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KR900701929A - 에폭시 수지 조성물 - Google Patents

에폭시 수지 조성물

Info

Publication number
KR900701929A
KR900701929A KR1019900701341A KR900701341A KR900701929A KR 900701929 A KR900701929 A KR 900701929A KR 1019900701341 A KR1019900701341 A KR 1019900701341A KR 900701341 A KR900701341 A KR 900701341A KR 900701929 A KR900701929 A KR 900701929A
Authority
KR
South Korea
Prior art keywords
epoxy resin
resin composition
phenolic
group
moles
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
KR1019900701341A
Other languages
English (en)
Other versions
KR940001169B1 (ko
Inventor
따다 히사시
아가따 이끼라
사루따 마사히로
무라따 다까시
구보오 다까도시
Original Assignee
나가이 야다로오
미쓰비시레이욘 가부시끼가이샤
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 나가이 야다로오, 미쓰비시레이욘 가부시끼가이샤 filed Critical 나가이 야다로오
Priority claimed from PCT/JP1988/001212 external-priority patent/WO1990006334A1/ja
Publication of KR900701929A publication Critical patent/KR900701929A/ko
Application granted granted Critical
Publication of KR940001169B1 publication Critical patent/KR940001169B1/ko
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/62—Alcohols or phenols
    • C08G59/621—Phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/32—Epoxy compounds containing three or more epoxy groups
    • C08G59/38—Epoxy compounds containing three or more epoxy groups together with di-epoxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50—Amines
    • C08G59/56—Amines together with other curing agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/62—Alcohols or phenols

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Epoxy Resins (AREA)
  • Reinforced Plastic Materials (AREA)

Abstract

내용 없음

Description

에폭시 수지 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (11)

  1. 하기 성분 (A),(B),(C),(D)를 필수성분으로 함유하는 것을 특징으로 하는 에폭시 수지 조성물.
    (A) 2관능 에폭시 수지
    (B) 3관능 에폭시 수지
    (C) 하기식으로 대표되는 페놀화합물
    (단, X1-X8은 Br, Cl 또는 H를 나타내고 X1-X8중 최소한 4개는 Br 또는 Cl 나타내며, R1및 R2는 H 또는 CH3이다.)
    (D) 4,4´-디아미노디페닐 설폰 또는 3,3´-디아미노디페닐 설폰
  2. 제1항에 있어서, 2관능에폭시수지(A)가 비스페놀 A형 또는 비스페놀 F형의 에폭시 수지인 것을 특징으로 하는 에폭시 수지 조성물.
  3. 제1항에 있어서, 3관능에폭시수지(B)가 N,N,O-트리글리시딜-P-또는 m-아미노페놀, 1,1,1-(트리글리시딜 옥시페닐)메탄, N,N,O-트리글리시딜-4-아미노-m-5-또는-5-아미노-O-크레졸의 1종 또는 2종 이상의 혼합물인 것을 특징으로 하는 에폭시 수지 조성물.
  4. 제1항에 있어서, (C)성분으로 테트라브로모 비스페놀 A을 사용하는 것을 특징으로 하는 에폭시 수지 조성물.
  5. 제1항에 있어서, A/B의 에폭시기의 몰비가 1/0.1∼1/1.2, 바람직하게는 1/0.2∼1/1.0인 것을 특징으로 하는 에폭시 수지 조성물.
  6. 제1항에 있어서, (C)의 사용량은 (A)와 (B)의 에폭시기에 대한 (C)의 페놀성 OH기의 비가 1/0.1∼1/0.7인 것을 특징으로 하는 에폭시 수지 조성물.
  7. 제1항에 있어서,(D)의 사용량은 (A)와 (B)의 에폭시기의 몰수에서 (C)의 페놀성 OH기의 몰수를 뺀 몰수와 (D)의 NH기의 몰수의 비가 1/0.5∼1/1.2인 것을 특징으로 하는 에폭시 수지 조성물.
  8. 제1항에 있어서, (A)의 일부 또는 전부를 (B)의 준비와 혼합하여 이를 (C)의 전부와 예비 반응시키는데 적어도 (C)의 OH의 80%를 예비반응시켜 사용함을 특징으로 하는 에폭시 수지 조성물.
  9. 제8항에 있어서, 예비반응에 사용된 (A)/(B)의 에폭시기의 몰비는 1/0.2~1/1.4이고 (C)의 사용량은 (A)/(B)의 에폭시기의 총 몰수와 (C)의 페놀성 PH의 몰수의 몰비가 1/0.2∼1/1인 것을 특징으로 하는 에폭시 수지 조성물.
  10. 제1항에 있어서, (D)의 사용량은 (A)와 (B)의 에폭시기의 몰수에서 (C)의 페놀성 PH기의 몰수를 뺀 몰수와 (D)의 NH기의 몰수의 비가 1/0.5∼1/1.2인 것을 특징으로 하는 에폭시 수지 조성물.
  11. 하기 성분 (A),(B),(C),(D),(E)를 필수성분으로 함유하는 것을 특징으로 하는 에폭시 수지 조성물.
    (A) 2관능 에폭시 수지
    (B) 3관능 에폭시 수지
    (C) 하기식으로 대표되는 페놀 화합물
    (단, X1-X8은 Br, Cl 또는 H를 나타내고 X1-X8중 최소한 4개는 Br 또는 Cl 나타내며 R1및 R2는 H 또는 CH3이다.)
    (D) 4,4´-디아미노디페닐설폰 또는 3,3´-디아미노디페닐 설폰
    (E) 보강용 섬유
    ※ 참고사항 : 최초출원내용에 의하여 공개하는 것임.
KR1019900701341A 1988-11-30 1988-11-30 에폭시 수지 조성물 Expired - Lifetime KR940001169B1 (ko)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/JP1988/001212 WO1990006334A1 (fr) 1987-06-02 1988-11-30 Resine epoxyde

Publications (2)

Publication Number Publication Date
KR900701929A true KR900701929A (ko) 1990-12-05
KR940001169B1 KR940001169B1 (ko) 1994-02-16

Family

ID=13930912

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019900701341A Expired - Lifetime KR940001169B1 (ko) 1988-11-30 1988-11-30 에폭시 수지 조성물

Country Status (4)

Country Link
US (1) US5053475A (ko)
EP (1) EP0397860B1 (ko)
KR (1) KR940001169B1 (ko)
DE (1) DE3856311T2 (ko)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5593770A (en) * 1989-10-25 1997-01-14 Thiokol Corporation Chemorheologically tailored matrix resin formulations containing anhydride curing agents
US5545278A (en) * 1989-10-25 1996-08-13 Thiokol Corporation Method for increasing fiber strength translation in composition pressure vessels using matrix resin formulations containing anhydride curing agents and surface-active agents
EP0705856A2 (en) * 1994-10-07 1996-04-10 Shell Internationale Researchmaatschappij B.V. Epoxy resin composition for semiconductor encapsulation
GB201717639D0 (en) * 2017-10-26 2017-12-13 Cytec Ind Inc Resin compositions and resin infusion process

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57109829A (en) * 1980-12-26 1982-07-08 Asahi Chem Ind Co Ltd Manufacturing of prepreg
JPS58122927A (ja) * 1982-01-19 1983-07-21 Yuka Shell Epoxy Kk プリプレグの製造方法
US4588778A (en) * 1983-05-12 1986-05-13 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Toughening reinforced epoxy composites with brominated polymeric additives
US4550129A (en) * 1983-05-12 1985-10-29 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Toughening reinforced epoxy composites with brominated polymeric additives
JPS59217722A (ja) * 1983-05-26 1984-12-07 Toray Ind Inc 炭素繊維プリプレグ用エポキシ樹脂組成物
US4603157A (en) * 1984-05-23 1986-07-29 Mitsubishi Rayon Co., Ltd. Intermediate for composite material
JPS61148226A (ja) * 1984-12-21 1986-07-05 Toto Kasei Kk 塗料用及び積層板用固体状エポキシ樹脂
US4605710A (en) * 1985-04-05 1986-08-12 Minnesota Mining And Manufacturing Company High temperature wire coating powder
JPH0778138B2 (ja) * 1985-12-16 1995-08-23 東レ株式会社 繊維強化プリプレグ用樹脂組成物
US4663400A (en) * 1986-04-28 1987-05-05 The Dow Chemical Company Epoxy resins prepared from trisphenols and dicyclopentadiene
EP0249263A3 (en) * 1986-06-09 1990-07-11 Shell Internationale Researchmaatschappij B.V. Thermoplastic polymer composition having thermosetting processing characteristics
JPH0610249B2 (ja) * 1986-06-30 1994-02-09 三菱レイヨン株式会社 エポキシ樹脂組成物
JPH0655808B2 (ja) * 1988-01-29 1994-07-27 三菱レイヨン株式会社 エポキシ樹脂組成物

Also Published As

Publication number Publication date
US5053475A (en) 1991-10-01
DE3856311T2 (de) 1999-08-26
DE3856311D1 (de) 1999-04-08
EP0397860A1 (en) 1990-11-22
EP0397860A4 (en) 1991-09-11
EP0397860B1 (en) 1999-03-03
KR940001169B1 (ko) 1994-02-16

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