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PL409053A1 - Method for obtaining phenol-formaldehyde resin for production of filter papers - Google Patents

Method for obtaining phenol-formaldehyde resin for production of filter papers

Info

Publication number
PL409053A1
PL409053A1 PL409053A PL40905314A PL409053A1 PL 409053 A1 PL409053 A1 PL 409053A1 PL 409053 A PL409053 A PL 409053A PL 40905314 A PL40905314 A PL 40905314A PL 409053 A1 PL409053 A1 PL 409053A1
Authority
PL
Poland
Prior art keywords
phenol
stage
production
mole
minutes
Prior art date
Application number
PL409053A
Other languages
Polish (pl)
Other versions
PL225883B1 (en
Inventor
Bronisław Kałędkowski
Grzegorz Rokosz
Mariusz Szemień
Andrzej Ziobrowski
Bogusława Kacała
Teresa Masłowska
Grzegorz Czochara
Grażyna Bieniek
Bolesław Łoziński
Janina Fila
Original Assignee
Instytut Ciężkiej Syntezy Organicznej BLACHOWNIA
Lerg Spółka Akcyjna
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Instytut Ciężkiej Syntezy Organicznej BLACHOWNIA, Lerg Spółka Akcyjna filed Critical Instytut Ciężkiej Syntezy Organicznej BLACHOWNIA
Priority to PL409053A priority Critical patent/PL225883B1/en
Publication of PL409053A1 publication Critical patent/PL409053A1/en
Publication of PL225883B1 publication Critical patent/PL225883B1/en

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  • Phenolic Resins Or Amino Resins (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Sposób otrzymywania żywicy fenolowej do produkcji papierów filtracyjnych polega na tym, że • w pierwszym etapie prowadzi się kondensację fenolu z formaldehydem przy stosunku molowym fenol : formaldehyd w granicach 1 : 1,7 ÷ 2,0, w obecności trzeciorzędowych alkiloamin o podstawnikach C2 ÷ C4 lub ich mieszanin, w ilości 5 - 20g na 1 mol fenolu, w temperaturze 60 ÷ 70°C, w czasie 30 ÷ 180 minut, • w drugim etapie prowadzi się reakcję w temperaturze 65 ÷ 75°C przez 240 ÷ 420 minut, • w trzecim etapie kontynuuje się proces w temperaturze 70 ÷ 100°C do uzyskania czasu żelowania w 130°C w granicach 230 ÷ 280 sekund, • w czwartym etapie wprowadza się mocznik w ilości 5 ÷ 10 g na 1 mol fenolu i prowadzi się reakcję w temperaturze 20 ÷ 50°C w czasie 30 ÷ 300 minut. Następnie mieszaninę reakcyjną zatęża się do zawartości poniżej 10% wagowych wody, potem rozcieńcza się ją alkoholami C1 ÷ C4 lub ich mieszaninami do lepkości w granicach 200 ÷ 600 mPa·S, dodaje się mono- i/lub dietanoloaminę w ilości 0,0005 ÷ 0,20 mola na 1 mol fenolu.The method of obtaining phenolic resin for the production of filter papers is that: • in the first stage, phenol and formaldehyde are condensed at a phenol: formaldehyde ratio of 1: 1.7 ÷ 2.0, in the presence of tertiary alkylamines with C2 ÷ C4 substituents or mixtures thereof, in an amount of 5 - 20g per 1 mole of phenol, at a temperature of 60 ÷ 70 ° C, for 30 ÷ 180 minutes, • in the second stage the reaction is carried out at a temperature of 65 ÷ 75 ° C for 240 ÷ 420 minutes, • in the third stage, the process is continued at 70 ÷ 100 ° C until gel time at 130 ° C within 230 ÷ 280 seconds, • in the fourth stage urea in the amount of 5 ÷ 10 g per 1 mole of phenol is introduced and the reaction is carried out temperature 20 ÷ 50 ° C for 30 ÷ 300 minutes. Then the reaction mixture is concentrated to less than 10% by weight of water, then it is diluted with C1 ÷ C4 alcohols or mixtures thereof to a viscosity within 200 ÷ 600 mPa · S, 0.0005 ÷ 0 mono- and / or diethanolamine is added , 20 moles per 1 mole of phenol.

PL409053A 2014-07-31 2014-07-31 Method for obtaining phenol-formaldehyde resin for production of filter papers PL225883B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL409053A PL225883B1 (en) 2014-07-31 2014-07-31 Method for obtaining phenol-formaldehyde resin for production of filter papers

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL409053A PL225883B1 (en) 2014-07-31 2014-07-31 Method for obtaining phenol-formaldehyde resin for production of filter papers

Publications (2)

Publication Number Publication Date
PL409053A1 true PL409053A1 (en) 2016-02-01
PL225883B1 PL225883B1 (en) 2017-05-31

Family

ID=55178468

Family Applications (1)

Application Number Title Priority Date Filing Date
PL409053A PL225883B1 (en) 2014-07-31 2014-07-31 Method for obtaining phenol-formaldehyde resin for production of filter papers

Country Status (1)

Country Link
PL (1) PL225883B1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111808249A (en) * 2020-07-22 2020-10-23 苏州兴业材料科技南通有限公司 Preparation method of phenolic resin for automobile filter paper

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111808249A (en) * 2020-07-22 2020-10-23 苏州兴业材料科技南通有限公司 Preparation method of phenolic resin for automobile filter paper

Also Published As

Publication number Publication date
PL225883B1 (en) 2017-05-31

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