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RU2001103899A - METHOD FOR PRODUCING ELECTRICITY, WATER VAPOR AND CARBON DIOXIDE FROM HYDROCARBON RAW MATERIAL - Google Patents

METHOD FOR PRODUCING ELECTRICITY, WATER VAPOR AND CARBON DIOXIDE FROM HYDROCARBON RAW MATERIAL

Info

Publication number
RU2001103899A
RU2001103899A RU2001103899/12A RU2001103899A RU2001103899A RU 2001103899 A RU2001103899 A RU 2001103899A RU 2001103899/12 A RU2001103899/12 A RU 2001103899/12A RU 2001103899 A RU2001103899 A RU 2001103899A RU 2001103899 A RU2001103899 A RU 2001103899A
Authority
RU
Russia
Prior art keywords
gas
hydrogen
carbon dioxide
water vapor
turbine
Prior art date
Application number
RU2001103899/12A
Other languages
Russian (ru)
Other versions
RU2213051C2 (en
Inventor
Хенрик О. ФЬЕЛЛХЕУГ
Хеннинг Рейер НИЛЬСЕН
Вернер СУАЕ
Мишель СЭНЬ
Original Assignee
Норск Хюдро Аса
Filing date
Publication date
Application filed by Норск Хюдро Аса filed Critical Норск Хюдро Аса
Priority claimed from PCT/NO1998/000213 external-priority patent/WO2000003126A1/en
Publication of RU2001103899A publication Critical patent/RU2001103899A/en
Application granted granted Critical
Publication of RU2213051C2 publication Critical patent/RU2213051C2/en

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Claims (11)

1. Способ получения электроэнергии, водяного пара и диоксида углерода в концентрированной форме из углеводородного сырья (1), включающий образование синтез-газа в автотермическом реакторе (АТР) (6) с подачей в него воздуха, теплообмен образовавшегося синтез-газа (8) и получение в результате этого водяного пара, отличающийся тем, что по крайней мере часть синтез-газа обрабатывается в реакторе конверсии СО (12) ив аппаратах выделения диоксида углерода (16, 19) для получения концентрированного диоксида углерода (21) и бедного водородсодержащего газа (17), который, по крайней мере, частично сжигается в газовой турбине с комбинированным циклом (24) для получения электроэнергии, и где воздух из турбинной установки (24) подается в АТР (6), и что отработанные газы (26) из газовой турбины (24) участвуют в теплообмене для получения водяного пара, который вместе с паром, выработанным ранее по ходу процесса, используется в паровой турбине (27) для получения электроэнергии, в основном без выброса СО2.1. A method of producing electricity, water vapor and carbon dioxide in concentrated form from hydrocarbon raw materials (1), including the formation of synthesis gas in an autothermal reactor (ATP) (6) with air supplied to it, heat exchange of the resulting synthesis gas (8) and producing water vapor as a result, characterized in that at least part of the synthesis gas is processed in a CO conversion reactor (12) and in carbon dioxide extraction apparatus (16, 19) to produce concentrated carbon dioxide (21) and poor hydrogen-containing gas ( 17), which is at least partially burned in a gas turbine with a combined cycle (24) to produce electricity, and where the air from the turbine unit (24) is supplied to the APR (6), and that the exhaust gases (26) from the gas turbine (24) participate in heat exchange to produce water vapor, which, together with the steam generated earlier in the process, is used in a steam turbine (27) to produce electricity, mainly without the emission of CO 2 . 2. Способ по п. 1, отличающийся тем, что используют установку риформинга, состоящую из АТР (6) в комбинации с реактором риформинга - теплообменником. 2. The method according to p. 1, characterized in that they use a reforming unit consisting of ATP (6) in combination with a reforming reactor - a heat exchanger. 3. Способ по п. 1, отличающийся тем, что 50-80% углеводородного сырья (1) подают в АТР (6), и остальное сырье подают в реактор риформинга - теплообменник. 3. The method according to p. 1, characterized in that 50-80% of the hydrocarbon feed (1) is fed to the Asia-Pacific region (6), and the rest of the feed is fed to the reforming reactor — a heat exchanger. 4. Способ по п. 1, отличающийся тем, что перед АТР (6) используют реактор предварительного реформинга. 4. The method according to p. 1, characterized in that before the APR (6) use a preliminary reforming reactor. 5. Способ по п. 1, отличающийся тем, используют только один реактор конверсии СО (12). 5. The method according to p. 1, characterized in that only one CO conversion reactor is used (12). 6. Способ по п. 1, отличающийся тем, что водяной пар подают в газовую турбину (24) для разбавления водородсодержащей газовой смеси (17). 6. The method according to p. 1, characterized in that the water vapor is fed into a gas turbine (24) to dilute the hydrogen-containing gas mixture (17). 7. Способ по п. 1, отличающийся тем, что отработанный газ (28) рециркулирует из газовой турбины (24) в АТР (6). 7. The method according to p. 1, characterized in that the exhaust gas (28) is recycled from the gas turbine (24) to the APR (6). 8. Способ по п. 1, отличающийся тем, что по крайней мере часть отработанного газа (28) из газовой турбины (24) смешивается с воздухом (25), подаваемым в указанную турбину. 8. The method according to p. 1, characterized in that at least a portion of the exhaust gas (28) from the gas turbine (24) is mixed with air (25) supplied to the specified turbine. 9. Способ по п. 1, отличающийся тем, что часть синтез-газа (11) используют для получения метанола, и что остальной синтез-газ затем обрабатывают в установках, расположенных далее по ходу технологической схемы, перед использованием для получения электроэнергии. 9. The method according to p. 1, characterized in that part of the synthesis gas (11) is used to produce methanol, and that the rest of the synthesis gas is then processed in plants located downstream of the flowchart, before being used to produce electricity. 10. Способ по п. 1, отличающийся тем, что часть водородсодержащего газа (17) из аппарата для удаления диоксида углерода (16) используют для получения аммиака (45), которое включает разделение указанного газа в мембранном аппарате (40) для того, чтобы довести отношение азот: водород до величины, требуемой для синтеза аммиака, и возвращение отделенного азота в основной поток водородсодержащего газа (17), и где поток, содержащий азот и водород в отношении 1: 3, обрабатывается в метанаторе перед синтезом аммиака. 10. The method according to p. 1, characterized in that part of the hydrogen-containing gas (17) from the apparatus for removing carbon dioxide (16) is used to produce ammonia (45), which includes the separation of the specified gas in the membrane apparatus (40) so that adjust the nitrogen: hydrogen ratio to the value required for the synthesis of ammonia, and return the separated nitrogen to the main stream of hydrogen-containing gas (17), and where the stream containing nitrogen and hydrogen in a ratio of 1: 3 is processed in a methanator before the synthesis of ammonia. 11. Способ по п. 1, отличающийся тем, что часть водородсодержащего газа (17) подают из аппарата для удаления диоксида углерода (16) для использования в качестве топлива в топливном элементе, вырабатывающем электроэнергию. 11. The method according to p. 1, characterized in that part of the hydrogen-containing gas (17) is supplied from the apparatus for removing carbon dioxide (16) for use as fuel in a fuel cell that generates electricity.
RU2001103899/12A 1998-07-13 1998-07-13 Method of generation of electric energy, water steam and carbon dioxide from hydrocarbon raw material RU2213051C2 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/NO1998/000213 WO2000003126A1 (en) 1998-07-13 1998-07-13 Process for generating electric energy, steam and carbon dioxide from hydrocarbon feedstock

Publications (2)

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RU2213051C2 RU2213051C2 (en) 2003-09-27

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US (1) US6505467B1 (en)
EP (1) EP1105625B1 (en)
JP (1) JP4190151B2 (en)
CN (1) CN1116501C (en)
AT (1) ATE249572T1 (en)
AU (1) AU744197B2 (en)
BR (1) BR9815946A (en)
CA (1) CA2337394C (en)
CZ (1) CZ294769B6 (en)
DE (1) DE69818111T2 (en)
DK (1) DK1105625T3 (en)
EE (1) EE04622B1 (en)
ES (1) ES2206972T3 (en)
HU (1) HU222969B1 (en)
ID (1) ID28247A (en)
IL (1) IL140627A (en)
NO (1) NO319178B1 (en)
NZ (1) NZ509572A (en)
PL (1) PL195221B1 (en)
RU (1) RU2213051C2 (en)
SK (1) SK286791B6 (en)
TR (1) TR200100067T2 (en)
WO (1) WO2000003126A1 (en)

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