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RU2000111550A - ADDITION PRODUCTS AMIN DIEPHIR - Google Patents

ADDITION PRODUCTS AMIN DIEPHIR

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Publication number
RU2000111550A
RU2000111550A RU2000111550/04A RU2000111550A RU2000111550A RU 2000111550 A RU2000111550 A RU 2000111550A RU 2000111550/04 A RU2000111550/04 A RU 2000111550/04A RU 2000111550 A RU2000111550 A RU 2000111550A RU 2000111550 A RU2000111550 A RU 2000111550A
Authority
RU
Russia
Prior art keywords
formula
product
diester
amine
addition
Prior art date
Application number
RU2000111550/04A
Other languages
Russian (ru)
Other versions
RU2189972C2 (en
Inventor
Томас ЭЛИС
Петер ФАНКХАУЗЕР
Дитмар ХЮГЛИН
Original Assignee
Циба Спешиалти Кемикалз Холдинг Инк.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Циба Спешиалти Кемикалз Холдинг Инк. filed Critical Циба Спешиалти Кемикалз Холдинг Инк.
Publication of RU2000111550A publication Critical patent/RU2000111550A/en
Application granted granted Critical
Publication of RU2189972C2 publication Critical patent/RU2189972C2/en

Links

Claims (1)

1. Продукт присоединения диэфир амина формулы
Figure 00000001

где R1, R2, R3 и R4, независимо один от другого, каждый обозначает С4-С22-алкил, С2-С22-алкенил или С5-С7-циклоалкил;
X1 и Х2, независимо один от другого, каждый обозначает водород; С1-С4-алкил, С2-С4-гидроксиалкил или С2-С4-гидроксигалоалкил;
Y означает радикал формулы (1b)
Figure 00000002

A1 означает С2-С3-алкилен или 2-гидрокси-n-пропилен;
Х3 означает водород; С1-С4-алкил, С2-С4-гидроксиалкйл или С2-С4-гидроксигалоалкил;
Figure 00000003
означает асимметрический атом углерода в R- или S-конфигурации, причем, если
C1= R, C2= R;
C1= S, C2= S и
C1= R, C2= S;
m1 равняется 1 или 2 и
n означает целое число от 1 до 4;
р равняется 0 или 1;
при этом продукт присоединения может быть в виде свободного основания, кислоты, кислой соли или соли четвертичного аммония.1. The product of the addition of diester of the amine of the formula
Figure 00000001

where R 1 , R 2 , R 3 and R 4 , independently of one another, are each C 4 -C 22 alkyl, C 2 -C 22 alkenyl or C 5 -C 7 cycloalkyl;
X 1 and X 2 , independently of one another, each is hydrogen; C 1 -C 4 alkyl, C 2 -C 4 hydroxyalkyl or C 2 -C 4 hydroxyhaloalkyl;
Y is a radical of formula (1b)
Figure 00000002

A 1 is C 2 -C 3 alkylene or 2-hydroxy-n-propylene;
X 3 means hydrogen; C 1 -C 4 alkyl, C 2 -C 4 hydroxyalkyl or C 2 -C 4 hydroxyhaloalkyl;
Figure 00000003
means an asymmetric carbon atom in the R or S configuration, and if
C 1 = R, C 2 = R;
C 1 = S, C 2 = S and
C 1 = R, C 2 = S;
m 1 is 1 or 2 and
n is an integer from 1 to 4;
p is 0 or 1;
wherein the addition product may be in the form of a free base, an acid, an acid salt or a quaternary ammonium salt. 2. Продукт присоединения диэфир амина по п. 1, отличающийся тем, что в формуле (1) A1 обозначает С2-С3-алкилен; m равняется 2 и р равняется 0.2. The addition product of the amine diester according to claim 1, characterized in that in the formula (1) A 1 is C 2 -C 3 alkylene; m equals 2 and p equals 0. 3. Продукт присоединения диэфир амина по п. 1 или 2, отличающийся тем, что X1 и Х2 обозначают водород.3. The product of the accession of the diester of the amine under item 1 or 2, characterized in that X 1 and X 2 denote hydrogen. 4. Продукт присоединения диэфир амина по любому из пп. 1-3, отличающийся тем, что R1, R2, R3 и R4 обозначают С4-С22-алкил.4. The product of the addition of the diester of the amine according to any one of paragraphs. 1-3, characterized in that R 1 , R 2 , R 3 and R 4 are C 4 -C 22 -alkyl. 5. Способ получения соединения формулы (1), в котором диаминотетракарбоновую кислоту формулы (lg) подвергают взаимодействию с тионилхлоридом и спиртом, с получением соответствующего соединения сложного эфира формулы (1f) в соответствии со следующей схемой:
Figure 00000004

6. Использование продукта присоединения диэфир амина формулы
Figure 00000005

где R1, R2, R3, R4, X1 и X2, Y и n имеют значения, приведенные в п. 1, в качестве комплексообразователя.5. A method of obtaining a compound of formula (1), in which diaminotetracarboxylic acid of formula (lg) is reacted with thionyl chloride and an alcohol to obtain the corresponding ester compound of formula (1f) in accordance with the following scheme:
Figure 00000004

6. Use of the product of addition of the diester of the amine of the formula
Figure 00000005

where R 1 , R 2 , R 3 , R 4 , X 1 and X 2 , Y and n have the meanings given in paragraph 1, as a complexing agent. 7. Использование по п. 6, отличающееся тем, что соединение формулы (2) используют в пищевых продуктах и напитках, в щелочных ваннах (составах) для удаления ржавчины и отложений кальция, в качестве добавок к жидкостям для замкнутых линий с охлаждающей водой, в продуктах личной гигиены, в качестве отбеливающих стабилизаторов, в чистящих средствах и детергентах и в текстильной и бумажной промышленности. 7. The use according to claim 6, characterized in that the compound of formula (2) is used in food products and beverages, in alkaline baths (compositions) to remove rust and calcium deposits, as additives to liquids for closed lines with cooling water, in personal care products, as bleaching stabilizers, in cleaning products and detergents, and in the textile and paper industries. 8. Использование по п. 6, отличающееся тем, что соединение формулы (2) используют в продуктах личной гигиены. 8. The use according to claim 6, characterized in that the compound of formula (2) is used in personal care products. 9. Использование по п. 8, отличающееся тем, что соединение формулы (2) используют в дезодорантах. 9. The use according to claim 8, characterized in that the compound of formula (2) is used in deodorants. 10. Продукт личной гигиены, содержащий 0,01 - 15 мас. % продукта присоединения диэфир амина формулы (1) или (2). 10. A personal care product containing 0.01 to 15 wt. % of the product of the addition of the diester of the amine of the formula (1) or (2). 11. Использование продукта присоединения диэфир амина формулы (1) в качестве пластификатора для материалов из органических волокон. 11. The use of the product of joining the diester of the amine of the formula (1) as a plasticizer for materials from organic fibers.
RU2000111550/04A 1997-11-06 1998-10-27 Compounds of dietheramine addition and method of their synthesis RU2189972C2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP97810833.0 1997-11-06
EP97810833 1997-11-06

Publications (2)

Publication Number Publication Date
RU2000111550A true RU2000111550A (en) 2002-05-10
RU2189972C2 RU2189972C2 (en) 2002-09-27

Family

ID=8230459

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2000111550/04A RU2189972C2 (en) 1997-11-06 1998-10-27 Compounds of dietheramine addition and method of their synthesis

Country Status (12)

Country Link
US (1) US6369268B1 (en)
EP (1) EP1028939A1 (en)
JP (1) JP2001522827A (en)
KR (1) KR20010031809A (en)
CN (1) CN1278243A (en)
AU (1) AU751838B2 (en)
BR (1) BR9813987A (en)
IL (1) IL135545A0 (en)
NZ (1) NZ504290A (en)
PL (1) PL340309A1 (en)
RU (1) RU2189972C2 (en)
WO (1) WO1999024392A1 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060011295A1 (en) * 2004-07-14 2006-01-19 Karsten Danielmeier Aspartic ester functional compounds
GB0714575D0 (en) 2007-07-26 2007-09-05 Innospec Ltd Composition
US8163861B2 (en) * 2009-01-15 2012-04-24 Living Proof, Inc. Beta-amino ester compounds and uses thereof
US20120136073A1 (en) 2010-11-15 2012-05-31 Life Technologies Corporation Amine-Containing Transfection Reagents and methods for making and using same
EP2612846A1 (en) * 2012-01-09 2013-07-10 Bayer MaterialScience AG Beta amino acid esters and use of same
AU2022309880A1 (en) * 2021-07-16 2024-02-08 Dow Global Technologies Llc Cleaning booster additive
WO2025172600A1 (en) * 2024-02-15 2025-08-21 Basf Se Method for preparing n-substituted tetrahydrofuran-3-amines

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH575909A5 (en) * 1972-08-21 1976-05-31 Ciba Geigy Ag
US5652201A (en) * 1991-05-29 1997-07-29 Ethyl Petroleum Additives Inc. Lubricating oil compositions and concentrates and the use thereof
US5462939A (en) * 1993-05-07 1995-10-31 Sterling Winthrop Inc. Peptidic ketones as interleukin-1β-converting enzyme inhibitors
DE4439421A1 (en) * 1994-11-04 1996-05-09 Huels Chemische Werke Ag New polyamines containing urea groups and processes for their preparation
GB9507661D0 (en) * 1995-04-13 1995-05-31 Ass Octel Process
US5652301A (en) * 1996-08-20 1997-07-29 Bayer Corporation Aqueous polyurea dispersions and their use for preparing coatings with excellent hydrolytic and thermal stability

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