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KR900701885A - 높은 인장 강도를 지닌 중합체성 생성물의 제조방법 - Google Patents

높은 인장 강도를 지닌 중합체성 생성물의 제조방법

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Publication number
KR900701885A
KR900701885A KR1019900700293A KR900700293A KR900701885A KR 900701885 A KR900701885 A KR 900701885A KR 1019900700293 A KR1019900700293 A KR 1019900700293A KR 900700293 A KR900700293 A KR 900700293A KR 900701885 A KR900701885 A KR 900701885A
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South Korea
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polymeric material
group
groups
deposition polymerization
drawn
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KR1019900700293A
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KR940008988B1 (ko
Inventor
잔 페닝 알버트
반 드 웨르프 함
Original Assignee
티모씨 엔. 비숍
유니온 카바이드 코포레이션
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/025—Polyxylylenes
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/96—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from other synthetic polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/34—Monomer units or repeat units incorporating structural elements in the main chain incorporating partially-aromatic structural elements in the main chain
    • C08G2261/342—Monomer units or repeat units incorporating structural elements in the main chain incorporating partially-aromatic structural elements in the main chain containing only carbon atoms
    • C08G2261/3424—Monomer units or repeat units incorporating structural elements in the main chain incorporating partially-aromatic structural elements in the main chain containing only carbon atoms non-conjugated, e.g. paracyclophanes or xylenes

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Textile Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Artificial Filaments (AREA)
  • Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Inorganic Fibers (AREA)
  • Heating, Cooling, Or Curing Plastics Or The Like In General (AREA)

Abstract

내용 없음

Description

높은 인장 강도를 지닌 중합체성 생성물의 제조방법.
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도 및 제2도는 파단 인장 강도와 인취율 간의 관계, 및 영 모듈러스와 인취율 간의 관계를 나타낸다. 이들 도면은 인취율이 증가함에 따라 파단 인장 강도 및 영 모듈러스가 명백하게 증가함을 보여주고 있다.
최대 인취율은 43임이 발견되었으며 수득될 수 있는 기계적 특성의 최대 값은 파산 신장 강도 3.0Gpa, 영 모듈러스 102Gpa 및 파단 연신 3%이다. 제3도는 이러한 중합체에 대한 전형적인 응력-장력 곡선을 나타낸다.

Claims (11)

  1. 증기 침착 중합반응에 의해 파단 연장 강도의 이론치가 1OGpa이상인 화학적으로 비-가교-결합된 중합제성 물질을 형성시키고, 이 물질을 실질적으로 산소를 함유하지 않는 조건하에서 1O을 초과하는 인취율로 인취시킴을 특징으로 하여, 높은 인장 강도를 지닌 중합체성 생성물을 제조하는 방법.
  2. 제1항에 있어서, 중기 침착 중합 반응에 의해 형성된 중합체성 물질의 파단 인장 강도의 이론치가 15Gpa이상, 바람직하게는 2OGpa 이상임을 특징으로 하는 방법.
  3. 제1항에 있어서, 중기 침착 중합 반응에 의해 생성된 중합체성 물질이 일반식(I a) 및/ 또는 (Ⅱ a)(여기서, 벤젠환은 하나 이상의 할로겐 원자, C1-C6알킬 그룹, C2-7알카노일 그룹, C2-7알카노일옥시 그룹 및/ 또는 시아노 그룹으로 치환될 수 있다)의 단위를 함유하는 동중 중합체 또는 공중합체로 이루어짐을 특징으로 하는 방법.
  4. 제1항에 있어서, 중합체성 물질이 일반식(I b) 및/ 또는 (Ⅱ b)(여기서, 벤젠환은 하나 이상의 할로겐원자, C1-C6알킬 그룹, C2-7알카노일 그룹, C2-7알카노일옥시 그룹 및/ 또는 시아노 그룹으로 치환될 수 있다)의 이가 라디칼을 증기 침착중합 반응시킴으로씨 형성됨을 특징으로 하는 방법.
  5. 제3 또는 4항에 있어서, 중기가 일반식(1c) 및/ 또는 (Ⅱ b)(여기서, 벤젠환은 하나 이상의 할로겐원자, C1-C6알킬 그룹, C2-7알카노일 그룹, C2-7알카노일옥시 그룹 및/ 또는 시아노그룹으로 치환될 수 있다)의 이합체를 열분해함으로써 수득됨을 특징으로 하는 방법.
  6. 제1 내지 5항중 어느 한 항에 있어서, 중기 침착 중합 반응에 의해 형성된 물질이 평균 분자량이 104내지 l07, 바람직하게는 105내지 l06, 가장 바람직하게는 300,O0O 내지 800,OOO인 중합체로 이루어짐을 특징으로 하는 방법.
  7. 제1 내지 6항중 어느 한 항에 있어서, 중합체성물질이 인취율 2O 이상, 바람직하게는 3O 이상, 가장 바람직하게는 4O 이상으로 인취됨을 특징으로 하는 방법.
  8. 제1 내지 7항중 어느 한 항에 있어서, 중합체성물질이 질소 또는 이상기체와 같은, 불활성 기체 대기중에서 인취됨을 특징으로 하는 방법.
  9. 제1 내지 8항중 어느 한 항에 있어서, 중합체성물질이 중합체의 콘디스(condis) 결정 조건 범위내의 온도에서 인취됨을 특징으로 하는 방법.
  10. 제9항에 있어서, 중합체성 물질이 폴리(파라-크실렌)을 함유하며 231℃ 내지 중합체의 융점, 바람직하게는 287℃ 내지 융점 온도에서 인취됨을 특징으로 하는 방법.
  11. 제1 내지 1O항중 어느 한 항에 있어서, 청구한 방법을 사용하여 제조된, 바람직하게는 필름, 고체 섬유, 동공 섬유, 사(yarn) 또는 리본 형태의 중합체성 생성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900700293A 1988-06-15 1989-06-15 인장 강도가 높은 폴리(파라-크실릴렌)의 제조방법 Expired - Lifetime KR940008988B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
NL88-01524 1988-06-15
NL8801524A NL8801524A (nl) 1988-06-15 1988-06-15 Werkwijze voor het vervaardigen van polymere produkten met hoge treksterkte.
PCT/US1989/002557 WO1989012655A2 (en) 1988-06-15 1989-06-15 A process for making polymeric products of high tensile strength

Publications (2)

Publication Number Publication Date
KR900701885A true KR900701885A (ko) 1990-12-04
KR940008988B1 KR940008988B1 (ko) 1994-09-28

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KR1019900700293A Expired - Lifetime KR940008988B1 (ko) 1988-06-15 1989-06-15 인장 강도가 높은 폴리(파라-크실릴렌)의 제조방법

Country Status (8)

Country Link
EP (1) EP0349032A3 (ko)
JP (1) JPH03500062A (ko)
KR (1) KR940008988B1 (ko)
AU (1) AU4315489A (ko)
BR (1) BR8906969A (ko)
DK (1) DK38890A (ko)
NL (1) NL8801524A (ko)
WO (1) WO1989012655A2 (ko)

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US6825303B2 (en) 2001-02-26 2004-11-30 Dielectric Systems, Inc. Integration of low ε thin films and Ta into Cu dual damascene
US6797343B2 (en) 2001-12-20 2004-09-28 Dielectric Systems, Inc. Dielectric thin films from fluorinated precursors
US7192645B2 (en) 2001-02-26 2007-03-20 Dielectric Systems, Inc. Porous low E (<2.0) thin films by transport co-polymerization
US6703462B2 (en) * 2001-08-09 2004-03-09 Dielectric Systems Inc. Stabilized polymer film and its manufacture
US6881447B2 (en) 2002-04-04 2005-04-19 Dielectric Systems, Inc. Chemically and electrically stabilized polymer films
US7026052B2 (en) 2001-02-26 2006-04-11 Dielectric Systems, Inc. Porous low k(<2.0) thin film derived from homo-transport-polymerization
US6962871B2 (en) 2004-03-31 2005-11-08 Dielectric Systems, Inc. Composite polymer dielectric film
US7309395B2 (en) 2004-03-31 2007-12-18 Dielectric Systems, Inc. System for forming composite polymer dielectric film
US7094661B2 (en) 2004-03-31 2006-08-22 Dielectric Systems, Inc. Single and dual damascene techniques utilizing composite polymer dielectric film
US20160136914A1 (en) * 2014-07-29 2016-05-19 W. L. Gore & Associates, Inc. Porous Articles Formed From Polyparaxylylene and Processes For Forming The Same
US12280525B2 (en) * 2014-07-29 2025-04-22 W. L. Gore & Associates, Inc. Porous articles formed from polyparaxylylene and processes for forming the same
CN108699263B (zh) * 2016-01-27 2021-09-07 W.L.戈尔及同仁股份有限公司 由聚对二甲苯形成的多孔制品以及用于形成该制品的方法
EP4380350A4 (en) 2021-08-05 2025-10-29 Gore & Ass Composite materials that promote the capture and attachment of seaweed holdfasts

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US3509075A (en) * 1966-05-04 1970-04-28 Union Carbide Corp Polymerization process and product thereof

Also Published As

Publication number Publication date
BR8906969A (pt) 1990-12-11
JPH03500062A (ja) 1991-01-10
NL8801524A (nl) 1990-01-02
AU4315489A (en) 1990-01-12
KR940008988B1 (ko) 1994-09-28
DK38890D0 (da) 1990-02-14
EP0349032A2 (en) 1990-01-03
DK38890A (da) 1990-02-14
WO1989012655A3 (en) 1990-03-08
WO1989012655A2 (en) 1989-12-28
EP0349032A3 (en) 1990-04-18

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