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RU2000102305A - ANHATIC COMPOSITION FOR BLOODING KERATIN FIBERS CONTAINING A COMBINATION OF ANIONIC AND / OR IONIFIC AMPHIPHILIC POLYMERS WITH A LESS MEASURING ONE FAT CHAIN AND CATIONIUM AND AGRI-MHPAAHI-APPAAILEAAIQAAXIMOFATTIMAILEAAIQIHIMTHIMTHOMMODIMO MEMO MHIMO MHIMO MHIMOFIMANO AIMPHILE AND AIMOFORMETRIMAILEPHILEPHILEMODIMOFIMANO AIMPHILEMETRIMAHIMODIMOFIMANO AIMPHILUM POLYMER WITH A LESS MEASURE OF A SINGLE FAT CHAIN AND Cationic NMF-NMR POLYMERS WITH LESS THAN ONE FAT CHAIN AND CATIO OR AMYPHILE AND AGRI-NMR THEMPHILEAAFIMAAI-THI-THILE-NMRAI will be applied. - Google Patents

ANHATIC COMPOSITION FOR BLOODING KERATIN FIBERS CONTAINING A COMBINATION OF ANIONIC AND / OR IONIFIC AMPHIPHILIC POLYMERS WITH A LESS MEASURING ONE FAT CHAIN AND CATIONIUM AND AGRI-MHPAAHI-APPAAILEAAIQAAXIMOFATTIMAILEAAIQIHIMTHIMTHOMMODIMO MEMO MHIMO MHIMO MHIMOFIMANO AIMPHILE AND AIMOFORMETRIMAILEPHILEPHILEMODIMOFIMANO AIMPHILEMETRIMAHIMODIMOFIMANO AIMPHILUM POLYMER WITH A LESS MEASURE OF A SINGLE FAT CHAIN AND Cationic NMF-NMR POLYMERS WITH LESS THAN ONE FAT CHAIN AND CATIO OR AMYPHILE AND AGRI-NMR THEMPHILEAAFIMAAI-THI-THILE-NMRAI will be applied.

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Publication number
RU2000102305A
RU2000102305A RU2000102305/14A RU2000102305A RU2000102305A RU 2000102305 A RU2000102305 A RU 2000102305A RU 2000102305/14 A RU2000102305/14 A RU 2000102305/14A RU 2000102305 A RU2000102305 A RU 2000102305A RU 2000102305 A RU2000102305 A RU 2000102305A
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composition according
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chain
less
polymer
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RU2000102305/14A
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Russian (ru)
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RU2200540C2 (en
Inventor
Фредерик ЛЕГРАН
Жан МИЛЛЕКАН
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Л'Ореаль
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1. Безводная композиция для обесцвечивания кератиновых волокон, в частности, кератиновых волокон человека, содержащая в подходящей для обесцвечивания среде по меньшей мере один щелочной агент и по меньшей мере одну перекисную соль, отличающаяся тем, что наряду с этим композиция содержит комбинацию по меньшей мере одного анионного и/или неионного амфифильного полимера, содержащего по меньшей мере одну жирную цепь, и по меньшей мере одного катионного или амфотерного субстантивного полимера.1. Anhydrous composition for bleaching keratin fibers, in particular, human keratin fibers, containing in a medium suitable for bleaching at least one alkaline agent and at least one peroxide salt, characterized in that the composition also contains a combination of at least one an anionic and / or non-ionic amphiphilic polymer containing at least one fatty chain, and at least one cationic or amphoteric substantive polymer. 2. Композиция по п.1, отличающаяся тем, что анионный амфифильный полимер, содержащий по меньшей мере одну жирную цепь, является сополимером, содержащим гидрофильные структурные звенья, образованные одним или несколькими мономерами с этиленовой ненасыщенностью, содержащие карбоксильную функцию, и гидрофобные структурные звенья, образованные одним или несколькими мономерами с этиленовой ненасыщенностью, содержащие гидрофобную боковую цепь. 2. The composition according to claim 1, characterized in that the anionic amphiphilic polymer containing at least one fatty chain is a copolymer containing hydrophilic structural units formed by one or more ethylenically unsaturated monomers, containing a carboxyl function, and hydrophobic structural units, formed by one or more ethylenically unsaturated monomers containing a hydrophobic side chain. 3. Композиция по п.1 или 2, отличающаяся тем, что мономер или мономеры с этиленовой ненасыщенностью, содержащие карбоксильную функцию, выбирают из этакриловой, метакриловой и акриловой кислот, преимущественно из метакриловой и акриловой кислот и их смесей. 3. The composition according to claim 1 or 2, characterized in that the monomer or monomers with ethylene unsaturation, containing a carboxyl function, are selected from ethacrylic, methacrylic and acrylic acids, mainly from methacrylic and acrylic acids, and mixtures thereof. 4. Композиция по любому из пп.1-3, отличающаяся тем, что мономер или мономеры с этиленовой ненасыщенностью, содержащие гидрофобную боковую цепь, выбирают из С10-С30-(предпочтительно С12-С22)алкиловых эфиров этакриловой, метакриловой и/или акриловой кислот.4. Composition according to any one of claims 1 to 3, characterized in that the monomer or ethylenically unsaturated monomers containing a hydrophobic side chain are selected from C 10 -C 30 - (preferably C 12 -C 22 ) alkyl esters of ethacrylic, methacrylic and / or acrylic acid. 5. Композиция по любому из пп.1-3, отличающаяся тем, что мономер или мономеры с этиленовой ненасыщенностью, содержащие гидрофобную боковую цепь, выбирают из аллиловых эфиров жирных спиртов, соответствующих формуле
СH2=CR'CH2-O-Bn-R (I)
в которой R' обозначает атом водорода или метильную группу,
В обозначает этиленокси-группу;
n обозначает целое число от 0 до 100;
R обозначает углеводородную группу, выбранную из остатков алкила, арилалкила, арила, алкиларила или циклоалкила, содержащих от 8 до 30, предпочтительно, от 10 до 24 атомов углерода.5. Composition according to any one of claims 1 to 3, characterized in that the monomer or monomers with ethylene unsaturation, containing a hydrophobic side chain, are selected from allyl esters of fatty alcohols corresponding to the formula
СH 2 = CR'CH 2 -OB n -R (I)
in which R 'denotes a hydrogen atom or a methyl group,
B represents ethyleneoxy;
n represents an integer from 0 to 100;
R is a hydrocarbon group selected from alkyl, arylalkyl, aryl, alkylaryl or cycloalkyl residues containing from 8 to 30, preferably from 10 to 24 carbon atoms. 6. Композиция по любому из предыдущих пунктов, отличающаяся тем, что анионный амфифильный полимер, содержащий по меньшей мере одну жирную цепь, содержит кроме того структурные звенья, образованные поперечно сшивающим мономером, содержащим две несопряженные этиленовые двойные связи. 6. Composition according to any one of the preceding paragraphs, characterized in that the anionic amphiphilic polymer containing at least one fat chain contains in addition structural units formed by a cross-linking monomer containing two non-conjugated ethylene double bonds. 7. Композиция по п. 6, отличающаяся тем, что названный выше поперечно сшивающий мономер выбирают из диаллилфталата, аллил(мет)акрилата, дивинилбензола, диметакрилата(поли)этиленгликоля, метилен-бис-акриламида, полиаллилсахарозы и полиаллилпентаэритрита. 7. The composition according to p. 6, characterized in that the above-mentioned cross-linking monomer is selected from diallyl phthalate, allyl (meth) acrylate, divinyl benzene, (poly) ethylene glycol dimethacrylate, methylene bis-acrylamide, polyallyl sucrose, and polyallyl pentaerythritol. 8. Композиция по пп.1-7, отличающаяся тем, что анионный амфифильный полимер, содержащий по меньшей мере одну жирную цепь, является сшитым сополимером акриловой кислоты и С10-С30-алкилакрилата.8. The composition according to claims 1-7, characterized in that the anionic amphiphilic polymer containing at least one fatty chain, is a crosslinked copolymer of acrylic acid and C 10 -C 30 -alkyl acrylate. 9. Композиция по п.1, отличающаяся тем, что названный выше неионный амфифильный полимер, содержащий по меньшей мере одну жирную цепь, выбирают из целлюлоз или гидроксиалкилцеллюлоз, модифицированных группами, содержащими по меньшей мере одну жирную цепь алкильного, арилалкильного или алкиларильного типа с преимущественно 8-22 атомами углерода в алкильной группе, или полиалкоксилированными алкилфенольными группами; гидроксипропилгуаров, модифицированных группами, содержащими по меньшей мере одну жирную цепь с 8-22 атомами углерода; полиуретанов, содержащих по меньшей мере одну жирную цепь алкильного или алкенильного типа с 8-30 атомами углерода; сополимеров винилпирролидона и гидрофобных мономеров с жирной цепью; сополимеров C1-С6-алкиловых эфиров (мет)акриловой кислоты и амфифильных мономеров с по меньшей мере одной жирной цепью; сополимеров гидрофильных (мет)акрилатов и гидрофобных мономеров, содержащих по меньшей мере одну жирную цепь.9. The composition according to claim 1, characterized in that the above-mentioned non-ionic amphiphilic polymer containing at least one fatty chain is selected from cellulose or hydroxyalkylcellulose, modified by groups containing at least one fatty chain of alkyl, arylalkyl or alkylaryl type with mainly 8-22 carbon atoms in the alkyl group, or polyalkoxylated alkylphenol groups; hydroxypropylguars modified with groups containing at least one fatty chain with 8-22 carbon atoms; polyurethanes containing at least one fatty chain of alkyl or alkenyl type with 8-30 carbon atoms; copolymers of vinylpyrrolidone and fatty chain hydrophobic monomers; copolymers of C 1 -C 6 -alkyl esters of (meth) acrylic acid and amphiphilic monomers with at least one fatty chain; copolymers of hydrophilic (meth) acrylates and hydrophobic monomers containing at least one fatty chain. 10. Композиция по п.9, отличающаяся тем, что неионный амфифильный полимер, содержащий по меньшей мере одну жирную цепь, является гидроксиэтилцеллюлозой, модифицированной группами, содержащими по меньшей мере одну С8-С22-алкильную группу, или полиуретаном, модифицированным по меньшей мере одной С10-С20-алкильной цепью.10. The composition according to claim 9, characterized in that the non-ionic amphiphilic polymer containing at least one fatty chain is hydroxyethylcellulose modified with groups containing at least one C 8 -C 22 -alkyl group, or polyurethane modified with at least measure one C 10 -C 20 -alkyl chain. 11. Композиция по любому из предыдущих пунктов, отличающаяся тем, что анионный амфифильный полимер и/или неионный амфифильный полимер, содержащие по меньшей мере одну жирную цепь, присутствуют в количестве от 0,03 до 30 и, предпочтительно, от 0,3 до 15% от общей массы безводной композиции. 11. Composition according to any one of the preceding paragraphs, characterized in that the anionic amphiphilic polymer and / or non-ionic amphiphilic polymer containing at least one fatty chain, are present in an amount of from 0.03 to 30 and, preferably, from 0.3 to 15 % of the total mass of the anhydrous composition. 12. Композиция по любому из предыдущих пунктов, отличающаяся тем, что катионный или амфотерный субстантивный полимер является полимером, содержащим структурные звенья с первичными, вторичными, третичными и/или четвертичными аминогруппами, которые могут либо составлять часть главной полимерной цепи, либо находиться в боковом заместителе, непосредственно связанном с главной цепью, и обладающим среднечисленной молекулярной массой от 500 до 5•106 и, предпочтительно, от 103 до 3•106.12. Composition according to any one of the preceding paragraphs, characterized in that the cationic or amphoteric substantive polymer is a polymer containing structural units with primary, secondary, tertiary and / or quaternary amino groups, which can either form part of the main polymer chain or be in a side substituent directly connected to the main chain, and having a number average molecular weight of from 500 to 5 • 10 6 and, preferably, from 10 3 to 3 • 10 6 . 13. Композиция по п.12, отличающаяся тем, что названный субстантивный полимер выбирают из производных кватернизованной целлюлозы и полиакрилатов с кватернизованными или некватернизованными амино-содержащими боковыми группами. 13. The composition according to p. 12, characterized in that the named substantive polymer is chosen from derivatives of quaternary cellulose and polyacrylates with quaternized or non-quaternary amino-containing side groups. 14. Композиция по п.13, отличающаяся тем, что производные кватернизованной целлюлозы выбирают из кватернизованных целлюлоз, модифицированных группами, содержащими по меньшей мере одну жирную цепь, выбираемыми из алкильных, арилалкильных и алкиларильных групп, содержащих по меньшей мере 8 атомов углерода, или их смесей; и кватернизованных гидроксиэтилцеллюлоз, модифицированных группами, содержащими по меньшей мере одну жирную цепь, выбираемыми из алкильных, арилалкильных и алкиларильных групп, содержащих по меньшей мере 8 атомов углерода, или их смесей. 14. The composition according to p. 13, characterized in that the derivatives of quaternary cellulose are selected from quaternized cellulose, modified by groups containing at least one fatty chain, selected from alkyl, arylalkyl and alkylaryl groups containing at least 8 carbon atoms, or mixtures; and quaternized hydroxyethyl celluloses modified with groups containing at least one fatty chain selected from alkyl, arylalkyl and alkylaryl groups containing at least 8 carbon atoms, or mixtures thereof. 15. Композиция по п. 12, отличающаяся тем, что названный катионный субстантивный полимер представляет собой гомополимер хлорида диметилдиаллиламмония или сополимер диметилдиаллиламмония с акриламидом. 15. The composition according to p. 12, characterized in that the named cationic substantive polymer is a homopolymer of dimethyldiallylammonium chloride or a copolymer of dimethyldiallylammonium with acrylamide. 16. Композиция по п.12, отличающаяся тем, что названный катионный субстантивный полимер представляет собой поли(четвертичный аммоний), образованный структурными звеньями, отвечающими формуле
Figure 00000001

Figure 00000002

или же формуле
Figure 00000003

в которой р обозначает целое число от 1 до 6;
D обозначает простую связь или группу -(СН2)r-СО, где r равно 4 или 7.16. The composition according to p. 12, characterized in that the named cationic substantive polymer is a poly (quaternary ammonium), formed by structural units corresponding to the formula
Figure 00000001

Figure 00000002

or formula
Figure 00000003

in which p denotes an integer from 1 to 6;
D means a simple bond or a group - (CH 2 ) r —CO, where r is 4 or 7. 17. Композиция по п. 12, отличающаяся тем, что названный амфотерный субстантивный полимер выбирают из Polyquaternium-22, Polyquaternium-39 и Polyquaternium-47. 17. The composition according to p. 12, characterized in that the named amphoteric substantive polymer is chosen from Polyquaternium-22, Polyquaternium-39 and Polyquaternium-47. 18. Композиция по любому из предыдущих пунктов, отличающаяся тем, что названный катионный или амфотерный субстантивный полимер присутствует в количестве от 0,03 до 30 и, предпочтительно, от 0,3 до 15% от общей массы безводной композиции. 18. Composition according to any one of the preceding paragraphs, characterized in that said cationic or amphoteric substantive polymer is present in an amount of from 0.03 to 30, and preferably from 0.3 to 15% of the total weight of the anhydrous composition. 19. Композиция по любому из предыдущих пунктов, отличающаяся тем, что массовое отношение анионного и/или неионного амфифильного полимера к катионному или амфотерному субстантивному полимеру составляет от 10/1 до 1/10 и, предпочтительно, от 5/1 до 1/5. 19. Composition according to any one of the preceding paragraphs, characterized in that the mass ratio of anionic and / or non-ionic amphiphilic polymer to cationic or amphoteric substantive polymer is from 10/1 to 1/10 and, preferably, from 5/1 to 1/5. 20. Композиция по любому из предыдущих пунктов, отличающаяся тем, что названный щелочной агент выбирают из аммониевых солей, таких как хлорид, сульфат, фосфат или нитрат аммония, силикатов, фосфатов или карбонатов щелочных или щелочно-земельных металлов, в частности, метасиликатов щелочных металлов. 20. Composition according to any one of the preceding paragraphs, characterized in that the said alkaline agent is selected from ammonium salts, such as ammonium chloride, sulfate, phosphate or nitrate, silicates, phosphates or carbonates of alkali or alkaline-earth metals, in particular alkali metal metasilicates . 21. Композиция по любому из предыдущих пунктов, отличающаяся тем, что названную перекисную соль выбирают из персульфатов, перкарбонатов и перборатов аммония или щелочных металлов, в частности, из персульфатов натрия и калия. 21. Composition according to any one of the preceding paragraphs, characterized in that the said peroxide salt is selected from persulfates, percarbonates and ammonium or alkali metal perborates, in particular, from sodium and potassium persulfates. 22. Композиция по п.21, отличающаяся тем, что названная перекисная соль присутствует в количестве от 20 до 70 и, предпочтительно, от 30 до 60% в расчете на безводную композицию. 22. The composition according to p. 21, characterized in that the peroxide salt is present in an amount of from 20 to 70 and, preferably, from 30 to 60%, calculated on the anhydrous composition. 23. Композиция по любому из предыдущих пунктов, отличающаяся тем, что она дополнительно содержит облегчающие процесс обесцвечивания добавки, выбираемые из следующей группы: агенты, регулирующие выделение кислорода; загущающие или гелеобразующие полимеры; анионные, неионогенные, катионные, амфотерные или цвиттерионные поверхностно-активные агенты и их смеси; минеральные и растительные масла; воски; гранулирующие добавки; связующие; минеральные наполнители; матирующие агенты, такие как оксид титана; красители; комплексообразователи и отдушки. 23. Composition according to any one of the preceding paragraphs, characterized in that it further comprises additives that facilitate the bleaching process, selected from the following group: agents that regulate the release of oxygen; thickening or gelling polymers; anionic, nonionic, cationic, amphoteric or zwitterionic surface-active agents, and mixtures thereof; mineral and vegetable oils; waxes; granulating additives; binders; mineral fillers; matting agents such as titanium oxide; colorants; complexing agents and fragrances. 24. Композиция по п.23, отличающаяся тем, что она содержит от 0,01 до 40 и, предпочтительно, от 0,1 до 30 мас.% по меньшей мере одного поверхностно-активного агента. 24. The composition according to p. 23, characterized in that it contains from 0.01 to 40 and, preferably, from 0.1 to 30 wt.% At least one surface-active agent. 25. Композиция по любому из предыдущих пунктов, отличающаяся тем, что она находится в виде порошка или суспензии или дисперсии порошка в безводном жидком органическом носителе. 25. Composition according to any one of the preceding paragraphs, characterized in that it is in the form of a powder or a suspension or dispersion of a powder in an anhydrous liquid organic carrier. 26. Композиция по любому из предыдущих пунктов, отличающаяся тем, что ее используют для получения готовой к применению обесцвечивающей композиции путем добавления водной композиции перекиси водорода. 26. Composition according to any one of the preceding paragraphs, characterized in that it is used to obtain a decolorizing composition ready for use by adding an aqueous composition of hydrogen peroxide. 27. Способ обесцвечивания кератиновых волокон, в частности, волос человека, включающий следующие стадии смешивание непосредственно перед применением безводной обесцвечивающей композиции, определенной в любом из пп.1-25, с водной перекисноводородной композицией; нанесение полученной смеси на подлежащий обесцвечиванию участок кератиновых волокон; выдерживание в течение времени, достаточного для получения желаемого обесцвечивания; и удаление обесцвечивающей смеси ополаскиванием водой с последующими промывкой шампунем и сушкой. 27. The method of bleaching keratin fibers, in particular, human hair, comprising the following stages of mixing immediately before use anhydrous bleaching composition, as defined in any of paragraphs.1-25, with an aqueous peroxide hydrogen composition; applying the mixture to be subject to bleaching area of keratin fibers; aging for a time sufficient to obtain the desired discoloration; and rinsing the bleach mixture with water followed by shampooing and drying. 28. Устройство с несколькими отделениями, или "набор", для обесцвечивания кератиновых волокон, в частности, кератиновых волокон человека, таких как волосы, отличающееся тем, что оно содержит по меньшей мере два отделения, в одном из которых находится безводная обесцвечивающая композиция по любому из пп.1-25, а в другом - водная композиция перекиси водорода. 28. A device with several compartments, or "kit", for bleaching keratin fibers, in particular, human keratin fibers, such as hair, characterized in that it contains at least two compartments, one of which contains an anhydrous bleaching composition according to any from PP.1-25, and in another - the aqueous composition of hydrogen peroxide.
RU2000102305/14A 1999-01-29 2000-01-28 Anhydrous composition for decolorization of keratin fibers containing combination of anionic and/or nonionic amphiphilous polymers with at least one fat chain and cationic or amphoteric substantive polymers RU2200540C2 (en)

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FR9901054 1999-01-29
FR9901054A FR2788974B1 (en) 1999-01-29 1999-01-29 KERATINIC FIBER DECOLORING ANHYDROUS COMPOSITION COMPRISING THE ASSOCIATION OF ANIONIC AND / OR NON-IONIC AMPHIPHILIC POLYMERS COMPRISING AT LEAST ONE FATTY CHAIN AND CATIONIC OR AMPHOTERIC SUBSTANTIVE POLYMERS

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RU2200540C2 RU2200540C2 (en) 2003-03-20

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