PL398819A1 - Sposób otrzymywania bisfenolu A - Google Patents
Sposób otrzymywania bisfenolu AInfo
- Publication number
- PL398819A1 PL398819A1 PL398819A PL39881912A PL398819A1 PL 398819 A1 PL398819 A1 PL 398819A1 PL 398819 A PL398819 A PL 398819A PL 39881912 A PL39881912 A PL 39881912A PL 398819 A1 PL398819 A1 PL 398819A1
- Authority
- PL
- Poland
- Prior art keywords
- reactor
- acetone
- phenol
- adsorber
- reaction mixture
- Prior art date
Links
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 title abstract 6
- 238000000034 method Methods 0.000 title abstract 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract 16
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 10
- 239000011541 reaction mixture Substances 0.000 abstract 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 4
- 238000004821 distillation Methods 0.000 abstract 3
- 125000003368 amide group Chemical group 0.000 abstract 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 2
- 238000002425 crystallisation Methods 0.000 abstract 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 239000003381 stabilizer Substances 0.000 abstract 2
- 230000002378 acidificating effect Effects 0.000 abstract 1
- 239000012223 aqueous fraction Substances 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 238000006482 condensation reaction Methods 0.000 abstract 1
- 230000008025 crystallization Effects 0.000 abstract 1
- 238000001704 evaporation Methods 0.000 abstract 1
- 230000008020 evaporation Effects 0.000 abstract 1
- 238000009434 installation Methods 0.000 abstract 1
- 238000005342 ion exchange Methods 0.000 abstract 1
- 239000003456 ion exchange resin Substances 0.000 abstract 1
- 229920003303 ion-exchange polymer Polymers 0.000 abstract 1
- 239000002351 wastewater Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/11—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms
- C07C37/20—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms using aldehydes or ketones
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/68—Purification; separation; Use of additives, e.g. for stabilisation
- C07C37/70—Purification; separation; Use of additives, e.g. for stabilisation by physical treatment
- C07C37/74—Purification; separation; Use of additives, e.g. for stabilisation by physical treatment by distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/68—Purification; separation; Use of additives, e.g. for stabilisation
- C07C37/70—Purification; separation; Use of additives, e.g. for stabilisation by physical treatment
- C07C37/84—Purification; separation; Use of additives, e.g. for stabilisation by physical treatment by crystallisation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Sposób otrzymywania bisfenolu A w reakcji kondensacji acetonu z fenolem w obecnosci silnie kwasnych, sulfonowanych zywic jonowymiennych polega na tym, ze - mieszanine reakcyjna zawierajaca aceton, fenol oraz produkty reakcji fenolu z acetonem kontaktuje sie z katalizatorem jonitowym w co najmniej dwu reaktorach, do osiagniecia calkowitej zawartosci wody nie wiekszej niz 2,5 cg/g, przy czym do reaktora (1) wprowadza sie aceton i fenol, a do reaktora (3) wprowadza sie mieszanine poreakcyjna z reaktora (1) wymieszana w mieszalniku (2) z lugami pokrystalizacyjnymi z krystalizatorów (8) oraz z acetonem, - mieszanine poreakcyjna po reaktorze (3) miesza sie w mieszalniku (4) z czescia roztworu fenolowego, nie wieksza niz 40 cg/g, otrzymanego w wyniku kontaktowania mieszaniny odwadniajacej zawierajacej nie wiecej niz 1,0% wody, z katalizatorem jonitowym w co najmniej jednym reaktorze (5), - mieszanine poreakcyjna z mieszalnika (4) kontaktuje sie w adsorberze (6) w temperaturze nie wyzszej niz 150°C z szybkoscia przeplywu nie wieksza niz 10 m/h ze stabilizatorem odczynu roztworów fenolowych w postaci stacjonarnego zloza o wielkosci ziaren nie wiekszej niz 1,2 mm posiadajacym grupy funkcyjne karboksylowe i/lub hydroksylowe i/lub amidowe, do uzyskania pH 5-6 mieszaniny poreakcyjnej po adsorberze (6), - mieszanine poreakcyjna po adsorberze (6) zateza sie w kolumnie destylacyjnej (7) przez odparowanie czesci lub calosci lotnych skladników, jako destylat zawierajacy fenol, aceton i wode o temperaturze wrzenia pod cisnieniem normalnym nie wyzszej niz 200°C, a z wywaru wydziela sie bisfenol A na drodze krystalizacji, - nie mniej niz 60% roztworu fenolowego z reaktora (5) kontaktuje sie w adsorberze (9) w temperaturze nie wyzszej niz 150°C z szybkoscia przeplywu nie wieksza niz 10 m/h ze stabilizatorem odczynu roztworów fenolowych w postaci stacjonarnego zloza o wielkosci ziaren nie wiekszej niz 1,2 mm posiadajacym grupy funkcyjne karboksylowe i/lub hydroksylowe i/lub amidowe do uzyskania pH 5-6 mieszaniny po adsorberze (9), a otrzymany roztwór miesza sie z destylatem z kolumny destylacyjnej (7) zawierajacym fenol, aceton i wode i kieruje sie do kolumny destylacyjnej (10), - fenol wydzielony na kolumnie (10) zawraca sie do reaktora (1), aceton do reaktora (1) i/lub (3), a frakcje wodna jako scieki usuwa sie z instalacji.
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL398819A PL217484B1 (pl) | 2012-04-16 | 2012-04-16 | Sposób otrzymywania bisfenolu A |
| PCT/PL2013/050005 WO2013157972A2 (en) | 2012-04-16 | 2013-02-07 | Method of producing bisphenol a |
| RU2014145957A RU2619461C2 (ru) | 2012-04-16 | 2013-02-07 | Способ получения бисфенола a |
| CN201380031512.8A CN104540799B (zh) | 2012-04-16 | 2013-02-07 | 制造双酚a的方法 |
| DE112013002048.3T DE112013002048T5 (de) | 2012-04-16 | 2013-02-07 | Verfahren zur Herstellung von Bisphenol A |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL398819A PL217484B1 (pl) | 2012-04-16 | 2012-04-16 | Sposób otrzymywania bisfenolu A |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL398819A1 true PL398819A1 (pl) | 2013-10-28 |
| PL217484B1 PL217484B1 (pl) | 2014-07-31 |
Family
ID=48949202
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL398819A PL217484B1 (pl) | 2012-04-16 | 2012-04-16 | Sposób otrzymywania bisfenolu A |
Country Status (5)
| Country | Link |
|---|---|
| CN (1) | CN104540799B (pl) |
| DE (1) | DE112013002048T5 (pl) |
| PL (1) | PL217484B1 (pl) |
| RU (1) | RU2619461C2 (pl) |
| WO (1) | WO2013157972A2 (pl) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102016116078B3 (de) | 2016-08-29 | 2018-01-04 | Epc Engineering Consulting Gmbh | Verfahren zur Herstellung eines Polycarbonats unter Einsatz einer Strippvorrichtung |
| CN117597324A (zh) * | 2021-07-05 | 2024-02-23 | Sabic环球技术有限责任公司 | 制造双酚a的方法 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3326986A (en) * | 1965-01-22 | 1967-06-20 | Dow Chemical Co | Process for purifying 4, 4'-isopropylidenediphenol |
| JPS5764519A (en) | 1980-10-08 | 1982-04-19 | Nippon Synthetic Chem Ind Co Ltd:The | Process for film forming of ethylene-vinyl acetate copolymer saponified matter |
| US4950806A (en) * | 1988-02-22 | 1990-08-21 | Mitsui Toatsu Chemicals, Inc. | Process for crystallizing adduct of bisphenol A with phenol |
| CS272518B1 (cs) | 1988-12-15 | 1991-02-12 | Wiesner Ivo | Termooxidačně stabilizovaný dian |
| JPH08333290A (ja) | 1995-06-12 | 1996-12-17 | Mitsubishi Chem Corp | ビスフェノールａの製造方法 |
| PL181992B1 (pl) | 1996-01-10 | 2001-10-31 | Inst Ciezkiej Syntezy Orga | Sposób przerobu wysokowrzących produktów ubocznych z procesu wytwarzania bisfenolu A |
| US5705714A (en) | 1996-07-01 | 1998-01-06 | General Electric Company | Removal of metals and color bodies from chemically recycled bisphenol-A |
| USH1943H1 (en) * | 1998-12-15 | 2001-02-06 | General Electric Co. | Process for the manufacture of bisphenol-A |
| US6133486A (en) | 1998-12-30 | 2000-10-17 | General Electric Company | Phenol recovery from BPA process waste streams |
| JP3903634B2 (ja) * | 1999-03-31 | 2007-04-11 | 三菱化学株式会社 | ビスフェノールａの製造方法 |
| TW530045B (en) * | 1999-04-13 | 2003-05-01 | Idemitsu Petrochemical Co | Method of producing bisphenol A |
| RU2195444C1 (ru) * | 2001-06-15 | 2002-12-27 | ЗАО Стерлитамакский нефтехимический завод | Способ получения пространственно-затрудненных бис-фенолов |
| US6858759B2 (en) * | 2002-12-20 | 2005-02-22 | General Electric Company | Process for manufacture of bisphenols |
| CN100582069C (zh) * | 2003-11-13 | 2010-01-20 | 三菱化学株式会社 | 制备双酚a的方法 |
-
2012
- 2012-04-16 PL PL398819A patent/PL217484B1/pl unknown
-
2013
- 2013-02-07 CN CN201380031512.8A patent/CN104540799B/zh not_active Expired - Fee Related
- 2013-02-07 RU RU2014145957A patent/RU2619461C2/ru not_active IP Right Cessation
- 2013-02-07 WO PCT/PL2013/050005 patent/WO2013157972A2/en not_active Ceased
- 2013-02-07 DE DE112013002048.3T patent/DE112013002048T5/de not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| PL217484B1 (pl) | 2014-07-31 |
| RU2619461C2 (ru) | 2017-05-16 |
| CN104540799B (zh) | 2017-05-24 |
| RU2014145957A (ru) | 2016-06-10 |
| WO2013157972A3 (en) | 2014-07-24 |
| CN104540799A (zh) | 2015-04-22 |
| WO2013157972A2 (en) | 2013-10-24 |
| DE112013002048T5 (de) | 2015-03-05 |
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