LU100677B1 - Nail polish with crackle effect - Google Patents
Nail polish with crackle effect Download PDFInfo
- Publication number
- LU100677B1 LU100677B1 LU100677A LU100677A LU100677B1 LU 100677 B1 LU100677 B1 LU 100677B1 LU 100677 A LU100677 A LU 100677A LU 100677 A LU100677 A LU 100677A LU 100677 B1 LU100677 B1 LU 100677B1
- Authority
- LU
- Luxembourg
- Prior art keywords
- nail polish
- aqueous
- composition
- layer
- weight
- Prior art date
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- PZTQVMXMKVTIRC-UHFFFAOYSA-L chembl2028348 Chemical compound [Ca+2].[O-]S(=O)(=O)C1=CC(C)=CC=C1N=NC1=C(O)C(C([O-])=O)=CC2=CC=CC=C12 PZTQVMXMKVTIRC-UHFFFAOYSA-L 0.000 description 1
- UOUJSJZBMCDAEU-UHFFFAOYSA-N chromium(3+);oxygen(2-) Chemical class [O-2].[O-2].[O-2].[Cr+3].[Cr+3] UOUJSJZBMCDAEU-UHFFFAOYSA-N 0.000 description 1
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 1
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- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 description 1
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- JMGZBMRVDHKMKB-UHFFFAOYSA-L disodium;2-sulfobutanedioate Chemical compound [Na+].[Na+].OS(=O)(=O)C(C([O-])=O)CC([O-])=O JMGZBMRVDHKMKB-UHFFFAOYSA-L 0.000 description 1
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 1
- SFNALCNOMXIBKG-UHFFFAOYSA-N ethylene glycol monododecyl ether Chemical compound CCCCCCCCCCCCOCCO SFNALCNOMXIBKG-UHFFFAOYSA-N 0.000 description 1
- 210000004905 finger nail Anatomy 0.000 description 1
- FOYKKGHVWRFIBD-UHFFFAOYSA-N gamma-tocopherol acetate Natural products CC(=O)OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 FOYKKGHVWRFIBD-UHFFFAOYSA-N 0.000 description 1
- 229960003180 glutathione Drugs 0.000 description 1
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- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 1
- 229910000271 hectorite Inorganic materials 0.000 description 1
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- DCYOBGZUOMKFPA-UHFFFAOYSA-N iron(2+);iron(3+);octadecacyanide Chemical compound [Fe+2].[Fe+2].[Fe+2].[Fe+3].[Fe+3].[Fe+3].[Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] DCYOBGZUOMKFPA-UHFFFAOYSA-N 0.000 description 1
- WTFXARWRTYJXII-UHFFFAOYSA-N iron(2+);iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Fe+2].[Fe+3].[Fe+3] WTFXARWRTYJXII-UHFFFAOYSA-N 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
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- XCOBTUNSZUJCDH-UHFFFAOYSA-B lithium magnesium sodium silicate Chemical compound [Li+].[Li+].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Na+].[Na+].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3 XCOBTUNSZUJCDH-UHFFFAOYSA-B 0.000 description 1
- NEMFQSKAPLGFIP-UHFFFAOYSA-N magnesiosodium Chemical compound [Na].[Mg] NEMFQSKAPLGFIP-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 1
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 1
- 229960002216 methylparaben Drugs 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 125000002801 octanoyl group Chemical group C(CCCCCCC)(=O)* 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 229960001173 oxybenzone Drugs 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 1
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229940068977 polysorbate 20 Drugs 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 235000010232 propyl p-hydroxybenzoate Nutrition 0.000 description 1
- 239000004405 propyl p-hydroxybenzoate Substances 0.000 description 1
- 229960003415 propylparaben Drugs 0.000 description 1
- 229960003351 prussian blue Drugs 0.000 description 1
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- 230000005855 radiation Effects 0.000 description 1
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- 230000009257 reactivity Effects 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 230000037307 sensitive skin Effects 0.000 description 1
- 229940047670 sodium acrylate Drugs 0.000 description 1
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- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 229940104870 sodium magnesium fluorosilicate Drugs 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- LROWVYNUWKVTCU-STWYSWDKSA-M sodium sorbate Chemical compound [Na+].C\C=C\C=C\C([O-])=O LROWVYNUWKVTCU-STWYSWDKSA-M 0.000 description 1
- DSOWAKKSGYUMTF-GZOLSCHFSA-M sodium;(1e)-1-(6-methyl-2,4-dioxopyran-3-ylidene)ethanolate Chemical compound [Na+].C\C([O-])=C1/C(=O)OC(C)=CC1=O DSOWAKKSGYUMTF-GZOLSCHFSA-M 0.000 description 1
- AXMCIYLNKNGNOT-UHFFFAOYSA-N sodium;3-[[4-[(4-dimethylazaniumylidenecyclohexa-2,5-dien-1-ylidene)-[4-[ethyl-[(3-sulfophenyl)methyl]amino]phenyl]methyl]-n-ethylanilino]methyl]benzenesulfonate Chemical compound [Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](C)C)C=2C=CC(=CC=2)N(CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S(O)(=O)=O)=C1 AXMCIYLNKNGNOT-UHFFFAOYSA-N 0.000 description 1
- AXBSROISAJEZHL-UHFFFAOYSA-M sodium;4-(3-ethyloctan-3-yloxy)-4-oxo-3-sulfobutanoate Chemical compound [Na+].CCCCCC(CC)(CC)OC(=O)C(S(O)(=O)=O)CC([O-])=O AXBSROISAJEZHL-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 229930003799 tocopherol Natural products 0.000 description 1
- 229960001295 tocopherol Drugs 0.000 description 1
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- 239000011732 tocopherol Substances 0.000 description 1
- 229940042585 tocopherol acetate Drugs 0.000 description 1
- UJMBCXLDXJUMFB-UHFFFAOYSA-K trisodium;5-oxo-1-(4-sulfonatophenyl)-4-[(4-sulfonatophenyl)diazenyl]-4h-pyrazole-3-carboxylate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-UHFFFAOYSA-K 0.000 description 1
- AZJYLVAUMGUUBL-UHFFFAOYSA-A u1qj22mc8e Chemical compound [F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].O=[Si]=O.O=[Si]=O.O=[Si]=O.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3 AZJYLVAUMGUUBL-UHFFFAOYSA-A 0.000 description 1
- 235000013799 ultramarine blue Nutrition 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
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- 235000010493 xanthan gum Nutrition 0.000 description 1
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- 239000000811 xylitol Substances 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 1
Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8147—Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q3/00—Manicure or pedicure preparations
- A61Q3/02—Nail coatings
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
Abstract
Composition aqueuse pour vernis à ongles permettant la réalisation d'un effet esthétique dit craquelé lors de l'application sur une couche de vernis à ongles, ladite composition aqueuse comprenant au moins une résine de copolymère de styrene/acrylates/ammonium methacrylate, au moins un plastifiant et au moins un épaississant.An aqueous nail varnish composition which makes it possible to achieve a so-called crackle-like aesthetic effect when applied to a layer of nail polish, said aqueous composition comprising at least one styrene / acrylate / ammonium methacrylate copolymer resin, at least one plasticizer and at least one thickener.
Description
VERNIS À ONGLES À EFFET CRAQUELÉNAIL POLISH WITH CRACKED EFFECT
Domaine technique [0001] La présente invention concerne une composition pour vernis à ongles qui peut s’appliquer sur les ongles ou les faux ongles, permettant d’obtenir un effet esthétique dit craquelé, cuir ou croco.TECHNICAL FIELD [0001] The present invention relates to a nail polish composition that can be applied to nails or false nails, to obtain an aesthetic effect said cracked, leather or crocodile.
Etat de la technique [0002] De nos jours, les vernis à ongles ne se limitent plus aux couleurs uniques et uniformes. Il est très courant d'appliquer sur les ongles des vernis à ongles procurant différents effets ou motifs.STATE OF THE ART [0002] Nowadays, nail polishes are no longer limited to single, uniform colors. It is very common to apply on the nails nail polish providing different effects or patterns.
[0003] Un des motifs connus sur le marché est l'effet craquelé encore appelé effet cuir ou croco. Cet effet se réalise facilement: par exemple, dans un premier temps une base colorée est appliquée sur l'ongle et une fois sèche celle-ci est recouverte par une seconde couche de vernis à effet craquelé. Ce dernier va sécher de manière irrégulière permettant l'effet craquelé.One of the known reasons on the market is the crackle effect still called leather or crocodile effect. This effect is easily achieved: for example, at first a colored base is applied to the nail and once dry it is covered by a second layer of cracked effect varnish. The latter will dry unevenly allowing the crackle effect.
[0004] Les vernis à ongles à effet craquelé présents actuellement sur le marché contiennent des silices et des silicones. L'inconvénient majeur de l'utilisation de la silice est que l'effet craquelé est très mat et oblige les consommateurs à utiliser un vernis supplémentaire pour apporter de la brillance. La présence de silicones dans les produits cosmétiques est très souvent critiquée dû à leur réactivité sur les peaux sensibles mais aussi par le fait que leur présence rend le vernis plus difficile à retirer des ongles.[0004] The crackle effect nail polishes presently on the market contain silicas and silicones. The major drawback of the use of silica is that the crackle effect is very dull and requires consumers to use an additional varnish to provide shine. The presence of silicones in cosmetic products is very often criticized due to their reactivity on sensitive skin but also by the fact that their presence makes the varnish more difficult to remove nails.
[0005] Afin de répondre à la demande, la présente invention se propose d'améliorer les compositions de vernis à ongles à effet craquelé déjà présents sur le marché.In order to meet the demand, the present invention proposes to improve the crackle effect nail polish compositions already on the market.
Objet de l'invention [0006] Un objet de la présente invention est par conséquent de trouver des compositions pour vernis à ongles permettant d'obtenir de manière simple un effet craquelé, susceptible de plaire aux consommateurs et pouvant remédier du moins partiellement aux inconvénients mentionnés ci-dessus.OBJECT OF THE INVENTION [0006] An object of the present invention is therefore to find nail varnish compositions making it possible to obtain in a simple manner a crackle effect which is likely to please consumers and which can at least partially remedy the disadvantages mentioned. above.
Description générale de l'invention [0007] Afin d’atteindre l’objectif mentionné ci-dessus, la présente invention propose, dans un premier aspect, une composition aqueuse pour vernis à ongles permettant la réalisation d'un effet esthétique dit craquelé lors de l'application sur une couche de vernis à ongles, ladite composition aqueuse comprenant au moins une résine de copolymère de styrene/acrylates/ammonium methacrylate, au moins un plastifiant et au moins un épaississant.GENERAL DESCRIPTION OF THE INVENTION [0007] In order to achieve the abovementioned objective, the present invention proposes, in a first aspect, an aqueous nail varnish composition that makes it possible to achieve an aesthetic effect, said to be cracked during applying to a layer of nail polish, said aqueous composition comprising at least one styrene / acrylate / ammonium methacrylate copolymer resin, at least one plasticizer and at least one thickener.
[0008] Dans un deuxième aspect, l'invention concerne un vernis à ongles comprenant une composition aqueuse pour vernis à ongles selon la présente invention.In a second aspect, the invention relates to a nail polish comprising an aqueous nail polish composition according to the present invention.
[0009] Dans un troisième aspect, l'invention propose également un procédé de décoration des ongles comprenant les étapes suivantes: (1) application d'une première couche de vernis à ongles sur la surface d'un ongle, (2) application d'une deuxième couche d'une composition aqueuse pour vernis à ongles selon l’invention ou d’un vernis à ongles selon l’invention sur la première couche de vernis à ongles ; et (3) séchage de ladite deuxième couche avec formation de craquelures aléatoires dans cette deuxième couche révélant à l’intérieur de ces craquelures la première couche de vernis à ongles.In a third aspect, the invention also provides a method of decorating the nails comprising the following steps: (1) application of a first layer of nail polish to the surface of a fingernail, (2) application of a second layer of an aqueous nail polish composition according to the invention or a nail polish according to the invention on the first layer of nail polish; and (3) drying said second layer with random crack formation in said second layer revealing within said cracks the first layer of nail polish.
[0010] Il est à noter que dans le contexte de la présente invention le terme « ongle » désigne tant les ongles naturels que les faux ongles.It should be noted that in the context of the present invention the term "nail" refers to both natural nails and false nails.
[0011] Les Inventeurs ont constaté de manière surprenante que les résines de copolymère de styrene/acrylates/ammonium methacrylate permettent d’obtenir non seulement un effet craquelé, bien qu’en principe ces composés soient a priori connus pour leurs propriétés filmogènes. Mais de plus, et contrairement aux solutions connues, la couche craquelée formée par les compositions aqueuses selon l’invention présente une bonne brillance et rend de ce fait inutile l’application d’un top coat.The inventors have found, surprisingly, that the styrene / acrylate / ammonium methacrylate copolymer resins make it possible to obtain not only a cracked effect, although in principle these compounds are a priori known for their film-forming properties. But in addition, and contrary to known solutions, the cracked layer formed by the aqueous compositions according to the invention has a good gloss and therefore makes it unnecessary to apply a top coat.
[0012] D’une manière générale, un effet craquelé est en principe d’autant plus visible que les craquelures sont nettes et larges et que le contraste entre la couche craquelée et la couleur de fond apparaissant à l’intérieur des craquelures est grand. Pour des raisons de contraste, l’effet craquelé est donc particulièrement marqué, si les compositions aqueuses selon l’invention sont appliquées sur une (première) couche de vernis à ongles préalablement appliquée qui a un rendu différent de la (deuxième) couche de composition aqueuse selon l’invention. Les Inventeurs ont de plus trouvé que l’intensité des craquelures, c’est-à-dire le nombre de craquelures par unité de surface et/ou la largeur des craquelures peut encore être améliorée, si la première couche de vernis à ongles est un vernis à ongles solvanté (c’est-à-dire non-aqueux) et la deuxième couche est appliquée avant le séchage à cœur de la première couche, c’est-à-dire généralement endéans une heure de l’application de la première couche. Il devient ainsi possible de manière simple et non contraignante en pratique de varier encore davantage l’intensité des craquelures apparaissant dans la deuxième couche en variant l’état de séchage de la première.In general, a cracked effect is in principle all the more visible that the cracks are sharp and wide and that the contrast between the cracked layer and the background color appearing inside the cracks is large. For reasons of contrast, the crackle effect is therefore particularly marked, if the aqueous compositions according to the invention are applied to a (first) layer of previously applied nail polish which has a different rendering of the (second) layer of composition aqueous composition according to the invention. The inventors have further found that the intensity of the cracks, that is to say the number of cracks per unit area and / or the width of the cracks can be further improved, if the first layer of nail polish is a solvent-based (i.e., non-aqueous) nail polish and the second layer is applied before drying in the core of the first layer, i.e., generally within one hour of application of the first layer layer. It thus becomes possible in a simple and non-binding manner in practice to further vary the intensity of the cracks appearing in the second layer by varying the drying state of the first layer.
[0013] Comme déjà mentionné, les compositions aqueuses selon l'invention comprennent comme agent principal responsable de l’apparition de craquelures au moins une résine de copolymère de styrene/acrylates/ammonium methacrylate. Il s’agit de préférence d’une résine de copolymère de styrene/acrylates/ammonium methacrylate de type SYNTRAN 5760 ou encore SYNTRAN 5620 PC, ....As already mentioned, the aqueous compositions according to the invention comprise as the main agent responsible for the appearance of cracks at least one styrene copolymer resin / acrylates / ammonium methacrylate. It is preferably a styrene / acrylates / ammonium methacrylate copolymer resin of the SYNTRAN 5760 or SYNTRAN 5620 PC type.
[0014] La quantité de résine(s) de copolymère copolymère de styrene/acrylates/ ammonium methacrylate est généralement comprise entre 2 % et 80 % en poids et de préférence entre 20 % et 60 % en poids de la composition aqueuse pour vernis à ongles.The amount of copolymer resin (s) of styrene / acrylates / ammonium methacrylate is generally between 2% and 80% by weight and preferably between 20% and 60% by weight of the aqueous nail polish composition. .
[0015] Les compositions aqueuses selon l'invention peuvent le cas échéant comprendre de faibles quantités d’une co-résine choisis parmi les émulsions ou dispersions aqueuses de polymères; de préférence les copolymères d'acrylates, comme le copolymère styrene/acrylates ou acrylate/ethylhexylacrylate ; parmi les copolymères de sels d'ammonium acrylates comme le copolymère d'ammonium acrylates ; parmi les dispersions vinyliques comme les polyvinylacétates, les polyvinylalcools ou les polyvinylpyrrolidones ; parmi les dispersions de type polyuréthane, comme le polyurethane-35, le polyurethane-61, le polyurethane-1, le polyurethane-32, le polyurethane-34, le PPG-17 / IPDI / copolymère de DMPA ; et parmi les copolymères d'alcool vinylique et d'éthylène ; ainsi que parmi leurs combinaisons ou mélanges.The aqueous compositions according to the invention may optionally comprise small amounts of a co-resin selected from aqueous emulsions or dispersions of polymers; preferably copolymers of acrylates, such as styrene / acrylates or acrylate / ethylhexyl acrylate copolymer; among the copolymers of ammonium acrylate salts such as the ammonium acrylate copolymer; among vinyl dispersions such as polyvinylacetates, polyvinylalcohols or polyvinylpyrrolidones; among the polyurethane type dispersions, such as polyurethane-35, polyurethane-61, polyurethane-1, polyurethane-32, polyurethane-34, PPG-17 / IPDI / DMPA copolymer; and among the copolymers of vinyl alcohol and ethylene; as well as among their combinations or mixtures.
[0016] Les co-résines peuvent être présentes dans la composition aqueuse selon l'invention à des quantités de 0,1 % à 2 % en poids, de préférence de 0,2 % à 0,5 % en poids de la composition aqueuse pour vernis à ongles.The co-resins may be present in the aqueous composition according to the invention in amounts of from 0.1% to 2% by weight, preferably from 0.2% to 0.5% by weight of the aqueous composition. for nail polish.
[0017] Comme mentionné ci-dessus, les compositions selon l’invention sont aqueuses, c’est-à-dire le solvant principal de ces compositions est l'eau. La quantité d'eau présente dans la composition aqueuse est généralement comprise entre 15 et 65 % en poids, de préférence entre 25 et 55 % en poids de la composition aqueuse pour vernis à ongles.As mentioned above, the compositions according to the invention are aqueous, that is to say the main solvent of these compositions is water. The amount of water present in the aqueous composition is generally between 15 and 65% by weight, preferably between 25 and 55% by weight of the aqueous nail polish composition.
[0018] La composition aqueuse selon l'invention peut néanmoins contenir un ou plusieurs co-solvants, notamment pour moduler les temps de séchage et faciliter la formation du film. Les co-solvants permettent également d'améliorer la dispersion ou la solubilisation de certains ingrédients. Ces co-solvants sont des ingrédients solubles dans le solvant principal. Parmi les co-solvants utilisables dans la présente invention, nous citerons notamment : • l'éthanol, • l'alcool isopropylique, • le propylène glycol, • le butylène glycol, • ou encore le propylène glycol n-butyl éther, • ou encore leurs combinaisons ou mélanges.The aqueous composition according to the invention may nevertheless contain one or more co-solvents, in particular to modulate the drying times and facilitate the formation of the film. Co-solvents also make it possible to improve the dispersion or the solubilization of certain ingredients. These co-solvents are soluble ingredients in the main solvent. Among the cosolvents that can be used in the present invention, mention may in particular be made of: • ethanol, • isopropyl alcohol, • propylene glycol, • butylene glycol, • or propylene glycol n-butyl ether, • or their combinations or mixtures.
[0019] Le cas échéant, les co-solvants peuvent être présents dans la composition selon l'invention à des quantités de 0,1 % à 15% en poids, de préférence de 1 % à 10% en poids de la composition aqueuse pour vernis à ongles.Where appropriate, the co-solvents may be present in the composition according to the invention in amounts of from 0.1% to 15% by weight, preferably from 1% to 10% by weight of the aqueous composition for nail polish.
[0020] La composition aqueuse selon la présente invention comprend un ou plusieurs plastifiants afin de moduler la dureté du film formé. Il s'agit en général de composés solubles ou compatibles avec le solvant principal (eau) et les éventuels co-solvants. Les plastifiants ont généralement des températures d'ébullition élevées. Ils ne sont donc pas volatiles. Parmi les plastifiants utilisables dans le cadre de la présente invention, nous citerons : • la glycérine, • l'acétyl tributyl citrate, • l'acétyl triéthyl citrate, • le tributyl citrate, • le triéthyl citrate, • ou encore leurs combinaisons ou mélanges.The aqueous composition according to the present invention comprises one or more plasticizers in order to modulate the hardness of the formed film. These are generally soluble compounds or compatible with the main solvent (water) and any co-solvents. Plasticizers generally have high boiling temperatures. They are not volatile. Among the plasticizers that can be used in the context of the present invention, mention may be made of: glycerine, acetyl tributyl citrate, acetyl triethyl citrate, tributyl citrate, triethyl citrate, or their combinations or mixtures .
[0021] La quantité de plastifiant(s) à mettre en oeuvre est généralement de l'ordre de 0,5 % à 6 % en poids de la composition aqueuse et de préférence entre 1 % et 5 % en poids de la composition aqueuse pour vernis à ongles.The amount of plasticizer (s) to be used is generally of the order of 0.5% to 6% by weight of the aqueous composition and preferably between 1% and 5% by weight of the aqueous composition for nail polish.
[0022] Les compositions aqueuses selon l'invention comprennent un ou plusieurs épaississants. Ces épaississants sont de préférence choisis parmi les carbomères ou polymères d'acide acrylique comme par exemple un copolymère d'hydroxyéthylacrylate et de sodium acryloyldiméthyltaurate, un copolymère de sodium acrylate et de sodium acryloyldiméthyltaurate, et/ou les dérivées de la cellulose.The aqueous compositions according to the invention comprise one or more thickeners. These thickeners are preferably chosen from carbomers or polymers of acrylic acid, for example a copolymer of hydroxyethylacrylate and of sodium acryloyldimethyltaurate, a copolymer of sodium acrylate and of sodium acryloyldimethyltaurate, and / or the derivatives of cellulose.
[0023] La quantité d'épaississant est généralement de 0,01 % à 1 % en poids de la composition aqueuse et de préférence entre 0,04 % et 0,1 % en poids de la composition aqueuse pour vernis à ongles.The amount of thickener is generally from 0.01% to 1% by weight of the aqueous composition and preferably between 0.04% and 0.1% by weight of the aqueous nail polish composition.
[0024] Les compositions aqueuses selon l'invention peuvent contenir, en outre, un ou plusieurs agents de rhéologie. Ces agents de rhéologie permettent de : • moduler la viscosité de la composition. • optimiser l'application de la formulation avec un pinceau, et/ou • permettre la tenue en suspension des particules solides au sein de la formulation, ces agents peuvent donc éviter notamment la sédimentation des agents de coloration mis en oeuvre.The aqueous compositions according to the invention may contain, in addition, one or more rheology agents. These rheology agents make it possible to: • modulate the viscosity of the composition. • optimize the application of the formulation with a brush, and / or • allow the suspension of solid particles within the formulation, these agents can therefore avoid in particular the sedimentation of the coloring agents used.
[0025] Parmi les agents de rhéologie utilisables dans les compositions aqueuses selon l'invention, on citera notamment : • les argiles compatibles avec les milieux aqueux comme la bentone EW (nom INCI : hectorite). • les dérivés de silice dénommés silica ou silica diméthyl silylate. • les silicates. Parmi les silicates utilisables dans la présente invention, nous citerons par exemple : o le sodium magnésium silicate, o le lithium magnésium sodium silicate, o le sodium magnésium fluorosilicate, et/ou o le magnésium aluminium silicate. • la cellulose et les dérivés de cellulose comme l'hydroxyéthylcellulose commercialisé sous la dénomination Natrosol par Ashland. • Les dérivées polysaccharide comme par exemple la gomme de xanthane. • les polyacrylates commercialisés sous la dénomination Sepiplus 400. Cet ingrédient est un mélange constitué de trois ingrédients (Polyacrylate-13, Polyisobutene et Polysorbate 20). Les polymères à base d'acide acrylique ou les copolymères à base d'acide acrylique et de ses esters, comme les polymères commercialisés sous les noms, CARBOPOL™ et SYNTHALEN™. • les polyacrylamides commercialisés sous la dénomination Sepigel 305 par Seppic. Le Sepigel 305 se présente sous la forme d'un mélange constitué de trois ingrédients : Polyacrylamide, C13-14 Isoparaffin et Laureth-7. • d'autres composés plus complexes pourront être utilisés dans la composition aqueuse selon la présente invention afin d'en moduler la viscosité et l'application. Parmi ces composés plus complexes, nous citerons par exemple : o le copolymère de PEG-150, d'alcool décylique et de méthylène diphényldiisocyanate saturé, o les copolymères d'acrylamide dont la dénomination INCI est polyacrylate-13.Among the rheology agents that can be used in the aqueous compositions according to the invention, mention may be made in particular of: • clays compatible with aqueous media such as bentone EW (INCI name: hectorite). • silica derivatives called silica or silica dimethyl silylate. • silicates. Among the silicates that can be used in the present invention, we may mention, for example: sodium magnesium silicate, lithium magnesium sodium silicate, sodium magnesium fluorosilicate, and / or magnesium aluminum silicate. Cellulose and cellulose derivatives, such as hydroxyethylcellulose sold under the name Natrosol by Ashland. • Polysaccharide derivatives such as xanthan gum. Polyacrylates marketed under the name Sepiplus 400. This ingredient is a mixture consisting of three ingredients (Polyacrylate-13, Polyisobutene and Polysorbate 20). Acrylic acid-based polymers or copolymers based on acrylic acid and its esters, such as polymers marketed under the names CARBOPOL ™ and SYNTHALEN ™. Polyacrylamides sold under the name Sepigel 305 by Seppic. Sepigel 305 is a mixture of three ingredients: Polyacrylamide, C13-14 Isoparaffin and Laureth-7. Other more complex compounds may be used in the aqueous composition according to the present invention in order to modulate the viscosity and the application. Among these more complex compounds, we will mention for example: the copolymer of PEG-150, of decyl alcohol and saturated methylene diphenyldiisocyanate, o copolymers of acrylamide whose INCI name is polyacrylate-13.
[0026] Selon un mode de réalisation préféré de l'invention, la composition aqueuse selon l'invention peut comprendre par exemple une quantité d'agent de rhéologie comprise entre 0,1 % et 5 %, et de préférence entre 0,3 % et 3,5 % en poids de la composition aqueuse pour vernis à ongles.According to a preferred embodiment of the invention, the aqueous composition according to the invention may comprise, for example, a quantity of rheology agent of between 0.1% and 5%, and preferably between 0.3% and 3.5% by weight of the aqueous nail polish composition.
[0027] Compte tenu de sa nature aqueuse, la composition selon l'invention contiendra généralement un ou plusieurs agents conservateurs. Ces conservateurs sont généralement nécessaires pour empêcher le développement de toute contamination bactérienne ou le développement de moisissures. Les conservateurs susceptibles d'être utilisés sont par exemple : • l'alcool benzylique (CAS 100-51-6), • le phenoxyéthanol (CAS 122-99-6) utilisé seul ou en combinaison avec l'éthylhexylglycérine (CAS 70445-33-9), • le formaldéhyde (CAS 50-00-0), • le dihydroacétate de sodium (CAS 4418-26-2), • le tétrasodium EDTA (CAS 64-02-8), • le disodium EDTA (CAS 6381-92-6), • le méthylchloroisothiazolinone (CAS 26172-55-4), • l'acide sorbique et ses sels (CAS 110-44-1, 7492-55-9, 7757-81-5, 24634-61-5), • le méthylisothiazolinone (CAS 2682-20-4), • le méthylparaben (CAS 99-76-3), • le propylparaben (CAS 94-13-3), • le diazolidinylurea (CAS 78491-02-8), • la chlorphénésine (CAS 104-29-0), • l'acide benzoïque et son sel de sodium (CAS 65-85-0 et 532-35-1), • le tocophérol (CAS 10191-41-0).Given its aqueous nature, the composition according to the invention will generally contain one or more preservatives. These preservatives are usually needed to prevent the development of any bacterial contamination or mold growth. Preservatives that may be used include, for example: • benzyl alcohol (CAS 100-51-6), • phenoxyethanol (CAS 122-99-6) used alone or in combination with ethylhexylglycerine (CAS 70445-33). -9), • formaldehyde (CAS 50-00-0), • sodium dihydroacetate (CAS 4418-26-2), • tetrasodium EDTA (CAS 64-02-8), • disodium EDTA (CAS 6381) -92-6), • methylchloroisothiazolinone (CAS 26172-55-4), • sorbic acid and its salts (CAS 110-44-1, 7492-55-9, 7757-81-5, 24634-61- 5), • methylisothiazolinone (CAS 2682-20-4), • methylparaben (CAS 99-76-3), • propylparaben (CAS 94-13-3), • diazolidinylurea (CAS 78491-02-8) • chlorophenesine (CAS 104-29-0), • benzoic acid and its sodium salt (CAS 65-85-0 and 532-35-1), • tocopherol (CAS 10191-41-0).
[0028] Les conservateurs seront utilisés à des pourcentages connus par l'homme de l'art qui tiendra compte également des réglementations en vigueur qui imposent généralement des pourcentages maximum d'utilisation dans les compositions aqueuses pour vernis à ongles.The preservatives will be used at percentages known to those skilled in the art which will also take into account the regulations in force which generally impose maximum percentages of use in aqueous nail polish compositions.
[0029] Les compositions aqueuses selon l'invention comprendront de préférence un ou plusieurs agents de coloration. On entend par agent de coloration toute matière première susceptible de modifier la couleur de ladite composition. D'une manière non limitative, on citera comme agent de coloration les colorants, les pigments organiques et inorganiques, les nacres, les paillettes et les particules métalliques. Si nécessaire ou souhaité, l’agent de coloration peut comprendre un ou plusieurs auxiliaires, comme par exemple un agent mouillant, etc.The aqueous compositions according to the invention will preferably comprise one or more coloring agents. By coloring agent is meant any raw material capable of modifying the color of said composition. In a nonlimiting manner, mention will be made, as coloring agent, of dyes, organic and inorganic pigments, nacres, flakes and metal particles. If necessary or desired, the coloring agent may comprise one or more auxiliaries, such as, for example, a wetting agent, etc.
[0030] Les pigments utilisables dans la composition aqueuse selon l'invention pourront être sélectionnés parmi le groupe constitué par le dioxyde de titane (Cl 77891), l'oxyde de fer noir (Cl 77499), l'oxyde de fer rouge (Cl 77491), le DC Red 6 Ba Lake (Cl 15850), le DC Red 7 Lake (Cl 15850 :1), le DC Red 34 Ca Lake (Cl 15880), le FDC Yellow 5 Al Lake (Cl 19140), le FDC Blue 1 Al Lake (Cl 42090), le bleu ultramarine (Cl 77007), le DC Violet 2 (Cl 60725), le Carmin (Cl 75470), les oxydes de chrome (Cl 77288 et Cl 77289), le Bleu de Prusse (Cl 77510). Les pigments fluorescents, phosphorescents, thermochromiques et photochromiques pourront également être utilisés dans la composition aqueuse selon l'invention.The pigments used in the aqueous composition according to the invention may be selected from the group consisting of titanium dioxide (Cl 77891), black iron oxide (Cl 77499), red iron oxide (Cl 77491), DC Red 6 Ba Lake (Cl 15850), DC Red 7 Lake (Cl 15850: 1), DC Red 34 Ca Lake (Cl 15880), FDC Yellow 5 Al Lake (Cl 19140), FDC Blue 1 Al Lake (Cl 42090), ultramarine blue (Cl 77007), DC Violet 2 (Cl 60725), Carmine (Cl 75470), chromium oxides (Cl 77288 and Cl 77289), Prussian Blue ( Cl 77510). The fluorescent, phosphorescent, thermochromic and photochromic pigments may also be used in the aqueous composition according to the invention.
[0031] Des nacres pourront être mises en œuvre pour apporter de la couleur ou des effets à la composition aqueuse selon l'invention. Les nacres sont généralement décrites comme des particules minérales naturelles ou synthétiques (mica naturel, mica synthétique appelé également fluorphlogopite, calcium sodium borosilicate, aluminium calcium sodium silicate) recouvertes d'une ou plusieurs couches d'oxydes métalliques, de métaux ou de pigments. Les nacres se présentent sous la forme de poudres ou de particules de différentes tailles allant de 5 pm à 750 pm dans leur dimension la plus grande.Nacres may be implemented to bring color or effects to the aqueous composition of the invention. Nacres are generally described as natural or synthetic mineral particles (natural mica, synthetic mica also called fluorophlogopite, calcium sodium borosilicate, aluminum calcium sodium silicate) coated with one or more layers of metal oxides, metals or pigments. The nacres are in the form of powders or particles of different sizes ranging from 5 pm to 750 pm in their largest dimension.
[0032] La composition aqueuse selon l'invention pourra comprendre également des paillettes. Les paillettes sont généralement des particules plastiques de faible taille constituées de couches de polyéthylène téréphtalate ou de polyuréthane prenant en sandwich des pigments. Les paillettes peuvent avoir des tailles et des formes variables. Ainsi les paillettes peuvent être rondes, hexagonales, carrées, en forme de bâtonnet II est important de noter que les paillettes peuvent également prendre la forme de tout signe, logo ou design particulier.The aqueous composition according to the invention may also comprise flakes. The flakes are generally small plastic particles consisting of layers of polyethylene terephthalate or polyurethane sandwiching pigments. Glitter can have varying sizes and shapes. Thus the flakes can be round, hexagonal, square, rod-shaped. It is important to note that glitter can also take the form of any sign, logo or particular design.
[0033] La composition aqueuse selon l'invention comprendra éventuellement des particules métalliques. En particulier la composition aqueuse pourra inclure des particules d'aluminium de taille et de forme variable selon l'effet recherché.The aqueous composition according to the invention will optionally comprise metal particles. In particular, the aqueous composition may include aluminum particles of variable size and shape depending on the desired effect.
[0034] Selon un mode de réalisation préféré de l'invention, la composition aqueuse peut comprendre une quantité d'agent de coloration comprise entre 0,1 % et 20 % en poids, de manière davantage préférée entre 0,5 % et 15 % en poids du poids total de la composition aqueuse. De préférence, la quantité et la nature des agents de coloration utilisés dans la composition aqueuse selon l'invention seront choisies de manière à ce qu'ils n'interfèrent pas avec l'effet recherché.According to a preferred embodiment of the invention, the aqueous composition may comprise a quantity of coloring agent of between 0.1% and 20% by weight, more preferably between 0.5% and 15% by weight. by weight of the total weight of the aqueous composition. Preferably, the amount and nature of the coloring agents used in the aqueous composition according to the invention will be chosen so that they do not interfere with the desired effect.
[0035] La composition aqueuse pour vernis à ongles peut en outre comprendre différents additifs courants, choisis par exemple parmi les absorbeurs UV.The aqueous nail polish composition may further comprise various common additives, chosen for example from UV absorbers.
[0036] Parmi les absorbants UV (ou protecteurs UV), on citera les absorbants UV qui permettent de protéger la composition ou les agents de coloration utilisés des rayonnements UV. Parmi les protecteurs UV utilisables dans l'invention, on citera la benzophénone-1 (CAS 131-56-6), la benzophénone-3 (CAS 131-57-7), la benzophénone-5 (CAS 6628-37-1), l'étocrylène (CAS 5232-99-5).Among UV absorbers (or UV protectors), there will be mentioned UV absorbers which protect the composition or the coloring agents used UV radiation. Among the UV protectors that can be used in the invention, mention will be made of benzophenone-1 (CAS 131-56-6), benzophenone-3 (CAS 131-57-7) and benzophenone-5 (CAS 6628-37-1). , Etocrylene (CAS 5232-99-5).
[0037] Les absorbants UV seront utilisés si nécessaire, seuls ou sous la forme de combinaisons dont le pourcentage total dans la formule peut aller de 0.1 à 1 % en poids, de préférence de 0,2 à 0,7 % en poids total de la formulation.UV absorbers will be used if necessary, alone or in the form of combinations whose total percentage in the formula can range from 0.1 to 1% by weight, preferably from 0.2 to 0.7% by total weight of the formulation.
[0038] On citera également les additifs ou agents dits « traitants » de l'ongle utilisables dans la composition aqueuse selon l'invention. Les additifs traitants peuvent représenter de 0,01 % à 5 %en poids sec, de préférence de 0,05 % à 2 % en poids sec par rapport au poids total de la composition. Parmi ces additifs « traitants », on citera : • le formaldéhyde utilisé comme durcisseur de l'ongle, • la vitamine E acétate (tocophéryl acétate), • la vitamine A palmitate (rétinyl palmitate), • les dérivés organiques ou inorganiques de calcium tels que le chlorure de calcium, le pantothénate de calcium, • le diméthyloxobenzodioxasilane, • la myrrhe, • les acides aminés soufrés comme la cystéine, ses sels et leurs dérivés, la cystine, le glutathion. Les acides aminés soufrés sont en effet capables de créer des ponts de réticulation entre la kératine et les groupes SH libres de ces dérivés soufrés, • la kératine hydrolysée d'origine végétale, • les alpha-hydroxyacides comme l'acide citrique, l'acide ascorbique, • la biotine, • l'urée et la diméthylurée.Mention may also be made of additives or agents known as "treating agents" for the nail that can be used in the aqueous composition according to the invention. The treating additives may represent from 0.01% to 5% by dry weight, preferably from 0.05% to 2% by dry weight relative to the total weight of the composition. These "treating" additives include: • formaldehyde used as a hardener for the nail, • vitamin E acetate (tocopheryl acetate), • vitamin A palmitate (retinyl palmitate), • organic or inorganic calcium derivatives such as calcium chloride, calcium pantothenate, • dimethyloxobenzodioxasilane, • myrrh, • sulfur-containing amino acids such as cysteine, its salts and derivatives, cystine, glutathione. The sulfur-containing amino acids are indeed capable of creating crosslinking bridges between keratin and the free SH groups of these sulfur-containing derivatives, • hydrolysed keratin of plant origin, • alpha-hydroxy acids such as citric acid, and acid. ascorbic acid, • biotin, • urea and dimethylurea.
[0039] La composition aqueuse selon l’invention peut comprendre l'ajout d’agents tensio-actifs ou surfactants. Parmi les surfactants utilisables, on peut citer les surfactants anioniques, les surfactants cationiques, les surfactants amphotères et les surfactants non-ioniques, par exemple : • le PEG-12 diméthicone, • le PEG / PPG-17/18 diméthicone, • la Lauroyl Lysine, • les sodium Cocoyl Apple Amino acids, • le Caprylyl / capryl glucoside, • le PEG-40 sorbitan Peroleate, • le Xylitylglucoside, • l'anhydroxylitol, • le Xylitol, • la Cocobetaine, • le Cocoamidopropylbetaine, • l'oxyde de lauramine, • le cocoamphoacétate de sodium, • le Cocoamide MIPA, • le sodium de diethylhexyl sulfosuccinate, • les amino acides de sodium de lauroyl, • le disodium de laureth sulfosuccinate, • l'acide carboxylique de laureth-5, et/ou • le sodium lauryl sulfate.The aqueous composition according to the invention may comprise the addition of surfactants or surfactants. Among the surfactants that can be used are anionic surfactants, cationic surfactants, amphoteric surfactants and nonionic surfactants, for example: PEG-12 dimethicone, PEG / PPG-17/18 dimethicone, Lauroyl Lysine, • sodium Cocoyl Apple Amino acids, • Caprylyl / capryl glucoside, • PEG-40 sorbitan Peroleate, • Xylitylglucoside, • Anhydroxylitol, • Xylitol, • Cocobetaine, • Cocoamidopropylbetaine, • Oxide lauramine, • sodium cocoamphoacetate, • cocoamide MIPA, • diethylhexyl sulfosuccinate sodium, • lauroyl sodium amino acids, • laureth disodium sulfosuccinate, • laureth-5 carboxylic acid, and / or • sodium lauryl sulfate.
[0040] Les surfactants peuvent être utilisés en des quantités de 0 % à 10 %, et de préférence de 0 % à 7 % en poids de la composition aqueuse totale. Ils peuvent être utilisés seuls ou sous la forme de combinaisons.The surfactants may be used in amounts of 0% to 10%, and preferably 0% to 7% by weight of the total aqueous composition. They can be used alone or in the form of combinations.
[0041] De préférence, la viscosité de la composition aqueuse selon l'invention est comprise entre 100 mPa.s et 1000 mPa.s, viscosité mesurée à 60 RPM avec un viscosimètre de type Brookfield.Preferably, the viscosity of the aqueous composition according to the invention is between 100 mPa.s and 1000 mPa.s, viscosity measured at 60 RPM with a Brookfield type viscometer.
Exemples [0042] L'exemple dans le Tableau ci-dessous illustre des formulations pour la réalisation d'une composition aqueuse selon l'invention. Les compositions aqueuses selon l'invention ne se limitent pas à cet exemple.EXAMPLES [0042] The example in the table below illustrates formulations for producing an aqueous composition according to the invention. The aqueous compositions according to the invention are not limited to this example.
[0043] La Fig. 1 illustre des exemples d’effets que l’utilisateur peut réaliser grâce aux compositions aqueuses selon l’invention indiquées dans le Tableau ci-dessous une fois que celles-ci sont appliquées sur l’ongle.[0043] FIG. 1 illustrates examples of effects that the user can achieve through the aqueous compositions according to the invention shown in the Table below once they are applied to the nail.
Claims (13)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| LU100677A LU100677B1 (en) | 2018-01-12 | 2018-01-12 | Nail polish with crackle effect |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| LU100677A LU100677B1 (en) | 2018-01-12 | 2018-01-12 | Nail polish with crackle effect |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| LU100677B1 true LU100677B1 (en) | 2019-07-17 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| LU100677A LU100677B1 (en) | 2018-01-12 | 2018-01-12 | Nail polish with crackle effect |
Country Status (1)
| Country | Link |
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| LU (1) | LU100677B1 (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2783708A1 (en) * | 1998-09-30 | 2000-03-31 | Oreal | System for applying make-up to the skin, lips, etc. to give special effects is based on the application of successive first and second layers of compositions each containing film-forming polymer |
| WO2015091063A1 (en) * | 2013-12-19 | 2015-06-25 | L'oreal | Nail coating assembly and use |
| WO2015097644A1 (en) * | 2013-12-23 | 2015-07-02 | Technology & Communication S.R.L. | Aqueous vehicle for colored compounds and pigments, water-based nail polish comprising said vehicle, and a process for their production |
-
2018
- 2018-01-12 LU LU100677A patent/LU100677B1/en active IP Right Grant
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2783708A1 (en) * | 1998-09-30 | 2000-03-31 | Oreal | System for applying make-up to the skin, lips, etc. to give special effects is based on the application of successive first and second layers of compositions each containing film-forming polymer |
| WO2015091063A1 (en) * | 2013-12-19 | 2015-06-25 | L'oreal | Nail coating assembly and use |
| WO2015097644A1 (en) * | 2013-12-23 | 2015-07-02 | Technology & Communication S.R.L. | Aqueous vehicle for colored compounds and pigments, water-based nail polish comprising said vehicle, and a process for their production |
Non-Patent Citations (3)
| Title |
|---|
| DATABASE GNPD [online] MINTEL; 12 April 2017 (2017-04-12), ANONYMOUS: "Waterbased Top Coat", XP055505876, retrieved from www.gnpd.com Database accession no. 4752049 * |
| DATABASE GNPD [online] MINTEL; 29 January 2013 (2013-01-29), ANONYMOUS: "Nail Art Pen", XP055505856, retrieved from www.gnpd.com Database accession no. 1982209 * |
| MIKE BRIND ET AL: "Water-based nail polish innovation", PERSONAL CARE, 4 April 2012 (2012-04-04), XP055505993, Retrieved from the Internet <URL:https://www.personalcaremagazine.com/story/9604/water-based-nail-polish-innovation> [retrieved on 20180911] * |
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