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RU1828458C - Method of roastingless filler making - Google Patents

Method of roastingless filler making

Info

Publication number
RU1828458C
RU1828458C SU884356255A SU4356255A RU1828458C RU 1828458 C RU1828458 C RU 1828458C SU 884356255 A SU884356255 A SU 884356255A SU 4356255 A SU4356255 A SU 4356255A RU 1828458 C RU1828458 C RU 1828458C
Authority
RU
Russia
Prior art keywords
fly ash
granules
ash
water
aggregate
Prior art date
Application number
SU884356255A
Other languages
Russian (ru)
Inventor
Йоханнес Спанйер Якобус
Дирк Радемакер Питер
Original Assignee
Арделит Холдинг Б.В.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Арделит Холдинг Б.В. filed Critical Арделит Холдинг Б.В.
Priority to LV920615A priority Critical patent/LV5112A3/en
Application granted granted Critical
Publication of RU1828458C publication Critical patent/RU1828458C/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/02Agglomerated materials, e.g. artificial aggregates
    • C04B18/021Agglomerated materials, e.g. artificial aggregates agglomerated by a mineral binder, e.g. cement
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/18Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing mixtures of the silica-lime type
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/02Selection of the hardening environment
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/582Recycling of unreacted starting or intermediate materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/60Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S106/00Compositions: coating or plastic
    • Y10S106/01Fly ash
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S264/00Plastic and nonmetallic article shaping or treating: processes
    • Y10S264/49Processes of using fly ash

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Civil Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Toxicology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Processing Of Solid Wastes (AREA)
  • Ceramic Products (AREA)
  • Glass Compositions (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Glanulating (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
  • Braking Arrangements (AREA)

Abstract

A mixture of inorganic binder, water and fly ash is granulated; the formed granules (7) are deposited upon a continuously supplied layer of fly ash embedding material (9) and said fly ash layer together with granules is fed into a hardening reactor (14). The granules are hardened by injecting steam (16) into the reactor so that the temperature of the granules is raised and maintained at a temperature comprised between 50 and 100 DEG C. After curing the hardened granules are separated from the embedding material which is used for forming new granules. The embedding material has a water absorbing capacity of 15-25% and the pH of the moist embedding material is above 4.

Description

Изобретение относитс  к изготовлению безобжигового заполнител , преимущественно из золы от сжигани  угл  или лигнита с добавкой св зующего и воды.FIELD OF THE INVENTION This invention relates to the manufacture of a non-calcined aggregate, mainly from ash from the combustion of coal or lignite with the addition of a binder and water.

Цель изобретени  - повышение прочности заполнител .The purpose of the invention is to increase the strength of the aggregate.

Способ осуществл ют следующим образомThe method is as follows

Зольную пыль теплоэлектростанций от сжигани  угл  смешивают с порошкообразной известью быстрого гашени  и водой до получени  однородной массы, которую гранулируют до размера гранул 7,9 - 10 мм. Сформованные зольные гранулы смешивают с зольной пылью, имеющей водопогло- щение не менее 10%, преимущественно 15 - 25%, и при их объемном соотношении 1 : (0,2 - 1), предпочтительно 1 : 0,4, подвергают твердению в вертикальных тепловых камерах непрерывного действи  в среде вод ного пара преимущественно при температуре 71 - 100°С При введении зольных гранул во влажную зольную пыль процесс ведут при рН увлажненной пыли свыше 4The fly ash of thermal power plants from burning coal is mixed with powdered quicklime lime and water until a homogeneous mass is obtained, which is granulated to a granule size of 7.9-10 mm. Formed fly ash granules are mixed with fly ash having a water absorption of at least 10%, preferably 15 to 25%, and when their volume ratio is 1: (0.2 - 1), preferably 1: 0.4, they are hardened in vertical heat chambers of continuous action in the environment of water vapor, mainly at a temperature of 71-100 ° C. When ash granules are introduced into wet ash dust, the process is conducted at a pH of moistened dust above 4

В таблице приведены конкретные примеры реализации способа со свойствами получаемого заполнител  из отвержденных зольных гранул.The table shows specific examples of the method with the properties of the obtained aggregate from the cured ash granules.

После тепловлажностной обработки от- вержденные зольные гранулы имеют насыпную плотность 900 - 1050 кг/м , прочность при сжатии составл ет 3,5 - 3,9 МПа.After heat and moisture treatment, the cured ash granules have a bulk density of 900–1050 kg / m, and the compressive strength is 3.5–3.9 MPa.

Способ обеспечивает равномерное твердение гранул без образовани  трещин при исключении конденсации пара на их поверхности, что позвол ет сохранить плотность наружных слоев гранул и тем самым повысить их прочностьThe method provides uniform hardening of the granules without cracking, with the exception of steam condensation on their surface, which allows to maintain the density of the outer layers of the granules and thereby increase their strength

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Гранулы можно подавать на слой зольной пыли, а затем вводить их в тепловую камеру. Пар можно подавать в тепловую камеру после загрузки смеси заполнител  и зольной пыли. В качестве св зующего воз- можно использование гидрооксида кальци , известкового молока или цемента. Заполнитель можно изготавливать из смеси извести, золы, песка и воды или из смеси, извести, золы, дигидрида сульфата кальци  и воды.Granules can be fed to a layer of fly ash, and then introduced into a heat chamber. Steam can be fed into the heat chamber after loading the aggregate and fly ash mixture. As a binder, calcium hydroxide, milk of lime or cement may be used. The aggregate may be made from a mixture of lime, ash, sand and water, or from a mixture of lime, ash, calcium sulfate dihydride and water.

Claims (8)

Формула изобретени  1. Способ изготовлени  безообжигово- го заполнител  преимущественно из золы от сжигани  угл  или лигнита с добавкой св зующего и воды путем формовани  гранул и последующего твердени  в вертикальных тепловых камерах непрерывного действи  в среде вод ного пара при 29,4 - 100°С, отличающийс  тем, что, целью повышени  прочности заполнител , сфор- мированнные зольные гранулы предварительно смешивают с зольной пылью с водопоглощением не менее 10% при их объемном соотношении 1 : (0,2 - 1), а процесс ведут при рН влажной зольной пыли более 4.SUMMARY OF THE INVENTION 1. A method of manufacturing a non-fired aggregate mainly from ash from the burning of coal or lignite with the addition of a binder and water by molding granules and subsequent hardening in vertical heat chambers of continuous action in the environment of water vapor at 29.4-100 ° C, characterized in that, in order to increase the strength of the aggregate, the formed ash granules are pre-mixed with fly ash with a water absorption of at least 10% at a volume ratio of 1: (0.2 - 1), and the process is carried out at a pH of wet fly ash more than 4. 2.Способ по п.1,отличающийс  тем, что гранулы заполнител  предварительно подают на слой зольной пыли, а затем ввод т их в тепловую камеру.2. The method according to claim 1, characterized in that the aggregate granules are first fed to the fly ash layer and then introduced into the heat chamber. 3.Способ по п.1.отличающийс  тем, что пар подают в камеру после загрузки смеси заполнител  и зольной пыли.3. The method according to claim 1, characterized in that the steam is fed into the chamber after loading the mixture of aggregate and fly ash. 4.Способ по п.1,отличающийс  тем, что твердение ведут при 71 - 100°С.4. The method according to claim 1, characterized in that the hardening is carried out at 71-100 ° C. 5.Способ по п.1,отличающийс  тем, что соотношении гранул заполнител  и зольной пыли составл ет предпочтительно 1 : 0,4.5. The method according to claim 1, characterized in that the ratio of aggregate to fly ash granules is preferably 1: 0.4. 6.Способ по п.1,отличающийс  тем, что водопоглощение зольной пыли составл ет 15-25%.6. The method according to claim 1, characterized in that the water absorption of fly ash is 15-25%. 7.Способ по п. 1. отличающийс  тем, что в качестве св зующего при изготовлении гранул используют гидроксид кальци , или известковое молоко, или цемент.7. A method according to claim 1. characterized in that calcium hydroxide or milk of lime or cement is used as a binder in the manufacture of granules. 8.Способ по п.1,отличающийс  тем, что заполнитель изготавливают из смеси извести, золы, песка и воды, или из смеси извести, золы, воды и других продуктов сгорани , или из смеси извести, золы, дигидра- та сульфата кальци  и воды.8. The method according to claim 1, characterized in that the aggregate is made from a mixture of lime, ash, sand and water, or from a mixture of lime, ash, water and other combustion products, or from a mixture of lime, ash, calcium sulfate dihydrate and water. Наименование показателейThe name of indicators Вид компонентов и их расход на приготовление сырьевой смеси, кг: Type of components and their consumption for the preparation of the raw mix, kg: зольна  пыльfly ash известьlime дигидрат сульфата кальци calcium sulfate dihydrate водаwater Объемное соотношение гранул с зольно пыльюVolume ratio of granules with fly ash рН влажной зольной пыли Температура твердени  зольных гранул, ° Водопоглощение зольной пыли, % Характеристика зольного грави  после тепловой обработки:pH of wet fly ash Hardening temperature of fly ash granules, ° Water absorption of fly ash,% Characteristics of fly ash after heat treatment: оabout Плотность насыпани , кг/м прочность, МПаDensity, kg / m strength, MPa Известный способKnown method 1,921.92 1,21,2 17,617.6 1:11: 1 7,0 100 257.0 100 25 900-1050 3,5900-1050 3.5 750-950 0,4-1,0750-950 0.4-1.0
SU884356255A 1987-07-22 1988-07-21 Method of roastingless filler making RU1828458C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
LV920615A LV5112A3 (en) 1987-07-22 1992-12-30 Uncooked filler gain

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/076,313 US4880582A (en) 1987-07-22 1987-07-22 Hardening granulated material at elevated temperatures

Publications (1)

Publication Number Publication Date
RU1828458C true RU1828458C (en) 1993-07-15

Family

ID=22131192

Family Applications (1)

Application Number Title Priority Date Filing Date
SU884356255A RU1828458C (en) 1987-07-22 1988-07-21 Method of roastingless filler making

Country Status (14)

Country Link
US (1) US4880582A (en)
EP (1) EP0301661B1 (en)
JP (1) JPH0813694B2 (en)
CN (1) CN1026665C (en)
AT (1) ATE88685T1 (en)
AU (1) AU600842B2 (en)
CA (1) CA1313030C (en)
DE (1) DE3880575T2 (en)
ES (1) ES2040831T3 (en)
IL (1) IL87143A (en)
LT (1) LT3819B (en)
RU (1) RU1828458C (en)
UA (1) UA11074A (en)
ZA (1) ZA885350B (en)

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US5364572A (en) * 1993-01-28 1994-11-15 Consolidation Coal Company Process for making high-strength synthetic aggregates
US5584895A (en) * 1994-04-18 1996-12-17 Ngk Insulators, Ltd. Process for preparing solidified material containing coal ash
EP0784035A1 (en) * 1995-12-22 1997-07-16 Hoogovens Technical Services Energy & Environment BV Method for processing particulate materials into hardened granules
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NL1005470C2 (en) * 1997-03-07 1998-09-08 Recycling Mij Feniks B V General construction material production from waste materials
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US6054074A (en) * 1998-09-22 2000-04-25 Consol, Inc. Method for making manufactured aggregates from coal combustion by-products
SE529971C2 (en) * 2005-03-23 2008-01-22 Delta Of Sweden Ab A material mixture comprising particles or grains and a binder consisting of at least two components
US7459411B2 (en) * 2005-10-14 2008-12-02 B.B.B.-Development And Production Of Building Products Ltd. Ceramic building elements
GB0621467D0 (en) * 2006-10-27 2006-12-06 Geodur Internat Ag Improvements relating to residues
WO2019167036A1 (en) 2018-02-27 2019-09-06 Dead Sea Works Ltd. Potash dust granulation process
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Also Published As

Publication number Publication date
EP0301661B1 (en) 1993-04-28
AU600842B2 (en) 1990-08-23
EP0301661A2 (en) 1989-02-01
DE3880575T2 (en) 1993-09-23
ES2040831T3 (en) 1993-11-01
ZA885350B (en) 1989-05-30
EP0301661A3 (en) 1990-02-07
US4880582A (en) 1989-11-14
CN1026665C (en) 1994-11-23
UA11074A (en) 1996-12-25
IL87143A (en) 1991-11-21
LT3819B (en) 1996-03-25
DE3880575D1 (en) 1993-06-03
IL87143A0 (en) 1988-12-30
JPH0813694B2 (en) 1996-02-14
JPS6451361A (en) 1989-02-27
ATE88685T1 (en) 1993-05-15
AU1925088A (en) 1989-01-27
CA1313030C (en) 1993-01-26
LTIP1772A (en) 1995-07-25
CN1032116A (en) 1989-04-05

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