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RU2004117078A - Улучшенный родиевый электрокатализатор и способ его получения - Google Patents

Улучшенный родиевый электрокатализатор и способ его получения Download PDF

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Publication number
RU2004117078A
RU2004117078A RU2004117078/15A RU2004117078A RU2004117078A RU 2004117078 A RU2004117078 A RU 2004117078A RU 2004117078/15 A RU2004117078/15 A RU 2004117078/15A RU 2004117078 A RU2004117078 A RU 2004117078A RU 2004117078 A RU2004117078 A RU 2004117078A
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RU
Russia
Prior art keywords
electrocatalyst
rhodium
sulfide
solution
carbon black
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RU2004117078/15A
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English (en)
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RU2311496C2 (ru
Inventor
Ю-Мин ТСОУ (US)
Ю-Мин ТСОУ
Хуа ДЕН (US)
Хуа ДЕН
Джан Никола МАРТЕЛЛИ (IT)
Джан Никола Мартелли
Роберт Дж. АЛЛЕН (US)
Роберт Дж. Аллен
КАСТРО Эмори С. ДЕ (US)
КАСТРО Эмори С. ДЕ
Original Assignee
Де Нора Элеттроди С.П.А. (It)
Де Нора Элеттроди С.П.А.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication of RU2004117078A publication Critical patent/RU2004117078A/ru
Application granted granted Critical
Publication of RU2311496C2 publication Critical patent/RU2311496C2/ru

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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/073Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
    • C25B11/075Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of a single catalytic element or catalytic compound
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/04Sulfides
    • B01J27/043Sulfides with iron group metals or platinum group metals
    • B01J27/045Platinum group metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46Ruthenium, rhodium, osmium or iridium
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G55/00Compounds of ruthenium, rhodium, palladium, osmium, iridium, or platinum
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/24Halogens or compounds thereof
    • C25B1/26Chlorine; Compounds thereof
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00Electrodes; Manufacture thereof not otherwise provided for
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8605Porous electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/88Processes of manufacture
    • H01M4/8803Supports for the deposition of the catalytic active composition
    • H01M4/881Electrolytic membranes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/88Processes of manufacture
    • H01M4/8825Methods for deposition of the catalytic active composition
    • H01M4/8842Coating using a catalyst salt precursor in solution followed by evaporation and reduction of the precursor
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90Selection of catalytic material
    • H01M4/92Metals of platinum group
    • H01M4/923Compounds thereof with non-metallic elements
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Electrochemistry (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Metallurgy (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)

Claims (14)

1. Электрокатализатор на основе сульфида родия, формируемый путем нагрева водного раствора соли родия до тех пор, пока не будет получено стационарное распределение изомеров, а затем продувки сероводорода в растворе с получением сульфида родия.
2. Электрокатализатор по п.1, где нагревание осуществляется с обратным холодильником.
3. Электрокатализатор по п.1, нанесенный на инертный электропроводящий носитель.
4. Электрокатализатор на основе сульфида родия, нанесенный на тонкодисперсную углеродную сажу.
5. Электрокатализатор на основе сульфида родия по п.3, где инертная электропроводящая подложка представляет собой тонкодисперсную углеродную сажу.
6. Электрокатализатор, формируемый путем нагревания водного раствора соли родия до тех пор, пока не будет получено стационарное распределение изомеров, а затем продувки сероводорода в растворе, осажденный на тонкодисперсную углеродную сажу.
7. Способ для получения электрокатализатора, включающий формирование раствора из растворимой соли родия, нагрева раствора с получением стационарного распределения изомеров родия, продувки сероводорода через полученный раствор, для осаждения сульфида родия и его извлечения.
8. Способ по п.7, где сульфид родия осаждается на тонкодисперсную углеродную сажу.
9. Мембранно-электродная сборка с электродом, имеющим осажденный электрокатализатор по п.1 на инертной электропроводящей подложке.
10. Сборка по п.9, где подложка представляет собой углеродную сажу.
11. Сборка по п.10, где углеродная сажа является тонкодисперсной.
12. В способе электролиза хлористоводородной кислоты в электролизере, усовершенствование, включающее использование мембранно-электродной сборки по п.9.
13. В способе электролиза хлористоводородной кислоты в электролизере, усовершенствование, включающее использование мембранно-электродной сборки по п.11.
14. Электрокатализатор, формируемый путем нагревания водного раствора соли родия до тех пор, пока не будет получено стационарное распределение изомеров, а затем продувки сероводорода в растворе для получения электрокатализатора.
RU2004117078/15A 2001-11-07 2002-11-07 Улучшенный родиевый электрокатализатор и способ его получения RU2311496C2 (ru)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US34476101P 2001-11-07 2001-11-07
US60/344,761 2001-11-07
US10/141,108 2002-05-08
US10/141,108 US6855660B2 (en) 2001-11-07 2002-05-08 Rhodium electrocatalyst and method of preparation

Publications (2)

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RU2004117078A true RU2004117078A (ru) 2005-03-27
RU2311496C2 RU2311496C2 (ru) 2007-11-27

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Country Link
US (1) US6855660B2 (ru)
EP (1) EP1444384B1 (ru)
JP (1) JP4223958B2 (ru)
KR (1) KR100908797B1 (ru)
CN (1) CN1320170C (ru)
AR (1) AR037186A1 (ru)
BR (1) BR0213935B1 (ru)
CA (1) CA2466362C (ru)
CZ (1) CZ307526B6 (ru)
DK (1) DK1444384T3 (ru)
ES (1) ES2574002T3 (ru)
HU (1) HU228452B1 (ru)
MX (1) MXPA04004382A (ru)
MY (1) MY128851A (ru)
PL (1) PL201791B1 (ru)
PT (1) PT1444384E (ru)
RU (1) RU2311496C2 (ru)
WO (1) WO2003040435A2 (ru)
ZA (1) ZA200403437B (ru)

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CN100515566C (zh) * 2005-12-12 2009-07-22 比亚迪股份有限公司 一种催化剂涂层膜的制备方法
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TWI429785B (zh) * 2007-02-22 2014-03-11 Industrie De Nora Spa 氧之電化學還原用觸媒及製法和氣體擴散電極
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CN101463487B (zh) * 2007-12-17 2010-06-09 中国电子科技集团公司第十八研究所 用于电解水的质子交换膜电极制备方法
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JP5558171B2 (ja) * 2010-03-31 2014-07-23 トヨタ自動車株式会社 回転ディスク電極法で使用される電極触媒を製造する、触媒製造方法および触媒製造装置
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CN103528913A (zh) * 2013-10-15 2014-01-22 中国海洋石油总公司 一种含铑化合物中铑含量测定方法
US12404592B2 (en) 2018-05-02 2025-09-02 Ohio State Innovation Foundation Heteroatom-doped carbon catalyst for electrocatalytic halogen production
CN110938832A (zh) * 2019-12-13 2020-03-31 陕西易莱德新材料科技有限公司 一种用于次氯酸钠电解槽的膜电极制备方法
CN112517001B (zh) * 2020-12-16 2023-04-07 广东济平新能源科技有限公司 铂黑催化剂的制备方法以及铂黑催化剂

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Also Published As

Publication number Publication date
CN1320170C (zh) 2007-06-06
DK1444384T3 (en) 2016-07-18
CA2466362A1 (en) 2003-05-15
HU228452B1 (en) 2013-03-28
US6855660B2 (en) 2005-02-15
CZ2004576A3 (cs) 2004-09-15
JP4223958B2 (ja) 2009-02-12
US20030086862A1 (en) 2003-05-08
RU2311496C2 (ru) 2007-11-27
PT1444384E (pt) 2016-06-02
CZ307526B6 (cs) 2018-11-14
MY128851A (en) 2007-02-28
EP1444384B1 (en) 2016-03-30
PL370375A1 (en) 2005-05-16
EP1444384A2 (en) 2004-08-11
JP2005508450A (ja) 2005-03-31
CN1578851A (zh) 2005-02-09
HUP0402367A2 (hu) 2005-03-29
PL201791B1 (pl) 2009-05-29
BR0213935B1 (pt) 2013-06-04
BR0213935A (pt) 2004-10-26
CA2466362C (en) 2010-06-22
AR037186A1 (es) 2004-10-27
ZA200403437B (en) 2005-07-27
MXPA04004382A (es) 2004-08-12
WO2003040435A2 (en) 2003-05-15
WO2003040435A3 (en) 2004-05-06
KR20040062624A (ko) 2004-07-07
ES2574002T3 (es) 2016-06-14
KR100908797B1 (ko) 2009-07-22

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