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KR910000813A - 마이크로캡슐을 함유하는 벌크 중합용 반응배합액 및 노르보넨계 폴리머의 제조방법 - Google Patents

마이크로캡슐을 함유하는 벌크 중합용 반응배합액 및 노르보넨계 폴리머의 제조방법 Download PDF

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Publication number
KR910000813A
KR910000813A KR1019890008993A KR890008993A KR910000813A KR 910000813 A KR910000813 A KR 910000813A KR 1019890008993 A KR1019890008993 A KR 1019890008993A KR 890008993 A KR890008993 A KR 890008993A KR 910000813 A KR910000813 A KR 910000813A
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KR
South Korea
Prior art keywords
thermally expandable
norbornene
microcapsules
cycloolefin monomer
cycloolefin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
KR1019890008993A
Other languages
English (en)
Inventor
죠셉 잰더 데니스
나까노 무네또시
오꾸무라 긴-이찌
마쓰이 마사요시
야마또 모또유끼
Original Assignee
원본미기재
더 비. 에프. 굿리치 컴페니
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 원본미기재, 더 비. 에프. 굿리치 컴페니 filed Critical 원본미기재
Publication of KR910000813A publication Critical patent/KR910000813A/ko
Withdrawn legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
    • C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
    • C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/141—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/32—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof from compositions containing microballoons, e.g. syntactic foams
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/22—Expandable microspheres, e.g. Expancel®
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2365/00—Characterised by the use of macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain; Derivatives of such polymers

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)

Abstract

내용 없음

Description

마이크로캡슐을 함유하는 벌크 중합용 반응배합액 및 노르보넨계 폴리머의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (8)

  1. (a) 노르보넨기를 함유하는 시클로올레핀모노머, (b)그 시클로올레핀모노머를 괴상 개환중합할수 있는 양의 메타쎄시스 촉매계 및 (c)열팽창성 마이크로캡슐을 함유하여 이루어지는 것을 특징으로 하는 괴상 중합용 반응성 배합액.
  2. 제 1 항에 있어서, 열팽창성 마이크로캡슐이 미팽창인 것이고, 배합량이 0.05~5중량%인 배합액.
  3. 제 1 항에 있어서, 마이크로캡슐이 기팽창의 것이고, 배합량이 1~50용량%인 배합액.
  4. (a) 노르보넨기를 가진 시클로올레핀모노머, (b) 메타쎄시스 촉매 또는 메타쎄시스 공촉매 중의 어느 성분 및 (c) 열팽창성 마이크로캡슐을 함유하여 이루어지는 것을 특징으로 하는 공급원료.
  5. 청구항 제1에 기재된 반응성 배합액을, 캐비티형과 코어형으로 온도차를 설정해서 보지한 금형내에 주입하여 반응사출성형을 수행하는 것을 특징으로 하는 노르보넨계 시클로올레핀 폴리머의 제조법.
  6. 제 5 항에 있어서, 열팽창성 마이크로캡슐이 기화성 팽창제를 내포하는 합성수지제 마이크로캡슐이고, 그 자신의 최고 팽창배율을 달성할 수 있는 온도가 70~200℃의 범위내이고, 또한 수분함유량이 5중량% 이하인 시클로올레핀폴리머의 제조법.
  7. 제 5 항에 있어서, 메타쎄시스 촉매계가, 30℃에서의 발열개시시간이 0.5분 이상인 것인 노르보넨계 폴리머의 제조법.
  8. 노르보넨기를 가진 시클로올레핀 모노머 및 메타쎄시스 공촉매를 포함한 반응성 배합액(A)와, 노르보넨기를 가진 시클로올레핀모노머, 메타쎄시스 촉매계 및 열팽창성 마이크로캡슐을 포함한 반응성 배합액(B)를 믹싱헤드로 혼합한후, 캐비티형과 코어형으로 온도차를 설정하여 보지한 금형내에 주입하여 반응 사출성형을 수행하는 것을 특징으로 하는 노르보넨계 시클로올레핀 폴리머의 제조법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890008993A 1988-06-28 1989-06-28 마이크로캡슐을 함유하는 벌크 중합용 반응배합액 및 노르보넨계 폴리머의 제조방법 Withdrawn KR910000813A (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US21270388A 1988-06-28 1988-06-28
US212,703 1988-06-28
US63-218479 1988-09-02
US304,215 1989-01-31
US07/304,215 US4891387A (en) 1988-06-28 1989-01-31 Bulk polymerized cycloolefin monomers containing microencapsulated blowing agents

Publications (1)

Publication Number Publication Date
KR910000813A true KR910000813A (ko) 1991-01-30

Family

ID=26907386

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019890008993A Withdrawn KR910000813A (ko) 1988-06-28 1989-06-28 마이크로캡슐을 함유하는 벌크 중합용 반응배합액 및 노르보넨계 폴리머의 제조방법

Country Status (7)

Country Link
US (1) US4891387A (ko)
EP (1) EP0348852A1 (ko)
KR (1) KR910000813A (ko)
BR (1) BR8903179A (ko)
CA (1) CA1327423C (ko)
DK (1) DK318389A (ko)
MX (1) MX170031B (ko)

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Also Published As

Publication number Publication date
DK318389D0 (da) 1989-06-27
BR8903179A (pt) 1990-05-29
DK318389A (da) 1989-12-29
MX170031B (es) 1993-08-04
US4891387A (en) 1990-01-02
EP0348852A1 (en) 1990-01-03
CA1327423C (en) 1994-03-01

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Legal Events

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PA0109 Patent application

Patent event code: PA01091R01D

Comment text: Patent Application

Patent event date: 19890628

PG1501 Laying open of application
PC1203 Withdrawal of no request for examination
WITN Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid