PE20191621A1 - Lixiviacion oxidativa presurizada, de bajo contenido de solidos y baja acidez de materiales de alimentacion sulfurados - Google Patents
Lixiviacion oxidativa presurizada, de bajo contenido de solidos y baja acidez de materiales de alimentacion sulfuradosInfo
- Publication number
- PE20191621A1 PE20191621A1 PE2019002038A PE2019002038A PE20191621A1 PE 20191621 A1 PE20191621 A1 PE 20191621A1 PE 2019002038 A PE2019002038 A PE 2019002038A PE 2019002038 A PE2019002038 A PE 2019002038A PE 20191621 A1 PE20191621 A1 PE 20191621A1
- Authority
- PE
- Peru
- Prior art keywords
- copper
- low
- silver
- pressurized
- sulfured
- Prior art date
Links
- 239000007787 solid Substances 0.000 title abstract 4
- 239000002253 acid Substances 0.000 title abstract 2
- 238000002386 leaching Methods 0.000 title abstract 2
- 239000000463 material Substances 0.000 title 1
- 230000001590 oxidative effect Effects 0.000 title 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 3
- 229910052802 copper Inorganic materials 0.000 abstract 3
- 239000010949 copper Substances 0.000 abstract 3
- 229910052709 silver Inorganic materials 0.000 abstract 3
- 239000004332 silver Substances 0.000 abstract 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 abstract 2
- 229910052785 arsenic Inorganic materials 0.000 abstract 2
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 abstract 2
- 239000007791 liquid phase Substances 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 abstract 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229910000365 copper sulfate Inorganic materials 0.000 abstract 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 abstract 1
- 238000000354 decomposition reaction Methods 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 229910052935 jarosite Inorganic materials 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 239000012071 phase Substances 0.000 abstract 1
- 239000002002 slurry Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0063—Hydrometallurgy
- C22B15/0065—Leaching or slurrying
- C22B15/0067—Leaching or slurrying with acids or salts thereof
- C22B15/0073—Leaching or slurrying with acids or salts thereof containing nitrogen
- C22B15/0076—Cyanide groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D11/00—Solvent extraction
- B01D11/02—Solvent extraction of solids
- B01D11/0215—Solid material in other stationary receptacles
- B01D11/0253—Fluidised bed of solid materials
- B01D11/0257—Fluidised bed of solid materials using mixing mechanisms, e.g. stirrers, jets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D11/00—Solvent extraction
- B01D11/02—Solvent extraction of solids
- B01D11/028—Flow sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D11/00—Solvent extraction
- B01D11/02—Solvent extraction of solids
- B01D11/0288—Applications, solvents
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
- C22B1/11—Removing sulfur, phosphorus or arsenic other than by roasting
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B11/00—Obtaining noble metals
- C22B11/04—Obtaining noble metals by wet processes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B11/00—Obtaining noble metals
- C22B11/08—Obtaining noble metals by cyaniding
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0063—Hydrometallurgy
- C22B15/0065—Leaching or slurrying
- C22B15/0067—Leaching or slurrying with acids or salts thereof
- C22B15/0071—Leaching or slurrying with acids or salts thereof containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/22—Treatment or purification of solutions, e.g. obtained by leaching by physical processes, e.g. by filtration, by magnetic means, or by thermal decomposition
- C22B3/24—Treatment or purification of solutions, e.g. obtained by leaching by physical processes, e.g. by filtration, by magnetic means, or by thermal decomposition by adsorption on solid substances, e.g. by extraction with solid resins
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/44—Treatment or purification of solutions, e.g. obtained by leaching by chemical processes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Geology (AREA)
- Geochemistry & Mineralogy (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
Proceso para recuperar uno o ambos de cobre y/o plata de una alimentacion sulfurada que contiene hierro, arsenico, cobre y plata por oxidacion a presion de una lechada de alimentacion acuosa hecha con dicha alimentacion sulfurada, en un recipiente presurizado, para formar una fase liquida que contiene acido sulfurico libre y sulfato de cobre acuoso, y para precipitar arsenico como compuestos solidos de Fe-As. El proceso incluye operar el recipiente presurizado con un contenido de solidos suficientemente bajo para mantener un nivel de acido libre menor que 30 g/l en la fase liquida, y proveer suficiente calor como para mantener en el recipiente presurizado una temperatura mayor a los 200 °C. El cobre metalico se recupera de la fase liquida y/o la plata se puede recuperar de los solidos mediante lixiviacion con cianuro sin necesidad de realizar un paso de descomposicion de la jarosita.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201762485607P | 2017-04-14 | 2017-04-14 | |
| PCT/CA2018/000071 WO2018187855A1 (en) | 2017-04-14 | 2018-04-10 | Low acidity, low solids pressure oxidative leaching of sulphidic feeds |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PE20191621A1 true PE20191621A1 (es) | 2019-11-06 |
Family
ID=63792008
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PE2019002038A PE20191621A1 (es) | 2017-04-14 | 2018-04-10 | Lixiviacion oxidativa presurizada, de bajo contenido de solidos y baja acidez de materiales de alimentacion sulfurados |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US11118244B2 (es) |
| BG (1) | BG113021A (es) |
| CA (1) | CA3054964A1 (es) |
| CL (1) | CL2019002915A1 (es) |
| PE (1) | PE20191621A1 (es) |
| PH (1) | PH12019502328A1 (es) |
| WO (1) | WO2018187855A1 (es) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11584975B1 (en) | 2021-08-26 | 2023-02-21 | Sherritt International Corporation | Integrated pressure oxidative leach of copper sulphidic feed with copper heap leach |
| WO2024130244A1 (en) * | 2022-12-16 | 2024-06-20 | Michigan Technological University | Extracting and recovering metals from cathode active materials from li-ion batteries using sulfide minerals and chemicals |
| CN116555583A (zh) * | 2023-03-17 | 2023-08-08 | 金川集团铜业有限公司 | 一种利用加压浸出处理高杂炉渣的工艺方法 |
Family Cites Families (46)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2686114A (en) | 1951-01-19 | 1954-08-10 | Chemical Construction Corp | Elimination of arsenic from metallic arsenide-sulfide concentrates |
| US3637371A (en) | 1967-02-10 | 1972-01-25 | Sherritt Gordon Mines Ltd | Direct pressure leaching of copper-iron sulphides |
| US3917519A (en) | 1974-02-27 | 1975-11-04 | Freeport Minerals Co | Process for the manufacture of electrolytic copper |
| US3962402A (en) | 1974-02-27 | 1976-06-08 | Freeport Minerals Company | Oxidation-leaching of chalcopyrite |
| US4149880A (en) | 1978-07-19 | 1979-04-17 | Kennecott Copper Corporation | Recovery of copper from arsenic containing metallurgical waste materials |
| US4244734A (en) | 1979-07-19 | 1981-01-13 | Hazen Research, Inc. | Process for recovering metal values from materials containing arsenic |
| ES8504266A1 (es) | 1983-10-04 | 1985-04-01 | Diaz Nogueira Eduardo | Procedimiento de lixiviacion de concentrados de sulfuros de cobre del tetra hidritico que contiene arsenico y antimonio en concentraciones elevadas. |
| CA1234991A (en) | 1984-09-27 | 1988-04-12 | Donald R. Weir | Recovery of gold from auriferous refractory iron- containing sulphidic ore |
| US5071477A (en) | 1990-05-03 | 1991-12-10 | American Barrick Resources Corporation of Toronto | Process for recovery of gold from refractory ores |
| CA2032357A1 (en) | 1990-12-14 | 1992-06-15 | Peter Maltby | Pressure oxidation methods for gold extraction and toxic waste treatment |
| US5458866A (en) | 1994-02-14 | 1995-10-17 | Santa Fe Pacific Gold Corporation | Process for preferentially oxidizing sulfides in gold-bearing refractory ores |
| AUPM790894A0 (en) * | 1994-09-05 | 1994-09-29 | Western Mining Corporation Limited | Mineral processing |
| US5698170A (en) | 1995-11-22 | 1997-12-16 | Placer Dome, Inc. | Hydrometallurgical process for copper-containing materials |
| US6251163B1 (en) | 1998-03-04 | 2001-06-26 | Placer Dome, Inc. | Method for recovering gold from refractory carbonaceous ores |
| ES2301557T3 (es) | 2000-07-25 | 2008-07-01 | Phelps Dodge Corporation | Metodo para la recuperacion de cobre a partir de menas sulfurosas utilizando lixiviacion a alta presion y temperatura, extraccion mediante disolventes y extraccion electrolitica. |
| AU2001278015B2 (en) | 2000-07-25 | 2004-12-23 | Freeport-Mcmoran Corporation | Processing elemental sulfur-bearing materials using high temperature pressure leaching for sulfuric acid production and metal recovery |
| CA2417417C (en) | 2000-07-25 | 2008-09-30 | Phelps Dodge Corporation | Method for recovery of copper from sulfidic ore materials using super-fine grinding and medium temperature pressure leaching |
| US6471849B1 (en) * | 2000-09-11 | 2002-10-29 | Cominco Engineering Services Ltd. | Process for the recovery of zinc from a zinc sulphide ore or concentrate |
| AUPR503101A0 (en) | 2001-05-15 | 2001-06-07 | Western Minerals Technology Pty Ltd | Improved leaching process |
| US6451088B1 (en) | 2001-07-25 | 2002-09-17 | Phelps Dodge Corporation | Method for improving metals recovery using high temperature leaching |
| US7476308B2 (en) | 2001-07-25 | 2009-01-13 | Phelps Dodge Corporation | Process for multiple stage direct electrowinning of copper |
| US6451089B1 (en) | 2001-07-25 | 2002-09-17 | Phelps Dodge Corporation | Process for direct electrowinning of copper |
| CN1204277C (zh) | 2001-11-09 | 2005-06-01 | 北京矿冶研究总院 | 一种从含铜硫化矿物提取铜的方法 |
| US6641642B2 (en) | 2001-12-21 | 2003-11-04 | Newmont Usa Limited | High temperature pressure oxidation of ores and ore concentrates containing silver using controlled precipitation of sulfate species |
| US6755891B2 (en) | 2002-04-16 | 2004-06-29 | Cominco Engineering Services Ltd. | Process for the treatment or removal of impurities in a hydrometallurgical extraction process |
| US7378011B2 (en) | 2003-07-28 | 2008-05-27 | Phelps Dodge Corporation | Method and apparatus for electrowinning copper using the ferrous/ferric anode reaction |
| CA2472495A1 (en) * | 2004-02-18 | 2005-08-18 | Sgs Lakefield Research Limited | Process to recover base metals |
| US7452455B2 (en) | 2004-07-22 | 2008-11-18 | Phelps Dodge Corporation | System and method for producing metal powder by electrowinning |
| US7378010B2 (en) | 2004-07-22 | 2008-05-27 | Phelps Dodge Corporation | System and method for producing copper powder by electrowinning in a flow-through electrowinning cell |
| WO2006049631A2 (en) | 2004-10-29 | 2006-05-11 | Phelps Dodge Corporation | Process for multiple stage direct electrowinning of copper |
| US7736487B2 (en) | 2004-10-29 | 2010-06-15 | Freeport-Mcmoran Corporation | Process for recovery of copper from copper-bearing material using pressure leaching, direct electrowinning and solution extraction |
| AP2325A (en) | 2004-10-29 | 2011-11-23 | Freeport Mcmoran Corp | Process for recovery of copper from copper-bearingmaterial using pressure leaching, direct electrow inning and solvent/solution extraction. |
| US7604783B2 (en) | 2004-12-22 | 2009-10-20 | Placer Dome Technical Services Limited | Reduction of lime consumption when treating refractor gold ores or concentrates |
| PE20070861A1 (es) | 2005-10-19 | 2007-08-29 | Dundee Precious Metals Inc | Procedimiento para recuperar valores metalicos a partir de materiales que contienen arsenico y/o antimonio |
| WO2007109841A1 (en) | 2006-03-28 | 2007-10-04 | Dundee Precious (Barbados) Inc | Improved processing of metal values from concentrates |
| US8252254B2 (en) | 2006-06-15 | 2012-08-28 | Barrick Gold Corporation | Process for reduced alkali consumption in the recovery of silver |
| AU2008200206B2 (en) | 2007-01-19 | 2012-09-06 | Ausenco Services Pty Ltd | Integrated hydrometallurgical and pyrometallurgical processing of base-metal sulphides |
| US8025859B2 (en) * | 2007-05-18 | 2011-09-27 | Cesl Limited | Process for gold and silver recovery from a sulphide concentrate |
| EP2245200A1 (en) | 2008-01-17 | 2010-11-03 | Freeport-McMoran Corporation | Method and apparatus for electrowinning copper using an atmospheric leach with ferrous/ferric anode reaction electrowinning |
| US8118907B2 (en) | 2008-08-25 | 2012-02-21 | Freeport-Mcmoran Corporation | Methods and systems for leaching a metal-bearing ore for the recovery of a metal value |
| AU2011332049B2 (en) | 2010-11-22 | 2015-11-19 | Barrick Gold Corporation | Alkaline and acid pressure oxidation of precious metal-containing materials |
| US8420048B1 (en) | 2011-12-20 | 2013-04-16 | Freeport-Mcmoran Corporation | System and method for parallel solution extraction of one or more metal values from metal-bearing materials |
| US9194023B2 (en) | 2012-10-23 | 2015-11-24 | Barrick Gold Corporation | Recovery of gold from roaster calcine leach tailings |
| FI125693B (en) | 2013-02-08 | 2016-01-15 | Outotec Oyj | Method and Arrangement to Reduce Autoflash and Slurry Migration in Autoclave Flash Systems |
| US11149328B2 (en) | 2013-11-01 | 2021-10-19 | Colorado School Of Mines | Method of leaching arsenic from ore comprising copper |
| WO2017004694A1 (en) * | 2015-07-06 | 2017-01-12 | Sherritt International Corporation | Recovery of copper from arsenic-containing process feed |
-
2018
- 2018-04-10 PE PE2019002038A patent/PE20191621A1/es unknown
- 2018-04-10 CA CA3054964A patent/CA3054964A1/en active Pending
- 2018-04-10 WO PCT/CA2018/000071 patent/WO2018187855A1/en not_active Ceased
- 2018-04-12 US US15/951,615 patent/US11118244B2/en active Active
-
2019
- 2019-10-11 PH PH12019502328A patent/PH12019502328A1/en unknown
- 2019-10-14 CL CL2019002915A patent/CL2019002915A1/es unknown
- 2019-11-07 BG BG113021A patent/BG113021A/bg unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CA3054964A1 (en) | 2018-10-18 |
| US11118244B2 (en) | 2021-09-14 |
| WO2018187855A1 (en) | 2018-10-18 |
| PH12019502328A1 (en) | 2020-09-28 |
| BG113021A (bg) | 2020-11-16 |
| CL2019002915A1 (es) | 2020-03-06 |
| US20180298466A1 (en) | 2018-10-18 |
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