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KR970006402A - 폴리카보네이트 및 모노비닐리덴 방향족 화합물의 방염 조성물 - Google Patents

폴리카보네이트 및 모노비닐리덴 방향족 화합물의 방염 조성물 Download PDF

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Publication number
KR970006402A
KR970006402A KR1019960030352A KR19960030352A KR970006402A KR 970006402 A KR970006402 A KR 970006402A KR 1019960030352 A KR1019960030352 A KR 1019960030352A KR 19960030352 A KR19960030352 A KR 19960030352A KR 970006402 A KR970006402 A KR 970006402A
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composition
weight
monovinylidene aromatic
flame retardant
aromatic compound
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KR100454799B1 (ko
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창 펭 리우
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채스킨 제이 엘
제네랄 일렉트릭 캄파니
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
    • C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L85/00—Compositions of macromolecular compounds obtained by reactions forming a linkage in the main chain of the macromolecule containing atoms other than silicon, sulfur, nitrogen, oxygen and carbon; Compositions of derivatives of such polymers
    • C08L85/02—Compositions of macromolecular compounds obtained by reactions forming a linkage in the main chain of the macromolecule containing atoms other than silicon, sulfur, nitrogen, oxygen and carbon; Compositions of derivatives of such polymers containing phosphorus

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

본 발명은 폴리카보네이트 수지, 모노비닐리덴 방향족 화갑물 및 소량의 포스페이트 방염제의 열가소성 수지블렌드를 포함하는 성형가능한 방염성 열가소성 수지 조성물에 관한 것으로, 이때 폴리카보네이트는 저분자량을 가지며 모노비닐리덴 방향족 화합물 및 전체 조성물은 비교적 적은 고무 함량을 갖는다. 상기 조성물은 높은 열편향 온도, 우수한 내충격성, 탁월한 방염성, 보다 용이한 가공을 위한 양호한 유동성의 독특한 조합을 가지며 테두리 균열이 없다.

Description

폴리카보네이트 및 모노비닐리덴 방향족 화합물의 방염 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. (A) 약 60 내지 약 85중량부의 폴리카보네이트 수지; (B) 모노비닐리덴 방향족 화합물의 중량을 기준으로 약 25중량% 미만의 평균 고무함량을 갖는, 약 10 내지 약 25중량부의 모노비닐리덴 방향족 화합물; (C) 약 8% 미만의 포스페이트 방염 화합물; 및 (D) 0 내지 약 3%의 테트라풀루오로에틸렌 중합체를 포함하는 방염성 열가소성 수지 조성물.
  2. 제1항에 있어서, 상기 열가소성 수지 조성물중의 전체 고무 함량이 전체 열가소성 조성물의 약 5 중량% 이하인 조성물.
  3. 제1항에 있어서, 3.2mm에서 V0의 UL 94 화염 등급을 갖는 조성물.
  4. 제3항에 있어서, 상기 열가소성 조성물의 0.125 in 봉이 약 4 ft - 1bs/in 이상의 노취된 아이조드 충격값을 갖는 조성물.
  5. 제3항에 있어서, 상기 열가소성 조성물의 0.125 in 인장봉(레소르시놀 디포스페이트가 표면에 도포되어 있다)이 50% 습도 및 25℃에서 0.75% 변형 지그상에서 12 시간후에 가시적인 테두리 균열을 나타내지 않는 조성물.
  6. 제1항에 있어서, 상기 모노비닐리덴 방향족 화합물이 아크릴로니트릴-부티디엔-스티렌, 아크릴로니트릴-스티렌-부틸 아크릴레이트, 메틸메타크릴레이트-아크릴로니트릴-부타디엔-스티렌, 아크릴로니트릴-에틸렌-프로필렌-비공액 디엔-스티렌 및 이들의 혼합물로 이루어진 그룹중에서 선택된 조성물.
  7. 제1항에 있어서, 상기 포스페이트 방염제가 하기 화학식을 갖는 조성물:
    상기 식에서, R1,R2,R3및 R4는 독립적으로 아릴 및 알크아릴 그룹으로 이루어진 그룹중에서 선택되고, X는 아릴렌 그룹이고, m은 각각 독립적으로 0 또는 1이고,n은 1 내지 약 35의 정수 또는 정수들의 혼합물이다.
  8. 제7항에 있어서, 상기 포스페이트 방염제에서 n이 1 내지 약 5의 정수 또는 정수들의 혼합물인 조성물.
  9. 제1항에 있어서, 상기 폴리카보네이트 수지의 중량 평균 분자량이 염화 메틸렌중의 겔 투과 크로마토그래피에 의해 측정시 약 30,000 미만인 조성물.
  10. 제1항에 있어서, 상기 열가소성 수지 조성물의 0.125in 봉의 열 변형 온도가 264psi에서 약85℃이상인 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019960030352A 1995-07-26 1996-07-25 폴리카보네이트및모노비닐리덴방향족화합물의방염조성물 Expired - Fee Related KR100454799B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US50707295A 1995-07-26 1995-07-26
US08/507,072 1995-07-26

Publications (2)

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KR970006402A true KR970006402A (ko) 1997-02-19
KR100454799B1 KR100454799B1 (ko) 2005-01-27

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KR1019960030352A Expired - Fee Related KR100454799B1 (ko) 1995-07-26 1996-07-25 폴리카보네이트및모노비닐리덴방향족화합물의방염조성물

Country Status (6)

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EP (1) EP0755977A3 (ko)
JP (1) JPH09104811A (ko)
KR (1) KR100454799B1 (ko)
CN (1) CN1178987C (ko)
SG (1) SG83084A1 (ko)
TW (1) TW386099B (ko)

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KR100331031B1 (ko) * 1998-12-01 2002-05-09 오길록 부분 파싱을 이용한 확률 기반 품사 태거의 오류 방지 장치 및그 방법
KR100376032B1 (ko) * 2000-10-12 2003-03-15 (주)언어와 컴퓨터 음절 바이그램 특성을 이용한 한글 문서의 오류 인식 및교정 방법

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EP0933396A3 (en) * 1998-01-28 1999-12-15 General Electric Company Flame retardant polycarbonate resin/abs graft copolymer blends
US6084054A (en) * 1998-03-30 2000-07-04 General Electric Company Flame retardant polycarbonate resin/ABS graft copolymer blends having low melt viscosity
DE69931942T2 (de) * 1998-07-27 2007-03-08 General Electric Co. Flammhemmende polycarbonat/kautschukmodifizierte pfropfcopolymermischung mit metallischem aussehen
US20010009946A1 (en) * 1998-09-29 2001-07-26 General Electric Company Polycarbonate resin/graft copolymer blends
DE19853105A1 (de) 1998-11-18 2000-05-25 Bayer Ag Flammwidrige Polycarbonat-ABS-Formmassen
DE19856484A1 (de) * 1998-12-08 2000-06-15 Bayer Ag Polycarbonat-Formmassen mit verbesserten mechanischen Eigenschaften
DE19914137A1 (de) * 1999-03-27 2000-09-28 Bayer Ag Flammwidrige mit Pfropfpolymerisat modifizierte Polycarbonat-Formmassen
DE19914139A1 (de) 1999-03-27 2000-09-28 Bayer Ag Flammwidrige, schlagzähmodifizierte Polycarbonat-Formmassen
BR0109053B1 (pt) 2000-03-09 2012-08-21 composições de policarbonato, seu emprego, bem como corpos moldados, placas ou laminados e peças assim obtidas.
AU2003246717A1 (en) 2002-07-29 2004-02-23 Bayer Materialscience Ag Flame-resistant polycarbonate moulding compounds
US8034866B2 (en) 2003-12-30 2011-10-11 Sabic Innovative Plastics Ip B.V. Polymer compositions, method of manufacture, and articles formed therefrom
US8067493B2 (en) 2003-12-30 2011-11-29 Sabic Innovative Plastics Ip B.V. Polymer compositions, method of manufacture, and articles formed therefrom
US7557154B2 (en) 2004-12-23 2009-07-07 Sabic Innovative Plastics Ip B.V. Polymer compositions, method of manufacture, and articles formed therefrom
US7807745B2 (en) 2006-01-27 2010-10-05 Sabic Innovative Plastics Ip B.V. Molding compositions containing polycarbonate and modified polybutylene terephthalate (PBT) random copolymers derived from polyethylene terephthalate (PET)
DE602007004072D1 (de) 2006-01-27 2010-02-11 Gen Electric Artikel aus zusammensetzungen mit modifizierten polybutylen-terephthalat-statistik-copolymeren aus polyethylen-terephthalat
US8492464B2 (en) † 2008-05-23 2013-07-23 Sabic Innovative Plastics Ip B.V. Flame retardant laser direct structuring materials
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WO2014104485A1 (ko) 2012-12-28 2014-07-03 제일모직 주식회사 열가소성 수지 조성물 및 이를 포함한 성형품
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CN112662156B (zh) * 2020-12-15 2023-02-14 上海金发科技发展有限公司 一种无锑阻燃改性pc/pet/abs组合物
CN115678237B (zh) * 2022-10-21 2024-07-12 金发科技股份有限公司 一种缓燃聚碳酸酯复合材料及其制备方法和应用

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Cited By (2)

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Publication number Priority date Publication date Assignee Title
KR100331031B1 (ko) * 1998-12-01 2002-05-09 오길록 부분 파싱을 이용한 확률 기반 품사 태거의 오류 방지 장치 및그 방법
KR100376032B1 (ko) * 2000-10-12 2003-03-15 (주)언어와 컴퓨터 음절 바이그램 특성을 이용한 한글 문서의 오류 인식 및교정 방법

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TW386099B (en) 2000-04-01
SG83084A1 (en) 2001-09-18
JPH09104811A (ja) 1997-04-22
EP0755977A3 (en) 1997-03-19
CN1145932A (zh) 1997-03-26
CN1178987C (zh) 2004-12-08
KR100454799B1 (ko) 2005-01-27
EP0755977A2 (en) 1997-01-29

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