KR900018203A - 3-하이드록시부티레이트 중합체 조성물 및 그 제조방법 - Google Patents
3-하이드록시부티레이트 중합체 조성물 및 그 제조방법 Download PDFInfo
- Publication number
- KR900018203A KR900018203A KR1019900007814A KR900007814A KR900018203A KR 900018203 A KR900018203 A KR 900018203A KR 1019900007814 A KR1019900007814 A KR 1019900007814A KR 900007814 A KR900007814 A KR 900007814A KR 900018203 A KR900018203 A KR 900018203A
- Authority
- KR
- South Korea
- Prior art keywords
- polymer
- organic
- ester
- component
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
- C08K5/5313—Phosphinic compounds, e.g. R2=P(:O)OR'
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
- C08K5/5317—Phosphonic compounds, e.g. R—P(:O)(OR')2
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyesters Or Polycarbonates (AREA)
- Biological Depolymerization Polymers (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
Abstract
Description
Claims (11)
- (a) HA 중합체(하이드록시알카노에이트 호모 또는 공중합체) (b)하기구조식;[식중, R은 유기기이다]을 갖는 유기포스폰 또는 유기포스핀산, 또는 그 에스테르, 또는 상기의 산 또는 에스테르의 유도체, 그리고 (c)주기율표 Ⅰ-Ⅴ족으로부터의 금속의 산화물, 수산화물 및 포화 또는 불포화 카복실산염으로 이루어지는 군으로부터 선택되는 금속 화합물로 구성되는 하이드록시알카노에이트 HA중합체 조성물.
- 제1항에 있어서, HA 중합체가 HB 중합체(3-하이드록시부티레이트 호모 또는 공중합체)인 조성물.
- 제1항에 있어서, HA 중합체가 하기의 구조식;[식중, X는 1-6의 정수이다]을 갖는 하이드록시알카노에이트 잔기를 포함하는 조성물.
- (a) HA 중합체(하이드록시알카노에이트 호모 또는 공중합체). (b) 하기의 구조식;[식중, R은 유기기이다]을 갖는 유기포스폰 또는 유기포스핀산, 또는 그 에스테르, 또는 상기의 산 또는 에스테르의 유도체, 그리고 (c)주기율표 Ⅰ-Ⅴ족으로부터의 금속의 산화물, 수산화물 및 포화 또는 불포화 카복실산염으로 이루어지는 군으로부터 선택되는 금속 화합물을 함께 철저히 혼합하는 것으로 구성되는 하이드록시알카노에이트 HA 중합체 조성물의 제조방법.
- 제4항에 있어서, 성분(b)가, R이 환식지방족기 또는 방향족기인 유기포스폰 또는 유기포스핀산, 또는 그 에스테르, 또는 상기의 산 또는 에스테르의 유도체인 조성물의 제조방법.
- 제5항에 있어서, R이 사이클로헥실기인 조성물의 제조방법.
- 제4항 내지 제6항중의 어느 한 항에 있어서, 성분(c)가 알루미늄, 안티몬, 주석, 소듐 또는 칼슘의 화합물인 조성물의 제조방법.
- 제4항 내지 제6항중의 어느 한 항에 있어서, 성분(c)가 마그네슘 또는 아연의 화합물인 조성물의 제조방법.
- 제4항 내지 제6항중의 어느 한 항에 있어서, 성분(c)가 스테아레이트 또는 팔미테이트인 조성물의 제조방법.
- 제8항에 있어서, 성분(c)가 스테아린산 아연, 스테아린산 마그네슘 또는 산화 아연인 조성물의 제조방법.
- 제4항 내지 제10항중의 어느 한 항에 있어서 성분(b)와 (c)가 성분(a)의 100부당 0.25-1.5부 범위로 함께 첨가되는 조성물의 제조방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB8912388.9 | 1989-05-30 | ||
| GB898912388A GB8912388D0 (en) | 1989-05-30 | 1989-05-30 | 3-hydroxybutyrate polymer composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR900018203A true KR900018203A (ko) | 1990-12-20 |
| KR0169967B1 KR0169967B1 (ko) | 1999-03-30 |
Family
ID=10657576
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019900007814A Expired - Fee Related KR0169967B1 (ko) | 1989-05-30 | 1990-05-30 | 3-하이드록시부티레이트 중합체 조성물 및 그 제조방법 |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US5061743A (ko) |
| EP (1) | EP0400855B1 (ko) |
| JP (1) | JP2888924B2 (ko) |
| KR (1) | KR0169967B1 (ko) |
| AT (1) | ATE124067T1 (ko) |
| CA (1) | CA2017885C (ko) |
| DE (1) | DE69020242T2 (ko) |
| DK (1) | DK0400855T3 (ko) |
| ES (1) | ES2073526T3 (ko) |
| GB (2) | GB8912388D0 (ko) |
| IN (1) | IN177061B (ko) |
| MW (1) | MW4690A1 (ko) |
| ZA (1) | ZA904073B (ko) |
| ZW (1) | ZW8390A1 (ko) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ATA258390A (de) * | 1990-12-19 | 1997-08-15 | Danubia Petrochem Polymere | Mischung aus vorwiegend einem polyhydroxyalkanoat und einer verbindung, die mindestens zwei reaktive gruppen wie säure- und/oder alkoholgruppen enthält und ein durch schmelzen der mischung hergestelltes polymerisat |
| DE4102170A1 (de) * | 1991-01-25 | 1992-08-06 | Danubia Petrochem Deutschland | Mischung aus vorwiegend einem polyhydroxyalkanoat und einer verbindung, die mindestens zwei reaktive gruppen wie saeure- und/oder alkoholgruppen enthaelt und ein durch schmelzen der mischung hergestelltes polymerisat |
| JP3243334B2 (ja) * | 1993-06-10 | 2002-01-07 | テルモ株式会社 | ヒドロキシアルカノエート重合体組成物 |
| WO1995010577A1 (en) | 1993-10-15 | 1995-04-20 | H.B. Fuller Licensing & Financing Inc. | Biodegradable/compostable hot melt adhesives comprising polyester of lactic acid |
| ZA95627B (en) * | 1994-01-28 | 1995-10-05 | Procter & Gamble | Biodegradable copolymers and plastic articles comprising biodegradable copolymers |
| SG49096A1 (en) * | 1994-01-28 | 1998-05-18 | Procter & Gamble | Biodegradable 3-polyhydtoxybuyrate/3- polyhydroxyhexanoate copolymer films |
| ID23491A (id) * | 1994-01-28 | 1995-09-07 | Procter & Gamble | Kopolimer-kopolimer yang dapat dibiodegradasi dan baha-bahan plastik yang terdiri dari kopolimer-kopolimer yang dapat dibiodegradasi |
| RU2144047C1 (ru) * | 1994-01-28 | 2000-01-10 | Дзе Проктер Энд Гэмбл Компани | Биоразлагаемые сополимеры, пластмассовые и впитывающие изделия, содержащие биоразлагаемые сополимеры |
| US6143947A (en) * | 1996-01-29 | 2000-11-07 | The Procter & Gamble Company | Fibers, nonwoven fabrics and absorbent articles comprising a biodegradable polyhydroxyalkanoate comprising 3-hydroxybutyrate and 3-hydroxyhexanoate |
| EP0996671B1 (en) * | 1997-07-25 | 2004-12-01 | Metabolix, Inc. | Nucleating agents for polyhydroxyalkanoates and other thermoplastic polyesters and methods for their production and use |
| EP0996670B1 (en) * | 1997-07-25 | 2006-05-31 | Metabolix, Inc. | Pha compositions and methods for their use in the production of pha films |
| US6025028A (en) * | 1997-07-25 | 2000-02-15 | Monsanto Company | Polyhydroxyalkanoate coatings |
| US6127512A (en) * | 1997-10-31 | 2000-10-03 | Monsanto Company | Plasticized polyhydroxyalkanoate compositions and methods for their use in the production of shaped polymeric articles |
| KR100545524B1 (ko) * | 2000-12-21 | 2006-01-24 | 더 프록터 앤드 갬블 캄파니 | 개선된 결정화 성질을 갖는 생분해성폴리히드록시알카노에이트 공중합체의 제조방법 |
| CA2428507C (en) * | 2000-12-21 | 2008-10-07 | The Procter & Gamble Company | Biodegradable polyhydroxyalkanoate copolymers having improved crystallization properties |
| WO2003057781A1 (en) * | 2001-12-28 | 2003-07-17 | Asahi Denka Co., Ltd. | Polylactic acid-based resin compositions, molded articles and process for producing the same |
| DE60316669T2 (de) * | 2002-02-15 | 2008-07-17 | Nippon Soda Co. Ltd. | Mit säure abbaubare harzzusammensetzungen mit ketenaldehyd-copolymer |
| US6774158B2 (en) * | 2002-03-20 | 2004-08-10 | E. I. Du Pont De Nemours And Company | Processing of polyhydroxyalkanoates using a nucleant and a plasticizer |
| US7091262B2 (en) * | 2003-08-01 | 2006-08-15 | Millennium Inorganic Chemicals, Inc. | Particulate inorganic solids treated with organophosphinic compounds |
| EP1693416B1 (en) * | 2003-12-02 | 2010-10-20 | Kaneka Corporation | Poly(3-hydroxyalkanoate) composition and molded object thereof |
| JP4597839B2 (ja) * | 2005-11-04 | 2010-12-15 | 株式会社リコー | 画像形成用トナーの製造方法 |
| TW201042103A (en) | 2008-12-23 | 2010-12-01 | Metabolix Inc | Production of non-woven materials from polyhydroxyalkanoate |
| TWI631163B (zh) * | 2011-09-30 | 2018-08-01 | 日產化學工業股份有限公司 | 聚(3-羥基烷酸酯)樹脂組成物 |
| WO2013176734A1 (en) | 2012-05-21 | 2013-11-28 | Tepha, Inc. | Resorbable bioceramic compositions of poly-4-hydroxybutyrate and copolymers |
| CN115698399B (zh) | 2020-06-02 | 2024-11-29 | 三菱瓦斯化学株式会社 | 高分子成型物的制造方法 |
| EP4159901A4 (en) | 2020-06-02 | 2024-12-04 | Mitsubishi Gas Chemical Company, Inc. | METHOD FOR PRODUCING A POLYMER MOLDED PRODUCT WITH PRETREATMENT BY HEATING |
| US20230272158A1 (en) * | 2020-07-07 | 2023-08-31 | Newlight Technologies, Inc. | Polyhydroxyalkanoate-based compositions and articles made therefrom |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL6606664A (ko) * | 1966-05-16 | 1967-11-17 | ||
| US3594347A (en) * | 1968-09-05 | 1971-07-20 | Allied Chem | Polyesters containing aryl phosphinates |
| DE2252210A1 (de) * | 1972-10-25 | 1974-05-09 | Hoechst Ag | Schwerentflammbare thermoplastische polyester |
| GB1465046A (en) * | 1973-05-14 | 1977-02-16 | Ici Ltd | Polyamide composition |
| IE39220B1 (en) * | 1973-05-14 | 1978-08-30 | Ici Ltd | Improved polyamide compositions |
| US4038258A (en) * | 1975-09-17 | 1977-07-26 | E. I. Du Pont De Nemours And Company | Antistatic composition containing an aliphatic polyester or polyether ester and a phosphonium salt |
| US4180495A (en) * | 1978-04-13 | 1979-12-25 | Pennwalt Corporation | Polyester resins flame retarded by poly(metal phosphinate)s |
| US4701518A (en) * | 1986-05-08 | 1987-10-20 | Monsanto Company | Antimicrobial nylon prepared in water with zinc compound and phosphorus compound |
| US4900299A (en) * | 1987-05-11 | 1990-02-13 | Mcneil-Ppc, Inc. | Biodegradable tampon application comprising poly(3-hydroxybutyric acid) |
-
1989
- 1989-05-30 GB GB898912388A patent/GB8912388D0/en active Pending
-
1990
- 1990-05-21 DK DK90305502.8T patent/DK0400855T3/da active
- 1990-05-21 EP EP90305502A patent/EP0400855B1/en not_active Expired - Lifetime
- 1990-05-21 GB GB909011349A patent/GB9011349D0/en active Pending
- 1990-05-21 ES ES90305502T patent/ES2073526T3/es not_active Expired - Lifetime
- 1990-05-21 DE DE69020242T patent/DE69020242T2/de not_active Expired - Lifetime
- 1990-05-21 AT AT90305502T patent/ATE124067T1/de not_active IP Right Cessation
- 1990-05-25 IN IN507DE1990 patent/IN177061B/en unknown
- 1990-05-28 ZA ZA904073A patent/ZA904073B/xx unknown
- 1990-05-28 ZW ZW83/90A patent/ZW8390A1/xx unknown
- 1990-05-30 KR KR1019900007814A patent/KR0169967B1/ko not_active Expired - Fee Related
- 1990-05-30 CA CA002017885A patent/CA2017885C/en not_active Expired - Lifetime
- 1990-05-30 US US07/530,560 patent/US5061743A/en not_active Expired - Lifetime
- 1990-05-30 JP JP2141247A patent/JP2888924B2/ja not_active Expired - Lifetime
- 1990-05-30 MW MW46/90A patent/MW4690A1/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE69020242T2 (de) | 1995-11-02 |
| ES2073526T3 (es) | 1995-08-16 |
| EP0400855B1 (en) | 1995-06-21 |
| JPH0324151A (ja) | 1991-02-01 |
| MW4690A1 (en) | 1991-02-13 |
| GB9011349D0 (en) | 1990-07-11 |
| CA2017885C (en) | 2000-11-21 |
| ATE124067T1 (de) | 1995-07-15 |
| GB8912388D0 (en) | 1989-07-12 |
| IN177061B (ko) | 1996-10-26 |
| EP0400855A1 (en) | 1990-12-05 |
| JP2888924B2 (ja) | 1999-05-10 |
| KR0169967B1 (ko) | 1999-03-30 |
| DK0400855T3 (da) | 1995-08-14 |
| ZA904073B (en) | 1991-02-27 |
| US5061743A (en) | 1991-10-29 |
| ZW8390A1 (en) | 1991-02-27 |
| DE69020242D1 (de) | 1995-07-27 |
| CA2017885A1 (en) | 1990-11-30 |
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