU 2004119970 A RU2004119970 A RU 2004119970A RU 2004119970 A RU2004119970 A RU 2004119970A
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Russia
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filter
per liter
diesel engine
catalytically active
metal
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RU2004119970/15A
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English (en)
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RU2398972C2 (ru
Inventor
Гурли МОГЕНСЕН (DK)
Гурли МОГЕНСЕН
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Хальдор Топсеэ А/С (DK)
Хальдор Топсеэ А/С
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9445—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC]
    • B01D53/945—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC] characterised by a specific catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D39/00—Filtering material for liquid or gaseous fluids
    • B01D39/14—Other self-supporting filtering material ; Other filtering material
    • B01D39/20—Other self-supporting filtering material ; Other filtering material of inorganic material, e.g. asbestos paper, metallic filtering material of non-woven wires
    • B01D39/2068—Other inorganic materials, e.g. ceramics
    • B01D39/2072—Other inorganic materials, e.g. ceramics the material being particulate or granular
    • B01D39/2075—Other inorganic materials, e.g. ceramics the material being particulate or granular sintered or bonded by inorganic agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/652—Chromium, molybdenum or tungsten
    • B01J23/6527—Tungsten
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
    • F01N3/022—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous
    • F01N3/0222—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous the structure being monolithic, e.g. honeycombs
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
    • F01N3/023—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters using means for regenerating the filters, e.g. by burning trapped particles
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
    • F01N3/033—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters in combination with other devices
    • F01N3/035—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters in combination with other devices with catalytic reactors
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/28—Construction of catalytic reactors
    • F01N3/2803—Construction of catalytic reactors characterised by structure, by material or by manufacturing of catalyst support
    • F01N3/2825—Ceramics
    • F01N3/2828—Ceramic multi-channel monoliths, e.g. honeycombs
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N2430/00—Influencing exhaust purification, e.g. starting of catalytic reaction, filter regeneration, or the like, by controlling engine operating characteristics
    • F01N2430/04—Influencing exhaust purification, e.g. starting of catalytic reaction, filter regeneration, or the like, by controlling engine operating characteristics by adding non-fuel substances to combustion air or fuel, e.g. additives
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N2510/00—Surface coverings
    • F01N2510/06—Surface coverings for exhaust purification, e.g. catalytic reaction
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N2570/00—Exhaust treating apparatus eliminating, absorbing or adsorbing specific elements or compounds
    • F01N2570/02—Lead
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/10—Internal combustion engine [ICE] based vehicles
    • Y02T10/12—Improving ICE efficiencies

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Biomedical Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Geology (AREA)
  • Toxicology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Exhaust Gas After Treatment (AREA)
  • Filtering Materials (AREA)
  • Processes For Solid Components From Exhaust (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Claims (8)

1. Фильтр с потоком по стенкам для очистки выхлопных газов дизельного двигателя, включающий оксиды ванадия и вольфрама и металлический палладий в качестве каталитически активного материала, нанесенные на двуокиси титана в качестве носителя, отличающийся тем, что его получают из спеченных частиц карбида кремния, на поверхность каждой из которых нанесен пористый слой диоксида титана.
2. Фильтр с потоком по стенкам по п.1, отличающийся тем, что он дополнительно включает металлическую платину в качестве каталитически активного материала.
3. Фильтр с потоком по стенкам по п.1 или 2, отличающийся тем, что он включает каталитически активный материал в следующих количествах:
20-50 г V2O5 на литр фильтра,
1-50 г WO3 на литр фильтра,
0,25-1 г Pd на литр фильтра,
до 2 г Pt на литр фильтра.
4. Фильтр с потоком по стенкам по п.1 или 2, отличающийся тем, что он включает каталитически активный материал в следующих количествах:
25-35 г V2O5 на литр фильтра,
25-35 г WO3 на литр фильтра,
0,4-1 г Pd на литр фильтра,
до 0,4 г Pt на литр фильтра.
5. Система выхлопных газов дизельного двигателя, включающая фильтр по любому из пп.1-4.
6. Способ каталитической очистки выхлопных газов сгорания дизельного топлива, включающий пропускание выхлопных газов через фильтр с потоком по стенкам, снабженный материалом, являющимся каталитически активным в восстановлении оксидов азота до азота и окислении углеродистых соединений до диоксида углерода и воды, причем каталитически активный материал включает оксиды ванадия, вольфрама и металлический палладий или его смесь с металлической платиной, нанесенные на диоксид титана в качестве носителя, отличающийся тем, что выхлопной газ пропускают через фильтр с потоком по стенкам, полученный из спеченных частиц карбида кремния, а поверхность каждой из них снабжена пористым слоем диоксида титана.
7. Способ по п.6, отличающийся тем, что каталитической очистке подвергают выхлопные газы сгорания дизельного топлива, содержащего заданное количество растворимого в органике комплекса металла, эффективного в окислении углеводородов и/или углеродистого вещества.
8. Способ по п.7, отличающийся тем, что в качестве комплекса металла используют органический комплекс одного или нескольких металлов, выбранных из I и II группы, лантаноидов, железа и марганца.
RU2004119970/15A 2003-07-02 2004-07-01 Фильтр с потоком по стенкам для очистки выхлопных газов дизельного двигателя, система выхлопных газов дизельного двигателя, включающая указанный фильтр, и способ каталитической очистки выхлопных газов сгорания дизельного топлива RU2398972C2 (ru)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DKPA200300999 2003-07-02
DKPA200300999 2003-07-02
DKPA200301173 2003-08-15
DKPA200301173 2003-08-15

Publications (2)

Publication Number Publication Date
RU2004119970A true RU2004119970A (ru) 2006-01-10
RU2398972C2 RU2398972C2 (ru) 2010-09-10

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RU2004119970/15A RU2398972C2 (ru) 2003-07-02 2004-07-01 Фильтр с потоком по стенкам для очистки выхлопных газов дизельного двигателя, система выхлопных газов дизельного двигателя, включающая указанный фильтр, и способ каталитической очистки выхлопных газов сгорания дизельного топлива

Country Status (12)

Country Link
US (1) US7625538B2 (ru)
EP (1) EP1493484B1 (ru)
JP (1) JP2005046836A (ru)
KR (1) KR101112014B1 (ru)
CN (1) CN100422515C (ru)
AT (1) ATE355884T1 (ru)
AU (1) AU2004202990B2 (ru)
CA (1) CA2472839C (ru)
DE (1) DE602004005107T2 (ru)
ES (1) ES2281714T3 (ru)
PL (1) PL1493484T3 (ru)
RU (1) RU2398972C2 (ru)

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EP1493484A1 (en) 2005-01-05
CN100422515C (zh) 2008-10-01
AU2004202990B2 (en) 2010-06-24
DE602004005107T2 (de) 2007-06-28
CA2472839C (en) 2012-09-25
ES2281714T3 (es) 2007-10-01
JP2005046836A (ja) 2005-02-24
RU2398972C2 (ru) 2010-09-10
KR20050004108A (ko) 2005-01-12
AU2004202990A1 (en) 2005-01-20
ATE355884T1 (de) 2007-03-15
CN1576528A (zh) 2005-02-09
DE602004005107D1 (de) 2007-04-19
PL1493484T3 (pl) 2007-05-31
KR101112014B1 (ko) 2012-02-15
CA2472839A1 (en) 2005-01-02
EP1493484B1 (en) 2007-03-07
US7625538B2 (en) 2009-12-01

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