PL123456B1 - Fungicide - Google Patents
Fungicide Download PDFInfo
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- PL123456B1 PL123456B1 PL1979230915A PL23091579A PL123456B1 PL 123456 B1 PL123456 B1 PL 123456B1 PL 1979230915 A PL1979230915 A PL 1979230915A PL 23091579 A PL23091579 A PL 23091579A PL 123456 B1 PL123456 B1 PL 123456B1
- Authority
- PL
- Poland
- Prior art keywords
- formula
- compound
- fungicide
- plants
- spraying
- Prior art date
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- 239000000417 fungicide Substances 0.000 title claims description 16
- 230000000855 fungicidal effect Effects 0.000 title claims description 11
- 150000001875 compounds Chemical class 0.000 claims description 16
- 239000013543 active substance Substances 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 150000003852 triazoles Chemical class 0.000 claims description 4
- LMBFAGIMSUYTBN-MPZNNTNKSA-N teixobactin Chemical compound C([C@H](C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H](CCC(N)=O)C(=O)N[C@H]([C@@H](C)CC)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H]1C(N[C@@H](C)C(=O)N[C@@H](C[C@@H]2NC(=N)NC2)C(=O)N[C@H](C(=O)O[C@H]1C)[C@@H](C)CC)=O)NC)C1=CC=CC=C1 LMBFAGIMSUYTBN-MPZNNTNKSA-N 0.000 claims description 3
- 241000196324 Embryophyta Species 0.000 description 7
- 238000005507 spraying Methods 0.000 description 6
- 239000000203 mixture Substances 0.000 description 4
- 239000002689 soil Substances 0.000 description 4
- 206010017533 Fungal infection Diseases 0.000 description 3
- 208000031888 Mycoses Diseases 0.000 description 3
- 239000012141 concentrate Substances 0.000 description 3
- 235000008504 concentrate Nutrition 0.000 description 3
- 244000038559 crop plants Species 0.000 description 3
- 231100000252 nontoxic Toxicity 0.000 description 3
- 230000003000 nontoxic effect Effects 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000004563 wettable powder Substances 0.000 description 3
- WURBVZBTWMNKQT-UHFFFAOYSA-N 1-(4-chlorophenoxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)butan-2-one Chemical compound C1=NC=NN1C(C(=O)C(C)(C)C)OC1=CC=C(Cl)C=C1 WURBVZBTWMNKQT-UHFFFAOYSA-N 0.000 description 2
- 229920001732 Lignosulfonate Polymers 0.000 description 2
- FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 description 2
- 239000007900 aqueous suspension Substances 0.000 description 2
- 229960000892 attapulgite Drugs 0.000 description 2
- 235000013339 cereals Nutrition 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- -1 for example Substances 0.000 description 2
- 235000019357 lignosulphonate Nutrition 0.000 description 2
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical class C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 2
- 229910052625 palygorskite Inorganic materials 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 240000004244 Cucurbita moschata Species 0.000 description 1
- 235000009854 Cucurbita moschata Nutrition 0.000 description 1
- 235000009852 Cucurbita pepo Nutrition 0.000 description 1
- 241000221785 Erysiphales Species 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 239000005802 Mancozeb Substances 0.000 description 1
- 229910000503 Na-aluminosilicate Inorganic materials 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 239000011717 all-trans-retinol Substances 0.000 description 1
- 235000019169 all-trans-retinol Nutrition 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 description 1
- YHAIUSTWZPMYGG-UHFFFAOYSA-L disodium;2,2-dioctyl-3-sulfobutanedioate Chemical compound [Na+].[Na+].CCCCCCCCC(C([O-])=O)(C(C([O-])=O)S(O)(=O)=O)CCCCCCCC YHAIUSTWZPMYGG-UHFFFAOYSA-L 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000004495 emulsifiable concentrate Substances 0.000 description 1
- 230000002538 fungal effect Effects 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- VSXGXPNADZQTGQ-UHFFFAOYSA-N oxirane;phenol Chemical class C1CO1.OC1=CC=CC=C1 VSXGXPNADZQTGQ-UHFFFAOYSA-N 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- LVTJOONKWUXEFR-FZRMHRINSA-N protoneodioscin Natural products O(C[C@@H](CC[C@]1(O)[C@H](C)[C@@H]2[C@]3(C)[C@H]([C@H]4[C@@H]([C@]5(C)C(=CC4)C[C@@H](O[C@@H]4[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@@H](O)[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@H](CO)O4)CC5)CC3)C[C@@H]2O1)C)[C@H]1[C@H](O)[C@H](O)[C@H](O)[C@@H](CO)O1 LVTJOONKWUXEFR-FZRMHRINSA-N 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000000429 sodium aluminium silicate Substances 0.000 description 1
- 235000012217 sodium aluminium silicate Nutrition 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 235000020354 squash Nutrition 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Dentistry (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Plural Heterocyclic Compounds (AREA)
Description
Przedmiotem wynalazku jest srodek grzybobój¬ czy stosowany do zwalczania infekcji grzybowych roslin uprawnych.Srodek grzybobójczy wedlug wynalazku zawie¬ ra jako substancje, czynna pochodna triazolu - 5 o wzorze 1 i zwiazek o wzorze 2, w polaczeniu z to najmniej jednym obojetnym, nietrujacym dla roslin nosnikiem.Wyzej wymienione zwiazki sa znane i moga byc wytwarzane metodami opisanymi w literaturze. Po- 10 chodna triazolu o wzorze 1 przedstawiono w opisie ^patentowym Stanów Zjednoczonych Ameryki nr 3 9il|2 752, a pochodna mocznika o wzorze 2 w opisie patentowym Wielkiej Brytanii nr 1 470 740.Nieoczekiwanie stwierdzono, ze nowy srodek 15 grzybobójczy wedlug wynalazku zawierajacy mie¬ szanine podanych substancji czynnych jest skutecz¬ ny w hamowaniu wzrostu lub zwalczaniu infekcji grzybowych roslin uprawnych. Jest on szczególnie uzyteczny w zwalczaniu grzybów atakujacych sze- 20 reg roslin uprawnych, takich jak zboza i fasola, a w szczególnosci roslin podatnych na atak macz- niaka lub rdzy, tzn. roslin takich jak winorosl, dynia i tyton, podatnych na atak takich drobno¬ ustrojów, jak Ooomycestes i Erysiphales. 25 Srodek grzybobójczy wedlug wynalazku stosuje sie do zwalczania infekcji grzybowych roslin, a zwlaszcza winorosli. Srodek stosuje sie do opry¬ skiwania lisci lub gleby, w zaleznosci od rodzaju gleby, w dowolnym etapie jej wzrostu, az do okre- 30 sów zbiorów. Stopien i czestotliwosc opryskiwania zalezy od ostrosci lub spodziewanej ostrosci zarazy grzybowej, a takze, co jest oczywiste dla fachow¬ ców, od wieku i stanu rosliny. Szczególna zaleta srodka grzybobójczego wedlug wynalazku polega jednak na tym, ze mozna go stosowac skutecznie ze zmniejszona czestotliwoscia, np. jedynie raz na 2 do 3 tygodni, przy zwalczaniu maczniaka win¬ nego, osiagajac w ten sposób znaczne obnizenie ko¬ sztów robocizny.\ Jak to zaznaczono powyzej, srodki grzybobójcze wedlug wynalazku mozna stosowac do opryskiwa¬ nia lisci lub gleby. Przy spryskiwaniu gleby zwia¬ zek o wzorze -1 stosuje sie w ilosci od 50 do 500 g/ha.Przy spryskiwaniu lisci^zwiazek o wzorze 1 ko¬ rzystnie stosuje sie w ilosci od 10 do 500 g/ha, a zwiazek o wzorze 2 korzystnie stosuje sie w ilo¬ sci od 50 do 500 g/ha. Zgodnie z tym stosunek wa¬ gowy zwiazku o wzorze ii, do zwiazku o wzorze 2 w srodkach grzybobójczych stosowanych do opry¬ skiwania lisci wynosi korzystnie od 10:1 do 1 : 50.Zwiazek o wzorze 2 korzystnie stosuje sie w po¬ laczeniu z jeszcze innym srodkiem grzybobójczym, takim jak np. zineb lub mancozeb, tak jak to po¬ dano w opisie patentowym Wielkiej Brytanii nr 1470 740. Nalezy zaznaczyc, ze te dodatkowe srodki grzybobójcze stosuje sie w ilosci równej w przyblizeniu polowie ich normalnej dawki, a tak¬ ze, ze zwiazek & wzorze 2 nie da sie pogodzic ze zwiazkami zwiekszajacymi alkalicznosc, 123 456123 456 W celu uproszczenia wytwarzania, magazynowa¬ nia i transportu, srodki grzybobójcze na podstawie zwiazków o wzorze 1 i 2 zazwyczaj produkuje sie w postaci koncentratów przeznaczonych do roz¬ cienczania woda w stopniu niezbednym do uzyska¬ nia w prosty sposób wyzej wspomnianych dawek, Takie koncentraty srodka grzybobójczego zawiera¬ ja od 0,5 do 90, a korzystnie od 5 do l^/o wago¬ wych substancji czynnych w polaczeniu z co naj¬ mniej jednym obojetnym, nietrujacym dla roslin nosnikiem. Wytwarza sie je ,w postaci zwilzalnego proszku lub pylu, wodnej zawiesiny, koncentratu do emulgowania lub granulatu. Koncentraty srodka grzybobójczego przeznaczone sa do odpowiedniego rozcienczania woda przed uzyciem. Wodna zawie¬ sine mozna sporzadzac w zwyczajnych zbiornikach opryskiwaczy, nadajacych sie do takiego celu.Oczywiste jest, ze tak otrzymane rozcienczone pre¬ paraty równiez stanowia srodki grzybobójcze we¬ dlug wynalazku, w których jednym lub wylacznym obojetnym nosnikiem nietrujacym dla roslin jest woda.Zwjlzalne proszki lub pyly zawieraja dokladnie wymieszane substancje czynne, jeden lub kilka obojetnych nosników oraz odpowiednie srodki po¬ wierzchniowo czynne. Obojetny nosnik moze sta¬ nowic glinka attapulgitowa, ziemia okrzemkowa, kaolin, mika, talk oraz oczyszczone krzemiany.Skutecznymi srodkami powierzchniowo czynnymi sa sulfonowane ligniny, naftalenosulfoniany i skon¬ densowane naftalenosulfoniany, bursztyniany alki¬ lowe, alkilobenzenosulfoniany, siarczany alkilowe oraz niejonowe srodki powierzchniowo czynne, ta¬ kie jak addukty tlenku etylenu z fenolem. Przy¬ kladem zwilzalnego proszku wchodzacego w zakres wynalazku jest preparat, o nastepujacym skladzie: V* wagowe Zwiazek o wzorze1 1 do 10' Zwiazek o wzorze2 \ 5 do 60 Srodek (srodki) powierzchniowo czynny 0 do 10 Srodek dyspergujacy 0 do 10 Srodek przeciwdzialajacy 5 zbrylaniu 0 do 15 Obojetny nosnik (nosniki) ' do 100 Wynalazek ilustruje nastepujacy przyklad.• Zwiazek o wzorze 1 znany jest pod nazwa tria- dimefon. W ponizszym przykladzie zwiazek o wzo- io rze 2 oznaczony jest litera „C".Przyklad I. Wytworzono nastepujacy zwil- zalnyn proszek: (I) °/o wagowe ZwiazekC 30,0 Triadimefon 10,0 Sól sodowa sulfoburszty- nianu dwuoktylowego 3,0 Sulfonowana lignina 4,0 Uwodniony glinokrzemian sodowy 8,0 Attapulgit l do 100,0 Substancje czynne dokladnie wymieszano z okre¬ slonymi dodatkami w zwyklej mieszance. Mieszan- 25 ke rozdrobniono dokladniej w mlynie fluidalnym na ziarno o srednicy 1 do 10 l*m, po czym ponow¬ nie wymieszano i odpowietrzono przed pakowa¬ niem. Srodek opisany w przykladzie przeznaczony jest zwlaszcza do opryskiwania lisci. 30 Zastrzezenia patentowe 1. Srodek grzybobójczy zawierajacy substancje czynna i obojetny nosnik, znamienny tym, ze jako substancje czynna zawiera pochodna triazolu, o wzorze 1 i zwiazek o wzorze 2. 2. Srodek wedlug zastrz. 1, znamienny tym, ze zawiera zwiazek o wzorze ii i zwiazek o wzorze 2, w stosunku wagowym od 10 : 1 do 1 : 50. 20? 123 456 -@— 0-CH-CO- C(CH3) Ylzór 1 O O c,h=nhcnhcccn N0CH3 Wzór Z PL PL PL The subject of the invention is a fungicide used to combat fungal infections of crop plants. The fungicide according to the invention contains as substances an active triazole derivative - 5 of the formula 1 and a compound of the formula 2, combined with at least one inert, non-toxic to plants carrier. The above-mentioned compounds are known and can be prepared by methods described in the literature. A triazole derivative of formula 1 is described in United States Patent No. 3,912,752, and a urea derivative of formula 2 is described in British Patent No. 1,470,740. Surprisingly, it has been found that the new fungicide according to the invention containing the mixture of the given active substances is effective in inhibiting the growth or combating fungal infections of crop plants. It is particularly useful in the control of fungi attacking a number of crop plants such as cereals and beans, and particularly plants susceptible to attack by mildew or rust, i.e. plants such as vines, squash and tobacco susceptible to attack by such microorganisms. organisms such as Ooomycestes and Erysiphales. The fungicide according to the invention is used to combat fungal infections of plants, especially vines. The agent is used to spray leaves or soil, depending on the type of soil, at any stage of its growth, up to the harvest period. The degree and frequency of spraying depend on the severity or expected severity of the fungal blight and, as is obvious to those skilled in the art, on the age and condition of the plant. However, a particular advantage of the fungicide according to the invention is that it can be used effectively with reduced frequency, e.g. only once every 2 to 3 weeks, in the control of vineyard mildew, thus achieving a significant reduction in labor costs. As noted above, the fungicides of the invention may be used for spraying leaves or soil. When spraying the soil, the compound of the formula -1 is used in an amount from 50 to 500 g/ha. When spraying the leaves, the compound of the formula 1 is preferably used in an amount from 10 to 500 g/ha, and the compound of the formula 2 preferably used in amounts from 50 to 500 g/ha. Accordingly, the weight ratio of the compound of formula II to the compound of formula 2 in the fungicides used for foliar spraying is preferably from 10:1 to 1:50. The compound of formula 2 is preferably used in combination with another another fungicide such as, for example, zineb or mancozeb, as described in British Patent No. 1,470,740. It should be noted that these additional fungicides are applied at approximately half their normal rate, and so that the compound & formula 2 cannot be reconciled with compounds increasing alkalinity, 123 456123 456 In order to simplify production, storage and transport, fungicides based on the compounds 1 and 2 are usually produced in the form of concentrates intended for dilution dilution with water to the extent necessary to obtain the above-mentioned doses in a simple manner. Such fungicide concentrates contain from 0.5 to 90, preferably from 5 to 1/0 by weight of active substances in combination with at least less one inert carrier that is non-toxic to plants. They are produced in the form of a wettable powder or dust, an aqueous suspension, an emulsifiable concentrate or granules. Fungicide concentrates are intended to be appropriately diluted with water before use. The aqueous suspension can be prepared in ordinary spray tanks suitable for such a purpose. It is obvious that the diluted preparations thus obtained also constitute fungicides according to the invention, in which water is one or the only inert carrier non-toxic to plants. powders or dusts contain thoroughly mixed active substances, one or more inert carriers and appropriate surfactants. The inert carrier may be attapulgite clay, diatomaceous earth, kaolin, mica, talc and purified silicates. Effective surfactants include sulfonated lignins, naphthalenesulfonates and condensed naphthalenesulfonates, alkyl succinates, alkylbenzenesulfonates, alkyl sulfates and non-ionic agents. surfactants , such as ethylene oxide-phenol adducts. An example of a wettable powder falling within the scope of the invention is a preparation having the following composition: clumping 0 to 15 Inert carrier(s) ' to 100 The invention is illustrated by the following example. • The compound of formula 1 is known by the name triadimefon. In the following example, the compound of formula 2 is marked with the letter "C". Example I. The following wettable powder was prepared: (I) °/o by weight Compound C 30.0 Triadimefon 10.0 Sodium dioctyl sulfosuccinate 3, 0 Sulfonated lignin 4.0 Hydrated sodium aluminosilicate 8.0 Attapulgite l to 100.0 The active substances were thoroughly mixed with the specified additives in a regular mixture. The mixture was ground finely in a fluidized bed mill into grains with a diameter of 1 to 10 l*m and then mixed and deaerated again before packaging. The agent described in the example is intended especially for spraying leaves. Patent claims 1. A fungicide containing an active substance and an inert carrier, characterized in that it contains a triazole derivative as the active substance, of formula 1 and a compound of formula 2. 2. Agent according to claim 1, characterized in that it contains a compound of formula II and a compound of formula 2, in a weight ratio of 10:1 to 1:50. 20? 123 456 -@ — 0-CH-CO- C(CH3) Ylór 1 O O c,h=nhcnhcccn N0CH3 Formula Z PL PL PL
Claims (2)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1282478 | 1978-04-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL123456B1 true PL123456B1 (en) | 1982-10-30 |
Family
ID=10011816
Family Applications (4)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL1979230914A PL122824B1 (en) | 1978-04-01 | 1979-03-31 | Fungicide |
| PL1979230915A PL123456B1 (en) | 1978-04-01 | 1979-03-31 | Fungicide |
| PL1979214575A PL119526B1 (en) | 1978-04-01 | 1979-03-31 | Fungicide |
| PL1979230916A PL122819B1 (en) | 1978-04-01 | 1979-03-31 | Fungicide |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL1979230914A PL122824B1 (en) | 1978-04-01 | 1979-03-31 | Fungicide |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL1979214575A PL119526B1 (en) | 1978-04-01 | 1979-03-31 | Fungicide |
| PL1979230916A PL122819B1 (en) | 1978-04-01 | 1979-03-31 | Fungicide |
Country Status (34)
| Country | Link |
|---|---|
| JP (1) | JPS54132233A (en) |
| AR (4) | AR225414A1 (en) |
| AT (1) | AT364196B (en) |
| AU (1) | AU527924B2 (en) |
| BE (1) | BE875198A (en) |
| BG (4) | BG31469A3 (en) |
| BR (1) | BR7901929A (en) |
| CA (1) | CA1128854A (en) |
| CH (1) | CH638079A5 (en) |
| CS (4) | CS217978B2 (en) |
| DD (1) | DD143552A5 (en) |
| DE (1) | DE2912491A1 (en) |
| DK (4) | DK126779A (en) |
| EG (1) | EG13864A (en) |
| ES (1) | ES479135A1 (en) |
| FR (4) | FR2422332A1 (en) |
| GB (1) | GB2077591B (en) |
| GR (1) | GR67710B (en) |
| HU (2) | HU189633B (en) |
| IE (1) | IE47941B1 (en) |
| IL (1) | IL56963A (en) |
| IN (1) | IN149760B (en) |
| IT (1) | IT1120402B (en) |
| LU (1) | LU81096A1 (en) |
| NL (1) | NL7902435A (en) |
| NO (4) | NO147202C (en) |
| NZ (1) | NZ190062A (en) |
| PL (4) | PL122824B1 (en) |
| PT (1) | PT69407A (en) |
| RO (2) | RO80251A (en) |
| SE (4) | SE446811B (en) |
| SU (1) | SU1311600A3 (en) |
| TR (1) | TR20289A (en) |
| ZA (1) | ZA791494B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CS217978B2 (en) | 1978-04-01 | 1983-02-25 | Lilly Industries Ltd | Fungicide means |
| DE3326664A1 (en) * | 1982-07-29 | 1984-02-02 | Lilly Industries Ltd., London | Fungicidal agent and process for its preparation |
| DE59400468D1 (en) * | 1993-09-24 | 1996-09-05 | Basf Ag | Fungicidal mixtures |
| PL224139B1 (en) | 2014-08-01 | 2016-11-30 | Ekobenz Spółka Z Ograniczoną Odpowiedzialnością | Fuel blend, particularly for engines with spark ignition |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3912752A (en) * | 1972-01-11 | 1975-10-14 | Bayer Ag | 1-Substituted-1,2,4-triazoles |
| OA04979A (en) * | 1974-04-09 | 1980-11-30 | Ciba Geigy | New aniline derivatives useful as microbicidal agents and their preparation process. |
| GB1561634A (en) * | 1975-10-29 | 1980-02-27 | Lilly Industries Ltd | Fungicidal compositions |
| DE2560510C2 (en) * | 1975-11-26 | 1989-02-16 | Bayer Ag, 5090 Leverkusen, De | |
| GB1559820A (en) * | 1975-12-09 | 1980-01-30 | Lilly Industries Ltd | Fungicidal compositions |
| GB1581527A (en) * | 1976-08-18 | 1980-12-17 | Lilly Industries Ltd | Fungicidal formulations |
| CS217978B2 (en) | 1978-04-01 | 1983-02-25 | Lilly Industries Ltd | Fungicide means |
-
1979
- 1979-03-23 CS CS802271A patent/CS217978B2/en unknown
- 1979-03-23 CS CS802270A patent/CS217977B2/en unknown
- 1979-03-23 CS CS802269A patent/CS217976B2/en unknown
- 1979-03-28 EG EG190/79A patent/EG13864A/en active
- 1979-03-28 GR GR58713A patent/GR67710B/el unknown
- 1979-03-28 AR AR275965A patent/AR225414A1/en active
- 1979-03-28 SE SE7902780A patent/SE446811B/en not_active IP Right Cessation
- 1979-03-28 AU AU45485/79A patent/AU527924B2/en not_active Ceased
- 1979-03-28 DK DK126779A patent/DK126779A/en not_active Application Discontinuation
- 1979-03-28 FR FR7907805A patent/FR2422332A1/en active Granted
- 1979-03-28 CA CA324,339A patent/CA1128854A/en not_active Expired
- 1979-03-28 IL IL56963A patent/IL56963A/en unknown
- 1979-03-29 BR BR7901929A patent/BR7901929A/en unknown
- 1979-03-29 IN IN307/CAL/79A patent/IN149760B/en unknown
- 1979-03-29 BG BG045202A patent/BG31469A3/en unknown
- 1979-03-29 ZA ZA791494A patent/ZA791494B/en unknown
- 1979-03-29 BG BG045203A patent/BG31470A3/en unknown
- 1979-03-29 TR TR20289A patent/TR20289A/en unknown
- 1979-03-29 CS CS792108A patent/CS221251B2/en unknown
- 1979-03-29 BG BG045204A patent/BG31471A3/en unknown
- 1979-03-29 PT PT69407A patent/PT69407A/en unknown
- 1979-03-29 CH CH290179A patent/CH638079A5/en not_active IP Right Cessation
- 1979-03-29 NL NL7902435A patent/NL7902435A/en not_active Application Discontinuation
- 1979-03-29 JP JP3768479A patent/JPS54132233A/en active Pending
- 1979-03-29 BG BG043056A patent/BG31364A3/en unknown
- 1979-03-29 LU LU81096A patent/LU81096A1/en unknown
- 1979-03-29 BE BE6/46792A patent/BE875198A/en not_active IP Right Cessation
- 1979-03-29 DE DE19792912491 patent/DE2912491A1/en not_active Ceased
- 1979-03-30 AT AT0239679A patent/AT364196B/en not_active IP Right Cessation
- 1979-03-30 SU SU792748355A patent/SU1311600A3/en active
- 1979-03-30 HU HU83114A patent/HU189633B/en unknown
- 1979-03-30 NO NO791074A patent/NO147202C/en unknown
- 1979-03-30 IT IT48541/79A patent/IT1120402B/en active
- 1979-03-30 RO RO79102292A patent/RO80251A/en unknown
- 1979-03-30 RO RO7997081A patent/RO75492A/en unknown
- 1979-03-30 GB GB8112001A patent/GB2077591B/en not_active Expired
- 1979-03-30 HU HU79LI338A patent/HU182518B/en unknown
- 1979-03-30 NZ NZ190062A patent/NZ190062A/en unknown
- 1979-03-30 ES ES479135A patent/ES479135A1/en not_active Expired
- 1979-03-30 DD DD79211922A patent/DD143552A5/en unknown
- 1979-03-31 PL PL1979230914A patent/PL122824B1/en unknown
- 1979-03-31 PL PL1979230915A patent/PL123456B1/en unknown
- 1979-03-31 PL PL1979214575A patent/PL119526B1/en unknown
- 1979-03-31 PL PL1979230916A patent/PL122819B1/en unknown
- 1979-06-29 FR FR7916982A patent/FR2424701A1/en active Granted
- 1979-06-29 FR FR7916986A patent/FR2424703A1/en active Granted
- 1979-06-29 FR FR7916985A patent/FR2424702A1/en active Granted
- 1979-08-08 IE IE665/79A patent/IE47941B1/en unknown
-
1981
- 1981-08-06 AR AR286355A patent/AR227932A1/en active
- 1981-08-06 AR AR286354A patent/AR228962A1/en active
- 1981-08-06 AR AR286356A patent/AR227933A1/en active
-
1982
- 1982-06-30 NO NO822279A patent/NO148767C/en unknown
- 1982-06-30 NO NO822278A patent/NO148768C/en unknown
- 1982-06-30 NO NO822277A patent/NO148766C/en unknown
-
1984
- 1984-02-22 SE SE8400976A patent/SE454399B/en not_active IP Right Cessation
- 1984-02-22 SE SE8400977A patent/SE8400977L/en not_active Application Discontinuation
- 1984-02-22 SE SE8400978A patent/SE8400978D0/en not_active Application Discontinuation
-
1988
- 1988-03-04 DK DK120788A patent/DK120788A/en unknown
- 1988-03-04 DK DK120688A patent/DK120688D0/en not_active Application Discontinuation
- 1988-03-04 DK DK120588A patent/DK120588A/en not_active Application Discontinuation
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